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1.
Stress dependence of recrystallized-grain and subgrain size in olivine   总被引：1，自引：0，他引：1  
New experiments on Mt. Burnet dunite have been carried out to evaluate the effects of important physical parameters on recrystallized-grain size and subgrain size in olivine deforming under steady-state conditions. The experiments, done under both wet and dry conditions in a Griggs solid-pressure-medium apparatus, were conducted in constant strain rate, constant stress and stress relaxation modes at 10 kbar confining pressure, temperatures from 1000°C to 1300°C, strain rates from 10−4 to 10−8/sec and stress differences of from 0.5 to 10 kbar. For dunite deformed under wet conditions, recrystallized-grain size is slightly temperature-dependent but under dry conditions it is only stress-dependent with D = 137 σ−1.27 for D in μm and σ in kbar. Subgrain sizes also depend only on stress; for the dry experiments d = 28 σ−0.62 and for the wet ones d = 15 σ−0.69. Subgrain sizes decrease with increasing stress but do not increase with decreasing stress and hence record only maximum stress levels. Recrystallized-grain sizes adjust to both increasing and decreasing stress levels, at minimal strains and times, and thus record the stress history. Because of this and of the inherent stability of recrystallized grains, this technique is regarded as more reliable than the subgrain size and free dislocation density and curvature methods for estimating stress magnitudes in tectonites having deformed in the steadystate.  相似文献   

2.
Room-temperature torsional-shear strengths of 1.27-cm-diameter × 0.25-cm-high disks of Nevada Test Site “Hardhat” granodiorite and a Mt. Burnette, Alaska, dunite were determined to about 90 kbar. Tests, for the most part, were run under linearly increasing pressure at constant rates of applied twist: about 3–30° at 5.73 · 10−4–10−2 degr./sec for granodiorite, and 18° at 5.73 · 10−3 and 10−2 degr./sec for dunite. Transitions are observed in the rate of shear-strength change for the granodiorite at about 15, 35 and 80 kbar. Minor and recoverable instabilities in strength occur over the pressure range 15–80 kbar. Beyond about 80 kbar, the shear strength increases sharply and is terminated with a strain-release of explosion-like violence. Strain rate showed some influence on strength and magnitude of energy-release at higher pressures. Residual microstructures showed that, below 15 kbar, intragranular extensional fracturing, intergranular sliding, and bulk consolidation mainly occur. Between 15 and 35 kbar, intragranular undulatory extinction, random and crystallographic ruptures, and initial intragranular slip are observed. The predominant mechanisms between 35 and 80 kbar are an increasing frequency of intragranular slip, and networks of short, irregular, intragranular ruptures. Bulk fracturing and faulting were not observed. Samples stressed to explosion-like failure showed extensive crystal fragmentation, and series of parallel bands. Alternate bands were birefringent and isotropic, respectively, and extended over a considerable part of the samples. Dunite showed a transition from diminishing to increasing shear strength at about 80 kbar, but no explosion-like release of strain energy to 95 kbar. Comparative data to 70 kbar also are given for a slightly serpentinized dunite, a granite, a gneiss, three extrusive porphyries, and a marble. X-ray diffraction powder patterns of all stressed samples revealed only a broadening of peaks and a reduction of intensities from higher levels of stress.  相似文献   

