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1.
从表生到深埋藏环境下有机酸对碳酸盐岩溶蚀的实验模拟 总被引：1，自引：0，他引：1
通过细粉晶白云岩、泥晶灰岩、泥灰岩和含生屑泥晶灰岩与2 ml/L乙酸溶液的溶解动力学实验,研究了从表生到深埋藏环境下有机酸对碳酸盐岩储层的改造作用机理。结果显示,四种类型碳酸盐岩的溶解速率在3.34×10–9~2.27×10–8 mol/(cm2·s)之间,并且溶解速率随埋藏深度(地层温度和地层压力)的增加而增大。从表生到中埋藏环境下,泥晶灰岩、泥灰岩和含生屑泥晶灰岩的溶解速率大于细粉晶白云岩;在深埋藏环境下,细粉晶白云岩的溶解速率逐渐与泥晶灰岩、泥灰岩和含生屑泥晶灰岩的一致,这揭示出在相对高温高压下,埋藏有机酸性流体对碳酸盐岩的溶蚀改造作用中,碳酸盐岩的溶蚀速率与其方解石和白云石含量的关系并不大。反应前后样品表面的扫描电子显微镜分析结果表明,细粉晶白云岩的晶间溶孔、晶内溶孔更加发育。细粉晶白云岩中白云石溶解成蜂窝状溶解孔,晶间缝溶蚀加大且相互连通,这种微观溶蚀特征更有利于油、气的储集及运移。结合岩石的溶蚀速率及其微观溶蚀演化特征,指出碳酸盐岩矿物成分和含量固然对其溶蚀作用具有控制影响,但是碳酸盐岩溶蚀形成的孔隙类型及其连通性能与碳酸盐岩有利储层形成的关系更为密切。 相似文献
2.
《海相油气地质》2013,(3):55-61
通过表面溶蚀和内部溶蚀两种实验方式,分别对六种类型碳酸盐岩用0.2%乙酸溶液进行溶蚀实验,对比研究了从表生环境到深埋藏环境下有机酸与不同类型碳酸盐岩的溶蚀作用机制。对比研究表明:(1)在近地表环境下(25℃,1.0 MPa),泥灰岩和含生物碎屑泥晶灰岩的溶解速率大于细晶白云岩,前两者约为后者的23倍;随着温压的增加,泥灰岩、含生物碎屑泥晶灰岩和细晶白云岩的溶解速率均相应增加,但细晶白云岩的溶解速率增加幅度更大;在深埋藏环境下(180℃,45 MPa到210℃,52.5 MPa),细晶白云岩的溶解速率逐渐与泥灰岩和含生物碎屑泥晶灰岩的溶解速率趋于一致。(2)在60℃,10 MPa时,白云质颗粒灰岩在乙酸溶液中的溶解能力大于粉细晶白云岩和亮晶鲕粒白云岩;随着温压的增加,有机酸溶液对石灰岩与白云岩的溶解能力均相应降低,且石灰岩溶蚀作用下降幅度更大,当温压达到或超过90℃、20 MPa时,粉细晶白云岩和亮晶鲕粒白云岩在乙酸溶液中的溶解能力大于白云质颗粒灰岩。根据实验结果推测:表生和相对浅埋藏的温压条件下,石灰岩的溶解速率和溶解能力大于白云岩,石灰岩的溶蚀作用较白云岩发育;但在深埋藏阶段,由于白云岩的溶解能力大于石灰岩,因此白云岩溶蚀产生的次生孔隙较石灰岩更为发育,这或许是深部的碳酸盐岩储层中多见白云岩储层的重要原因。 相似文献
3.
塔里木盆地塔中地区奥陶系碳酸盐岩储层空隙研究 总被引：11，自引：0，他引：11
空隙是构成碳酸盐岩储层的基本单元,空隙发育史对应了成岩演化史,且不同类型空隙的储层具有不同的分布规律。塔里木盆地塔中地区奥陶系碳酸盐岩储层的空隙可以分为６类２１种,以裂缝—孔洞型为主,礁、丘、滩相碳酸盐岩、中—细晶白云岩与古岩溶和构造岩溶的复合区为有利空隙发育带,也是风化壳型油气藏和内幕型油气藏的有利储集相带。 相似文献
4.
