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1.
Knowledge of Martian igneous basaltic compositions is crucial for constraining mantle evolution, including early differentiation and mantle convection. Primitive magmas provide direct information about their mantle source regions, but most Martian meteorites either contain cumulate olivine or crystallized from fractionated melts. The recently discovered Martian meteorite Northwest Africa (NWA) 5789 is an olivine‐phyric shergottite. NWA 5789 has special significance among the Martian meteorites because it appears to represent one of the most magnesian Martian magmas known, other than Yamato (Y) 980459. Its most magnesian olivine cores (Fo85) are in Mg‐Fe equilibrium with a magma of the bulk rock composition, suggesting that the bulk represents a magma composition. Based on the Al/Ti ratio of its pyroxenes, we infer that the rock began to crystallize at a high pressure consistent with conditions in Mars’ lower crust/upper mantle. It continued and completed its crystallization closer to the surface, where cooling was rapid and produced a mesostasis of radiating sprays of plagioclase and pyroxene. The mineralogy, petrology, mineral chemistry, and bulk rock composition of NWA 5789 are very similar to those of Y‐980459. The similarities between the two meteorites suggest that NWA 5789 (like Y‐980459) represents a primitive, mantle‐derived magma composition. They also suggest the possibility that NWA 5789 and Y‐980459 formed in the same lava flow. However, based on the mineralogy and texture of its mesostasis, NWA 5789 must have cooled more slowly than Y‐980459. NWA 5789 will help elucidate the igneous geology and geochemistry of Mars.  相似文献   

2.
Abstract— The only well‐known terrestrial analogue of impact craters in basaltic crusts of the rocky planets is the Lonar crater, India. For the first time, evidence of the impactor that formed the crater has been identified within the impact spherules, which are ?0.3 to 1 mm in size and of different aerodynamic shapes including spheres, teardrops, cylinders, dumbbells and spindles. They were found in ejecta on the rim of the crater. The spherules have high magnetic susceptibility (from 0.31 to 0.02 SI‐mass) and natural remanent magnetization (NRM) intensity. Both NRM and saturation isothermal remanent magnetization (SIRM) intensity are ?2 Am2/Kg. Demagnetization response by the NRM suggests a complicated history of remanence acquisition. The spherules show schlieren structure described by chains of tiny dendritic and octahedral‐shaped magnetite crystals indicating their quenching from liquid droplets. Microprobe analyses show that, relative to the target basalt compositions, the spherules have relatively high average Fe2O3 (by ?1.5 wt%), MgO (?1 wt%), Mn (?200 ppm), Cr (?200 ppm), Co (?50 ppm), Ni (?1000 ppm) and Zn (?70 ppm), and low Na2O (?1 wt%) and P2O5 (?0.2 wt%). Very high Ni contents, up to 14 times the average content of Lonar basalt, require the presence of a meteoritic component in these spherules. We interpret the high Ni, Cr, and Co abundances in these spherules to indicate that the impactor of the Lonar crater was a chondrite, which is present in abundances of 12 to 20 percent by weight in these impact spherules. Relatively high Zn yet low Na2O and P2O5 contents of these spherules indicate exchange of volatiles between the quenching spherule droplets and the impact plume.  相似文献   

