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Emission rates of biogenic volatile organic compounds emitted by the forests were estimated for five geographical regions as well as for all Switzerland. Monoterpene and isoprene emissions rates were calculated for each main tree species separately using the relevant parameters such as temperature, light intensity and leaf biomass density. Biogenic emissions from the forests were found to be about 23% of the total annual VOC emissions (anthropogenic and biogenic) in Switzerland. The highest emissions are in July and lowest in January. Calculations showed that the coniferous trees are the main sources of the biogenic emissions. The major contribution comes from the Norway spruce (picea abies) forests due to their abundance and high leaf biomass density. Although broad-leaved forests cover 27% of all the forests in Switzerland, their contribution to the biogenic emissions is only 3%. Monoterpenes are the main species emitted, whereas only 3% is released as isoprene. The highest emission rates of biogenic VOC are estimated to be in the region of the Alps which has the largest forest coverage in Switzerland and the major part of these forests consists of Norway spruce. The total annual biogenic VOC emission rate of 87 ktonnes y–1 coming from the forests is significantly higher than those from other studies where calculations were carried out by classifying the forests as deciduous and coniferous. The difference is attributed to the high leaf biomass densities of Norway spruce and fir (abies alba) trees which have a strong effect on the results when speciation of trees is taken into account. Besides the annual rate, emission rates were calculated for a specific period during July 4–6, 1991 when a photochemical smog episode was investigated in the Swiss field experiment POLLUMET. Emission rates estimated for that period agree well with those calculated for July using the average temperatures over the last 10 years. 相似文献
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Formation of Artefacts and its Suppression during the Determination of Volatile Halogenated Hydrocarbons in Water by Means of Headspace Gas Chromatography under the Standard Conditions of DIN 38407-F5. Part II: Increased Trihalomethane Formation in Chlorinated Swimming-pool Water A comparison of two analytical standard procedures for the determination of trihalomethanes (THM) in water (headspace gas chromatography and pentane extraction/gas chromatography) yielded strongly differing results. Under the conditions recommended by the German Standard Method DIN 38407-F5 (60…80°C for at least 60 min) degradation of thermo-labile chlorination products occurs resulting in elevated THM concentrations. The reactions involved are partly pH-dependant, and these can be suppressed by sample acidification. The degradation of trihalogen acetic acids, however, can only be influenced by minimizing the equilibration time and temperature. Other intermediate chlorination products (haloacetonitriles) are also degraded to THM after preceding hydrolysis to the corresponding carboxylic acids. Comparative results obtained with a purge and trap method at ambient temperature, i.e. without thermal stress during the enrichtment step, are lower than with static headspace GC but still high in comparison to the pentane extraction method. Presumably volatile THM-precursors are also trapped and subsequently decomposed upon thermal desorption from the trap. As the static headspace GC is the most rational method of LHKW determination available, the recommended experimental sample handling conditions should be modified in a way that deterioration reactions are reduced as far as possible. 相似文献
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Laboratory experiments under controlled environmental conditions are a useful tool to investigate the influence of different environmental parameters on VOC emissions from plants individually. Before using the obtained results to interpret measurements under ambient conditions, it has to be ensured that the laboratory system is suitable for performing emission rate measurements under ambient-like conditions to derive algorithms describing the emissions of volatile organic compounds as a function of physical variables like temperature and light intensity. Here we compare results from monoterpene emission rate measurements with Scots pines (Pinus sylvestris L.) under both ambient environmental conditions using a mobile plant enclosure chamber, and under controlled laboratory conditions in a continuously stirred tank reactor. The different analytical instruments to quantify monoterpene emissions were compared in an intercalibration experiment. Measurements of the mixing ratios of -pinene, -pinene, 3-carene, camphene, and limonene on the order of some hundred parts per trillion differed by less than 20%. The laboratory system has proven capable of providing ambient-like conditions and results of monoterpene emission rate measurements under laboratory conditions could be extrapolated to the natural environment. Monoterpene emission rate measurements with identical specimens of Scots pines conducted within small temporal differences under similar laboratory and outdoor conditions agreed well. Both laboratory and outdoor experiments clearly showed that distinct and constant values neither exist for the standard emission rates nor for the emission pattern of monoterpenes from Scots pine. Temporal variations in the standard emission rates from identical specimens and plant-to-plant variations were on the order of one magnitude. 相似文献
