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湘南高温热液矿床中硼同位素组成及分馏作用研究 总被引：4，自引：0，他引：4
根据湘南高温地热区硼同位素研究，总结了硼同位素的分馏特征。湘南高温热液交代矿床硼酸盐矿物的σ^11B值均为负值（－1．34％～－13．28％）；不同蒸馏阶段获得样品的σ^11B值有较大差异，早期蒸馏硼产晚期蒸馏硼酸有较高的σ^11B值，晚期蒸发阶段样品的σ^11B值较早期阶段的σ^11B值低近40％，表明在热液交代过程中^11B较^10B活跃，优先进人流体相或蒸汽相；水岩作用中硼同位素分馏与硅化交代强度成正相关关系，并且是硅置换^11B，造成岩石亏损^11B，而呈现低的σ^11B值；水化反应中硼被吸入，并优先吸入^11B，导致蚀变岩中σ^11B升高。研究认为，硼同位素分馏特征可以用于分析成矿流体演化及水岩作用性质，而不限于分析成矿物质来源。 相似文献
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豫西矿集区岩浆热液叠加改造型矿床特征 总被引：1，自引：0，他引：1
文章对豫西矿集区成矿类型进行了划分,归纳为3大类6个成矿类型.对岩浆热液叠加改造型矿床定义、成矿地质背景、构造转换与成矿进行了阐述,并通过对上宫金矿的矿石矿物共生组合、矿化蚀变特征、同位素地质特征研究,认为岩浆热液叠加改造型矿床赋矿地层古老,经历了长期的构造演化;成矿物质多种来源,具深源特性和造山带物质的痕迹;矿石的物质组成复杂,矿物共生组合种类繁多;成矿围岩遭受了强烈的变质、蚀变作用,蚀变岩石类型较多,矿化多期次叠加;具有多成因性. 相似文献
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阿西金矿床流体成矿的地球化学示踪研究 总被引：8，自引：0，他引：8
依据阿西金矿床Ｈ、Ｏ同位素组成特点对成矿流体的来源进行了示踪研究,并且研究了矿床的水岩交换作用,讨论了水－岩作用与金成矿的关系。根据矿床中典型热液矿物和岩矿石的稀土元素地球化学特征对成矿流体作用过程进行了示踪研究,与同位素地球化学示踪研究取得了基本一致的结果。根据成矿流体活动踪迹建立找矿标志,是进行矿产资源预测的新思路。 相似文献
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锌同位素在矿床学中的应用：认识与进展 总被引：8，自引：1，他引：7
文章报道了安徽铜陵新桥和凤凰山矽卡岩型矿床中闪锌矿和共生黄铁矿间的Zn同位素组成,获得了锌同位素在这2个矿物间的分馏系数,系统总结了锌同位素在不同储库和不同类型矿床中的分布特征,结合最新的研究成果,较全面地总结了锌同位素在矿床学领域的应用,得出了锌同位素可以用来示踪流体演化和源区变化的基本认识。在成矿流体体系的演化过程中,随着矿物的沉淀,流体的逐渐富集重同位素,晚期矿物相对于早期矿物富集锌的重同位素。在热液流体对同一源区淋滤萃取的过程中,重同位素优先被淋滤出来,晚期淋滤出的流体相对早期淋滤出的流体富集轻同位素。 相似文献
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通过对凤太盆地八卦庙金矿和八方山一二里河铅锌矿的矿床地质、矿床地球化学、流体地球化学的研究，发现两类矿床δ（^30Si）分布范围与海底喷流沉积成因硅质岩的硅同位素接近，表明其属热水沉积成因。矿床δ（^34S）比较接近，但铅锌矿矿石中硫源来源更广。碳酸盐的碳、氧同位素特征显示两类矿床均具有热水沉积特点，金矿的样品更趋向于火成岩，表明受后期岩浆热液影响更大。经过流体包裹体测温，金矿床均一温度变化范围大，具有多期次多阶段的特征。矿床同位素和流体包裹体特征表明，金矿床与铅锌矿床在成矿物源、成矿流体特征等方面都存在很多相似性，反映出热水喷流作用与两类矿床成因有密切的关系，但二者又存在差异。结合成矿地质背景，认为铅锌矿的形成与定位受区域热变质改造和动力作用控制，而金矿的形成主要受晚期岩浆热液活动控制，由此建立了金矿与铅锌矿的成矿模式。 相似文献
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广东长坑大型-超大型金银矿床的地球化学与成因带 总被引：12，自引：0，他引：12