3.
Abstract— We examine the occurrences, textures, and compositional patterns of spinels in the olivine‐phyric shergottites Sayh al Uhaymir (SaU) 005, lithology A of Elephant Moraine A79001 (EET‐A), Dhofar 019, and Northwest Africa (NWA) 1110, as well as the Iherzolitic shergottite Allan Hills (ALH) A77005, in order to identify spinel‐olivine‐pyroxene assemblages for the determination of oxygen fugacity (using the oxybarometer of Wood [1991]) at several stages of crystallization. In all of these basaltic martian rocks, chromite was the earliest phase and crystallized along a trend of strict Cr‐Al variation. Spinel (chromite) crystallization was terminated by the appearance of pyroxene but resumed later with the appearance of ulvöspinel. Ulvöspinel formed overgrowths on early chromites (except those shielded as inclusions in olivine or pyroxene), retaining the evidence of the spinel stability gap in the form of a sharp core/rim boundary (except in ALH A77005, where subsolidus reequilibration diffused this boundary). Secondary effects seen in chromites include reaction with melt before ulvöspinel overgrowth, reaction with melt inclusions, reaction with olivine hosts (in ALH A77005), and exsolution of ulvöspinel or ilmenite. All chromites experienced subsolidus Fe/Mg reequilibration. Spinel‐olivine‐pyroxene assemblages representing the earliest stages of crystallization in each rock essentially consist of the highest‐Cr#, lowest‐fe# chromites not showing secondary effects plus the most magnesian olivine and equilibrium low‐Ca pyroxene. Assemblages representing the onset of ulvöspinel crystallization consist of the lowest‐Ti ulvöspinel, the most magnesian olivine in which ulvöspinel occurs as inclusions, and equilibrium low‐Ca pyroxene. The results show that, for early crystallization conditions, oxygen fugacity (fO2) increases from SaU 005 and Dhofar 019 (?QFM ‐3.8), to EET‐A (QFM ‐2.8) and ALH A77005 (QFM ‐2.6), to NWA 1110 (QFM ‐1.7). Estimates for later conditions indicate that in SaU 005 and Dhofar 019 oxidation state did not change during crystallization. In EET‐A, there was an increase in fO2 that may have been due to mixing of reduced material with a more oxidized magma. In NWA 1110, there was a dramatic increase, indicating a non‐buffered system, possibly related to its high oxidation state. Differences in fO2 among shergottites are not primarily due to igneous fractionation but, rather, to derivation from (and possibly mixing of) different reservoirs.  相似文献   

4.
The ChemCam instrument on the Mars Science Laboratory (MSL) rover, Curiosity, observed numerous igneous float rocks and conglomerate clasts, reported previously. A new statistical analysis of single‐laser‐shot spectra of igneous targets observed by ChemCam shows a strong peak at ~55 wt% SiO2 and 6 wt% total alkalis, with a minor secondary maximum at 47–51 wt% SiO2 and lower alkali content. The centers of these distributions, together with the rock textures, indicate that many of the ChemCam igneous targets are trachybasalts, Mg# = 27 but with a secondary concentration of basaltic material, with a focus of compositions around Mg# = 54. We suggest that all of these igneous rocks resulted from low‐pressure, olivine‐dominated fractionation of Adirondack (MER) class‐type basalt compositions. This magmatism has subalkaline, tholeiitic affinities. The similarity of the basalt endmember to much of the Gale sediment compositions in the first 1000 sols of the MSL mission suggests that this type of Fe‐rich, relatively low‐Mg#, olivine tholeiite is the dominant constituent of the Gale catchment that is the source material for the fine‐grained sediments in Gale. The similarity to many Gusev igneous compositions suggests that it is a major constituent of ancient Martian magmas, and distinct from the shergottite parental melts thought to be associated with Tharsis and the Northern Lowlands. The Gale Crater catchment sampled a mixture of this tholeiitic basalt along with alkaline igneous material, together giving some analogies to terrestrial intraplate magmatic provinces.  相似文献   

5.
Abstract– The oxygen fugacities recorded in the nakhlites Nakhla, Yamato‐000593 (Y‐000593), Lafayette, and NWA998 were studied by applying the Fe,Ti‐oxide oxybarometer. Oxygen fugacities obtained cluster closely around the FMQ (Fayalite–Magnetite–Quartz) buffer (NWA998 = FMQ ? 0.8; Y‐000593 = FMQ ? 0.7; Nakhla = FMQ; Lafayette = FMQ + 0.1). The corresponding equilibration temperatures are 810 °C for Nakhla and Y‐000593, 780 °C for Lafayette and 710 °C for NWA998. All nakhlites record oxygen fugacities significantly higher and with a tighter range than those determined for Martian basalts, i.e., shergottites whose oxygen fugacities vary from FMQ ? 1 to FMQ ? 4. It has been known for some time that nakhlites are different from other Martian meteorites in chemistry, mineralogy, and crystallization age. The present study adds oxygen fugacity to this list of differences. The comparatively large variation in fO2 recorded by shergottites was interpreted by Herd et al. (2002) as reflecting variable degrees of contamination with crustal fluids that would also carry a light rare earth element (REE)‐enriched component. The high oxygen fugacities and the large light REE enrichment of nakhlites fit qualitatively in this model. In detail, however, it is found that the inferred contaminating phase in nakhlites must have been different from those in shergottites. This is supported by unique 182W/184W and 142Nd/144Nd ratios in nakhlites, which are distinct from other Martian meteorites. It is likely that the differences in fO2 between nakhlites and other Martian meteorites were established very early in the history of Mars. Parental trace element rich and trace element poor regions (reservoirs) of Mars mantle ( Brandon et al. 2000 ) must have been kept isolated throughout Martian history. Our results further show significant differences in closure temperature among the different nakhlites. The observed range in equilibration temperatures together with similar fO2 values is attributable to crystallization of nakhlites in the same cumulate pile or lava layer at different burial depths from 0.5 to 30 m below the Martian surface in agreement with Mikouchi et al. (2003) and is further confirmed by similar crystallization ages of about 1.3 Ga ago (e.g., Misawa et al. 2003 ).  相似文献   

