Evaluation of riverbed magnetic susceptibility for mapping biogeochemical hot spots in groundwater-impacted rivers     

Chen Wang  Martin A. Briggs  Frederick D. Day-Lewis  Lee D. Slater 《水文研究》2021,35(5):e14184

Redox hot spots occurring as metal-rich anoxic groundwater discharges through oxic wetland and river sediments commonly result in the formation of iron (Fe) oxide precipitates. These redox-sensitive precipitates influence the release of nutrients and metals to surface water and can act as ‘contaminant sponges’ by absorbing toxic compounds. We explore the feasibility of a non-invasive, high-resolution magnetic susceptibility (MS) technique to efficiently map the spatial variations of magnetic Fe oxide precipitates in the shallow bed of three rivers impacted by anoxic groundwater discharge. Laboratory analyses on Mashpee River (MA, USA) sediments demonstrate the sensitivity of MS to sediment Fe concentrations. Field surveys in the Mashpee and Quashnet rivers (MA, USA) reveal several discrete high MS zones, which are associated with likely anoxic groundwater discharge as evaluated by riverbed temperature, vertical head gradient, and groundwater chemistry measurements. In the East River (CO, USA), widespread cobbles/rocks exhibit high background MS from geological ferrimagnetic minerals, thereby obscuring the relatively small enhancement of MS from groundwater induced Fe oxide precipitates. Our study suggests that, in settings with low geological sources of magnetic minerals such as lowland rivers and wetlands, MS may serve as a complementary tool to temperature methods for efficiently mapping Fe oxide accumulation zones due to anoxic groundwater discharges that may function as biogeochemical hot spots and water quality control points in gaining systems.  相似文献   

基于噪声谱比法的内蒙古西部地区台站场地响应研究     

张珂  王鑫  王树波  张红才  宋晓燕 《大地测量与地球动力学》2020,40(6):646-651

利用内蒙古西部12个台站的地脉动噪声数据，采用噪声谱比法研究台站的场地响应情况。分析表明，台站场地响应按曲线形态可分为3类，且可能受地形地貌、局部构造和台基状况等条件影响。对比分析噪声谱比法与Moya方法的场地响应结果发现，场地响应曲线形态基本一致，只有极少数台站存在明显差异。结果表明，内蒙古西部区域大部分台站的台基状况总体较好，场地响应曲线较为平坦，无明显频率放大点。  相似文献   

伏牛山地区森林生态系统服务权衡/协同效应多尺度分析   总被引：3，自引：0，他引：3  

张静静  朱文博  朱连奇  李艳红 《地理学报》2020,75(5):975-988

森林生态系统服务权衡与协同研究已成为当前相关学科的研究热点和前沿,对服务权衡与协同关系的多尺度分析有助于更加有效地实施森林资源管理。综合森林类型图、NDVI、气象和土壤等多源数据,借助CASA模型、InVEST 3.2模型和ArcGIS 10.2软件,开展伏牛山地区森林生态系统服务评估,运用空间叠置方法从多个空间尺度（区域、南北坡、垂直带）探讨服务权衡与协同效应。结果表明：① 研究区森林生态系统平均蓄积量为49.26 m ³/hm ²,碳密度为156.94 t/hm ²,供水深度为494.46 mm,土壤保持量为955.4 t/hm ²,生境质量指数为0.79。② 区域尺度上,28.79%的森林服务之间存在高协同效应,10.15%的森林存在低协同效应,61.06%的森林存在强权衡和弱权衡效应。③ 南北坡尺度上,南坡服务之间的协同关系优于北坡。垂直带尺度上,南坡中山落叶阔叶林带（SIII）服务之间协同关系最好,北坡低山落叶阔叶林带（NI）协同关系最差。  相似文献   

Modeling spatially non-stationary land use/cover change in the lower Connecticut River Basin by combining geographically weighted logistic regression and the CA-Markov model   总被引：2，自引：0，他引：2  

Hui Wang  Scott R. Stephenson  Shijin Qu 《International journal of geographical information science》2019,33(7):1313-1334

