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1.
为探究石英闪长玢岩成因及幔源基性岩浆对斑岩铜矿的贡献,本文选取德兴矿床石英闪长玢岩开展了锆石U-Pb定年、Hf同位素和全岩地球化学研究。获得石英闪长玢岩LA-ICP-MS锆石U-Pb年龄为169 Ma,与成矿花岗闪长斑岩侵位时间一致,岩体为中侏罗世岩浆活动的产物。石英闪长玢岩具有低的SiO2(58.41%~63.12%)和K2O(1.68%~2.94%)含量及A/CNK值(0.85~1.04),富集大离子亲石元素和轻稀土元素,亏损高场强元素Nb、Ta、Ti和重稀土元素,属于钙碱性到高钾钙碱性系列岩石。具有相对亏损的锆石Hf同位素组成,εHf(t)=2.20~7.93(最大值7.93),指示其源区为岩石圈地幔。锆石稀土元素配分模式图显示出明显的正Ce异常,岩浆氧逸度(lg fO2)为-20.05~-6.66,达到磁铁矿-赤铁矿氧逸度等级,指示石英闪长玢岩结晶自高氧逸度岩浆。全岩地球化学特征显示,德兴石英闪长玢岩与成矿花岗闪长斑岩及其暗色包体符合岩浆混合的演化趋势,说明成矿花岗闪长斑岩可能是中侏罗世幔源基性岩浆和地壳酸性岩浆大规模混合作用的产物,并且石英闪长玢岩代表了岩浆混合过程中的幔源基性端员。结合前人研究成果,认为在中侏罗世伸展构造背景下,软流圈物质上涌导致新元古代受交代的岩石圈地幔部分熔融形成幔源基性岩浆,基性岩浆的底侵作用诱发下地壳物质熔融并与之发生一定程度的岩浆混合作用,形成了花岗闪长斑岩的母岩浆。高氧逸度幔源岩浆的加入可抑制斑岩体系硫化物的过早饱和,同时为德兴矿床注入了成矿所需的部分挥发分和金属元素。 相似文献
2.
华北克拉通在中生代时期发生大规模的岩石圈减薄,伴生的早白垩世火山岩为研究克拉通破坏提供了窗口,但其中镁铁质火山岩成因和岩浆源区性质的争议,制约了对克拉通破坏机制和中生代岩石圈减薄结束时间的认识。本文用激光剥蚀电感耦合等离子质谱（LA-ICP-MS）方法对兴城玄武玢岩中的锆石、金红石进行了系统的微量元素分析,以揭示岩浆源区性质及其演化,并进一步探讨了华北克拉通中生代岩石圈减薄的机制和结束时间。锆石tTi温度计计算结果表明,兴城玄武玢岩锆石结晶温度为695~779℃,平均温度为730℃,说明玄武玢岩可能起源于俯冲带地幔楔交代橄榄岩。微量元素分析结果显示,锆石富集HREE,LREE与HREE分异明显,Nb、Ti亏损,Th、U和Hf相对富集,Ce、Eu呈不同程度的正、负异常;金红石Nb、Ti、Hf等高场强元素呈不同程度富集,Sr明显亏损,无明显的Ce、Eu异常。微量元素特征也显示玄武玢岩岩浆起源于岩石圈地幔交代橄榄岩,后期经历了氧化作用和分离结晶作用。结合区域内相关地质资料,认为兴城玄武玢岩岩浆为古老岛弧型岩浆。华北克拉通中生代岩石圈减薄的结束时间可约束到早白垩世晚期（约105 Ma）,高角度俯冲的古太平洋板块回撤为华北克拉通岩石圈减薄的一级动力学机制,热化学侵蚀或拆沉为二级机制。 相似文献
3.