6.
Abstract— Pyroxene structural data, along with analyses of titanomagnetite, fayalite and mesostasis of the new nakhlite Miller Range (MIL) 03346, define equilibration near 1 bar, 1100 °C, and oxygen fugacity near the FMQ buffer. There is a clear progression of oxygen fugacity (fO2) in Martian meteorites from reduced Allan Hills (ALH) 84001 to intermediate shergottites to oxidized nakhlites. This trend can be explained by polybaric graphite‐CO‐CO2 equilibria in the Martian mantle. Shergottites would have formed at pressures between 1.2 and 3.0 GPa, and nakhlite parent liquids formed at pressures >3.0 GPa, consistent with geochemical and petrologic data for the shergottites and nahklites. Carbon buffering in the Martian mantle could be responsible for variation in fO2 in Martian meteorites (rather than assimilation or crustal interaction), as well as C‐H‐O fluids that could be the source of ˜30 ppb CH4 detected by recent spacecraft missions. The conundrum of an oxidized current mantle and basalts, but reduced early mantle during core‐mantle equilibrium exists for both the Earth and Mars. A polybaric buffering role for graphite can explain this discrepancy for Mars, and thus it may not be necessary to have an oxidation mechanism like the dissociation of MgFe‐perovskite to account for the oxidized terrestrial mantle.  相似文献   

7.
Abstract— The origin of hematite detected in Martian surface materials is commonly attributed to weathering processes or aqueous precipitation. Here, we present a new hematite formation mechanism that requires neither water nor weathering. Glass‐rich basalts with Martian meteorite‐like chemistry (high FeO, low Al2O3) oxidized at high (700 and 900 °C) temperatures in air and CO2, respectively, form thin (<1 μm) hematite coatings on their outermost surfaces. Hematite is manifested macroscopically by development of magnetism and a gray, metallic sheen on the glass surface and microscopically by Fe enrichment at the glass surface observed in element maps. Visible and near‐infrared, thermal infrared, and Raman spectroscopy confirm that the Fe enrichment at the oxidized glass surfaces corresponds to hematite mineralization. Hematite formation on basaltic glass is enabled by a mechanism that induces migration of Fe2+ to the surface of an oxidizing glass and subsequent oxidation to form hematite. A natural example of the hematite formation mechanism is provided by a Hawaiian basalt hosting a gray, metallic sheen that corresponds to a thin hematite coating. Hematite coating development on the Hawaiian basalt demonstrates that Martian meteorite‐like FeO contents are not required for hematite coating formation on basalt glass and that such coatings form during initial extrusion of the glassy basalt flows. If gray hematite originating as coatings on glassy basalt flows is an important source of Martian hematite, which is feasible given the predominance of igneous features on Mars, then the requirement of water as an agent of hematite formation is eliminated.  相似文献   

8.
The nature of strong martian crustal field sources is investigated by mapping and modeling of Mars Global Surveyor magnetometer data near Apollinaris Patera, a previously proposed volcanic source, supplemented by large-scale correlative studies. Regional mapping yields evidence for positive correlations of orbital anomalies with both Apollinaris Patera and Lucus Planum, a nearby probable extrusive pyroclastic flow deposit that is mapped as part of the Medusae Fossae Formation. Iterative forward modeling of the Apollinaris Patera magnetic anomaly assuming a source model consisting of one or more uniformly magnetized near-surface disks indicates that the source is centered approximately on the construct with a scale size several times larger and comparable to that of the Apollinaris Patera free-air gravity anomaly. A significantly lower rms deviation is obtained using a two-disk model that favors a concentration of magnetization near the construct itself. Estimates for the dipole moment per unit area of the Lucus Planum source together with maximum thicknesses of ∼3 km based on topographic and radar sounding data lead to an estimated minimum magnetization intensity of ∼50 A/m within the pyroclastic deposits. Intensities of this magnitude are similar to those obtained experimentally for Fe-rich Mars analog basalts that cooled in an oxidizing (high fO2) environment in the presence of a strong (?10 μT) surface field. Further evidence for the need for an oxidizing environment is provided by a broad spatial correlation of the locations of phyllosilicate exposures identified to date using Mars Express OMEGA data with areas containing strong crustal magnetic fields and valley networks in the Noachian-aged southern highlands. This indicates that the presence of liquid water, which is a major crustal oxidant, was an important factor in the formation of strong magnetic sources. The evidence discussed here for magnetic sources associated with relatively young volcanic units suggests that a martian dynamo existed during the late Noachian/early Hesperian, after the last major basin-forming impacts and the formation of the northern lowlands.  相似文献   

