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1.
张邵春 《湖南地质》2002,21(4):299-301
采用新型无硒混合添加剂制取高纯无硒电解金属锰,可以使电解金属锰中硒含量控制在O.001%以内,锰含量达到“三九”锰标准,具有显著的经济价值。  相似文献   

2.
碘量法快速测定电解金属锰中硒   总被引:1,自引:0,他引:1  
王香桂 《岩矿测试》2006,25(1):93-94
采用在HCl介质中定量加入Na2S2O3溶液,用淀粉作指示剂,过量的Na2S2O3以碘标准溶液进行滴定,间接测定电解金属锰中的硒。方法的加标回收率为92.5%-107.5%,对w(Se)=0.078%的样品进行10次测定的RSD为3.02%,用于实际样品测定,结果与国标法相符。  相似文献   

3.
采用7步连续浸提法对库布齐沙漠响沙湾沙粒中磷的各种存在形态进行了分析测定,并对沙粒样进行了分级形态研究。结果表明:在库布齐沙漠响沙湾沙粒中总磷(TP)的含量为137.21~362.09μg/g,其主要成分为无机磷(IP),平均占TP的比例为94.60%;而有机磷(Or—P)的含量为7.88~19.12μg/g,平均占TP的5.40%。在所有不同粒度的沙样中,自生钙结合磷(Ca—P)含量最高,占TP的58.95%~80.05%,其次是原生碎屑磷(De—P)。占TP的8.13%~30.22%,二者占IP的绝大部分;其他各形态磷含量的高低顺序为:有机磷(Or—P)〉吸附态磷(Ads—P)〉铁结合态磷(Fe—P)〉闭蓄态磷(Obs—P)〉铝结合态磷(AI—P)。在所取沙漠颗粒物样中TP、Ca—P、De—P、Or—P、AI—P各自的含量都是随颗粒物粒度的减小而增大,而Ads—P含量则相反;Fe—P、Obs—P的含量受颗粒物粒度变化的影响不大。  相似文献   

4.
太湖五里湖表层沉积物中不同形态磷的分布特征   总被引:23,自引:0,他引:23  
利用连续提取法(SEDEX)详细调查了太湖五里湖表层沉积物中不同形态磷的组成和分布特征。结果显示:其中磷的含量较高,受人为污染输入的影响较大,并且已经有了一定的释放。总磷的变化范围为2.05~4.05mg/g。平均约为2.80mg/g。总磷主要由无机磷组成(70%~90%),大多数无机磷为CDB溶液提取的铁结合态磷(75%~85%)。CDB溶液的n(Fe)/n(P)都较小(2.0~5.3)。说明CDB溶液提取的铁主要是以无定形态存在的,并且铁与磷酸盐之间的吸附可能已经达到了平衡状态。除底部个别样品以外。多数样品n(Gorg)/n(Norg)较小(8.8~10.6),所有样品的n(Gorg)/n(Porg)都较大(135~320),表明沉积物在早期成岩作用过程中,湖泊内源自生有机质降解时有机磷优先释放。无机磷,特别是铁结合态磷,在氧化还原条件变化的情况下。能够通过沉积物一水体界面被再次释放到水体中去,这可能对湖泊的水体质量和营养状况有一定的影响。  相似文献   

5.
密云水库沉积物中磷的形态和分布特征   总被引:26,自引:3,他引:26       下载免费PDF全文
采用连续提取化学分析技术,对密云水库的柱状沉积物和表层沉积物样品进行了磷形态的提取分析,研究了各种形态磷在表层及垂立方向上的分布特征。分析结果表明,密云水库沉积物中以无机磷为主,有机磷次之,无机磷占总磷的76.88%。95.09%。沉积物中总磷及其不同形态无机磷在垂直方向上的分布变化规律为:总磷、可溶态磷含量随深度增加而降低,Ca—P合量随深度增加而增加,Al—P和闭蓄态磷变化幅度不大,Fe—P、有机磷的垂直方向变化情况较复杂。潮、白河流域总磷与各形态磷在表层及垂直方向上的分布差异在一定程度上反映出近年来水库所受上游流域工业活动和人为污染的影响情况。  相似文献   

