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1.
《大地构造与成矿学》2015,(5)
因铅锌矿床的定年一直比较困难,关于黔东铅锌矿带的时代和成因认识较为混乱。本文对位于该成矿带赋存于下寒武统清虚洞组藻灰岩中的贵州铜仁卜口场铅锌矿床开展了闪锌矿Rb-Sr与方解石Sm-Nd同位素定年。矿石光薄片显示方解石和不透明矿物沿网状裂隙充填交代。用于定年的方解石,部分与方铅矿沿着同一闪锌矿细脉充填,部分沿方铅矿细脉充填,表明方解石晚于闪锌矿形成,可能属于成矿期后期产物。获得闪锌矿矿物Rb-Sr等时线年龄466±13 Ma(MSWD=2.0)和闪锌矿矿物+弱酸提取相+硫化物相Rb-Sr等时线年龄483±9 Ma(MSWD=8.0),二者在误差范围内一致,应代表了该铅锌矿床的主成矿期。获得方解石Sm-Nd等时线年龄422±48 Ma(MSWD=0.71),可能代表了同一成矿作用的后期阶段。即卜口场铅锌矿床后期改造成矿作用可能存在早奥陶世(483~466 Ma)和早志留世(~422 Ma)两个阶段。闪锌矿和闪锌矿分相Rb-Sr等时线对应的初始87Sr/86Sr比值分别为0.70920和0.70908,方解石Sm-Nd等时线对应的初始143Nd/144Nd比值为0.511520(εNd(t)为–11.2),指示其流体来源具有Sr、Nd富集特征,为成矿流体主要是地层封存水与区域热液流体提供了佐证。 相似文献
2.
新疆白杨河大型铍铀矿床成矿流体特征及矿床成因初探 总被引：5，自引：0，他引：5
新疆和布克赛尔县白杨河大型铍铀矿床是亚洲最大的铍矿床,其矿体产出于晚石炭世微晶花岗斑岩与上泥盆统塔尔巴哈台组(D3t)中酸性火山岩的接触带上,该矿床为典型的热液矿床.萤石作为白杨河铍铀矿床中与成矿作用密切相关的脉石矿物,发育大量气液包裹体.通过对萤石中流体包裹体的显微测温,获得了其主成矿期包裹体的均一温度,为237～372℃(n=40),平均为308.5℃,反映该矿床为中高温热液矿床.萤石以相对富集中稀土(MREE) ((La/Yb)N=3.18～3.55),强烈亏损Eu (δEu=0.01),REE分布模式呈“V”字型为特征.萤石锶钕同位素数据显示出较高的锶同位素初始比值(0.7106),以及正εNd(t)值(3.50～2.95),相似于微晶花岗斑岩的锶钕同位素组成((87Sr/86Sr)i=0.7143～0.7466,εNd(t)=4.06～5.29),由此提出成矿流体主要来自微晶花岗斑岩岩浆分异的晚期热液.主成矿期的萤石包裹体显示高温、低盐度的特征,推断成矿流体源于微晶花岗斑岩晚期岩浆热液与大气降水的混合. 相似文献
3.
