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1.
在青藏高原腹地的沱沱河—开心岭地区的区域地质调查中新发现的高铝玄武岩,利用激光等离子体质谱法(LA-ICP-MS)测试的锆石206Pb-238U年龄(380.1±5.6)Ma(MSWD=0.21),表明其形成时代为晚泥盆世。玄武岩具有高Al2O3(平均20.16%)和低SiO2(平均48.32%)、低Na2O(平均2.29%)、低K2O(平均0.39%)、低TiO2(均值0.754%)、低Alk(均值2.68%)的特点,并有(低钾)拉斑玄武系列向钙碱性系列过渡的特征,CIPW标准矿物属石英拉斑玄武岩(Q含量2.77%~9.32%),高铝、低钾、贫碱的特点与典型的高铝玄武岩一致。岩石的稀土总量均一且总体偏低,ΣREE含量为32.69×10-6~41.01×10-6,稀土配分模式近水平,δEu为1.12~1.28,均值为1.2,具有较强的正Eu和Ce异常。岩石富集亲石元素LILE,亏损高场强元素,具有较高Sr、Ba、Ce正异常和Nb负异常,岩石化学特点及相关的一系列岩石化学图解均表明其为岛弧玄武岩,表明分布于昌都—兰坪地块的晚泥盆世高铝玄武岩形成于岛弧环境,它的发现为三江地区古生代火山地层的确定、古特提斯洋的演化提供了丰富的资料。  相似文献   

2.
西藏阿里地区火山岩的岩石系列及特征   总被引:2,自引:0,他引:2  
西藏阿里地区冈底斯构造带分布有早白垩世的玄武岩-安山岩-英安岩系列及晚白垩—第三纪的玄武岩-安山岩-流纹岩系列,它们分别属于拉斑玄武及钙碱性系列。前者主要由地幔导源的玄武岩浆经分离结晶作用形成,而钙碱性系列主要由混合作用及同化作用形成。此外其岩浆房的fO_2与fH_2O高,液相线温度偏低并与地壳导源的岩基活动有密切的关系.  相似文献   

3.
对卡拉岗组火山岩岩石化学特征分析和研究结果表明,火山岩碱性程度为碱性-钙碱性,岩石系列为高铝玄武岩系列、拉斑玄武系列碱性玄武岩系列,求得钙碱指数为52,属张性环境,在全碱-二氧化硅图上样品落入玄武岩区及流纹岩区,分异指数频率曲线表明具有大陆拉张的双峰式特点,认为该区下二叠统计卡拉岗组火山岩产于双峰式大陆拉张构造环境。  相似文献   

4.
作为华北克拉通破坏的响应,华北地区广泛发育新生代玄武岩。尽管前人对这些玄武岩做了大量的研究,但是对其地幔源区性质及成因机制仍存在激烈争论。本文首次报道山东山旺新生代玄武岩中橄榄石斑晶捕获的熔体包裹体的研究结果。相对于全岩成分,熔体包裹体的成分更加复杂,碱性玄武岩中熔体包裹体不仅有碱性玄武质,碱性粗面玄武质成分,同时还有拉斑玄武质成分。这指示新生代玄武岩的形成主要是受控于贫硅与富硅熔体的混合。碱性玄武岩中的熔体包裹体中存在拉斑玄武质熔体意味着在山东地区新生代玄武岩中首次发现拉斑玄武质组分,暗示新生代玄武岩地幔源区比之前认识的更加复杂和不均一,碱性玄武岩地幔源区同样存在富硅组分。综合华北、东北新生代玄武岩数据,可以把这些玄武岩划分为三类:低硅,高硅以及中间类型。低硅玄武岩具有高的~(176)Hf/~(177)Hf,~(143)Nd/~(144)Nd,~(206)Pb/~(204)Pb,FeO,Na_2O+K_2O和Sm/Yb,低的SiO2_和Ba/Th比值;高硅玄武岩具有低的~(176)Hf/~(177)Hf,~(143)Nd/~(144)Nd,~(206)Pb/~(204)Pb,FeO,Na_2O+K_2O和Sm/Yb,高SiO_2和Ba/Th比值,(Th/La)_N1和(Th/Ba)_N1。结合实验岩石学数据推断低硅玄武岩形成于贫硅辉石岩和富含角闪石的岩石的部分熔融,这些辉石岩和富含角闪石的岩石形成于近期的岩石圈地幔交代事件;高硅玄武岩的地幔源区含有富硅的古老大洋下地壳组分,结合实验岩石学数据推断高硅玄武岩形成于富硅辉石岩和橄榄岩的部分熔融。  相似文献   