对研究程度较高的北美奥陶系碳酸盐岩油气田特征参数作了统计和分析,对比中国下古生界碳酸盐岩油气田,分析了古老碳酸盐岩油气储层的特点及主要控制因素。北美大陆奥陶纪沉积环境以环潮坪—浅水陆棚为主,储集岩可简单地划分为四种岩相类型,包括泥晶灰岩、粒泥灰岩、泥粒灰岩以及颗粒灰岩。晶间孔、角砾岩相关孔隙及溶蚀孔隙是最主要的孔隙类型,其中尤以晶间孔最为普遍。中国下古生界碳酸盐岩油气储层的演化更为复杂,原生孔隙损失殆尽。北美和中国的研究都表明,岩溶储层和白云岩储层是主要的有效储层。当埋深超过3000m时,白云岩是主要的储层岩石类型。在埋深增大的情况下白云岩保持更好的储集性能,这是一个基本的趋势。中国下古生界碳酸盐岩埋深较大,所以白云岩储层是一个特别值得关注的领域。 相似文献
5.
塔中地区奥陶系碳酸盐岩表生岩溶分布特征及主控因素 总被引：15，自引：0，他引：15
奥陶系碳酸盐岩是塔中地区最主要的储集层位，岩溶作用是影响奥陶系碳酸盐岩储层发育的重要因素．塔中地区遭受了多期构造运动，发育多个风化面．由于只有碳酸盐岩才会发育岩溶作用，而碳酸盐岩地层直接暴露地表的范围可能仅限于局部地区，因此不能简单的将风化壳下的构造形态当作古岩溶的地貌，而是要分层系的研究各期次岩溶作用的发育情况．在塔中隆起带上， 相似文献
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7.
灰岩和白云岩溶解速率控制机理的比较 总被引：14，自引：2，他引：12
碳酸盐岩溶解的速率控制过程包括:(1)岩石表面上的非均相化学反应;(2)离子从岩石表面通过扩散向溶液中的传输;(3)CO2向H 和HCO-3的转换.通常是这3个过程中的最慢过程决定着碳酸盐岩的溶解速率.然而,实验和理论分析发现,在条件相似的情况下,白云岩的初始溶解速率不仅只有灰岩的1/3～1/60,而且灰岩和白云岩的溶解呈现出不同的速率控制机理.如对灰岩而言,在实验中加入能催化CO2转换反应的生物碳酸酐酶(CA)后,其溶解速率增加出现在CO2分压>100Pa的区域,最高可达10倍;而对白云岩,其溶解速率增加出现在CO2分压<10000Pa的区域,且增加仅3倍左右.此外,虽然2类岩石的溶解也均受水动力条件(旋速或流速)的控制,且主要出现在CO2分压<1000Pa的区域,但灰岩的溶解对水动力条件的变化比白云岩溶解更敏感.这些发现在解释和揭示自然界白云岩和灰岩岩溶发育及其相关资源环境问题的差异方面具有重要意义. 相似文献
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中国天然气碳酸盐岩储层形成的成岩模式 总被引：6，自引：2，他引：6
碳酸盐岩储层形成和成岩环境密切相关，本文根据我国实际情况将成岩环境划分为海洋、埋藏和表生三种环境。碳酸盐岩储气层的形成主要为白云岩化作用和岩溶作用。对次生孔隙的储集空间成因，提出了白云岩化形成白云岩溶孔的机制。岩溶作用是在地壳抬升的表生环境作用下，碳酸盐岩发生溶解、溶蚀、坍塌等作用的总和。提出了碳酸盐岩储层形成的成岩模式，明确指出在成岩过程中有三次储集层形成，每次伟层的形成，都可形成气田。并论证了储集层形成的地质条件、变化因素、形成时间以及对储层条件评价。 相似文献
10.