对长坑金银矿床的化学组成、同位素特征、流体性质、成矿物理化学条件和机理的系统研究表明,与矿化最密切的硅质岩应主要为热液交代成因;金、银矿体的稀土和微量元素特征既有共性又有异性;矿床的硫、铅、碳、锶同位素组成特征反映它们均为壳源物质或沉积成因;成矿流体相对富Ｃａ、Ｋ,主要来自演化了的加热大气水或建造水;矿床形成于中低温的热液条件,矿化机制包括热液沸腾、流体混合与水岩反应。总之,长坑矿床为微细浸染型金矿与碳酸盐岩交代型银矿构成的新颖矿床组合,金、银矿体是统一的热液作用在不同的成矿环境和控矿条件下的产物,它们与区域内的铅锌（银）矿床应属于一个成矿系列。 相似文献
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庙顶Cu-Au矿床是近年来在四川省冕宁县锦屏山地区新发现的中型铜金矿床,其位于扬子板块西缘NNE向锦屏山深大断裂与近SN向箐河-程海断裂交汇部位所夹的锐角区域内。文章在总结矿床地质特征的基础上,通过对矿床开展系统的C、H、O、S稳定同位素地球化学和流体包裹体的研究及成矿机制的探讨,初步认为庙顶铜金矿床的成矿流体应为岩浆热液来源,岩浆热液流体在运移过程中与围岩发生了一定程度的水岩反应,从而导致围岩玄武岩中的Au、Cu等成矿元素遭受淋滤而进入成矿流体,并在后期还有少量大气降水的加入。矿床的形成经历了高温到中温,最后到低温的演化过程,矿床成因类型属岩浆热液交代矿床。 相似文献
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铁元素是岩浆-热液成矿系统中参与成矿的重要金属元素之一,岩浆-热液矿床中富铁矿物(黄铁矿、磁铁矿、黄铜矿、磁黄铁矿、斑铜矿、毒砂、菱铁矿)的δ56Fe值变化较大(-2.07‰～+1.58‰),指示铁同位素在岩浆演化、流体出溶和热液演化过程中均存在明显的分馏,因此,在约束岩浆-热液成矿系统中成矿金属的迁移-富集-沉淀过程和示踪成矿物质来源方面具有巨大的应用潜力。通过整理和分析前人研究资料,文章总结了岩浆-热液成矿系统岩浆演化、流体出溶和热液演化过程中铁同位素地球化学行为的研究现状。岩浆演化过程中铁同位素会发生显著分馏,如部分熔融过程中,熔体相比残余固相富集重铁同位素;矿物分离结晶会引起残余熔体铁同位素组成的变化,主要受含Fe2+或Fe3+矿物结晶的影响,如磁铁矿分离结晶会导致残余熔体铁同位素组成变轻,总体反映岩浆氧化还原状态对铁同位素分馏的主要控制作用,因此,含矿岩体铁同位素组成及其变化可用于确定岩浆的氧化还原状态。流体出溶是含矿岩浆演化成为岩浆热液矿床的关键过程,出溶流体相对于母岩富集轻铁同位素,但实验研究表明出溶流体铁... 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations. 相似文献
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《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
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Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA 总被引：1，自引：0，他引：1
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources. 相似文献
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S. M. Moosavirad J. Rasouli M. R. Janardhana M. R. Moghadam M. Shankara 《Arabian Journal of Geosciences》2013,6(10):3623-3634
This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds. 相似文献
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