9.
The fall and recovery of the Tissint meteorite in 2011 created a rare opportunity to examine a Martian sample with a known, short residence time on Earth. Tissint is an olivine‐phyric shergottite that accumulated olivine antecrysts within a single magmatic system. Coarse olivine grains with nearly homogeneous cores of Mg# >80 suggest slow re‐equilibration. Many macroscopic features of this sample resemble those of LAR 06319, including the olivine crystal size distribution and the presence of evolved oxide and olivine compositions. Unlike LAR 06319, however, no magmatic hydrous phases were found in the analyzed samples of Tissint. Minor and trace element compositions indicate that the meteorite is the product of closed‐system crystallization from a parent melt derived from a depleted source, with no obvious addition of a LREE‐rich (crustal?) component prior to or during crystallization. The whole‐rock REE pattern is similar to that of intermediate olivine‐phyric shergottite EETA 79001 lithology A, and could also be approximated by a more olivine‐rich version of depleted basaltic shergottite QUE 94201. Magmatic oxygen fugacities are at the low end of the shergottite range, with log fO2 of QFM‐3.5 to ‐4.0 estimated based on early‐crystallized minerals and QFM‐2.4 estimated based on the Eu in pyroxene oxybarometer. These values are similarly comparable to other depleted shergottites, including SaU 005 and QUE 94201. Tissint occupies a previously unsampled niche in shergottite chemistry: containing olivines with Mg# >80, resembling the enriched olivine‐phyric shergottite LAR 06319 in its crystallization path, and comparable to intermediate olivine‐phyric shergottite EETA 79001A, depleted olivine‐phyric shergottite DaG 476, and depleted basaltic shergottite QUE 94201 in its trace element abundances and oxygen fugacity. The apparent absence of evidence for terrestrial alteration in Tissint (particularly in trace element abundances in the whole‐rock and individual minerals) confirms that exposure to the arid desert environment results in only minimal weathering of samples, provided the exposure times are brief.  相似文献   

10.
Abstract— Martian crust endured several large meteoroid impacts subsequent to the demise of an early global magnetic field. Shock pressures associated with these impacts demagnetized parts of the crust, to an extent determined by shock resistance of magnetic materials in the crust. Impacts that form large basins generate pressures in excess of 1 GPa within a few crater radii of their impact sites. Crustal materials near the surface experience significantly reduced impact pressure, which varies with depth and distance from the impact point. We present new demagnetization experiments on magnetite (Fe3O4), hematite (α‐Fe2O3), and titanohematite (Fe2‐xTixO3 where x <0.2). Our measurements show that pressures of ?1 GPa are sufficient to partially demagnetize all of these minerals. The efficiency of demagnetization by impact pressure is proportional to the logarithm of the minerals' magnetic coercivity. The impact pressure magnetic response from exsolved titanohematite samples is consistent with the magnetization decay near Prometheus impact basin and may point to an oxidized igneous rock in Terra Sirenum region at the time of acquisition of magnetic remanence. The remaining magnetic anomalies near large impact basins suggest moderate crustal coercivity. These anomalies point to titanomagnetite as a magnetic carrier and more reduced condition during crustal formation.  相似文献   