湘西渣滓溪钨锑矿床白钨矿的Sm-Nd和Sr同位素地球化学 总被引：4，自引：0，他引：4
渣滓溪钨锑矿床位于湘西雪峰山弧形构造带的中段,是我国典型的脉状充填型锑矿床。本文对渣滓溪矿区不同产状产出的白钨矿进行了Sm-Nd和Sr同位素研究。研究表明,渣滓溪矿区白钨矿Sm/Nd变化范围相对较宽（0.36~0.63）,143Nd/144Nd为0.51211~0.51288;在147Sm/144Nd-143Nd/144Nd图解中,该矿白钨矿样品没有明显的线性分布趋势,无法厘定出该矿的准确成矿时间。该矿白钨矿的Nd(t)明显可分为两组（-10.2~-14.7和-3.79~+0.01）,其成矿流体中的Nd主要有两个来源,一部分可能来自晚元古代地层或下伏陆壳基底的碎屑岩,另一部分很可能与冷家溪群的基性、超基性岩有关。与Nd同位素不同,渣滓溪成矿流体中Sr同位素组成均一化程度较高,该矿白钨矿87Sr/86Sr为0.7304~0.7329;该矿这种明显富放射成因87Sr的成矿热液,排除了成矿流体来自海水和赋矿围岩作为唯一矿源层的可能性,下伏陆壳的结晶基底很可能是这种高放射成因Sr的提供者。沃溪和渣滓溪矿区白钨矿Sr-Nd同位素组成的对比研究表明,两矿区的成矿物质来源有所不同,前者应来自一种更古老、更成熟、更富放射成因Sr的下伏陆壳基底。 相似文献
4.
油气成藏和有机质参与金属成矿的内在联系是近年来国内外地学界关注的热点问题.根据流体包裹体岩相学观察和激光拉曼光谱分析,在鄂西宜昌地区震旦系陡山沱组和下寒武统牛蹄塘组页岩储层及震旦系灯影组MVT（Mississippi Valley type）铅锌矿床中发现了高密度甲烷包裹体,并利用甲烷包裹体的甲烷拉曼散射峰v1计算了甲烷包裹体的密度;同时采用Rb-Sr、Sm-Nd同位素定年确定了MVT铅锌矿成矿年代.鄂阳页1井陡山沱组页岩石英脉和何家坪MVT铅锌矿方解石样品中甲烷包裹体密度分别为0.237~0.278 g/cm3和0.213~0.271 g/cm3,属于高密度甲烷包裹体.何家坪铅锌矿共生矿物闪锌矿和方铅矿的Rb-Sr等时线年龄为189.1±1.8 Ma,方解石的Sm-Nd等时线年龄为189.9±2.0 Ma,指示铅锌矿形成于燕山早期的构造挤压运动;共生矿物的初始87Sr/86Sr值（0.711 92）和方解石的初始87Sr/86Sr值（0.712 03~0.712 27）指示何家坪铅锌矿成矿流体的Sr同位素主要来源于页岩层.何家坪铅锌矿中捕获的以流体包裹体形式存在的高密度甲烷流体最有可能来源于陡山沱组页岩和/或牛蹄塘组页岩内高密度超压甲烷流体.页岩气层和MVT铅锌矿中高密度甲烷包裹体的发现及MVT铅锌矿成矿时间的确定为探讨有机质参与MVT铅锌矿成矿提供了新证据. 相似文献
5.
扬子西南缘是我国重要的铁铜金矿产资源产区,分布许多铁铜多金属矿床,而本次研究的大红山矿床属扬子西南缘内最大的铁铜多金属矿床之一.铁、铜矿化方解石脉中方解石测年结果表明,Sm-Nd等时线年龄为(818士3) Ma,代表方解石脉中磁铁矿、黄铜矿矿化年龄为818Ma.结合扬子西南缘成岩成矿关系、背景研究,揭示该矿化事件与Rodinia超大陆裂解期大陆裂谷环境有关.据方解石Sm-Nd同位素体系中(143Nd/144Nd)i值0.5112649和εNd(t=818Ma)值范围介于-6.3～-6.2之间的组成特点,指示方解石中Nd为壳幔混源,且以幔源为主. 相似文献
6.