应用薄片、铸体和阴极发光等室内分析技术,对鲁西隆起奥陶系碳酸盐岩及济阳坳陷潜山奥陶系钻井岩心样品进行了成岩作用及储集特征详细研究。奥陶系碳酸盐岩原生孔隙消失殆尽,次生成因的孔、洞和缝是主要储集空间。其中裂缝储集层在各层段均有发育,但白云岩段优于其它岩性段;构造缝主要分布在构造轴部和断裂带附近,溶蚀缝在不整合面附近较为发育。孔洞型储集层主要发育在白云岩层段,以晶间孔、晶间溶孔和晶内溶孔为主要储集空间;有少量有效孔隙分布在灰岩段,以铸模孔、粒内溶孔和粒内孔为主。马家沟组八陡段顶部发育溶蚀角砾岩、纹层状结晶灰岩,砾间缝、晶间缝和溶洞为主要储集空间。白云岩段是奥陶系碳酸盐岩主要储集层段,构造因素、岩性和成岩作用(尤其是胶结作用和溶蚀作用)是造成奥陶系碳酸盐岩储集层剖面分布差异性的主要控制因素。 相似文献
11.
不同水流速度下温度对奥陶系碳酸盐岩溶蚀速度的影响 总被引：1，自引：0，他引：1
为了解不同水流速度下温度对碳酸盐岩溶蚀速度的影响,以自行设计、制造的能够模拟水流条件,并且可同时容纳24个样品的溶蚀试验装置为平台,以淮南张集矿、潞安漳村矿和兖州东滩矿奥陶系灰岩为代表性岩石试样,选取不同温度、水流速度及CO2压力,进行了溶蚀试验。试验结果显示,在水流速度较低时(16.67 mL/min),环境温度的变化对溶蚀速度的影响比较微小(平均溶蚀变化量为0.000 6 g/cm2)。在水流速度较大时(60 mL/min),温度的改变对溶蚀速度影响较大(平均溶蚀变化量为0.0038 g/cm2)。也就是说在地下水的强径流带,温度对溶蚀速度的影响相对较大,溶蚀速度较快,所以岩溶较发育。 相似文献
12.
Recent work on the weathering of high standing islands (HSI’s) of New Zealand (Goldsmith et al., 2008), Dominica (Goldsmith et al., 2010) Martinique and Guadeloupe (Rad et al., 2006) and portions of the Philippines (Schopka et al., 2011) shows weathering rates based on stream water chemistry for areas draining andesitic terrains are comparable to weathering rates determined for basaltic terrains, indicating that andesite weathering might be much more important in drawing down atmospheric CO2 than previously recognized. While an easily erodible parent material has been largely attributed to sustaining rates at these locations, little is known to known regarding its associated reaction kinetics. We conducted a series of batch dissolution experiments on andesitic material collected from ∼10,000 year old tephra deposits from Dominica to determine the dissolution rate of major and trace mineral phases to better understand geochemical processes controlling weathering flux from these areas. Dissolution experiments were conducted over a range of pH (4 and 7) on bulk samples and mineral separates.The dissolution rates based on Si release from the Dominica tephra bulk samples were similar, and ranged from 0.04 to 0.13 μmole Si/g-day in water, and ∼0.14 to 0.27 μmole Si/g-day in dilute acid (initial pH ∼4). Although the bulk of the ash is predominately composed of vesicular felsic (Na–Al–Si) volcanic glass, reaction rates and stoichiometry indicate ash dissolution is dominated by the reactivity of trace Mg or Ca-bearing silicate phases (olivine, pyroxene or amphiboles) and Ca–phosphate phases (apatite), especially under slightly acidic conditions. Analysis of reacted phases by SEM shows little evidence of alteration of glassy material, whereas surfaces of Ca–Mg inosilicates, olivine and apatite show etched features indicative of dissolution. Results of the dissolution experiments suggest that, although these phases are relatively minor components of the ash, they contribute disproportionately to the overall weathering flux, and their reactivity may be particularly important in areas where physical weathering and erosion are constantly exposing new fresh surfaces available for chemical reaction. 相似文献
13.
