污水-海水混合过程中磷转移的动力学   总被引：5，自引：0，他引：5       下载免费PDF全文

陈松  林汝健  廖文卓 《海洋与湖沼》1993,24(1):59-64

模拟研究厦门市污水排海时污水-海水混合过程中磷含量和形态的变化,及其在海水-颗粒物界面交换的动力学过程;提供转移模式,确定转移速率,进行磷的容量校正,为厦门西海域环境容量估算和水质控制提供定量参数和理论依据。  相似文献   

天然水体中酚的降解动力学     

吴欣然  夏福兴  吴玲  陈邦林 《海洋科学》1992,16(1):33-37

本文报道了天然水体中低浓度酚的降解动力学;计算了它的降解速率常数、降解活化能等。降解半表期是t_(1/2)=1.5d~(-1)(10℃),t_(1/2)=O.74d~(-1)(30℃)。低浓度酚的降解动力学跟天然水体中酚的降解情况比较接近。本文的结果对环境评价、蓄水库工程设计等很有参考价值。  相似文献   

On the relevance of iron adsorption to container materials in small-volume experiments on iron marine chemistry: Fe-aided assessment of capacity, affinity and kinetics     

A.C. Fischer  J.J. Kroon  T.G. Verburg  T. Teunissen  H.Th. Wolterbeek 《Marine Chemistry》2007,107(4):533-546

Iron chemistry in seawater has been extensively studied in the laboratory, mostly in small-volume sample bottles. However, little has been reported about iron wall sorption in these bottles. In this paper, radio-iron ⁵⁵Fe was used to assess iron wall adsorption, both in terms of capacity, affinity and kinetics. Various bottle materials were tested. Iron sorption increased from polyethylene/polycarbonate to polymethylmetacrylate (PMMA)/high-density polyethylene/polytetrafluoroethylene to glass/quartz, reaching equilibrium in a 25–70 h period. PMMA was studied in more detail: ferric iron (Fe(III)) adsorbed on the walls of the bottles, whereas ferrous iron (Fe(II)) did not. Considering that in seawater the inorganic iron pool mostly consists of ferric iron, the wall will be a factor that needs to be considered in bottle experiments.The present data indicate that for PMMA with specific surface (S)-to-volume (V) ratio S/V, both iron capacity (42 ± 16 × 10^− 9 mol/m² or 1.7 × 10^− 9 mol/L recalculated for the S/V-specific PMMA bottles used) and affinity (log K_Fe'W = 11.0 ± 0.3 m²/mol or 12.4 ± 0.3 L/mol, recalculated for the S/V-specific PMMA bottles used) are of similar magnitude as the iron capacity and -affinity of the natural ligands in the presently used seawater and thus cannot be ignored.Calculation of rate constants for association and dissociation of both Fe'L (iron bound to natural occurring organic ligands) and Fe'W (iron adsorbed on the wall of vessels) suggests that the two iron complexes are also of rather similar kinetics, with rate constants for dissociation in the order of 10 ⁻⁴–10^− 5 L/s and rate constants for association in the order of 10⁸ L/(mol s). This makes that iron wall sorption should be seriously considered in small-volume experiments, both in assessments of shorter-term dynamics and in end-point observations in equilibrium conditions. Therefore, the present data strongly advocate making use of iron mass balances throughout in experiments in smaller volume set-ups on marine iron (bio) chemistry.  相似文献   

封闭体系有机质与有机碳氢氮恢复动力学研究   总被引：3，自引：0，他引：3  

彭平安  秦艳  张辉  刘大永  张善文  隋风贵  李钜源  李政 《海相油气地质》2008,13(2):27-36

在封闭体系的条件下,对典型的Ⅰ、Ⅱ、Ⅲ型干酪根在热演化过程中的损失进行生烃动力学研究,获得了Ⅰ、Ⅱ、Ⅲ型干酪根的总量、有机碳、氢以及氮质量损失动力学参数。用Kinetics软件计算了封闭体系干酪根有机碳丰度、氢碳原子比和氮碳原子比的恢复系数。认为在对高成熟—过成熟干酪根进行生烃评价时,Ⅰ、Ⅲ型干酪根残余有机碳丰度需要进行恢复,而Ⅱ型干酪根残余有机碳丰度不需要恢复。三种类型干酪根的氢碳原子比均需要进行恢复。  相似文献   

库车坳陷侏罗系煤成气动力学模拟研究   总被引：1，自引：0，他引：1  

周强  李贤庆  杨园园  田辉  申家贵 《中国煤田地质》2006,18(1):24-27

应用黄金管—高压釜封闭体系热模拟实验与GC、GC-IRMS分析技术,结合KINETICS专用软件,对库车坳陷侏罗系煤成气进行了动力学模拟研究。库车坳陷侏罗系煤具有高的产气性,在高演化阶段主要产甲烷气;侏罗系煤热解气甲烷碳同位素为-36‰～-25‰,乙烷碳同位素为-28‰～-16‰;甲烷、C2-C5气态烃的生成活化能分别为(47～64k)calm/ol、(55～72k)calm/ol,频率因子各为5.265×1013s-1、5.388×1018s-1。在此基础上,进一步探讨了克拉2气田天然气的成因。研究认为,克拉2气田天然气属阶段捕获的煤成气,主要聚集了5～1Ma时期的天然气,其成熟度Ro分布范围为1.3%～2.5%。  相似文献   