太行山-大兴安岭构造岩浆带中生代侵入岩Nd、Sr、Pb同位素特征及物质来源探讨 总被引：3，自引：7，他引：3
太行山-大兴安岭构造岩浆带是中国东部中生代大规模岩浆活动的集中区，它纵跨华北克拉通和兴蒙海西造山带两个大地构造单元，既是我国东部规模最大的北北东向深大断裂带之一，又是我国东部北北东向延伸的地壳厚度陡变带与重力异常高梯度带，因而具有十分重大的地质意义。本文针对研究区在中生代岩浆活动物质来源认识方面的不足，首次对太行山-大兴安岭整个构造岩浆带40余个代表性岩体的Nd、Sr、Pb同位素地球化学特征进行了全面系统的研究，发现不同区段(南、北太行山地区、大兴安岭中-南地区)、不同侵入期次(早、中、晚)岩石具有明显不同的Nd、Sr、Pb同位素特征，可以推断其岩浆源区性质各不相同：南太行山地区基-中性岩浆均来源于富集地幔储库；北太行山地区早期基-中性岩浆主要来源于富集地幔的部分熔融；中期中-酸性岩浆来源与下地壳关系密切；晚期富碱质中-酸性岩浆来源可能与下地壳、甚至中地壳物质有关；大兴安岭地区中-酸性岩浆来源与亏损地幔关系密切，可能源自与亏损地幔有联系的年轻的下地壳。由此表明，中生代华北克拉通地区岩石圈地幔为富集地幔，而兴蒙造山带地区岩石圈地幔则为亏损地幔。此外，根据岩石的Nd模式年龄，初步认为2543～1485Ma可能指示华北克拉通岩石圈地幔发生富集作用的时间，而983～540Ma则可能为大兴安岭地区地壳生长的一个重要时期。 相似文献
4.
山东中侏罗世-早白垩世侵入岩的锆石Hf同位素组成及其意义 总被引：4，自引：2，他引：4
对山东中侏罗世-早白垩世侵入岩中锆石的原位Hf同位素分析显示,形成于晚太古代(上交点年龄～2.5Ga)的继承锆石具有正的ε_(Hf)(t)值( 8～ 1),Hf同位素模式年龄集中在2.6～2.8Ga,与辽宁古生代金伯利岩中基性下地壳捕虏体中锆石Hf组成和Hf模式年龄十分一致,Hf模式年龄也与研究区变质岩和花岗岩的全岩Nd模式年龄相同,因此,这些继承锆石来自于晚太古代由岩浆底侵形成的基性下地壳。新生锆石出现在继承锆石周围或者以独立颗粒出现,其U-Pb年龄为177Ma和132～126Ma,ε_(Hf)(t)值均为负值(-23～-1)。山东中生代侵入岩的形成与富集岩石圈地幔,亏损地幔和地壳三个端员之间的相互作用有关。其中根据来源于晚太古代下地壳的侏罗纪铜石二长花岗岩限定的研究区下地壳ε_(Hf)(t)平均值为-20,根据来源于富集岩石圈地幔的早白垩纪沂南辉长岩限定的富集地幔端员的ε_(Hf)(t)为-16。部分样品锆石ε_(Hf)(t)变化非常大(-20～-1),示踪了岩浆作用过程中亏损地幔物质的参与程度的逐渐增强。这种变化是华北晚中生代岩石圈大规模减薄作用的结果。 相似文献
5.