ZHANG Ronghu HU Shumin SU YanfengOpen Research Laboratory of Geochemical Kinetics Institute of Mineral Resources Chinese Academy of Geological Sciences Baiwanzhuang Ro Beijing China 《《地质学报》英文版》2002,76(3):351-366
This study reports the kinetic experimental results of albite in water and in KCI solution at 22 MPa in the temperature range of 25 to 400℃. Kinetic experiments have been carried out in an open flow-through reaction system (packed bed reactor). Albite dissolution is always incongruent in water at most temperatures, but becomes congruent at 300℃ (close to the critical point 374℃). At temperatures from 25 to 300℃, the incongruent dissolution of albite is reflected by the fact that sodium and aluminum are easily dissolved into water; from 300 to 400℃ it is reflected by silicon being more easily dissolved in water than Al and Na. Maximum albite dissolution rates in the flow hydrothermal systems have been repeatedly observed at 300℃, independent of flow rates.The kinetic experiments of albite dissolution in a KCl aqueous solution (0.1 mol KCl) indicate that the dissolution rate of albite increases with increasing temperature. Maximum silicon release rates of albite have been observed at 400℃, while ma 相似文献
14.
Thermobarometric modelling of zircon and monazite growth in melt-bearing systems: examples using model metapelitic and metapsammitic granulites 总被引：10，自引：0，他引：10
U–Pb age data collected from zircon and monazite are used to draw fundamental inferences about tectonic processes in the Earth. Despite the emphasis placed on zircon and monazite ages, the understanding of how to relate the timing of growth of zircon and monazite to an evolving rock system remains in its infancy. In addition, few studies have presented large datasets of geochronological data from zircon and monazite occurring in the same metamorphic rock sample. Such information is crucial for understanding the growth of zircon relative to monazite in a systematic and predictive manner, as per this study. The data that exist support the generally held conception that zircon ages tend to be older than monazite ages within the same rock. Here experimental data for zircon and monazite saturation in melt-bearing rocks are integrated with phase diagram calculations. The calculations constrain the dissolution and growth behaviour of zircon and monazite with respect to evolving pressure, temperature and silicate mineral assemblages in high-grade, melt-bearing, metasedimentary rocks. Several key results emerge from this modelling: first, that in aluminous metapelitic rocks (i.e. garnet + cordierite + sillimanite assemblages), zircon ages are older than monazite ages in the same rock; second, that the growth rate of accessory minerals is nonlinear and much higher at and near saturation than at lower temperatures; and third, that the difference in zircon and monazite ages from the same rock may be ascribed to differences in the temperature(s) at which zircon and monazite grow rather than differences in closure temperature systematics. Using our methodology the cooling rate of granulites from the Reynolds Range, central Australia, have been constrained at ∼4 °C Myr−1 . This study serves as a first-pass template on which further research in applying the technique to a field study can be based. 相似文献
15.
Why asymptotic limit of the acid dissolution capacity can lead to a sharp dissolution front in chemical dissolution of porous rocks? 
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下载免费PDF全文 The use of the asymptotic limit can greatly simplify the theoretical analysis of chemical dissolution front instabilities in fluid‐saturated rocks and therefore make it possible to obtain mathematical solutions, which often play a crucial role in understanding the propagation behavior of chemical dissolution fronts in chemical dissolution systems. However, there has been a debate in recent years that the asymptotic limit of the acid dissolution capacity (i.e., the acid dissolution capacity number approaching zero) alone cannot lead to a sharp dissolution front of the Stefan type in the acidization dissolution system, in which the dissolvable minerals of carbonate rocks are chemically dissolved by the injected acid flow. The acid dissolution capacity number is commonly defined as the ratio of the volume of the carbonate rock dissolved by an acid to that of the acid. In this paper, we use four different proof methods, including (i) direct use of the fundamental concepts; (ii) use of the mathematical governing equations of an acidization dissolution system; (iii) use of the different time scaling approach; and (iv) use of a moving coordinate system approach, to demonstrate that the asymptotic limit of the acid dissolution capacity can indeed lead to sharp dissolution fronts of the Stefan type in acidization dissolution systems on a much larger time scale (than the dissolution time scale). Our new finding is that on the reaction time scale, the condition of the conventional time derivative of porosity approaching zero alone can ensure that the acidization dissolution front has a sharp shape of the Stefan type. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献
16.