5.
新疆北部科克森套地区玄武岩出露于超镁铁质岩体的北侧,与玄武质凝灰岩共生,厚度达50~80 m;玄武岩普遍具有片理化、斑状结构;岩石地球化学特征表明,该玄武岩属低碱(Na2O+K2O均<3%,σ值在0.60~1.19)、低钛(TiO2在0.73%~1.22%)、富镁(MgO在7.43%~9.72%)的拉斑玄武岩系列,具有原始岩浆特征(其Mg#值在0.65~0.71),稀土总量较低(ΣREE在29.68×10-6~44.91×10-6),稀土及微量元素配分曲线平缓,可能形成于洋中脊构造环境。该区玄武岩的发现和岩石地球化学研究,佐证了科克森套蛇绿岩套的存在。  相似文献   

6.
分布于新疆西昆仑东段北缘(策勒—于田—民丰一线以南)的中新元古代火山岩主要为一套浅变质的(玄武)安山岩,夹有极少量的流纹岩。安山岩的SiO2在52.36%~58.30%之间,平均为54.55%,TiO2均低于0.3%,平均为0.22%。Na2O+K2O为1.70%~3.75%,Na2O均高于K2O,Na2O/K2O在2.44~4.61之间,M/F为0.62~0.78,MgO/(MgO+TFe)在0.36~0.45之间。岩石硅碱成分显示以钙碱性为主。稀土元素研究表明,安山岩的稀土总量低,在15.52×10-6~17.92×10-6之间,接近大洋拉斑玄武岩。安山岩的(La/Yb)N为0.69~1.33,(Ce/Yb)N为0.75~1.17,轻重稀土分异不明显。除1028-I3号样的δEu为0.6之外,其余样品的δEu在0.91~1.13之间,基本没有Eu异常。在稀土元素的球粒陨石配分曲线上,所有安山岩形成一个群体,稀土配分模式接近大洋拉斑玄武岩。岩石的微量元素安山岩的Th/Yb为0.04~0.10,Th/Ta=5.92~11.22,Zr/Hf=20.46~29.40,Th/Y之比为0.04~0.08。微量元素的N—MORB配分模式显示岩石富集Sr、Ba、Rb、K、Th等大离子亲石元素,Cr亏损,与拉斑质的火山弧玄武岩相似。综合分析火山岩的岩石学、岩石地球化学特征,结合区域构造背景,认为该套火山岩产于洋内弧环境。  相似文献   

7.
通过对新疆卡拉麦里姜巴斯套组火山岩野外地质特征、岩石学和高精度同位素年代学的研究,发现姜巴斯套组火山岩具典型双峰式组合,岩石类型包括玄武岩-酸性火山碎屑岩-玄武粗面安山岩;得到玄武粗面安山岩LA-ICP-MS锆石U-Pb年龄为(319.8±2)Ma(加权均方偏差值为3),表明姜巴斯套组火山岩形成于早石炭世谢尔普霍夫阶。对火山岩地球化学特征的研究表明,姜巴斯套组火山岩钙碱性系列、高钾钙碱性系列和钾玄岩系列岩石兼而有之,岩石的稀土元素配分曲线均为轻稀土元素富集型,无明显Eu异常,玄武岩和玄武粗面安山岩具有K正异常和Sr负异常,酸性火山碎屑岩表现出Nb、Ta和Ti显著亏损。总体来说,姜巴斯套组火山岩富集大离子亲石元素,相对亏损高场强元素。玄武岩和玄武粗面安山岩表现出大陆裂谷(大陆板内拉张区域)岩石特征;酸性火山碎屑岩表现出岛弧或者活动大陆边缘岩石属性。总之,姜巴斯套组火山岩形成于卡拉麦里洋盆闭合碰撞造山后的拉张伸展环境,卡拉麦里地区在早石炭世末期就进入了碰撞后的陆内伸展拉伸阶段。  相似文献   