3.
Vp and Vs values have been measured experimentally and calculated for granulite-facies lower crustal xenoliths from central Ireland close to the Caledonian Iapetus suture zone. The xenoliths are predominantly foliated and lineated metapelitic (garnet–sillimanite–K-feldspar) granulites. Their metapelitic composition is unusual compared with the mostly mafic composition of lower crustal xenoliths world-wide. Based on thermobarometry, the metapelitic xenoliths were entrained from depths of c. 20–25 ± 3.5 km and rare mafic granulites from depths of 31–33 ± 3.4 km. The xenoliths were emplaced during Lower Carboniferous volcanism and are considered to represent samples of the present day lower crust.Vp values for the metapelitic granulites range between 6.26 and 7.99 km s− 1 with a mean value of 7.09 ± 0.4 km s− 1. Psammite and granitic orthogneiss samples have calculated Vp values of 6.51 and 6.23 km s− 1, respectively. Vs values for the metapelites are between 3.86 and 4.34 km s− 1, with a mean value of 4.1 ± 0.15 km s− 1. The psammite and orthogneiss have calculated Vs values of 3.95 and 3.97 km s− 1, respectively.The measured seismic velocities correlate with density and with modal mineralogy, especially the high content of sillimanite and garnet. Vp anisotropy is between 0.15% and 13.97%, and a clear compositional control is evident, mainly in relation to sillimanite abundance. Overall Vs anisotropy ranges from 1% to 11%. Poisson's ratio (σ) lies between 0.25 and 0.35 for the metapelitic granulites, mainly reflecting a high Vp value due to abundant sillimanite in the sample with the highest σ. Anisotropy is probably a function of deformation associated with the closure of the Iapetus ocean in the Silurian as well as later extension in the Devonian. The orientation of the bulk strain ellipsoid in the lower crust is difficult to constrain, but lineation is likely to be NE–SW, given the strike-slip nature of the late Caledonian and subsequent Acadian deformation.When corrected for present-day lower crustal temperature, the experimentally determined Vp values correspond well with velocities from the ICSSP, COOLE I and VARNET seismic refraction lines. Near the xenolith localities, the COOLE I line displays two lower crustal layers with in situ Vp values of 6.85–6.9 and 6.9–8.0 km s− 1, respectively. The upper (lower velocity) layer corresponds well with the metapelitic granulite xenoliths while the lower (higher velocity) layer matches that of the basic granulite xenoliths, though their metamorphic pressures suggest derivation from depths corresponding to the present-day upper mantle.  相似文献   

4.
Previous experiments by Raleigh et al. (1971) have shown that at strain rates of 10−2.sec−1 to 10−7.sec−1 only slip occurs in dry enstatite at temperatures above 1300°C and 1000°C, respectively.The present experiments have been conducted on polycrystalline enstatite under wet conditions in this regime where enstatite only slips, polygonizes and recrystallizes. Slip occurs throughout the whole regime on the system (100)[001] and at strains greater than 40% the system (010)[001] is observed. Polygonization and intragranular recrystallization begin at about 1300°C and 10−4.sec−1 and the orientation of these neoblasts is host-controlled. At lower strain rates intergranular neoblasts develop and their fabric is one of [100] maximum parallel with σ1 and [010] and [001] girdles in the σ2 = σ3 plane, similar to those in natural enstatite tectonites.Dislocation substructures of experimentally deformed enstatite have been examined by transmission electron microscopy. The samples were deformed within the field in which slip polygonization and recrystallization are the dominant deformation mechanisms. Samples within this regime have microstructures that are characterized by stacking faults and partial dislocations. Under the conditions of steady-state flow in olivine, these microstructures inhibit the operation of recovery mechanisms in enstatite.Other samples deformed within the polygonization and recrystallization field have microstructures that confirm the optical observations of intragranular and intergranular growth of neoblasts. It is suggested that the former result from strain-induced tilt of subrains, whereas the latter may result from bulge nucleation into adjacent subgrains.Mechanical data from constant strain-rate experiments at steady state, stress relaxation and temperature-differential creep tests are best fit to a power-law creep equation with the stress exponent, n~3 and the apparent activation energy for creep, Q~65 kcal/mole. Extrapolation of this equation to a representative natural geologic strain rate of 10−4. sec−1, over the temperature interval 1000–2000°C, gives an effective viscosity range of 1020–1018 poise and stresses in the range of 7-0.1 bar, respectively. Comparison with corrected wet-olivine mechanical data (Carter, 1976) over the same environment indicates that olivine is consistently the weaker of the two minerals and will recrystallize whilst enstatite will only slip and kink, thus accounting for the different habits of olivine and enstatite in ultramafic tectonites.  相似文献   

