共查询到19条相似文献，搜索用时 125 毫秒
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介绍了根据自己研究测定的Ｌｉ，Ｋ／Ｃｌ，ＳＯ４－Ｈ２Ｏ体系２５℃的渗透系数等热力学性质获得的Ｐｉｔｚｅｒ混合参数，并用自由能最小化方法计算了２５℃ Ｌｉ，Ｋ／Ｃｌ．ＳＯ４－Ｈ２Ｏ体系的相图。结合测定得到的该体系５０℃、７５℃的相图和复盐ＬｉＫＳＯ４转变温度的研究，整个体系相平衡和热力学的研究结果可用于盐湖卤水中锂盐的分离提取。 相似文献
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含HCl四元水盐本系溶解度预测及其在工艺上的应用Ⅰ：HCl的Pitzer参数 … 总被引：1，自引：1，他引：0
Ｈ,Ｌｉ,Ｍｇ／Ｃｌ－Ｈ２Ｏ体系的相平衡关系研究对于从锂的液体资源中有效的分离提取锂盐有重要意义。本文报导我们在这一方面的前期工作,即适用于高离子强度的ＨＣｌ的Ｐｉｔｚｅｒ参数的获得的问题。文中给出了一些有意义的结果。 相似文献
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本文用Ｍｅｉｓｓｎｅｒ公式、Ｂｒｏｍｌｅｙ公式、Ｃｈｅｎ公式、Ｐｉｔｉｅｒ公式及经作者改进的平均球近似（ＭＳＡ）方法对锂盐水溶液（最大浓度达２０ｍｏｌ／ｋｇ）的离子平均活度系数进行了计算和比较，结果表明改进后的ＭＳＡ方法的计算精度最高。另外，本文还应用改进的ＭＳＡ法，使用由单一电解质水溶液离子平均活度系数得到的参数，不用任何混合参数，预测了２９８．１５ｋ时ＬｉＣｌ＋Ｌｉ２ＳＯ４和ＬｉＣｌ＋ＫＣｌ水溶液的等温溶解度图．其结果与文献实验值基本一致。 相似文献
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用等温溶解平衡法研究了盐湖卤水体系Ｌｉ＋，Ｎａ＋，Ｋ＋，Ｍｇ２＋／ＳＯ＿４￣２－Ｈ２Ｏ２５℃溶解度，获得了该五元体系２５℃溶解度相图的十个无变量点和十个结晶区．十个结晶区分别对应于原始组份Ｋ２ＳＯ４、Ｌｉ２ＳＯ４·Ｈ２Ｏ、ＭｇＳＯ４·７Ｈ２Ｏ、Ｎａ２ＳＯ４·１０Ｈ２Ｏ、复盐３Ｋ２ＳＯ４·Ｎａ２ＳＯ４、Ｎａ２ＳＯ４·ＭｇＳＯ４·４Ｈ２Ｏ、Ｌｉ２ＳＯ４·３Ｎａ２ＳＯ４·１２Ｈ２Ｏ、２Ｌｉ２ＳＯ４·Ｎａ２ＳＯ４·Ｋ２ＳＯ４·Ｌｉ２ＳＯ４·Ｋ２ＳＯ４和Ｋ２ＳＯ４·ＭｇＳＯ４·６Ｈ２Ｏ，此外没有产生新的复盐或固溶体，用现代电解质溶液理论－Ｐｉｔｚｅｒ模型校验该体系的溶解度测定值，结果令人满意． 相似文献
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本文测定了三元系ＲＥＣｌ３（ＲＥ＝Ｌａ，Ｐｒ，Ｓｍ）－ＨＯＡｃ－Ｈ２Ｏ（３０℃）的平衡态的溶度数据并绘制了相应的溶度图．在三个体系中分别形成ＬａＣｌ３·７Ｈ２Ｏ，ＰｒＣｌ３·６Ｈ２Ｏ，ＳｍＣｌ３·６Ｈ２Ｏ三种物质．ＨＯＡｃ对ＬｓＣｌ３·７Ｈ２Ｏ，ＰｒＣｌ３·６Ｈ２Ｏ，ＳｍＣｌ３·６Ｈ２Ｏ盐析作用程度的不同，表明了轻稀土元素的“一分组效应”，同时依据ＨＯＡｃ对ＬａＣｌ３·７Ｈ２Ｏ，ＰｒＣｌ３·６Ｈ２Ｏ，ＳｍＣｌ３·６Ｈ２Ｏ有盐折作用这一结论，提出了一种制备ＬａＣｌ３·７Ｈ２Ｏ，ＰｒＣｌ３·６Ｈ２Ｏ，ＳｍＣｌ３·６Ｈ２Ｏ的新方法． 相似文献
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Ｈ＾＋,Ｌｉ＾＋,Ｍｇ＾２＋／Ｃｌ＾－－Ｈ２Ｏ四元体系０℃,２０℃,４０℃的溶解度预测中需要大量参数,而这些参数的获得,依赖于盐酸－碱金属氯化物－水三元体系和ＨＣｌ－ＬｉＣｌ－ＭｇＣｌ２－Ｈ２Ｏ四元体系的热力学性质。总结了近５０年来国内外对上述体系的热力学性质的研究,为Ｈ＾＋,Ｌｉ＾＋,Ｍｇ＾２＋／Ｃｌ＾－－Ｈ２Ｏ四元体系０℃,２０℃,４０℃的溶解度预测奠定基础,同时为Ｐｉｔｚｅｒ模型增添更合理的 相似文献
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中国天气发生器降水模拟参数的气候变化特征 总被引：6，自引：0，他引：6
利用中国672个站点1951-2007年的逐日降水资料,分1951-1978和1979-2007两个时段分析了中国天气发生器BCC/RCG-WG降水模拟参数的气候变化特征.结果表明,在气候变化背景条件下,我国各地干日到湿日的降水转移概率P(WD)和湿日到湿日的降水转移概率P(WW)除了西部部分地区有增大的趋势外,其余大部地区均有减小的趋势.相对于P(WW),全国各地P(WD)的减小幅度更大.日降水量GAMMA分布形态参数ALPHA除西北地区西部部分地区有减小趋势外,其余大部地区略有增大趋势,尺度参数BETA在全国各地基本都保持增大的趋势,其中西北地区西部等地增大趋势尤为明显.相对于BETA的变化幅度,ALPHA的减小幅度较小,基本在6%以内. 相似文献
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利用中国699 个气象站点1951-2007 年的逐日最高气温、最低气温和日照时数资料,分1951-1978 年和1979-2007 年两个时段分析了气候变化对BCC/RCG-WG天气发生器中我国各地逐日非降水变量模拟参数的影响.结果表明,最高气温、最低气温和日照时数三个变量平均值傅立叶级数展开式的年平均值和基波振幅较标准差傅立叶级数展开式的年平均值和基波振幅的变化幅度明显偏大,而平均值傅立叶级数展开式的基波位相变化幅度较标准差的基波位相变化幅度明显偏小;三个变量当天以及后延一天之间的相关系数的绝对变化较小.说明在气候变化背景下,最高气温等三个非降水变量的年平均值和年内变幅有明显的变化,而三个变量年际间的变异、峰值出现时间以及各变量之间的相关性变化较小. 相似文献