11.
Dynamic crystallization experiments were performed on a liquid having the bulk composition of olivine‐phyric shergottite Yamato 980459, to constrain the igneous thermal history of this meteorite. Key characteristics of the meteorite's mineralogy and texture, including several morphologically distinct olivine and pyroxene crystal populations and a glassy mesostasis devoid of plagioclase, were replicated upon cooling from 1435 to 909 °C at 1 atmosphere under reducing conditions. Three sequential cooling ramps are required to produce synthetic samples with textures and compositions matching Yamato 980459. Olivine phenocrysts formed at <1 °C h?1, presumably at depth in the Martian crust. Pyroxene phenocrysts formed mainly at ~10 °C h?1, consistent with crystallization within a lava flow at depths of 25–45 cm. Increased cooling rate (~100 °C h?1) in a third stage suppressed the formation of plagioclase and produced groundmass crystals, consistent with crystallization at lava flow depths of 5–7 cm. Although Y 980459 is unique among Martian meteorites (i.e., preserving a primary glassy mesostasis), its emplacement did not require unique physical conditions. Rather, the second and third cooling stages may reflect cooling within the core of a pāhoehoe‐like flow and subsequent breakout on the surface of Mars.  相似文献   

12.
Abstract— The Martian meteorite Yamato (Y‐) 980459 is an olivine‐phyric shergottite. It has a very primitive character and may be a primary melt of the Martian mantle. We have conducted crystallization experiments on a synthetic Y‐980459 composition at Martian upper mantle conditions in order to test the primary mantle melt hypothesis. Results of these experiments indicate that the cores of the olivine megacrysts in Y‐980459 are in equilibrium with a melt of bulk rock composition, suggesting that these megacrysts are in fact phenocrysts that grew from a magma of the bulk rock composition. Multiple saturation of the melt with olivine and a low‐calcium pyroxene occurs at approximately 12 ± 0.5 kbar and 1540 ± 10°C, suggesting that the meteorite represents a primary melt that separated from its mantle source at a depth of ?100 km. Several lines of evidence suggest that the Y‐980459 source underwent extensive melting prior to and/or during the magmatic event that produced the Y‐980459 parent magma. When factored into convective models of the Martian interior, the high temperature indicated for the upper Martian mantle and possibly high melt fraction for the Y‐980459 magmatic event suggests a significantly higher temperature at the core‐mantle boundary than previously estimated.  相似文献   

13.
One of the typical magnetic characteristics of lunar materials is the composition of their ferromagnetic constituent. Lunar breccias often contain kamacite (less than 7 weight per cent of Ni content) as well as almost pure metallic iron. Metallic ferromagnetics in most igneous rocks are almost pure iron, but the kamacite phase also has been found in some Apollo 15 igneous rocks. It seems likely therefore the metallic ferromagnetics in the lunar crust are more or less similar to those in chondrites.Another typical magnetic characteristic of lunar materials is the presence of a considerable amount of superparamagnetically fine particles of metallic iron. A higher relative content of such fine iron particles results in a higher value of the ratio of magnetic susceptibility (o) to saturation magnetization (I s), a smaller ratio of the coercive force (H c) to remanence coercive force (H RC), and an extremely higher ratio of the viscous component (I v) to the stable one (I s) of the remanent magnetization.Communication presented at the Lunar Science Institute Conference on Geophysical and Geochemical Exploration of the Moon and Planets, January 10–12, 1973.  相似文献   

14.
Abstract— Recent discovery of intense magnetic anomalies on Mars, which are due to remanent magnetization, requires some explanation for the possible minerals responsible for the anomalous signature. Thermoremanent magnetization (TRM) in single domain (SD) and multidomain (MD) sized magnetite, hematite, and pyrrhotite, all potential minerals, are considered. The intensity of TRM (in 0.05 mT) is in descending order: SD‐sized magnetite, SD‐sized pyrrhotite, MD‐sized hematite, MD‐sized pyrrhotite, MD‐sized magnetite, SD‐sized hematite. The TRM intensity is <4% of the saturation isothermal remanence (SIRM) for all but the MD hematite, which may have >50% of the SIRM. Each of these minerals and estimated concentrations of magnetic remanence carriers (assumed to be titanomagnetite) in the Shergotty‐Nakhla‐Chassigny martian meteorites are used in a thin sheet approximation model to reveal the concentration of each mineral required for the generation of an observed magnetic anomaly (1500 nT at 100 km altitude) assuming TRM acquisition in a 0.05 mT magnetic field.  相似文献   

