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1.
Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff 下载免费PDF全文
We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AICC] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component. 相似文献
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The distribution of dissolved and participate concentrations of As, Cr and V was investigated in the mixing area of the Po river in five surveys over the period March 1992-March 1995. The data obtained indicate noticeable contamination of coastal waters of the northern Adriatic with Cr but not As or V. Total dissolved concentrations for As and V were comparable with oceanic levels but were higher by a factor of 4 for Cr. These results suggest either low anthropogenic inputs of As and V, from terrigenous and atmospheric sources, or efficient removal mechanisms. The investigated metals had low reactivity during freshwater-seawater mixing and the distribution of concentrations in the dissolved and solid phases suggests that the dilution process is the main factor controlling the transport of these metals to the sea in low-to-medium solid transport conditions. Further investigations are required to elucidate the behavior of these metals during high solid transport conditions. Significant changes in the speciation of As occurred during the transition between the two end-member matrices. In the coastal waters of the northern Adriatic, the arsenite fraction in winter, and the arsenite and dimethylarsinate fractions in summer increased with respect to riverine waters. Changes in the speciation of chromium were minor, but also showed a small increase in reduced species in marine waters. 相似文献
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北达巴特斑岩铜钼矿产于华力西期流纹斑岩中,矿体呈脉状,铜矿体地表为氧化物,钼矿体主要赋存于深部的流纹斑岩中,其矿化作用呈上铜下钼的双层矿化结构模式,矿化为细脉浸染状。矿床的成因类型为斑岩型铜钼矿。 相似文献
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三峡库区高切坡致灾因素及防护对策——以重庆市万州区为例 总被引:1,自引:0,他引:1
三峡库区百万移民的搬迁建设导致大量高切坡的形成。未及时治理或治理不当的高切坡,不同程度地发生破坏,影响了人们的正常生活,甚至引发了地质灾害。因此,科学认识及治理高切坡十分必要。重庆市万州区高切坡主要有风化及差异风化、崩塌和土体滑塌等破坏形式。影响破坏的因素主要为工程地质条件、气候及时间效应。针对高切坡不同的破坏形式,以安全、经济及环境和谐的人文理念作为设计指导思想,充分论证了高切坡的防护方案,即:削坡、排水以及格构防护较适合万州区高切坡的防护。这些措施,既能很好地解决高切坡的防护问题,又能兼顾环保、降低造价。研究结果可以作为三峡地区高切坡类地质灾害防护设计的参考。也可为其它流域类似问题借鉴。 相似文献
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含盐量对松嫩平原碳酸盐渍土抗剪强度的影响 总被引:2,自引:0,他引:2
松嫩平原分布着大量的碳酸盐渍土,其不良的工程性质给穿越其中的道路质量造成不同程度的影响。由于盐渍土所含易溶盐成分主要为碳酸氢钠,该研究通过向碳酸盐渍土内加入碳酸氢钠制备不同含盐量的盐渍土,进行室内直剪试验。试验表明:随着含盐量的增加土的粘聚力减小,内摩擦角有先减小后变大的趋势;随着含水量的增加,土的含盐量越高,土的粘聚力减小越明显。易溶盐在土中的状态形式是影响其抗剪强度参数变化的一个重要原因。 相似文献
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GM(1,1)动态模型在吴江市地下水水位预测中的应用 总被引:1,自引:0,他引:1
以吴江市地下水水位预测为例,详细阐述了地下水水位时间序列的GM(1,1)动态模型的原理和建立过程,并根据模型的预测值和实测值,对模型的精度进行了检验,结果表明,模型的预测精度达到了99.27%,等级属于Ⅰ级,具有实际的应用价值,为地下水资源的科学管理提供了依据。 相似文献
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地下连续墙治理地下水污染 总被引:12,自引:1,他引:11
介绍一种治理已被严重污染的地下水的方法。即修建一道底部深入到不透水岩层的地下墙,把污染物封闭在由底部不透水岩层和周围地下防渗墙组成的“地下盆”中,降低周围地下水中有害物质的浓度,然后再治理封闭圈内的污染物,以达到彻底根治地下水污染的目的。 相似文献