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Geographical data sets sometimes contain missing observations that need to be estimated. A statistical approach to the problem is discussed for multivariate normal spatial data sets satisfying the first-order spatial Markov property with constant mean, where the information at neighboring or contiguous observed sites is used to estimate the missing values. The completed data are used to estimate the parameters of the distribution. The procedure is iterative. The approach is a special case of the Orchard and Woodbury missing information principle. The paper concludes with an illustrative empirical example using rainfall data from an area of Kansas and Nebraska. The quality of the estimates for different sites are compared. 相似文献
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《The Professional geographer》2013,65(3):338-339
Geographical data sets sometimes contain missing observations that need to be estimated. A statistical approach to the problem is discussed for multivariate normal spatial data sets satisfying the first-order spatial Markov property with constant mean, where the information at neighboring or contiguous observed sites is used to estimate the missing values. The completed data are used to estimate the parameters of the distribution. The procedure is iterative. The approach is a special case of the Orchard and Woodbury missing information principle. The paper concludes with an illustrative empirical example using rainfall data from an area of Kansas and Nebraska. The quality of the estimates for different sites are compared. 相似文献
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H ,L i ,Mg2 / Cl-- H2 O四元体系 0°C,2 0°C,4 0°C的溶解度预测中需要大量参数 ,而这些参数的获得 ,依赖于盐酸 -碱金属氯化物 -水三元体系和 HCl- L i Cl- Mg Cl2 - H2 O四元体系的热力学性质。总结了近 50年来国内外对上述体系的热力学性质的研究 ,为 H ,L i ,Mg2 / Cl-- H2 O四元体系 0°C,2 0°C,4 0°C的溶解度预测奠定基础 ,同时为 Pitzer模型增添更合理的参数。 相似文献
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重庆北碚中梁山土壤发育过程中粒度与磁化率关系探究 总被引：1，自引：0，他引：1
以中梁山黄壤、石灰土与紫色土剖面为研究对象,分别对其进行粒度相关参数与质量磁化率和频率磁化率的测定,对二者之间的关系进行分析,得出以下结论:3种土壤的总体磁化率较低,频率磁化率所反映的过渡性稳定单畴与超顺磁颗粒对每个剖面上的磁性贡献不一,且对风化成壤程度具有指示作用,说明了3个剖面中黄壤发育较成熟,最差是紫色土;相关性分析表明:石灰土中各参数之间的相关性不显著,因此频率磁化率、质量磁化率不能作为反映气候变化的指标,而在黄壤中由于频率磁化率与标准差的相关性显著,质量磁化率与偏度相关性显著,紫色土中质量磁化率与砂粒级含量相关性显著,可以建立线性回归方程,南方地区黄壤的频率磁化率、质量磁化率以及紫色土的质量磁化率可以在一定程度上作为衡量气候变化的指标。 相似文献
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D. J. Doornbos 《Geophysical Journal International》1982,69(1):235-251
Summary. Parameters pertaining to the kinematics of a finite source are usually estimated by fitting specific fault models to the data. On the other hand, these parameters, including source location, are also contained in the moment tensors of higher degree. In this paper, the seismic response is represented in terms of 20 source parameters which are related to components of the moment tensors; they are also related to the parameters of fault models, as will be demonstrated for a number of 'classical' models. A linearized inversion for the moment tensor shows that with real data, or with realistic synthetic data, the results are not necessarily physically