5.
Simultaneous measurements of compressional and shear wave velocities, Vp and Vs, in acidic and basic igneous rocks and volcanic glasses, were made up to 900°C and at 10–20 kbar.The effects of pressure and temperature on Vp and Vs in glasses and glassy rocks change at about 600°C, presumably the glass transition temperature. These effects are directly related to the silica content in the samples. and for obsidian are negative at room temperature and 245°C, but are positive at 655°C. The velocity—pressure relations for obsidian display an obvious hysteresis phenomena. for basalt glass is slightly negative, but is positive for usual substances at room temperature, and for obsidian and glassy andesite are positive up to about 600°C but are negative above that temperature. However, for basalt glass as well as other crystalline rocks, and are negative at all temperatures. Glass once heated above the glass transition temperature Tg under pressure P1 retains the memory of pressure P1 after it is cooled down below Tg and while subjected to another pressure P2. An abrupt shift of the velocities correlating to pressure P2 occurs when the glass is again heated to Tg. Vp−T and Vs−T relations for obsidian, glassy andesite, and basalt glass clearly exhibit this pressure memory.  相似文献   

6.
Coupled measurements of δ18O and accelerator mass spectrometry (AMS) 14C in a particular species of planktonic foraminifera may be used to calculate sea-level estimates for the last deglaciation. Of critical importance for this type of study is a knowledge of the seasonality of foraminiferal growth, which can be provided by δ18O measurements of modern shells (core tops, plankton tows). Isotopic (δ18O, AMS-14C dating) and faunal records (transfer function sea surface temperature) were obtained from two cores in the North Atlantic at about 37°N. The locations were chosen to obtain high sedimentation rate records removed from the major ice-melt discharge areas of the last deglaciation. Based upon Globigerina bulloides data, four δ18O-based sea-level estimates were calculated: −67 ± 7 m at 12,200 yr B.P. and −24 ± 8 m at about 8200 yr B.P. for core SU 81-18; −83 ± 10 m at 12,200 yr B.P. and −13 ± 11 m at about 8500 yr B.P. for core SU 81-14. Using a second working hypothesis concerning the seasonability of G. bulloides growth, it is suggested that the sea-level rose by about 40 m during the millennium which followed 14,500 yr B.P.  相似文献   

7.
Long-term creep tests of gabbro which have been performed with a maximum bending stress (20 bar) under a high confining pressure (1 kbar) and various temperatures, are described. Methods and techniques used in the experiment are mainly similar to those reported previously by the same authors (Itô and Sasajima, 1980) except for the application of high pressure and temperature. The techniques include the bending system, size and preparation of the sample, and the determination of its deformation by use of interference fringes of Na-D light. In order to measure a very small deformation of creep, intermittent breaks of the application of loading, confining pressure and temperature are necessary, and the creep curve is constructed from the intermittent advance of permanent deformation.The experiment has revealed two strange phenomena : one is a sinuous progress of the creep curve, and the other is that the deformation recovery shows strange behavior after the unloading. These results are discussed in close connection with the mechanism of the “turn back of creep” denoted by Itô and Sasajima (1980). The mean creep curves, at 25°C. 95°C and 150°C, obtained so far lead to viscosities of 1.6 · 1020, 1.9 · 1019 and 4.8 · 1018 poise, respectively and the maximum strain rates employed in the samples were 4.2 · 10−14, 3.6 · 10−13 and 1.4 · 10−12/sec, respectively, which cover the geological strain rate. Although we have only three data points, the logarithm of viscosity is linearly related to the reciprocal of absolute temperature (see Fig. 7), and an activation energy for creep of gabbro is found to be 7.6 kcal/mol. It should be noted that viscosities obtained are considerably smaller than those estimated for the crust and mantle, and that the activation energy is surprisingly smaller than those obtained by high-pressure experiments of rock deformation, which have been carried out under a strain rate larger than 10−8/sec.  相似文献   