华北克拉通东部古太平洋板块俯冲与回撤作用:来自辽西兴城地区晚中生代花岗质岩石的记录与启示 总被引：2，自引：0，他引：2
目前对于华北克拉通东部晚中生代花岗质岩石的成因仍存在地幔柱、加厚/拆沉下地壳部分熔融、俯冲板片脱水导致地壳熔融等不同认识。辽西兴城地区晚中生代花岗质岩石主要由二长花岗岩、石英闪长岩、花岗斑岩和石英正长岩组成,岩浆成因锆石U-Pb同位素定年结果显示岩浆活动主要发生于晚侏罗世(156Ma)、早白垩世早期(139Ma)、早白垩世中期(130～125Ma)。岩石地球化学测试分析结果显示岩石属于高钾钙碱性系列且具有富集K、Pb等大离子亲石元素而相对亏损Nb、Ta、Ti等高场强元素等活动陆缘岩浆岩特点,表明辽西地区晚中生代岩浆活动的发生与俯冲作用有关。晚侏罗世-早白垩世早期(156～139Ma)花岗质岩石地球化学特征与I型花岗岩类似,同时具有富集的Hf同位素组成(εHf(t)=-22.70～-18.66)和古老的Hf同位素二阶段模式年龄(tDM2=2387～2767Ma),其初始岩浆可能来源于古老中上地壳的部分熔融;形成于130Ma的花岗质岩石同样具有与I型花岗岩相类似的岩石地球化学特征,但其Hf同位素组成突变为亏损(εHf(t)=+3.64～+6.22、tDM1=537～969Ma),其初始岩浆起源于新元古代新生地壳物质的部分熔融并混入少量亏损地幔物质组分;形成于125Ma的花岗质岩石为碱性A型花岗岩,岩石地球化学特征与其他岩石有所不同,具有负的εHf(t)值(-17.30～-11.56)和相对古老的Hf同位素二阶段年龄(tDM2=1917～2278Ma),初始岩浆可能起源于较为古老的中下地壳部分熔融并有幔源物质的参与。华北克拉通东部形成于160～139Ma的花岗质岩石具有I型、高钾钙碱性、与埃达克质岩石类似的高Sr/Y、低Y含量特征和富集的Hf同位素组成,而形成于130～120Ma的花岗质岩石具有A型、碱性、与典型岛弧岩浆岩类似的岩石地球化学特征和相对亏损的Hf同位素组成,同时晚中生代岩浆活动具有向洋年轻化的特点,表明华北克拉通东部156～139Ma期间可能受到古太平洋板块的持续俯冲作用,而139～130Ma古太平洋俯冲板片开始回撤,130～125Ma进入古太平洋俯冲板片持续回撤导致的强烈区域伸展作用阶段。古太平洋俯冲板片脱水交代岩石圈地幔并形成幔源岩浆,幔源岩浆不断底侵作用于古老/新生地壳使其发生部分熔融为花岗质岩石提供岩浆来源。 相似文献
6.
胶辽半岛金伯利岩中地幔捕虏体岩石学特征：古生代岩石圈地幔及其不均一性 总被引：29，自引：5，他引：24
华北东部古生代岩石圈地幔经历过复杂的多旋回多阶段熔融岩浆、重结晶、变质和剪切变形历史,因而岩石组成、结构复杂.地幔橄榄岩的主元素、地幔矿物特别是金刚石中的包裹体的Mg#值及Cr#值等显示古生代岩石圈地幔高度难熔亏损玄武质的成分特征,而地幔橄榄岩的不相容元素、同位素显示高度富集的特点.这种高难熔和强富集两重性是克拉通岩石圈地幔的特征.Pb同位素反映华北东部古生代岩石圈地幔具冈瓦纳大陆地幔的特点.复县和蒙阴古生代岩石圈地幔尽管都表现为太古代克拉通地幔的特征,但存在着不均一性,前者受克拉通化后的深部作用影响强于后者.与新生代地幔Sr、Nd同位素对比表明富集的古生代岩石圈地幔向亏损新生代的地幔转变和减薄伴有新生地幔物质对古老岩石圈的置换和混合作用. 相似文献
7.
河北承德盆地114 Ma大北沟组玄武岩地球化学及其对华北克拉通岩石圈地幔减薄作用的制约 总被引：4，自引：0，他引：4
华北克拉通罕见年龄界于120～100Ma的火山岩。承德盆地大北沟组火山岩下部主要由柱状节理橄榄玄武岩组成,中上部主要由安山岩组成。对紧邻玄武岩的上覆安山岩的火山锆石U-PbLA-ICPMS定年结果表明,形成年龄为(113.6±0.87)Ma,代表了该套火山岩的喷发年龄,表明它们形成于早白垩世晚期。对3件玄武岩样品的分析结果表明,它们亏损高场强元素(Nb、Ta、Zr、Hf),初始87Sr/86Sr同位素比值为0.7059,εNd(114Ma)为-11.04,具有富集型岩石圈地幔的特征。但该套玄武岩的主量和微量元素特征则介于华北克拉通中生代年龄>120Ma具古老富集型地幔特征的玄武岩和年龄<100Ma具亏损软流圈性质的玄武岩之间,表明113.6Ma时华北克拉通岩石圈地幔在元素组成方面已具有由富集地幔向亏损型软流圈地幔转变的特征。大北沟组玄武岩的地球化学特征表明,114Ma时华北克拉通岩石圈地幔已减薄。 相似文献
8.