环境中Al13的研究进展     

刘璟  赵峰华  刘建权 《地球科学进展》2007,22(3):305-312

铝的水解反应及其水解聚合铝形态的研究，特别是具有Keggin结构的Al13聚合形态一直是地球化学、环境科学、形态分析以及生物毒理学等众多领域的研究热点之一。综述了近20年来Al13的分析方法、形成和转化机制、影响因素以及动力学方面研究的进展。  相似文献   

Investigation of NaCl deliquescence in porous substrates using RH-XRD     

Kirsten Linnow  Herbert Juling  Michael Steiger 《Environmental Geology》2007,52(2):317-327

We report on the use of X-ray diffractometry under controlled conditions of temperature and relative humidity (RH-XRD) for the investigation of NaCl deliquescence in the pore space of glass filter frits, which were used as model substrates. The study confirms that RH-XRD is an appropriate experimental technique for the in situ observation of phase transformation in porous materials. It is used for an investigation of both the deliquescence kinetics and the deliquescence humidity within pores of different median pore diameter. Several major influences affecting deliquescence rates in the pore space close to the surface of a porous material are discussed. It appears that quite short-term variation of ambient relative humidity, e.g., typical daily fluctuations, might induce damaging deliquescence–crystallization cycles within the pore space of building materials. In agreement with theoretical considerations it was found that confinement of NaCl crystals in pores with median diameters in the range 1.4–70 μm does not affect the deliquescence humidity of the salt.  相似文献   

Inhibition Concentration of Phenolic Substances under Different Cultivation Conditions. Part I: Phenol Oxidation by Mixed Microbial Population in a Model System     

J. Pca  G. G. S. Martius 《洁净——土壤、空气、水》1996,24(3):127-131

The effects of oxygen supply rate and the presence or absence of nutrients on the kinetics of phenol degradation and oxygen consumption by a mixed microbial population were tested in a model system. The values for the maximum specific rate of phenol degradation (q_Smax), the saturation constant (K_S), and the inhibition concentration (S_CR) were determined for unlimited growth (K_La = 340 h^?1, growth medium) with 1.7 mmol g^?1 h^?1, 65 mg L^?1, and 190 mg L^?1. Under limitation conditions, alterations occur depending on the type of limitation. Nutrient limitations lead to values of 0.8 mmol g^?1 h^?1, 45 mg L^?1, and 160 mg L^?1, and oxygen limitations lead to 1.2 mmol g^?1 h^?1. 30 mg L^?1, and 120 mg L^?1, respectively. The results suggest that with excess oxygen, the rate of phenol degradation was higher and the inhibition effect of phenol was suppressed to some extent. Under the same high oxygen supply rate, the presence of nutrients in the model water significantly supported the phenol degradation rate.  相似文献   

南海北部神狐区域 SH2 站位甲烷水合物成藏动力学模拟研究     

关进安  梁德青  万丽华  谷任国 《工程地质学报》2014,22(5):997-1002

南海北部神狐区域海底的高丰度水合物储层与生物成因为主的甲烷气源表明该区域很可能是一种特殊的复合型海洋水合物系统,其成藏动力学机制有待进一步的研究和澄清。建立了一个耦合沉积层地质属性-流体流动过程-水合物反应动力学的传输-反应模型,区别了两种不同类型的水合物形成(分解)动力学过程:(1)在通常情况下溶解甲烷和游离气共同形成水合物,(2)特殊情况下游离气直接生成水合物,结果表明在神狐海域热力学环境下游离气形成水合物速度比溶解甲烷快约4倍,气体含量和动力学常数比值越大生成水合物越快,而对比水合物分布的模拟结果与实测数据表明该区域水合物储层聚集和产状很可能受到了其他地质活动的影响。  相似文献   

A shrinking particle—shrinking core model for leaching of a zinc ore containing silica     

Vida Safari  Gilnaz Arzpeyma  Fereshteh Rashchi  Navid Mostoufi   《International Journal of Mineral Processing》2009,93(1):79-83

A new mathematical model was developed for leaching of zinc ores containing silicates such as hemimorphite which produce a gel during leaching with sulfuric acid. This model is based on the shrinking core model in which the particle size and the reacting core shrink simultaneously. It was shown that the actual dissolution time of the ore particles is longer than the time corresponding to the dissolution of chemical zinc oxide itself. It was suggested that because of the existence of silicates in the ore, a gelatinous layer was formed around the reacting core. Since the gel product is soft, it breaks apart when the particles collide and as a result, the particles shrink. However, a thin gelatinous layer always covers the reacting core which increases the mass transfer resistance and increases the leaching time. This model was applied to leaching of a zinc-rich tailing containing hemimorphite and the thickness of the gelatinous layer as well as the diffusion coefficient in this layer was determined.  相似文献