长石溶解模拟实验研究综述 总被引：2，自引：0，他引：2
在综合分析前人研究成果基础上,对长石溶解模拟实验研究进行了综述.研究表明,长石溶解与其成分、结构、反应的温压条件以及流体性质等有关.在相同的温压条件下,3种长石的稳定性依次为:钾长石>钠长石>钙长石,且温度升高可加强长石的溶解能力,促进长石的溶解,而压力的变化对长石的溶解影响不大.长石的溶解速率在酸性区域随pH值增大而减小、在中性区域溶解速率低且受影响小、在碱性区域随pH值增大而增大.有机酸通过提供H+、络合金属元素来提高长石的溶解度.长石的溶蚀速率与颗粒的总表面积大小以及颗粒表面粗糙度有关,总表面积越大,表面越粗糙,则反应速率越快,而且溶液的矿化度越低越有利于长石的溶解.长石的溶解过程由表面反应和扩散反应所控制,描述长石溶蚀机理的模型主要包括:表面反应模型和淋滤层扩散模型. 相似文献
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塔中北斜坡鹰山组碳酸盐岩溶蚀的模拟实验研究 总被引：1，自引：0，他引：1
为了研究碳酸盐岩的微观溶蚀机理,本文采用溶蚀实验和镜像观察的方法,研究了塔中北斜坡鹰山组3种类型碳酸盐岩的溶蚀过程及微观溶蚀特征。结果表明:在相同实验条件下,亮晶生屑灰岩、云质灰岩和泥晶颗粒灰岩的溶蚀量基本一致。由于对物质成分和岩石微结构的选择性溶蚀,它们的微观溶蚀特征存在明显差异。亮晶生屑灰岩和泥晶颗粒灰岩样表面整体被溶蚀降低。云质灰岩样表面方解石部分整体被溶蚀降低,形成铸模孔,白云石溶蚀成蜂窝状溶蚀孔,并突出岩石表面,白云石晶间缝溶蚀加大且相互连通,这对油、气和地下水储渗具有重要意义。 相似文献
18.
准噶尔盆地腹部深埋储层次生孔隙成因机理研究 总被引：7，自引：4，他引：3
准噶尔盆地腹部勘探目的层埋深大,一般在5 500～6 000 m左右,属于深埋储层。在对大量薄片分析鉴定的基础上,运用扫描电镜、阴极发光和X衍射粘土分析等手段,对研究目的层的孔隙类型和成因机理进行了研究。研究发现孔隙类型以次生溶蚀孔隙为主。中晚侏罗世发育的车莫古隆起导致非持续埋藏的成岩背景,由于中途开启地层抬升暴露,酸性大气淡水对粒间方解石胶结物淋滤溶蚀,产生次生溶孔;白垩系之后再度埋藏发生有机酸内幕溶蚀作用。由于地层抬升剥蚀导致成岩阶段滞后,勘探目的层现今处于晚成岩A1亚期是次生孔隙保存的重要条件。 相似文献
19.
新一代试样分解技术—微波溶样的现状与展望 总被引：2，自引：1，他引：2
本文通过回顾新一代试样分解技术－微波溶样的发展过程，在详述微波密封溶解优点的基础上，研讨了微波溶样的原理和有关设备的选择与设计，本文还评述了这一新技术的应用现状并展望该技术在分析领域中今后的发展前景。 相似文献
20.
Victor W. Truesdale 《Aquatic Geochemistry》2007,13(4):267-287
The full potential of batch dissolution experiments in geochemical and industrial applications has been hampered by the lack
of an equation to describe the increase in dissolved solid concentration with time. This study provides new experimental results
on the dissolution of salts and new equations, which describe dissolution according to the shrinking sphere model. Sieved
salts were found to dissolve according to the shrinking sphere model while the dissolution of the parent material, raw (agglomerated)
salt, fitted an exponential dissolution curve. The implications of this to the development of a systematic approach to batch
dissolution, irrespective of the solid, is explored. Mathematical equations are derived for the dissolution of solids in under-saturated
systems, which are much simpler than ones available, so far. In turn these provide easier comprehension of the workings of
the shrinking sphere model. Finally, existing results for biogenic silica dissolution are reviewed in the light of the above-mentioned
experimental and modelling advances. An earlier claim that shrinking sphere dissolution had been observed is refuted. 相似文献