8.
The 1.27 Ga old Ivigtut (Ivittuut) intrusion in South Greenland is world-famous for its hydrothermal cryolite deposit [Na3AlF6] situated within a strongly metasomatised A-type granite stock. This detailed fluid inclusion study characterises the fluid present during the formation of the cryolite deposit and thermodynamic modelling allows to constrain its formation conditions.Microthermometry revealed three different types of inclusions: (1) pure CO2, (2) aqueous-carbonic and (3) saline-aqueous inclusions. Melting temperatures range between − 23 and − 15 °C for type 2 and from − 15 to − 10 °C for type 3 inclusions. Most inclusions homogenise between 110 and 150 °C into the liquid.Stable isotope compositions of CO2 and H2O were measured from crushed inclusions in quartz, cryolite, fluorite and siderite. The δ13C values of about − 5‰ PDB are typical of mantle-derived magmas. The differences between δ18O of CO2 (+ 21 to + 42‰ VSMOW) and δ18O of H2O (− 1 to − 21.7‰ VSMOW) suggest low-temperature isotope exchange. δD (H2O) ranges from − 19 to − 144‰ VSMOW. The isotopic composition of inclusion water closely follows the meteoric water line and is comparable to Canadian Shield brines. Ion chromatography revealed the fluid's predominance in Na, Cl and F. Cl/Br ratios range between 56 and 110 and may imply intensive fluid–rock interaction with the host granite.Isochores deduced from microthermometry in conjunction with estimates for the solidification of the Ivigtut granite suggest a formation pressure of approximately 1–1.5 kbar for the fluid inclusions. Formation temperatures of different types of fluid inclusions vary between 100 and 400 °C. Thermodynamic modelling of phase assemblages and the extraordinary high concentration in F (and Na) may indicate that the cryolite body and its associated fluid inclusions could have formed during the continuous transition from a volatile-rich melt to a solute-rich fluid.  相似文献   

9.
The chromites from the alpine type ultramafic intrusive of Sukinda, India, display a typical partly inverse spinel form and occur in two distinct zones: Brown Ore Zone (BOZ) and Grey Ore Zone (GOZ). The host ultramafites are mostly altered and are represented by the serpentinite, tremolite-talc(chlorite) schist, talc-serpentine schist and chlorite rock. The less altered variants are dunite, harzburgite and websterite. A dyke of orthopyroxenite runs through the main ultramafic body.The composition of olivine (Fo92), orthopyroxene (En92–89) and Al2O3 contents of the parental liquid (10.40–11.45%) determined from chromites, suggest that the parent melt is of boninitic affinity. The chemical plot of TiO2 content against cr# of chromites corroborates a boninitic parental melt. The Fe–Mg partitioning in olivine and chromite depicts the temperature for chromitites as 1200 °C. A compositional plot of mg# and cr# suggests crystallization at high pressure conditions, corresponding to the kimberlite xenolith field. From the P–T diagram of pyrolite melting and mineral assemblage, the pressure of crystallization is stipulated to be ≥1.2 GPa. The fO2 values estimated from Fe3+/Cr+Al+Fe3+ ratios range from 10−8.3 to 10−9.3 for the GOZ and 10−7.1 to 10−7.3 for the BOZ. The fO2 values together with the pressure range suggest crystallization at upper mantle conditions. The heterogeneity in chemical composition and fO2 conditions for the GOZ and BOZ could be linked to heterogeneity in the upper mantle.  相似文献   

10.
Shear deformation of hot pressed plagioclase–olivine aggregates was studied in the presence and absence of mineral reaction. Experiments were performed at 900 °C, 1500 MPa, and a constant shear strain rate of 5×10−5 s−1 in a solid medium apparatus. Whether the mineral reaction between plagioclase and olivine takes place or not is controlled by choosing the appropriate plagioclase composition; labradorite (An60) does not react, anorthite (An92) does. Labradorite–olivine aggregates deformed without reaction are very strong and show strain hardening throughout the experiment. Syndeformational reaction between olivine and anorthite causes a pronounced strain weakening. The reaction produces fine-grained opx–cpx–spinel aggregates, which accommodate a large fraction of the finite strain. Deformation and reaction are localised within a 0.5-mm-wide sample. Three representative samples were analysed for their fabric anisotropy R* and shape-preferred orientation α* (fabric angle with the shear plane) using the autocorrelation function (ACF). Fabric anisotropy can be calibrated to quantify strain variations across the sheared samples. In the deformed and reacted anorthite–olivine aggregate, there is a strong correlation between reaction progress and strain; regions of large shear strain correspond to regions of maximum reaction progress. Within the sample, the derived strain rate variations range up to almost one order of magnitude.  相似文献   