河南栾川三道沟铅锌银矿床方解石地球化学特征及Sm-Nd年龄研究 总被引：1，自引：0，他引：1
《地球化学》2016,(2)
三道沟铅锌银矿床位于华北陆块南缘栾川多金属矿集区西部。受断裂控制的薄脉状矿体赋存于新元古界栾川群南泥湖组碎屑岩、碳酸盐岩地层中。本文在矿床地质特征和矿物学研究的基础上,对早、中、晚3个成矿阶段的9件热液方解石进行微量元素、稀土元素和Sm-Nd同位素测年研究。结果表明方解石的稀土元素总量(?REE)为6.42~216μg/g,富集重稀土元素,HREE/LREE比值为1.47~5.94;δEu=0.62~2.71,具弱Ce异常;强烈亏损Nb和Zr,富集Pb。从成矿早阶段到晚阶段,∑REE值、LREE/HREE比值和δEu值逐渐减小。Y/Ho-La/Ho图解和Tb/Ca-Tb/La图解均指示该矿床方解石为热液成因。方解石147Sm/144Nd和143Nd/144Nd同位素比值具有良好的线性关系,等时线年龄为(138.3±2.6)Ma(2σ,MSWD=2.3)。结合矿集区内成岩-成矿年代学资料,认为三道沟矿床与区内最晚阶段的花岗质岩浆活动(136~142 Ma)有关,属于栾川Mo-W-Pb-Zn-Ag多金属成矿系统中的热液脉型铅锌银矿床。 相似文献
7.
福建北部元古代麻源群地层发育,对其中7个变质岩和2个白云母花岗岩样品进行了Sm-Nd及Rb-Sr同位素年龄研究。7个样品的Sm-Nd同位素全岩等时线年龄为2116±22(2δ)Ma,INd=0.51027±2(2δ),εNd(t)=7.29±0.17。6个样品的Rb-Sr同位素全岩等时线年龄为375±28(2δ)M,(87Sr/86Sr)i=0.707±34(2δ).2116Ma的年龄值代表麻源群原岩的成岩年龄,375Ma年龄值代表麻源群的变质年龄。 相似文献
8.
白云鄂博矿床白云岩的Sm—Nd、Rb—Sr同位素体系 总被引：17，自引：4，他引：17
白云鄂博矿床的年龄和成因长期争论.本文报道了白云鄂博矿床白云岩及其组成矿物的Sm-Nd、Rb-Sr同位素分析结果.采自该矿床主、东矿等地的15个白云岩样品的Sm-Nd同位素分析结果呈现一条等时线,等时年龄1273±100(2σ)Ma,INd=0.510919士36(2d),MSWD1.01.全岩Rb-Sr同位素分析结果分散,不构成等时线.87Rb/86Sr0～2.092×100-2,87Sr/86Sr0.70341～0.70541.白云岩矿物的Sm-Nd同位素分析结果给予了与全岩类似的Sm-Nd等时年龄,t=1250士210(2σ)Ma,1Nd=0.510914±77(2σ),MSWD
0.56.白云鄂博矿床可能是中元古代末期大离子亲石微量元素略为富集地幔源区部分熔融岩浆活动产物. 相似文献
9.
《地球化学》2015,(5)
我国华南石炭系含硅质岩、硅质条带和结核的白云岩地层之中产有一种独特的碳酸盐岩型滑石矿床。该类滑石成矿作用与岩浆活动及变质作用无明显的成因联系;矿体均受向斜构造的控制;矿石质量较好,矿物组成除了滑石以外,仅有少量的方解石。其中,桂中镇圩滑石矿床的经济价值最为重要,其储量达2167万吨。为了查明其成因,笔者对该矿床中与滑石共生的方解石进行了锶同位素地球化学研究。研究结果表明,方解石的Rb含量极低,平均值低于0.10×10–6;Sr含量较高,平均为135.74×10–6,Rb/Sr值小于0.0013,因而,其锶同位素组成可以代表矿化时成矿流体的锶同位素组成。其次,方解石的锶同位素组成较为均一,其87Sr/86Sr值介于0.708220~0.708911之间,平均值为0.708511。对比研究发现,该矿床中方解石的锶同位素组成明显低于盆地卤水和同期岩浆岩,略高于含矿碳酸盐岩、同期海水和海底热液的锶同位素组成,与以碳酸盐岩为主的喀斯特地区的河水、岩溶水和石笋的锶同位素组成较为相似。结合矿床地质特征,笔者认为镇圩滑石矿床的成矿流体很可能为大气降水,属于古岩溶交代成因,这与华南中-晚三叠世逐步隆升为海陆交互相和陆相的地质事实也相吻合。因此,华南早在中-晚三叠世就已经开始喀斯特作用的发育。 相似文献
10.