8.
近年来,研究认为在地幔深度发生的岩浆与岩浆之间的相互作用过程能够作为解释板内玄武岩组成不均一性的机制之一(Herzberg,2011)。然而,迄今为止并没有十分有力的地球化学证据支持这一模式。本次研究选择中国东南部福建龙海地区的小规模溢流玄武岩作为研究对象,通过元素和同位素地球化学研究,解释了在地幔深度碱性玄武质岩浆和拉斑质岩浆之间的相互作用过程。龙海玄武岩主要由拉斑玄武岩组成,含少量碱性玄武岩,w(Si O2)变化相对较小(49.0%~52.8%),但全碱质量分数显著变化(w(K2O+Na2O)=2.3%~6.4%)。依据玄武岩的演化程度,我们将其划分为低钛(演化程度低,Ti O2/Mg O0.25,为拉斑玄武岩)和高钛(演化程度高,Ti O2/Mg O0.25,主要为碱性玄武岩,含少量拉斑玄武岩)两类玄武岩。对低钛玄武岩的原始岩浆计算发现,其具有低的Ca O含量和高的Fe O/Mn O比值,并且相图上落在了4 GPa下与斜方辉石、单斜辉石和石榴子石相平衡的区域,暗示其源区主要岩性为辉石岩。但是,这些玄武岩的Sm/Yb比与Ti/Gd、Zr/Hf比之间呈现很好的线性关系,暗示低钛玄武岩源区经历了两端元混合过程。另一端元具有低的Ti/Gd比和高的Zr/Hf比,表明其源区另一种岩性为碳酸盐化的橄榄岩。高钛玄武岩具有与低钛玄武岩几乎一致的Sr-Nd-Pb-Hf同位素组成,暗示它们具有相似的成因。但是,随着高钛玄武岩Sm/Yb比值的增加,其表现出显著的石榴子石效应。这一组成特征,以及其稀土元素的交叉配分特征,可以用单斜辉石和石榴子石的分离结晶来解释。而高钛玄武岩在相图上同样落在了石榴子石-辉石区域,也支持其曾经与石榴子石和单斜辉石相平衡。由于石榴子石的分离结晶通常深度大于70 km,要大于研究区的岩石圈厚度,因此该分离结晶过程应该发生在软流圈。而硅饱和的拉斑质岩浆(起源自辉石岩)与硅不饱和的碱性岩浆(起源自碳酸盐化的橄榄岩)在地幔深部相遇,就能够诱发该分离结晶作用:富硅拉斑质岩浆+贫硅碱性岩浆→富硅碱性岩浆+石榴子石+单斜辉石。基于上述观察,我们提出高钛玄武岩形成于拉斑质岩浆与碱性岩浆之间的相互作用及其伴随的深部岩浆演化过程。  相似文献   

9.
长白山区二道白河流域早更新世玄武质熔岩的成因   总被引:2,自引:1,他引:1  
马晗瑞  杨清福  盘晓东  武成智  陈聪 《岩石学报》2015,31(11):3484-3494
采用岩石化学和同位素分析方法,研究了二道白河流域早更新世玄武质熔岩的成因。玄武质熔岩由钠质拉斑玄武岩和钾质粗面玄武岩、玄武质粗面安山岩组成。它们的REE分配形式比较相近,表明它们来自共同的源区。Sr、Nd、Pb同位素示踪表明,二道白河流域早更新世玄武质熔岩岩浆源区接近于似原始地幔。它们的Mg#=100Mg O/(Mg O+Fe O)低于中国东部新生代玄武岩原始岩浆的Mg#(60~68),Ni(27.76×10-6~200.6×10-6)低于原始地幔,Rb/Sr(0.05~0.09)、Ba/Rb(15.64~264)高于原始地幔,说明这些岩石不是源自原始地幔。玄武质熔岩的DI变化于42~67,具有高Ca、高Sr、Eu正异常,微量元素图解显示玄武岩保留部分熔融趋势,粗面玄武岩、玄武质粗安岩具有结晶分异趋势,岩浆上升过程中发生了不同程度的地壳混染作用。玄武质熔岩的Nb/Ta之比为14.8~15.8,与勘察加半岛深俯冲带火山类似。Nb/Ta-(Na2O-K2O)关系图解显示研究区玄武质岩浆的形成与俯冲板片的部分熔融有关。  相似文献   

10.
闽北早古生代岛弧火山岩的岩石地球化学特征   总被引:1,自引:0,他引:1  
陈汉林  曾华生 《矿物学报》1994,14(2):186-194
作者系统地研究了福建政和早古生代岛弧火山岩的岩石地球化学特征。研究表明该火山岩是以岛弧拉斑玄武岩-钙碱性火山岩组合为特征的岛弧火山岩系列,并具有从拉斑系列向钙碱性系列演化的特征;该火山岩源于亏损地幔,并且受到一定的陆壳物质混染,基性的拉斑玄武质系列受到陆壳物质混染较少,而中性钙碱性系列则受到较大程度混染。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

13.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

14.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

15.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

16.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

17.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

18.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

19.
滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.  相似文献   

20.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

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