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Zeolites have been used for a long time for purification and catalytical purposes. Recently, first products appeared on the market using zeolites also for improving the indoor air quality so far volatile organic compounds (VOC) are concerned. However, porous compounds like zeolites can be found also in plaster material. Therefore, it was manifest to evaluate the capability of plaster with regard to air cleaning. In this article, the contribution of plaster compounds toward adsorption and catalytical decomposition of VOCs is evaluated using α‐pinene, chlorobenzene, 2‐ethoxyethylacetate, and pentanal as target substances under standard conditions (23°C, 50% r.H.). These compounds were chosen because of their VOC typical physicochemical properties like molecular dimensions, density, boiling point, vapor pressure, and octanol–water distribution coefficient (logkow). Hydrated lime and metakaolin were found out to have good adsorption properties under these circumstances. Also natural zeolites showed good results especially on pentanal. By investigations in environmental chambers the reduction potential of test plasters on chlorobenzene and 2‐ethoxyethylacetate concentrations could be shown. Application of coatings had no or only temporary influence on the performance of the plaster. Additional tests in small chambers demonstrated the possibility to improve the properties of plasters with help of FAU‐ or MFI‐type zeolites but the experiments also showed that α‐pinene and pentanal undergo chemical reactions. Further effort should be made on investigations also toward other compounds, especially more volatile ones like formaldehyde. Also additional building materials like insulation material or boards should be taken into account. 相似文献
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In this work, investigations dealing with the determination of hydrocarbons in contaminated soil water are presented. The hydrocarbons under investigation range from low to high volatility compounds. A GC‐FID method was developed that due to its efficiency, routine suitability, relative rapidity, and low cost is suitable for the analysis of complex chemical mixtures of highly volatile hydrocarbons (with boiling points between 69 and 190°C). The standard used was a gasoline mixture with boiling points ranging from 100 to 190°C. For this standard, no supplementary preparation is needed and it is suitable for the whole range of hydrocarbons under investigation. The determination of the hydrocarbon content of the samples was performed applying univariate and multivariate statistical analysis to the experimental data. In the characterization of a contamination with highly volatile hydrocarbons of soil water originating from different depth layers from the chemistry location Leuna (Sachsen‐Anhalt, Germany), the advantages of a multivariate method are demonstrated in exemplary manner. 相似文献
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O. Klemm W. R. Stockwell H. Schlager M. Krautstrunk 《Journal of Atmospheric Chemistry》2000,35(1):1-18
The ozone forming potential of VOCs and NOx for plumes observed from several cities and a power plant in eastern Germany was investigated. A closed box model with a gas phase photochemical reaction mechanism was employed to simulate several scenarios based upon aircraft observations. In several of the scenarios, the initial concentrations of NOx, VOCs, and SO2, were reduced to study the factors limiting the O3 production. Ozone production was limited by the initial VOC concentrations for all of the simulated plumes. Higher O3 concentrations were produced with reduced initial NOx. In one sample with high SO2 mixing ratios (>100 ppb), SO2 was also identified as a significant contributor to the production of O3. 相似文献
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利用Aura/OMI月均甲醛对流层垂直柱浓度数据对2005年—2016年中国广东省和江苏省的大气甲醛的时空变化规律、不同排放源的前体物的潜在贡献进行了分析。甲醛在广东省主要集中在珠三角地区,在江苏省分布则相对较为均匀。2005年—2010年,随着经济发展,在两省都发现了大面积的甲醛增加趋势;相应的,在2011年—2016年,由于减排等治理措施的实施,在两省都有大面积的甲醛减少现象。广东省的甲醛主要呈现出春季、秋季高于冬季再高于夏季的特征;而江苏地区夏季甲醛浓度远高于其他季节,并与光照强度的季节性特征较为一致。此外,由于广东省甲醛分布的均一性较差,因此区域性因素(如地形等)对广东省甲醛分布可能有着较大的影响。各个排放源中,工业源、交通源对珠三角潜在贡献可能较大;自然源对梅州等林地覆盖地区可能有相对较高的影响;在江苏省,各个排放源对甲醛的贡献相对均衡,但夏季较为频繁的生物质燃烧可能对夏季高值甲醛有着相对较高的贡献。 相似文献
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中南半岛近海偶极子结构是指在夏季与越南离岸流伴生的一对中尺度涡现象，其中气旋涡位于离岸流北侧，反气旋涡位于离岸流南侧，偶极子结构对于中南半岛近海水文要素具有重要影响。本文基于卫星高度计数据和HYCOM海洋模式的模拟结果，以2012年为例研究了该偶极子的演变过程，结果表明：偶极子结构7月出现，9月初鼎盛，10月消失；鼎盛时，两个涡旋直径均大于300km，在温跃层引起的最大位温异常可达±5℃。垂向结构上，反气旋涡呈中心对称，而气旋涡有非对称性，且影响深度大于反气旋涡。在200m以下，气旋涡有随深度增加向东倾斜的趋势，而反气旋涡有随深度增加向西偏移的趋势，但该趋势在200m层以上并不显著。对偶极子涡旋区域进行能量分析，结果表明偶极子能量主要来自于越南离岸流提供的正压和斜压能量，即越南离岸流区域是偶极子结构的主要能量源，局地风场对偶极子结构的维持也具有重要作用。能量既可以由离岸流输送给涡旋，也可以从涡旋向离岸流转化，但总体上是离岸流向涡旋提供能量。 相似文献