江苏栖霞山铅锌多金属矿床深部碳-氧-锶同位素地球化学特征及其指示意义 总被引：1，自引：0，他引：1
以栖霞山铅锌多金属矿床深部找矿钻孔岩心为对象,开展碳-氧-锶同位素地球化学研究。结果表明,栖霞山矿床矿石样品δ13CV-PDB同位素值为-5.1‰～1.9‰,且由浅部至深部,矿石样品的δ13C、δ18O值处于增大的趋势,指示成矿流体中的碳起源于碳酸盐岩、源自地幔和岩浆的深源碳。对锶同位素的研究显示,栖霞山矿石~(87)Sr/~(86)Sr值为0.704816～0.71405,部分大于矿体围岩黄龙组灰岩的~(87)Sr/~(86)Sr值(0.708329～0.709685),部分小于矿体围岩黄龙组灰岩的~(87)Sr/~(86)Sr值,并与不同来源的Sr同位素对比,揭示栖霞山矿石中Sr兼具基底地层Sr和幔源Sr的混合来源特征,且在围岩蚀变过程中~(87)Sr/~(86)Sr的变化应主要由成矿流体引起。结合本区成矿地质特征认为,栖霞山矿床成矿流体可能来自花岗岩的期后热液,在热动力作用下,流经元古宇基底地层,形成具有混合物质来源的成矿流体,成矿作用过程主要为成矿流体与围岩碳酸盐岩发生水-岩反应所致。 相似文献
11.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations. 相似文献
12.
《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2. 相似文献
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针对兖州煤田下组煤深部开采受奥灰高承压水威胁以及当地大型煤化工企业生产用水量大的现状,在已进行的水文地质勘探及放水试验基础上,评价奥灰富水性,并采用有限差分法进行奥灰疏水降压数值模拟研究,提出水煤共采观点。研究结果表明:兖州煤田深部奥灰水压高,合理布置水煤共采孔,可以实现奥灰水位的有效疏降,疏降中心区水位最大降深可达110 m,突水系数显著下降,提高了下组煤开采的安全性;同时可提供煤化工43200 m3/d的供水量,能达到可持续的、水资源保护性的供水效果,实现下组煤的水煤共采。 相似文献
16.
Hirokazu Fujimaki 《Contributions to Mineralogy and Petrology》1986,94(1):42-45
Concentration ratios of Hf, Zr, and REE between zircon, apatite, and liquid were determined for three igneous compositions: two andesites and a diorite. The concentration ratios of these elements between zircon and corresponding liquid can approximate the partition coefficient. Although the concentration ratios between apatite and andesite groundmass can be considered as partition coefficients, those for the apatite in the diorite may deviate from the partition coefficients. The HREE partition coefficients between zircon and liquid are very large (100 for Er to 500 for Lu), and the Hf partition coefficient is even larger. The REE partition coefficients between apatite and liquid are convex upward, and large (D=10–100), whereas the Hf and Zr partition coefficients are less than 1. The large differences between partition coefficients of Lu and Hf for zircon-liquid and for apatite-liquid are confirmed. These partition coefficients are useful for petrogenetic models involving zircon and apatite. 相似文献
17.