meaningful, unless constraints are imposed. The constraints are precisely those appearing as a priori assumptions in the conventional methods of source analysis; it is thus possible to investigate the impact of these assumptions. We will discuss in particular the assumption of a general deviatoric point source (not necessarily a double couple) versus that of a plane fault in finite sources. Although at this stage experience with practical performance of the new method is limited, it is suggested that in the appropriate circumstances constrained inversion for the seismic moment tensors offers a viable alternative to estimate kinematic source parameters. 相似文献
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Isothermal Evaporating Phase Equilibria in the Quaternary System (LiCl+NaCl+Li2SO4+Na2SO4+H2O)at 348.15 K and 0.1 MPa:An Experimental and Theoretical Study 
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下载免费PDF全文 The gradient solar pond technique is an economic separating process employed in the inorganic chemical industrial production of salt lake chemical engineering processes. In this paper,a novel isothermal evaporation experimental method was employed to simulate the evaporation phase equilibrium for the reciprocal quaternary system( LiCl + NaCl + Li_2 SO_4+ Na_2 SO_4+ H_2 O) at 348. 15 K to serve as a useful guide for lithium salt production via the depth solar ponds. The isothermal evaporation equilibrium solubilities and physicochemical properties,including the densities and pH values,were experimentally investigated. The dry-salt phase diagram,water-phase diagram,and the diagram of the physicochemical properties versus composition were plotted with respect to the experimental data. The drysalt phase diagram consists of three invariant points,seven univariant solubility curves,and five crystallization regions,specifically halite( NaCl,Ha),thenardite( Na_2 SO_4,Th),double salt( Li_2 SO_4·Na_2 SO_4,Db_2),lithium sulfate monohydrate( Li_2 SO_4·H_2 O,Ls),and lithium chloride monohydrate( LiCl·H_2 O,Lc). Based on Pitzer and its extended HMW model,the Pitzer single salt parameters,mixing ion interaction parameters,and thermodynamic stable equilibrium constants for the quaternary system at 348. 15 K were obtained. The calculated phase diagram and experimental isothermal phase diagram at 348. 15 K exhibited a great difference. Based on these results,the isothermal evaporation phase diagram can truly reflect the salt sedimentary in salt lakes and can be applied as a useful guide for the solar pond process. 相似文献
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应用电导率仪在288~308 K温度范围内测定了LiCl在纯有机溶剂(异丙醇)中的电导率;利用公式计算了LiCl的摩尔电导率;按Kohlrausch经验公式,使用Origin软件进行线性拟合,作图外推求得LiCl在异丙醇中的无限稀释摩尔电导率λ0值;并讨论了LiCl在异丙醇中的电导率、摩尔电导率、活度系数和相对偏摩尔自由能随溶液浓度和温度的变化关系及其温度对LiCl溶液无限稀释摩尔电导率的影响。 相似文献