Simulating land use/cover change (LUCC) and determining its transition rules have been a focus of research for several decades. Previous studies used ordinary logistic regression (OLR) to determine transition rules in cellular automata (CA) modeling of LUCC, which often neglected the spatially non-stationary relationships between driving factors and land use/cover categories. We use an integrated geographically weighted logistic regression (GWLR) CA-Markov method to simulate LUCC from 2001–2011 over 29 towns in the Connecticut River Basin. Results are compared with those obtained from the OLR-CA-Markov method, and the sensitivity of LUCC simulated by the GWLR-CA-Markov method to the spatial non-stationarity-based suitability map is investigated. Analysis of residuals indicates better goodness of fit in model calibration for geographically weighted regression (GWR) than OLR. Coefficients of driving factors indicate that GWLR outperforms OLR in depicting the local suitability of land use/cover categories. Kappa statistics of the simulated maps indicate high agreement with observed land use/cover for both OLR-CA-Markov and GWLR-CA-Markov methods. Similarity in simulation accuracy between the methods suggests that the sensitivity of simulated LUCC to suitability inputs is low with respect to spatial non-stationarity. Therefore, this study provides critical insight on the role of spatial non-stationarity throughout the process of LUCC simulation.  相似文献   

全二维气相色谱-电子捕获检测器测定复杂基质土壤中24种有机氯和拟除虫菊酯类农药     

时磊  孙艳艳  沈小明  吕爱娟  蔡小虎  刘娇  沈加林 《岩矿测试》2020,39(6):856-865

目前针对环境样品中有机氯和拟除虫菊酯类农药的检测方法主要有气相色谱法和气相色谱-质谱法（GC-MS），由于气相色谱法采用电子捕获检测器从而具有较高的灵敏度，在污染物的环境行为研究中得到广泛应用，GC-MS法的定性效果好，但检测灵敏度相对偏低。本文研究了2018年土壤详查江苏地区样品中有机氯农药和拟除虫菊酯的残留状况，结果显示，即使经过多次净化仍有20%的样品存在假阳性或基质干扰现象。为了提高定性准确度，同时保证检测灵敏度，实验建立了复杂基质土壤中20种有机氯农药和4种拟除虫菊酯的全二维气相色谱-电子捕获检测器检测方法，最终选择中等极性的TG-35MS为第一色谱柱，非极性的（DB-1）为第二色谱柱，将鲜样与无水硫酸钠混合均匀后，以正己烷-丙酮（1：1，V/V）为提取剂进行索氏提取，采用全二维气相色谱-电子捕获检测器进行检测，外标法定量。各物质的质量浓度均在1.0~500μg/L内与其峰面积呈线性关系，相关系数均大于0.995，检出限为0.02~0.17μg/kg。用标准加入法进行回收实验，测得回收率为80.7%~103.5%，测定值的相对标准偏差（n=6）为1.84%~10.12%。本方法将高灵敏度检测器与全二维色谱相结合，在保证检测灵敏度的同时增加了峰容量，有效去除了基质干扰。相比2018年土壤详查参考方法HJ 835—2017的检出限0.02~0.09mg/kg（全扫模式），本方法检出限显著降低，且操作简单，可为复杂基质样品中的痕量超痕量检测提供参考。  相似文献   

An efficient and robust approach to predict ship self-propulsion coefficients     

《Applied Ocean Research》2019

Achieving a reliable and accurate numerical prediction of the self-propulsion performance of a ship is still an open problem that poses some relevant issues. Several CFD methods, ranging from boundary element methods (BEM) to higher-fidelity viscous Reynolds averaged Navier–Stokes (RANS) based solvers, can be used to accurately analyze the separate problems, i.e. the open water propeller and the hull calm water resistance. However, when the fully-coupled self-propulsion problem is considered, i.e. the hull advancing at uniform speed propelled by its own propulsion system, several complexities rise up. Typical flow simplifications adopted to speed-up the simulations of the single analysis (hull and propeller separately) lose their validity requiring a more complex solver to tackle the fully-coupled problem. The complexity rises up further when considering a maneuver condition. This aspect increases the computational burden and, consequently, the required time which becomes prohibitive in a preliminary ship design stage.The majority of the simplified methods proposed in literature to include propeller effects, without directly solve the propeller flow, in a high-fidelity viscous solver are not able to provide all the commonly required self-propulsion coefficients. In this work, a new method to enrich the results from a body force based approach is proposed and investigated, with the aim to reduce as much as possible the computational burden without losing any useful result. This procedure is tested for validation on the KCS hull form in self-propulsion and maneuver conditions.  相似文献   