华北克拉通北缘在早石炭世晚期—中二叠世出露大量中酸性侵入岩体,但基性-超基性岩体出露较少,因而缺乏对该时期地幔性质的认识。笔者对位于内蒙古地轴以南百余千米的孤山子超基性岩体开展锆石U-Pb定年、微量元素、Lu-Hf同位素组成测试分析。结果显示,孤山子超基性岩体LA-ICP-MS锆石U-Pb加权平均年龄为296.9±2.6 Ma,为早二叠世的岩浆活动产物。锆石(样号:GSZ-B3)微量元素含量低,具有强Ce正异常和弱Eu负异常特征以及较低的εHf(t)=-1.9~-7.5(n=17),表明其源区主要为富集的岩石圈地幔。锆石tDM、tCDM远大于其U-Pb年龄,表明岩石圈地幔形成过程中有再造古老地壳加入。对比内蒙古地轴上的同时代波罗诺岩体含角闪辉长岩(297±1 Ma)的锆石εHf(t)(-17.0~-14.1),孤山子超基性岩体的锆石εHf(t)明显偏大,表明孤山子超基性岩体的源区富集程度相对较小。此外,孤山子超基性岩体还有2个锆石测点εHf(t)分别为3.2、4.0,指示母岩浆中有少量亏损幔源物质加入,这暗示了华北克拉通北缘局部地区,在晚古生代已有岩石圈拉张减薄的趋势。 相似文献
9.
鲁西早白垩世基性侵入岩的锆石Hf同位素组成变化及其成因 总被引：1，自引：0，他引：1
鲁西北部地区的淄博和临朐辉长闪长岩的锆石原位U-Pb定年分析显示,它们分别形成于128±2Ma和132±1Ma,与鲁西早白垩世大规模岩浆活动时间一致,是华北克拉通岩石圈减薄过程的岩浆活动产物。与鲁西北部同时期的济南、邹平辉长岩相比,淄博和临朐辉长闪长岩的锆石εHf(t)值(分别为-5.1～-2.4和-2.4～+3.2)明显较高,并具有相对年轻的亏损地幔Hf模式年龄TDM(分别为876～984Ma和639～867Ma),对应于相对高的全岩εNd(t)值,指示其岩浆源区有更大比例的软流圈地幔物质贡献。鲁西北部地区的早白垩世基性侵入岩的岩浆源区以华北克拉通内部的古老富集岩石圈地幔为主,从华北克拉通内部往郯庐断裂带锆石εHf(t)值显示出升高趋势,表明软流圈地幔物质的参与比例增大。郯庐断裂带是导致鲁西地区早白垩世基性岩浆活动时空不均一性的重要岩石圈薄弱带。 相似文献
10.