11.
Finite-element folds of similar geometry   总被引：3，自引：0，他引：3  
Model folds of similar geometry have been produced by using the finite-element method and the constitutive relations of a layer of wet quartzite embedded in a marble matrix with an initially sinusoidal configuration and a 10° limb dip. The power law for steady-state flow of Yule Marble (Heard and Raleigh, 1972) is used for the matrix and our new law for Canyon Creek quartzite deformed in the presence of water is used for the layer. The equiv- alent viscosity of the wet quartzite is highly temperature-sensitive, giving rise to a strong temperature dependence of the quartzite: marble viscosity ratio which, at a strain rate of 10−14/sec, drops from 543 at 200° to 0.13 at 800°C. At 375°C (ηq/ηm = 10), concentric folds develop at all strains to 80% natural shortening and stress, finite strain and viscosity distributions are somewhat similar to those found previously. Raising the temperature to 550° C (ηq/ηm = 1), at any stage of prior amplification, causes the folds to flatten with increasing strain, accompanied by attenuation of limbs and thickening of hinges, leading to folds with similar geometries and isoclinal folds at extreme strains. The effects are more pronounced at higher temperatures and at 700° C (ηq/ηm = 0.3) limb attenuation is so severe as to give rise to unrealistic geometries. At temperatures below about 600° C (ηq/ηm = 2), similar folds do not form. It thus appears as if a viscosity contrast near unity is required to produce similar folds in rocks, under the conditions simulated and different temperature dependencies of viscosities of materials in layered sequences is one important means of reducing viscosity contrasts.  相似文献   

12.
Aggregates composed of olivine and magnesiowüstite have been deformed to large strains at high pressure and temperature to investigate stress and strain partitioning, phase segregation and possible localization of deformation in a polyphase material. Samples with 20 vol.% of natural olivine and 80 vol.% of (Mg0.7Fe0.3)O were synthesized and deformed in a gas-medium torsion apparatus at temperatures of 1127 °C and 1250 °C, a confining pressure of 300 MPa and constant angular displacement rates equivalent to constant shear strain rates of 1–3.3 × 10− 4 s− 1. The samples deformed homogeneously to total shear strains of up to γ  15. During constant strain rate measurements the flow stress remained approximately stable at 1250 °C while it progressively decreased after the initial yield stress at the lower temperature. Mechanical data, microstructures and textures indicate that both phases were deforming in the dislocation creep regime. The weaker component, magnesiowüstite, controlled the rheological behavior of the bulk material and accommodated most of the strain. Deformation and dynamic recrystallization lead to grain refinement and to textures that were not previously observed in pure magnesiowüstite and may have developed due to the presence of the second phase. At 1127 °C, olivine grains behaved as semi-rigid inclusions rotating in a viscous matrix. At 1250 °C, some olivine grains remained largely undeformed while deformation and recrystallization of other grains oriented for a-slip on (010) resulted in a weak foliation and a texture typical for pure dry olivine aggregates. Both a-slip and c-slip on (010) were activated in olivine even though the nominal stresses were up to 2 orders of magnitude lower than those needed to activate these slip systems in pure olivine at the same conditions.  相似文献   

13.
The densification curves for the hot-pressing of pure olivine powders were obtained as a function of grain size (5 μ–2000 μ), temperature (1000–1600°C), and compacting stress (166–298 bars). This range of variables was found to straddle two fields of hot-pressing behavior, one dominated by power-law creep, one by Coble creep. The time required to density a powder to 99% of the single crystal density could be represented by the shorter of the two times: t1 = 2.2 · 103σ−3.4exp(85,000/RT)t2 = 1.3 · 104σ−1.5(G)+3exp(85,000/RT) where the compacting stress or pressure, σ, is given in bars and the grain size, G, in centimeters. It was also possible to estimate the parameters appropriate to Coble creep in a solid polycrystalline aggregate from the hot-pressing data; and these were:
Full-size image (1K)
The strain rates computed from this formula are close to those predicted by Stocker and Ashby (1973) and those found by Twiss (1976).  相似文献   