15.
Abstract— Core from the Yaxcopoil‐1 (Yax‐1) hole, drilled as a result of the Chicxulub Scientific Drilling Project (CSDP), has been analyzed to investigate the relationship between opaque mineralogy and rock magnetic properties. Twenty one samples of suevite recovered from the depth range 818–894 m are generally paramagnetic, with an average susceptibility of 2000 times 10?6 SI and have weak remanent magnetization intensities (average 0.1 A/m). The predominant magnetic phase is secondary magnetite formed as a result of low temperature (<150 °C) alteration. It occurs in a variety of forms, including vesicle infillings associated with quartz and clay minerals and fine aggregates between plagioclase/diopside laths in the melt. Exceptional magnetic properties are found in a basement clast (metamorphosed quartz gabbro), which has a susceptibility of >45000 times 10?6 SI and a remanent magnetization of 77.5 A/m. Magnetic mafic basement clasts are a common component in the Yax‐1 impactite sequence. The high susceptibility and remanence in the mafic basement clasts are caused by the replacement of amphiboles and pyroxenes by an assemblage with fine <1 μm magnetite, ilmenite, K‐feldspar, and stilpnomelane. Replacement of the mafic minerals by the magnetic alteration assemblage occurred before impact. Similar alteration mechanisms, if operative within the melt sheet, could explain the presence of the high amplitude magnetic anomalies observed at Chicxulub.  相似文献   

16.
Abstract– Northwest Africa (NWA) 5298 is an evolved basaltic shergottite that has bulk characteristics and mineral compositions consistent with derivation from an oxidized reservoir in Mars. Chemically zoned clinopyroxene (64.5%, augite and pigeonite), with interstitial lath‐shaped plagioclase (29.4%, An40 to An55), constitutes the bulk of this meteorite. The plagioclase has been converted by shock to both isotropic maskelynite and spherulitic, birefringent feldspar representing a quenched vesicular melt. The remainder of the rock consists of minor amounts of Fe‐Ti oxides (ilmenite and titanomagnetite), phosphates (merrillite and apatite), silica polymorph, fayalite, pyrrhotite, baddeleyite, and minor hot desert weathering products (calcite and barite). Oxygen fugacity derived from Fe‐Ti oxide thermobarometry is close to the quartz‐fayalite‐magnetite (QFM) buffer indicating that the late stage evolution of this magma occurred under more oxidizing condition than those recorded in most other shergottites. Merrillite contains the largest abundances of rare earth elements (REE) of all phases, thereby controlling the REE budget in NWA 5298. The calculated bulk rock REE pattern normalized to CI chondrite is relatively flat. The evolution of the normalized REE patterns of the bulk rock, clinopyroxene, plagioclase, and phosphate in NWA 5298 is consistent with closed‐system chemical behavior with no evidence of crustal contamination or postcrystallization disturbance of the REE contents of these phases.  相似文献   

17.
Northwest Africa (NWA) 7397 is a newly discovered, enriched, lherzolitic shergottite, the third described example of this group. This meteorite consists of two distinct textural lithologies (1) poikilitic—comprised of zoned pyroxene oikocrysts, with chadacrysts of chromite and olivine, and (2) nonpoikilitic—comprised of olivine, low‐Ca and high‐Ca pyroxene, maskelynite, and minor abundances of merrillite, spinel, ilmenite, and pyrrhotite. The constant Ti/Al ratios of pyroxene oikocrysts suggests initial crystallization of the poikilitic lithology at depth (equivalent to pressures of approximately 10 kbar), followed by crystallization of the nonpoikilitic lithology at shallower levels. Oxygen fugacity conditions become more oxidizing during crystallization ranging from fO2 conditions of approximately QFM‐2 to QFM‐0.7. Magma calculated to be in equilibrium with the major rock‐forming minerals is LREE‐enriched relative to depleted or intermediate shergottites and has flat overall profiles. Therefore, we suggest that the parental magma for NWA 7397 had sampled an enriched, oxidized, Martian geochemical source, similar to that of other enriched basaltic and olivine‐phyric shergottites. We present a polybaric formation model for the lherzolitic shergottite NWA 7397, to account for the petrologic constraints. Three successive stages in the development of NWA 7397 are discussed (1) formation of a REE‐enriched parental magma from a distinct Martian mantle reservoir; (2) magma ponding and development of a staging chamber concomitant with initial crystallization of the poikilitic lithology; and (3) magma ascent to the near surface, with entrainment of cumulates from the staging chamber and subsequent crystallization of the nonpoikilitic lithology en route to the surface.  相似文献   