基性的碱性岩通常形成于伸展环境,具有富碱和不相容元素富集等地球化学特征,它们来源于深部富集地幔,是探索地幔交代和深部地球动力学的"岩石探针"。华北克拉通北缘燕辽裂谷内发育团山子组和大红峪组钾质火山岩以及侵入串岭沟组的钠质岩脉,它们共同组成了长城纪碱性岩系列。本文利用SHRIMP锆石U-Pb同位素方法对平谷-蓟县地区钾质火山岩进行年代学测试,获得误差范围内一致的年龄:1613±11Ma、1634±18Ma(团山子组)和1605±19Ma、1630±10Ma(大红峪组),说明钾质火山岩喷发的持续时间短,且与侵入串岭沟组的钠质岩脉同期(~1625Ma)。钾质火山岩和钠质岩脉的锆石Hf-O同位素组成相似:εHf(t)=-2~+4(正态分布峰值+0.6),δ^18O=4.5‰~7.7‰明显高于正常地幔锆石的值,钾质火山岩和钠质岩脉的母岩浆源自相同的富集地幔,源区受到高δ^18O物质的交代作用而富含钾质矿物,如角闪石或金云母。华北克拉通中-新元古代岩浆事件是伸展环境的产物,其锆石Hf同位素组成在~1.32Ga发生突变,由富集到亏损,暗示岩石圈地幔经历强烈的交代改造作用,可能成为检验地幔柱或者板块深俯冲驱动超大陆裂解机制的窗口。 相似文献
11.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations. 相似文献
12.
针对兖州煤田下组煤深部开采受奥灰高承压水威胁以及当地大型煤化工企业生产用水量大的现状,在已进行的水文地质勘探及放水试验基础上,评价奥灰富水性,并采用有限差分法进行奥灰疏水降压数值模拟研究,提出水煤共采观点。研究结果表明:兖州煤田深部奥灰水压高,合理布置水煤共采孔,可以实现奥灰水位的有效疏降,疏降中心区水位最大降深可达110 m,突水系数显著下降,提高了下组煤开采的安全性;同时可提供煤化工43200 m3/d的供水量,能达到可持续的、水资源保护性的供水效果,实现下组煤的水煤共采。 相似文献
13.
《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2. 相似文献
14.
Hirokazu Fujimaki 《Contributions to Mineralogy and Petrology》1986,94(1):42-45
Concentration ratios of Hf, Zr, and REE between zircon, apatite, and liquid were determined for three igneous compositions: two andesites and a diorite. The concentration ratios of these elements between zircon and corresponding liquid can approximate the partition coefficient. Although the concentration ratios between apatite and andesite groundmass can be considered as partition coefficients, those for the apatite in the diorite may deviate from the partition coefficients. The HREE partition coefficients between zircon and liquid are very large (100 for Er to 500 for Lu), and the Hf partition coefficient is even larger. The REE partition coefficients between apatite and liquid are convex upward, and large (D=10–100), whereas the Hf and Zr partition coefficients are less than 1. The large differences between partition coefficients of Lu and Hf for zircon-liquid and for apatite-liquid are confirmed. These partition coefficients are useful for petrogenetic models involving zircon and apatite. 相似文献
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17.
The distribution of Cu, Co, As and Fe was studied downstream from mines and deposits in the Idaho Cobalt Belt (ICB), the largest Co resource in the USA. To evaluate potential contamination in ecosystems in the ICB, mine waste, stream sediment, soil, and water were collected and analyzed for Cu, Co, As and Fe in this area. Concentrations of Cu in mine waste and stream sediment collected proximal to mines in the ICB ranged from 390 to 19,000 μg/g, exceeding the USEPA target clean-up level and the probable effect concentration (PEC) for Cu of 149 μg/g in sediment; PEC is the concentration above which harmful effects are likely in sediment dwelling organisms. In addition concentrations of Cu in mine runoff and stream water collected proximal to mines were highly elevated in the ICB and exceeded the USEPA chronic criterion for aquatic organisms of 6.3 μg/L (at a water hardness of 50 mg/L) and an LC50 concentration for rainbow trout of 14 μg/L for Cu in water. Concentrations of Co in mine waste and stream sediment collected proximal to mines varied from 14 to 7400 μg/g and were highly elevated above regional background concentrations, and generally exceeded the USEPA target clean-up level of 80 μg/g for Co in sediment. Concentrations of Co in water were as high as in 75,000 μg/L in the ICB, exceeding an LC50 of 346 μg/L for rainbow trout for Co in water by as much as two orders of magnitude, likely indicating an adverse effect on trout. Mine waste and stream sediment collected in the ICB also contained highly elevated As concentrations that varied from 26 to 17,000 μg/g, most of which exceeded the PEC of 33 μg/g and the USEPA target clean-up level of 35 μg/g for As in sediment. Conversely, most water samples had As concentrations that were below the 150 μg/L chronic criterion for protection of aquatic organisms and the USEPA target clean-up level of 14 μg/L. There is abundant Fe oxide in streams in the ICB and several samples of mine runoff and stream water exceeded the chronic criterion for protection of aquatic organisms of 1000 μg/L for Fe. There has been extensive remediation of mined areas in the ICB, but because some mine waste remaining in the area contains highly elevated Cu, Co, As and Fe, inhalation or ingestion of mine waste particulates may lead to human exposure to these elements. 相似文献
18.