14.
Geochronological data, major and trace element abundances, Nd and Sr isotope ratios, δ18O whole rock values and Pb isotope ratios from leached feldspars are presented for garnet-bearing granites (locality at Oetmoed and outcrop 10 km north of Omaruru) from the Damara Belt (Namibia). For the granites from outcrop 10 km N′ Omaruru, reversely discordant U–Pb monazite data give 207Pb/235U ages of 511±2 Ma and 517±2 Ma, similar to previously published estimates for the time of regional high grade metamorphism in the Central Zone. Based on textural and compositional variations, garnets from these granites are inferred to be refractory residues from partial melting in the deep crust. Because P–T estimates from these xenocrystic garnets are significantly higher (800°C/9–10 kbar) than regional estimates (700°C/5 kbar), the monazite ages are interpreted to date the peak of regional metamorphism in the source of the granites. Sm–Nd garnet–whole rock ages are between 500 and 490 Ma indicating the age of extraction of the granites from their deep crustal sources. For the granites from Oetmoed, both Sm–Nd and Pb–Pb ages obtained on igneous garnets range from 500 to 490 Ma. These ages are interpreted as emplacement ages and are significantly younger than the previously proposed age of 520 Ma for these granites based on Rb/Sr whole rock age determinations. Major and trace element compositions indicate that the granites are moderately to strongly peraluminous S-type granites. High initial 87Sr/86Sr ratios (>0.716), high δ18O values of >13.8‰, negative initial Nd values between −4 and −7 and evolved Pb isotope ratios indicate formation of the granites by anatexis of mid-crustal rocks similar to the exposed metapelites into which they intruded. The large range of Pb isotope ratios and the lack of correlation between Pb isotope ratios and Nd and Sr isotope ratios indicate heterogeneity of the involved crustal rocks. Evidence for the involvement of isotopically highly evolved lower crust is scarce and the influence of a depleted mantle component is unlikely. The crustal heating events that produced these granites might have been caused by crustal thickening and thrusting of crustal sheets enriched in heat-producing elements. Very limited fluxing of volatiles from underthrust low- to medium-grade metasedimentary rocks may have also been a factor in promoting partial melting. Furthermore, delamination of the lithospheric mantle and uprise of hot mantle could have caused localized high-T regions. The presence of coeval A-type granites at Oetmoed that have been derived at least in part from a mantle source supports this model.  相似文献   

15.
Cantilever torque magnetometry is utilized widely in physics and material science for the determination of magnetic properties of thin films and semiconductors. Here, we report on its first application in rock magnetism, namely the determination of K1 and K2 of single crystal octahedra of natural magnetite. The design of cantilever magnetometers allows optimization for the specific research question at hand. For the present study, a cantilever magnetometer was used that enables measurement of samples with a volume up to 64 mm3. It can be inserted into an electromagnet with a maximum field of 2 T. The cantilever spring is suitable for torque values ranging from 7.5 × 10− 7 N·m to 5 × 10− 6 N·m. The torque is detected capacitively; the measured capacitance is converted into torque by using a calibrated feedback coil. The magnetometer allows in-situ rotation of the sample in both directions and is, therefore, also suitable to analyze rotational hysteresis effects.The evaluation of the magnetite anisotropy constants involved Fourier analysis of the torque signal on the magnetite crystals' (001) and (110) planes. The absolute anisotropy constant has been computed using the extrapolation-to-infinite-field method. The value of K1 at room temperature is determined at − 1.28 × 104 [J m− 3] (± 0.13, i.e. 10%) and that of K2 at − 2.8 × 103 [J m− 3] (± 0.1, i.e. 2%). These values concur with earlier determinations that could not provide an instrumental error, in contrast with this work.The cantilever magnetometer performs four times faster than other torque magnetometers used for rock magnetic studies. This makes the instrument also suitable for magnetic fabric analysis.  相似文献   

16.
The intrinsic room temperature magnetic properties of pure calcite were determined from a series of natural crystals, and they were found to be highly dependent on the chemical composition. In general, dia-, para-, and ferromagnetic components contribute to the magnetic susceptibility and the anisotropy of magnetic susceptibility (AMS). With a combination of magnetic measurements and chemical analysis these three contributions were determined and related to their mineralogical sources. The intrinsic diamagnetic susceptibility of pure calcite is − 4.46 ± 0.16 × 10− 9 m3/kg (− 12.09 ± 0.5 × 10− 6 SI) and the susceptibility difference is 4.06 ± 0.03 × 10− 10 m3/kg (1.10 ± 0.01 × 10− 6 SI). These diamagnetic properties are easily dominated by other components. The paramagnetic contribution is due to paramagnetic ions in the crystal lattice that substitute for calcium; these are mainly iron and manganese. The measured paramagnetic susceptibility agrees with the values calculated from the known concentration of paramagnetic ions in the crystals according to the Curie law of paramagnetic susceptibility. Substituted iron leads to an increase in the AMS. The paramagnetic susceptibility difference was found to correlate linearly with the iron content for concentrations between 500 and 10,000 ppm. An empirical relation was determined: (k1 − k3)para (kg/m3) = Fe-content (ppm) × (1 ± 0.1) × 10− 12 (kg/m3/ppm). The maximum susceptibility difference (Δk = k1 − k3) was found to be unaffected by iron contents below 100 ppm. Ferromagnetic contributions due to inclusions of ferromagnetic minerals can dominate the susceptibility. They were detected by acquisition of isothermal remanent magnetization (IRM) and their contribution to the AMS was separated by high-field measurements.  相似文献   