The distribution of Cu, Co, As and Fe was studied downstream from mines and deposits in the Idaho Cobalt Belt (ICB), the largest Co resource in the USA. To evaluate potential contamination in ecosystems in the ICB, mine waste, stream sediment, soil, and water were collected and analyzed for Cu, Co, As and Fe in this area. Concentrations of Cu in mine waste and stream sediment collected proximal to mines in the ICB ranged from 390 to 19,000 μg/g, exceeding the USEPA target clean-up level and the probable effect concentration (PEC) for Cu of 149 μg/g in sediment; PEC is the concentration above which harmful effects are likely in sediment dwelling organisms. In addition concentrations of Cu in mine runoff and stream water collected proximal to mines were highly elevated in the ICB and exceeded the USEPA chronic criterion for aquatic organisms of 6.3 μg/L (at a water hardness of 50 mg/L) and an LC50 concentration for rainbow trout of 14 μg/L for Cu in water. Concentrations of Co in mine waste and stream sediment collected proximal to mines varied from 14 to 7400 μg/g and were highly elevated above regional background concentrations, and generally exceeded the USEPA target clean-up level of 80 μg/g for Co in sediment. Concentrations of Co in water were as high as in 75,000 μg/L in the ICB, exceeding an LC50 of 346 μg/L for rainbow trout for Co in water by as much as two orders of magnitude, likely indicating an adverse effect on trout. Mine waste and stream sediment collected in the ICB also contained highly elevated As concentrations that varied from 26 to 17,000 μg/g, most of which exceeded the PEC of 33 μg/g and the USEPA target clean-up level of 35 μg/g for As in sediment. Conversely, most water samples had As concentrations that were below the 150 μg/L chronic criterion for protection of aquatic organisms and the USEPA target clean-up level of 14 μg/L. There is abundant Fe oxide in streams in the ICB and several samples of mine runoff and stream water exceeded the chronic criterion for protection of aquatic organisms of 1000 μg/L for Fe. There has been extensive remediation of mined areas in the ICB, but because some mine waste remaining in the area contains highly elevated Cu, Co, As and Fe, inhalation or ingestion of mine waste particulates may lead to human exposure to these elements. 相似文献
18.
E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
19.
Todd Dunn 《Contributions to Mineralogy and Petrology》1987,96(4):476-484
The crystal/liquid partition coefficients of Lu, Hf, Ti, Mn and Ca have been measured between olivine, clinopyroxene and basaltic melt. The Ti, Mn, and Ca partition coefficients were determined at natural abundance levels. The Lu and Hf partition coefficients were determined at doping levels ranging from 0.5 to 1.5 wt% “trace element” as oxide in order to allow analysis by electron microprobe. Olivine/liquid partition coefficients for Lu, Hf, Ti, Mn, and Ca were determined at 1 bar and temperatures from 1150 to 1177° C. Clinopyroxene/liquid partition coefficients were determined for Lu, Hf, Ti, and Mn at pressures of 10, 15, and 20 kbars and temperatures from 1250 to 1290° C. The olivine/liquid partition coefficients of Hf, Lu, Ti, and Ca are small. D(Hf-ol) is zero within the analytical uncertainty. Both D(Lu-ol) and D(Mn-ol) decrease with increasing temperature, but D(Ti-ol) and D(Ca-ol) are constant over the narrow temperature range studied. The partition coefficient results are summarized below.
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20.
Stratiform quartz-sulphide lodes in Ingladhal occur in a typical Precambrian green-stone-belt environment comprising metabasalts, tuff, chert and cherty iron-sulphide formation. Unusually high cobalt contents of metavolcanics and of sulphide minerals in orebodies suggest a consanguinity between ores and rocks. 90% of total nickel, 70% of total cobalt but only 30% of total copper in rocks occur in silicate phases and thus indicate an early separation of copper from cobalt and nickel. Unusually high non-sulphide copper in barren bedded cherts implies availability of Cu-rich solution prior to their lithification. Pyrite in sediments, in volcanics, and in orebodies is characterized by a distinctive pattern of Co-Ni distribution in each case. Partitioning of Co and Ni between coexisting sulphide pairs is complex, but gross equilibrium is indicated. Very high trace metal content of orebody pyrite sharply contrasts with very low such values in pyrite from adjacent sediments and points to a higher temperature of formation of orebodies. 相似文献
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