联合BDS/GPS的北斗广域差分实时电离层延迟格网改正方法研究     

房成贺  陈俊平  兰孝奇  张磊 《大地测量与地球动力学》2019,39(2):169-177

研究并实现中国区域北斗广域差分实时电离层延迟格网改正算法，针对北斗单系统实时建立电离层延迟格网的不足，提出联合BDS/GPS的北斗广域差分实时电离层延迟改正方法。比较BDS、GPS以及BDS/GPS观测的实时电离层延迟格网，并利用北斗单频单点伪距定位进行精度验证。结果表明，在有效格网点覆盖充足的地区，BDS与GPS实时电离层延迟格网定位效果相当；而联合BDS/GPS观测的实时电离层延迟格网极大提高了偏远地区的单频定位精度与可定位历元数，也使原本单系统格网覆盖充足的地区定位效果得到进一步增强和稳定。  相似文献   

小兴安岭-张广才岭铁力地区侏罗纪辉绿岩年代学、地球化学、锆石Hf同位素特征及其构造意义   总被引：1，自引：0，他引：1  

葛茂卉  张进江  刘恺 《岩石学报》2020,36(3):726-740

小兴安岭-张广才岭地区中生代岩浆活动的成因及动力学背景对于揭示古太平洋的构造演化具有重要意义。本文选取小兴安岭-张广才岭铁力地区出露的辉绿岩墙为研究对象,进行锆石LA-ICP-MS U-Pb年代学、全岩地球化学和锆石Hf同位素等分析,对该基性岩的形成时代、岩石成因、岩浆源区以及形成的大地构造背景进行讨论。研究表明:辉绿岩锆石具有高Th/U比值( 0.3),CL图像显示微弱的振荡环带结构,具有岩浆锆石特征,~(206)Pb/~(238)U加权平均年龄为187±2Ma,即形成于早侏罗世;该岩体主要经历了橄榄石和单斜辉石的分离结晶作用,未遭受明显的地壳混染作用,并且具有Rb、Ba、U、Pb、K和Sr等流体活动元素相对富集,Th、Nb和Ta等非流体活动性元素相对亏损的地球化学特征,暗示其形成于被俯冲流体富集交代的亏损地幔部分熔融,源区可能为尖晶石-石榴石二辉橄榄岩,部分熔融程度约为6%～20%。结合该地区同时代的岩浆岩、变形构造、矿床特征和黑龙江蓝片岩的相关报道,本文认为小兴安岭-张广才岭地区在中生代期间处于活动大陆边缘环境,其岩浆岩的形成主要是由于存在于佳木斯地块和松嫩-小兴安岭地块间的牡丹江洋西向俯冲造成的。  相似文献   

Geography Deserts: State and Regional Variation in the Formal Opportunity to Learn Geography in the United States, 2005–2015     

Mark C. Jones  Marcos Luna 《The Journal of geography》2019,118(2):88-100

The formal opportunity to learn geography in the United States is unevenly distributed across space, creating possible geography deserts. Data on the number of exams taken in Advanced Placement Human Geography (APHG) and bachelor’s degrees earned in geography are mapped at the state and regional scales. Normalized rates are ranked and grouped into quintiles. For APHG exams, states in the southeastern region of the United States are in the uppermost quintiles while states in the northeastern region are in the lowermost quintiles. The pattern for bachelor’s degrees in geography is somewhat the spatial inverse of that for APHG.  相似文献   

GPS/PWV时间序列特征提取方法的研究     

胡广保  叶世榕  张彦祥  夏朋飞  夏凤雨 《大地测量与地球动力学》2019,39(1):36-40

针对GAMIT/GLOBK软件解算得到的4 a GPS/PWV时间序列的特征提取问题，提出基于滤波辅助的部分集成经验模态分解（PEEMD）与Hilbert谱分析相结合的特征提取方法。首先，在PEEMD方法的基础上,结合滤波辅助的PEEMD方法与Hilbert谱分析，建立GPS/PWV时间序列特征提取模型；然后，将所提出的方法应用于TNML测站4 a的GPS/PWV长时间序列和7 d的GPS/PWV短时间序列分析中，并将滤波辅助的PEEMD结果与传统的小波分解结果进行对比。结果表明，该特征提取方法能准确有效地提取出 GPS/PWV时间序列中的周年周期和日周期特征分量，滤波辅助的PEEMD分解结果与小波分解结果一致，且提取的特征分量与原始信号更加吻合。  相似文献