17.
The recent tectonics of the Arctic Basin and northeastern Asia are considered as a result of interaction between three lithospheric plates: North-America, Eurasia and Spitsbergen. Seismic zones (coinciding in the Norway-Greenland basin with the Kolbeinsey, Mohns and Knipovich ridges, and in the Arctic Ocean with the Gakkel Ridge) clearly mark the boundaries between them. In southernmost Svalbard (Spitsbergen), the secondary seismic belt deviates from the major seismic zone. This belt continues into the seismic zone of the Franz Josef Land and then merges into the seismic zone of the Gakkel Ridge at 70°–90°E. The smaller Spitsbergen plate is located between the major seismic zone and its secondary branch.Within northeastern Asia, earthquake epicenters with magnitude over 4.5 are concentrated within a 300-km wide belt crossing the Eurasian continent over a distance of 3000 km from the Lena estuary to the Komandorskye Islands. A single seismic belt crosses the northern sections of the Verkhoyansky Ridge and runs along the Chersky Ridge to the Kolymo-Okhotsk Divide.To compute the poles of relative rotation of the Eurasian, North-American and Spitsbergen plates we use 23 new determinations of focal-mechanism solutions for earthquakes, and 38 azimuths of slip vectors obtained by matching of symmetric mountain pairs on both sides of the Knipovich and Gakkel ridges; we also use 14 azimuths of strike-slip faults within the Chersky Ridge determined by satellite images. The following parameters of plate displacement were obtained: Eurasia/North America: 62.2°N, 140.2°E (from the Knipovich Ridge section south of the triple junction); 61.9°N, 143.1°E (from fault strikes in the Chersky Ridge); 60.42°N, 141.56°C (from the Knipovich section and from fault strikes in the Chersky Ridge); 59.48°N, 140.83°E, α = 1.89 · 10−7 deg/year (from the Knipovich section, from fault strikes in the Chersky Ridge and from the Gakkel Ridge section east of the triple junction). The rate was calculated by fitting the 2′ magnetic lineations within the Gakkel Ridge).North-America/Spitsbergen: 70.96°N, 121.18°E, α = −2.7 · 10−7 deg/year from the Knipovich Ridge section north of the triple junction, from earthquakes in the Spitsbergen fracture zone and from the Gakkel Ridge section west of the triple junction). Eurasia/Spitsbergen: 70.7°N, 25.49°E, α = −0.99 · 10−7 deg/year (from closure of vector triangles).  相似文献   

18.
Lime mortar and plaster were sampled from Roman, medieval and early modern buildings in Styria. The historical lime mortar and plaster consist of calcite formed in the matrix during setting and various aggregates. The stable C and O isotopic composition of the calcite matrix was analyzed to get knowledge about the environmental conditions during calcite formation. The δ13Cmatrix and δ18Omatrix values range from −31 to 0‰ and −26 to −3‰(VPDB), respectively. Obviously, such a range of isotope values does not represent the local natural limestone assumed to be used for producing the mortar and plaster. In an ideal case, the calcite matrix in lime mortar and plaster is isotopically lighter in the exterior vs. the interior mortar layer according to the relationship δ18Omatrix = 0.61 · δ13Cmatrix − 3.3 (VPDB). Calcite precipitation by uptake of gaseous CO2 into alkaline Ca(OH)2 solutions shows a similar relationship, δ18Ocalcite = 0.67 · δ13Ccalcite − 6.4 (VPDB). Both relationships indicate that the 13C/12C and 18O/16O values of the calcite reflect the setting behaviour of the lime mortar and plaster. Initially, CO2 from the atmosphere is fixed as calcite, which is accompanied by kinetic isotope fractionation mostly due to the hydroxylation of CO2 (δ13Cmatrix ≈  −25‰ and δ18Omatrix ≈ −20‰). As calcite formation continued the remaining gaseous CO2 is subsequently enriched in 13C and 18O causing later formed calcite to be isotopically heavier along the setting path in the matrix. Deviations from such an ideal isotopic behaviour may be due to the evolution of H2O, e.g. evaporation, the source of CO2, e.g. from biogenic origin, relicts of the natural limestone, and secondary effects, such as recrystallization of calcite. The results of the field and experimental study suggest that isotope values can be used as overall proxies to decipher the origin of carbonate and the formation conditions of calcite in the matrix of ancient and recent lime mortar and plaster. Moreover, these proxies can be used to select calcite matrix from historical lime mortar and plaster for 14C dating.  相似文献   

