An Investigation of Digestion Methods for Trace Elements in Bauxite and Their Determination in Ten Bauxite Reference Materials Using Inductively Coupled Plasma‐Mass Spectrometry          下载免费PDF全文

Wen Zhang  Liang Qi  Zhaochu Hu  Cunjiang Zheng  Yongsheng Liu  Haihong Chen  Shan Gao  Shenghong Hu 《Geostandards and Geoanalytical Research》2016,40(2):195-216

Trace elements from samples of bauxite deposits can provide useful information relevant to the exploration of the ore‐forming process. Sample digestion is a fundamental and critical stage in the process of geochemical analysis, which enables the acquisition of accurate trace element data by ICP‐MS. However, the conventional bomb digestion method with HF/HNO₃ results in a significant loss of rare earth elements (REEs) due to the formation of insoluble AlF₃ precipitates during the digestion of bauxite samples. In this study, the digestion capability of the following methods was investigated: (a) ‘Mg‐addition’ bomb digestion, (b) NH₄HF₂ open vessel digestion and (c) NH₄F open vessel digestion. ‘Mg‐addition’ bomb digestion can effectively suppress the formation of AlF₃ and simultaneously ensure the complete decomposition of resistant minerals in bauxite samples. The addition of MgO to the bauxite samples resulted in (Mg + Ca)/Al ratios ≥ 1. However, adding a large amount of MgO leads to significant blank contamination for some transition elements (V, Cr, Ni and Zn). The NH₄HF₂ or NH₄F open vessel digestion methods can also completely digest resistant minerals in bauxite samples in a short period of time (5 hr). Unlike conventional bomb digestion with HF/HNO₃, the white precipitates and the semi‐transparent gels present in the NH₄HF₂ and NH₄F digestion methods could be efficiently dissolved by evaporation with HClO₄. Based on these three optimised digestion methods, thirty‐seven trace elements including REEs in ten bauxite reference materials (RMs) were determined by ICP‐MS. The data obtained showed excellent inter‐method reproducibility (agreement within 5% for REEs). The relative standard deviation (% RSD) for most elements was < 6%. The concentrations of trace elements in the ten bauxite RMs showed agreement with the limited certified (Li, V, Cr, Cu, Zn, Ga, Sr, Zr and Pb) and information values (Co, Ba, Ce and Hf) available. New trace element data for the ten RMs are provided, some of which for the first time.  相似文献   

Application of objective analysis to metallic traces in the atmospheric aerosol     

Christophe Migon  Bernard Gentili 《Journal of Atmospheric Chemistry》1993,16(3):277-284

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关于南国冰臼群成因的商榷之二   总被引：7，自引：1，他引：7  

韩同林  劳雄  郭克毅 《热带地理》2001,21(2):189-194,F003

南国冰臼群分布区大量冰川堆积、冰川条痕石及变形砾石的发现，再次有力地证明是“冰臼”不是“壶穴”的正确结论，由冰川漂砾经融冻作用形成的“石海”，与化学风化作用产生的花岗岩“石蛋”地貌特征，有天渊之别，不应混为一谈；边滩是由河流冲积物组成，不能与基岩冰床相提并论；圆滚水钻与急流旋涡及风蚀作用，形成的动力学性质、方向和方式完全不同，不该阴错阳差；节理、构造只影响冰臼的形态和发育程度，不是控制形成的动力学性质、方向和方式完全不同，不该阴错阳差；节理、构造只影响冰臼的形态和发育程度，不是控制冰臼的发育部位，不致于是非不辨，南国地区古冰川遗迹的大量发现，证明距今约二三百万年的第四纪早期确实曾发生过大规模的古冰川运动，为争论了半个多世纪的中国东部中低山区有无第四纪冰川问题，从此画上一个圆满的句号。  相似文献   

质疑粤西北的冰川遗迹   总被引：1，自引：1，他引：1  

刘尚仁  彭华 《热带地理》2001,21(2):183-188

从地貌、沉积物、第四纪地层关系、古气候、古环境等方面论证了广东封开-怀集-带所谓的冰川谷、冰蚀三角面、悬谷、角峰、刃脊、冰半、鼻山尾、冰碛砾石、蛇形丘以及近百万年来发生过3次冰期，是既不符合地学基础理论也不符合野外实际，所以是不确实的，那里没有第四纪冰川遗迹。  相似文献   

新疆沙尔湖煤田煤层特征及对比   总被引：1，自引：0，他引：1  

韦欣  王玲  许孝万 《中国煤炭地质》2010,(9):9-14

沙尔湖煤田含煤地层为中侏罗统西山窑组,根据岩性特征、含煤性以及其组合特征,将西山窑组分为上、中、下三段,可采煤层均分布在中段,煤层层数多,厚度变化较大,可采煤层6～27层,可采煤层总厚114.35～139.90m,根据各煤层之间的沉积间距及其与上、下岩层的旋回韵律,又将其划分为Ⅰ、Ⅱ、Ⅲ煤组。以大量地质资料为基础,总结了主要含煤层段的岩相组合特点,揭示了各煤层间的差异及组合特征,利用有效的对比方法,特别是数字测井在煤层对比中的应用,对可采煤层进行系统对比分析,对煤层对比的可靠性进行评价,保证了层位对比的正确可靠,并解决了勘查工作中终孔层位难以确定的问题,为正确划分煤系地层、准确估算煤炭资源量提供了可靠依据。  相似文献   