E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
19.
The dielectric constants and dielectric loss values of 4 Ca-containing minerals were determined at 1 MHz using a two-terminal method and empirically determined edge corrections. The results are: vesuvianitel κ′ a=9.93 tan δ=0.006 κ′ c=9.79 tan δ=0.005 vesuvianitel κ′ a=10.02 tan δ=0.002 κ′ c=9.85 tan δ=0.003 zoisite1 κ′ a =10.49 tan δ=0.0006 κ′ b =15.31 tan δ=0.0008 κ′ c=9.51 tan δ=0.0008 zoisite2 κ′ a =10.55 tan δ=0.0011 κ′ b =15.45 tan δ=0.0013 κ′ c=9.39 tan δ=0.0008 epidote κ′ 11= 9.52 tan δ=0.0008 κ′ 22=17.1 tan δ=0.0009 κ′ 33= 9.37 tan δ=0.0006 fluorapatite1 κ′ a =10.48 tan δ=0.0008 κ′ c = 8.72 tan δ=0.0114 fluorapatite2 κ′ a =10.40 tan δ=0.0010 κ′ c=8.26 tan δ=0.0178 The deviation (δ) between measured dielectric polarizabilities as determined from the Clausius-Mosotti equation and those calculated from the sum of oxide polarizabilities according to α D (mineral)=∑ α D (oxides) for vesuvianite is ～ 0.5%. The large deviations of epidote and zoisite from the additivity rule with Δ=+ 10.1 and + 11.7%, respectively, are attributed to “rattling” Ca ions. The combined effects of both a large F thermal parameter and possible F-ion conductivity in fluorapatite are believed to be responsible for Δ=+2–3%. Although variation of oxygen polarizability with oxygen molar volume (Vo) is believed to affect the total polarizabilities, the variation of Vo in these Ca minerals is too small to observe the effect. 相似文献
20.
Geochemistry and petrology of selected coal samples from Sumatra, Kalimantan, Sulawesi, and Papua, Indonesia 总被引：4，自引：1，他引：3
Harvey E. Belkin Susan J. Tewalt James C. Hower J.D. Stucker J.M.K. O'Keefe 《International Journal of Coal Geology》2009,77(3-4):260-268
Indonesia has become the world's largest exporter of thermal coal and is a major supplier to the Asian coal market, particularly as the People's Republic of China is now (2007) and perhaps may remain a net importer of coal. Indonesia has had a long history of coal production, mainly in Sumatra and Kalimantan, but only in the last two decades have government and commercial forces resulted in a remarkable coal boom. A recent assessment of Indonesian coal-bed methane (CBM) potential has motivated active CBM exploration. Most of the coal is Paleogene and Neogene, low to moderate rank and has low ash yield and sulfur (generally < 10 and < 1 wt.%, respectively). Active tectonic and igneous activity has resulted in significant rank increase in some coal basins. Eight coal samples are described that represent the major export and/or resource potential of Sumatra, Kalimantan, Sulawesi, and Papua. Detailed geochemistry, including proximate and ultimate analysis, sulfur forms, and major, minor, and trace element determinations are presented. Organic petrology and vitrinite reflectance data reflect various precursor flora assemblages and rank variations, including sample composites from active igneous and tectonic areas. A comparison of Hazardous Air Pollutants (HAPs) elements abundance with world and US averages show that the Indonesian coals have low combustion pollution potential. 相似文献