19.
Tunnel excavation at Äspö Island, Sweden, has caused severe groundwater disturbance, gradually extending deeper into the tunnel as present-day Baltic seawater intrudes through fractures connecting to the surface. However, the paleo-hydrogeochemical conditions have remained in the deep highly saline waters that have avoided mixing. A correlation has been observed between dissolved 4He concentration and Cl− ion concentration, measured every two years from 1995 to 2001 at Äspö. Groundwater mixing conditions can be examined by the correlations between 1/Cl, 36Cl/Cl, and 3H concentrations. Subsurface production is responsible for the majority of the 36Cl and excess dissolved 4He of interstitial groundwater in fractures. The secular equilibrium ratio of 36Cl/Cl in rock was theoretically estimated to be (5.05 ± 0.82) × 10−14 based on the neutron flux intensity, a value comparable to the measured 36Cl/Cl ratio in rock and groundwater. The degassing crustal 4He flux was estimated to be 2.9 × 10−8  1.3 × 10−6 (ccSTP/cm2a) using the HTO diffusion coefficient for the Äspö diorite. The 4He accumulation rate ranges from 6.8 × 10−10 (for the in situ accumulation rate) to 7.0 × 10−9 (ccSTP/(gwater · a) considering both 4He in situ production and the degassing flux, assuming 4He is accumulated constantly in groundwater. By comparing the subsurface 36Cl increase with 4He concentrations in groundwater, the 4He accumulation rate was determined from data for groundwater arriving at the secular equilibrium of 36Cl/Cl. The 4He accumulation rate was found to be (1.83 ± 0.72) × 10−8 ccSTP/(gwater · a) without determining the magnitude of degassing 4He flux.  相似文献   

20.
Individual and monthly precipitation samples from the polluted atmosphere of Bologna (Emilia-Romagna province) were collected during March 1996 to May 1997 and analyzed for major ions in solution and S isotopes in dissolved SO4.Weighted mean enrichment factors relative to seawater are found to be 1.0 for Na, 15.2 for K, 105 for Ca, 3.3 for Mg, 17.3 for SO4 and 663 for HCO−3. Very good positive correlations are observed for the Ca2+–Mg2+–HCO−3–SO2−4–NO−3 system, indicating that dissolution of Ca (±Mg)-carbonate particles by H2SO4 and HNO3 from combustion of oil and gas is a major process controlling the chemical composition of rain and snow. Na+ and Cl− in monthly precipitation derive essentially from sea spray, but the contribution of Na+ from continental sources is appreciable in a number of individual rains. NH+4 appears to be on average more abundant in spring and summer precipitation, its main sources being microbial activity in soils and application of fertilizers. K+ is probably of continental origin from soil dust.The S isotopic composition of SO4 is systematically positive, with mean δ34S values of +3.2±1.6‰ (n=40) in individual precipitation and +2.8±1.4‰ (n=12) in monthly precipitation. These isotopic compositions are interpreted in terms of a dominant contribution of S from anthropogenic emissions and subordinate contributions from biogenic and marine sources. Pollutant SO4 is estimated to have a δ34S value in the range +2.5 to +4.5‰, whereas a distinctive δ34S of −4.5‰ or lower indicates SO4 from oxidation of biogenic gases.The isotopic and chemical compositions of SO4 do not depend on wind direction, thus testifying to a mostly local source for pollutant S in the Bologna atmosphere.  相似文献   

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