贵州刘家田井田测井曲线特征及在煤岩层对比中的应用     

伍远学 《中国煤炭地质》2014,(7):82-85

刘家田井田含煤地层龙潭组为海陆交互相沉积,含煤23~33层,可采煤层11层。含煤地层分上、中、下三段,上、中段视电阻率、自然伽马及伽马伽马曲线除了在煤层上呈异常反映外,其余地层测井曲线特征不明显;12、17号煤层视电阻率和伽马伽马曲线呈高幅值箱状反映,自然伽马曲线呈低幅值反映;视电阻率曲线在17号至24号煤层之间存在厚层高异常反映。下段自然伽马曲线有4~7处高幅值异常反映特征。在上、中、下段测井曲线特征对比基础上,利用标志层、煤组特征等对比法进行了煤层对比,大大提高了对比的可靠性。  相似文献   

基于最大特征值估计的C3算法及应用     

隋京坤  郑晓东  李艳东 《物探与化探》2014,(6)

第三代相干体算法(C3算法)具有分辨率高、压制噪声能力强的优点,但是该算法需要计算协方差矩阵的特征值,所以耗时较多。为提高大矩阵特征值分解的运算速度,提出了一种估计最大特征值的快速收敛算法,通过运用A2k矩阵的迹来构造一种收敛速度更快的特征值估计方法,并给出了这种方法的误差估计表达式,实现计算精度的有效控制。文中还讨论了地震数据体边缘补地震道方法,解决了将递推算法应用到平面方向时空间窗越过边界的问题。实例表明,本算法的计算效率明显高于常规的C3算法。  相似文献   

Determination of Ga,Ge, Mo,Ag, Cd,In, Sn,Sb, W,Tl and Bi in USGS Whole‐Rock Reference Materials by Standard Addition ICP‐MS          下载免费PDF全文

Richard M. Gaschnig  Roberta L. Rudnick  William F. McDonough 《Geostandards and Geoanalytical Research》2015,39(3):371-379

A procedure for determining a wide range of chalcophile and siderophile elements in typical crustal rocks using standard addition and ICP‐SFMS (inductively coupled plasma sector field mass spectrometry) is presented. New results for Ga, Ge, Mo, Ag, Cd, In, Sn, Sb, W, Tl and Bi abundances in USGS whole‐rock reference materials AGV‐2, BHVO‐1, BIR‐1, G‐2, GSP‐1 and W‐2 are reported using this analytical procedure. Intermediate precision of means based on multiple dissolved aliquots of each USGS reference material was 10% RSD or better for Ga, Ge, In and Sn in all, and similarly good for Ag, Cd, Sb, Tl and Bi in most reference materials. Poorer intermediate precision of Mo and W measurements in several reference materials is probably due to higher analytical blanks on these elements and powder heterogeneity due to a sulfide‐related nugget effect in the specific case of Mo in GSP‐1. Results for all elements fell within the range of available published data with the exception of Ag, which yielded systematically higher concentrations than found in the literature for five of the six reference materials, likely reflecting interference from unresolved polyatomic species.  相似文献   

Mass Fractions of S,Cu, Se,Mo, Ag,Cd, In,Te, Ba,Sm, W,Tl and Bi in Geological Reference Materials and Selected Carbonaceous Chondrites Determined by Isotope Dilution ICP‐MS          下载免费PDF全文

Zaicong Wang  Harry Becker  Frank Wombacher 《Geostandards and Geoanalytical Research》2015,39(2):185-208

Mass fractions of S, Cu, Se, Mo, Ag, Cd, In, Te, Ba, Sm, W and Tl were determined by isotope dilution sector field ICP‐MS in the same sample aliquot of reference materials using HF‐HNO₃ digestion in PFA beakers in pressure bombs and glassy carbon vessels in a high‐pressure asher (HPA‐S) for comparison. Additionally, Bi was determined by internal standardisation relative to Tl. Because isobaric and oxide interferences pose problems for many of these elements, efficient chromatographic separation methods in combination with an Aridus desolvator were employed to minimise interference effects. Repeated digestion and measurement of geological reference materials (BHVO‐1, BHVO‐2, SCo‐1, MAG‐1, MRG‐1 and UB‐N) gave results with < 5% relative intermediate precision (1s) for most elements, except Bi. Replicates of NIST SRM 612 glass digested on a hot plate were analysed by the same methods, and the results agree with reference values mostly within 2% relative deviation. Data for the carbonaceous chondrites Allende, Murchison, Orgueil and Ivuna are also reported. Digestion in a HPA‐S was as efficient as in pressure bombs, but some elements displayed higher blank levels following HPA‐S treatment. Pressure bomb digestion yielded precise data for volatile S, Se and Te, but may result in high blanks for W.  相似文献   

浅谈山东省地质遗迹及其保护          下载免费PDF全文

杨斌  刘书才  黄文院 《山东国土资源》2002,18(6):33-36

山东省地质遗迹资源丰富 ,种类繁多 ,可划分为地质剖面古生物化石产地类、溶洞 (群 )类、泉 (群 )瀑布类、异石名山奇峰类、海岛浴场湖泊类、火山 (口 )类、湿地类等 7大类。地质遗迹是地球发展演化过程中遗留下来的自然遗产 ,是极其珍贵的不可再生的自然资源。人们通过各种地质遗迹现象 ,可以追溯地质演化历史以及各地质历史时期的古地理、古气候、古生态环境状况。地质遗迹在科研、教学、科普教育和旅游观赏等方面具有极为重要的意义。地质遗迹保护应坚持积极保护与合理开发相结合 ,加强管理与宣传教育相结合 ,长期规划与短期安排相结合以及总体部署、分步实施的原则  相似文献