18.
Abstract— Activities of chromite in multicomponent spinels with compositions similar to those of H chondrites were experimentally determined by equilibrating Pt‐alloys with spinel at known temperature and fO2. Our results are consistent with predictions based on the spinel solid solution model incorporated into the MELTS program. Therefore, we combined literature formulations for the activities of components in spinel, the ferromagnesian silicates, and alloys with measured and literature (bulk alloy) compositions of the meteoritic phases to constrain T‐fO2 conditions for the H‐group chondrites Avanhandava (H4), Allegan (H5), and Guareña (H6). Log10fO2 values based on the assemblage of olivine + orthopyroxene + metal are 2.19–2.56 log units below the iron‐wüstite (IW) buffer for any equilibration temperature between 740 and 990 °C, regardless of petrographic type. Only lower limits on fO2 could be determined from spinel + metal equilibria because of the extremely low concentrations of Cr in the alloys of equilibrated H chondrites (≤3 ppb). Log10fO2 values required by spinel + metal equilibria are inconsistent with those for olivine + orthopyroxene + metal if equilibration temperatures were at or above those inferred from olivine‐spinel thermometry. This probably indicates that the closure for spinel + metal equilibria occurred under retrograde conditions at temperatures below ～625 °C for Allegan and Guareña and below ～660 °C for Avanhandava.  相似文献   

19.
Abstract— A composition approximating the lithology A groundmass of the Elephant Moraine (EET) 79001 martian basalt (Eg; McSween and Jarosewich, 1983) has been used to investigate the petrogenesis of the meteorite and the behavior of Cr and V at different oxygen fugacities. Crystallization experiments were carried out over a range of temperatures, and oxygen fugacities of either iron‐wüstite (IW) or IW + 2 (i.e., 1.5 log units below the quartz‐fayalite‐magnetite (QFM) buffer). Comparison of trace element concentrations (obtained by secondary ion mass spectrometry (SIMS) analysis) in experimental silicates with those of natural silicates supports the Fe‐Ti oxide‐derived oxygen fugacity of QFM ?1.8 ± 0.3 for this basalt (Herd et al., 2001). Experimental distribution coefficients, in conjunction with SIMS analyses of rims from the olivine and pyroxene xenocrysts in lithology A, as well as analyses of lithology A groundmass pigeonite cores, are used to calculate coexisting liquid concentrations of V and Cr. Liquid compositions derived from pigeonite xenocryst rims and groundmass pigeonite cores are similar, suggesting that the rims of orthopyroxene xenocrysts are overgrowths, which have not previously been accounted for when reconstructing the groundmass composition. This implies that the Eg composition requires modification. A similar exercise for the ferroan rims on olivine xenocrysts yields very different liquid compositions, indicating that these rims are not overgrowths but are part of the xenocryst assemblage. These results are shown to be consistent with the petrography of lithology A xenocrysts.  相似文献   

20.
The degree to which dust enrichment enhances the oxygen fugacity (fO2) of a system otherwise solar in composition depends on the dust composition. Equilibrium calculations were performed at 10?3 bar in systems enriched by a factor of 104 in two fundamentally different types of dust to investigate the iron oxidation state in both cases. One type of dust, called SC for solar condensate, stopped equilibrating with solar gas at too high a temperature for FeO or condensed water to be stabilized in any form, and thus has the composition expected of a nebular condensate. The other has CI chondrite composition, appropriate for a parent body that accreted from SC dust and low‐temperature ice. Upon total vaporization at 2300 K, both systems have high fO2, >IW. In the SC dust‐enriched system, FeO of the bulk silicate reaches ~10 wt% at 1970 K but decreases to <1 wt% below 1500 K. The FeO undergoes reduction because consumption of gaseous oxygen by silicate recondensation causes a precipitous drop in fO2. Thus, enrichment in dust having the composition of likely nebular condensates cannot yield a sufficiently oxidizing environment to account for the FeO contents of chondrules. The fO2 of the system enriched in water‐rich, CI dust, however, remains high throughout condensation, as gaseous water remains uncondensed until very low temperatures. This allows silicate condensates to achieve and maintain FeO contents of 27–35 wt%. Water‐rich parent bodies are thus excellent candidate sources of chondrule precursors. Impacts on such bodies may have created the combination of high dust enrichment, total pressure, and fO2 necessary for chondrule formation.  相似文献   

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