6.
马建华 Fili.  GM 《世界地质》1994,13(4):90-94,111
长期以来,海洋中的磷处于限制生长状态,因此,研究自古以来海洋中磷的集聚变化对于确定海洋古生产率模式是很重要的。我们测定了加利福尼亚谢尔海滩的磷含量和集聚速率,即富磷海相沉积岩的一个岩段,其中含有蒙特雷组普遍存在的磷质和硅质岩相。磷含量在这些岩相的主要岩性中分布很广。在磷质页岩中,重量已达到0.36wt%~3.9wt%,与此相比,白云岩和硅质岩中只有0.02wt%~0.42wt%。磷集聚速率(此处记录的所有数值的单位为umo1Pcm ̄(-2)a ̄(-1))随样品岩性和岩段位置的不同而表现出很大的差异。两种岩相中的磷质页岩的磷集聚速率(1.5~29)都大大高于白云岩和硅质岩(0.1~3.1)。此外,上部硅质岩相的磷质页岩与下部磷质岩相的磷质页岩相比,前者的磷集聚速率(3.1~29)通常高于后者(1,5~14)。根据各岩相的线性沉积速率模式以及观察磷质页岩、白云岩和硅质岩的相对磷含量而计算出的磷平均集聚速率,在磷质和硅质岩相之间是相差不大的。这表明这两种岩相(其动物群和沉积学特征被认为反映了中中新世期间的主要海洋和气候变化)具有相似的磷埋藏量。磷的总集聚速率与其它中新世和现代成磷环境也差不多相同。我们设计了多种沉  相似文献   

7.
本区前震旦纪沉积变质磷灰岩矿床,呈层状,似层状及透镜状,产于中元古界红安群黄麦岭组下段和上段含磷岩系中。下部含磷岩系分布于大磊山周围,有磷灰岩1-3层,平均厚2-18m;上部含磷岩系发育在左家湾-双峰尖一带,产磷灰岩1-2层,厚1.5-13m。本区沉积变质磷灰岩可分为浅粒磷灰岩、变粒磷灰岩、锰质磷灰岩及碳酸质磷灰岩等四种类型,其P2O5含量一般为4.6-26.1%之间。黄麦岭组属于海湾-浅海机沉积  相似文献   

8.
镁斜磷铁锰矿产于四川某地含铍伟晶岩的中部,该伟晶岩分带性弱,但钠长石化发育,与之共生的矿物有镁电气石、蓝色绿柱石、石榴石、白云母、石英及黄铁矿等。镁斜磷铁锰矿为肉红色块状体,玻璃光泽,摩氏硬度5.5-6.0,比重3.81,具(001)解理,在单偏光下无色或带有灰色的白色,多色性弱,突起较高,Ng=1.734,Nm=1.728,N_P=1.675,Ng-N_P=0.059,斜消光,R>Υ。镁斜磷铁锰矿的化学成分W(B)/%是Mgo6.2l.Cao0.07,Al_2O_30.8i,Sio_2o.39,MnOl4.36.Feo_35.48,P_2o_54l.85,∑99.17。  相似文献   

9.
江西雅山黄玉锂云母花岗岩中富磷锆石研究   总被引:5,自引:2,他引:3  
雅山黄玉锂云母花岗岩是雅山复式岩体的最晚阶段岩体,具较高的磷含量(WP2O5=0.15% ̄0.55%),长石矿物是磷的主要赋存矿物,磷以PAlSi-2替换方式进入长石结构中;锆石是雅山花岗岩重要的稀有元素副放物之一,它除了高度富铪、铀外,与一般锆石相比,还表现出显著富磷的特征,P2O5含量变化主要为WP2O5=0.23% ̄4.96%。磷主要以(Y,HRE3E,Fe)^3+P^5+(Zr,Hf)^4  相似文献   

10.
长江河田及其上海岸带水体沉积物中磷的存在形态   总被引:7,自引:0,他引:7  
刘敏  陆敏 《地学前缘》2000,7(B08):94-98
讨论了磷的5种存在形态及其分布规律。河口及岸带水体沉积物中磷主要是以有机磷(OP)和无机磷(IP)形式存在的,有机磷是有机质的组成部分,无机磷又可分为可溶性磷(DP)、铁结合磷(Fe-P)、铝结合磷(Al-P)、铝结合磷(Al-P)、钙结合磷(Ca-P)。研究发现,沉积物中总磷含量水平在692.79~1570.99μg/g之间,无机磷含量在220.02~928.33μg/g之间,占总磷含量的31.8%~60.5~,而有机磷含量在394.89~642.66μg/g之间,为总磷含量的39.5%~68.2%。在分析水体喾物中各形态磷的含量和变化的基础上,对磷在时空上的变化,与有机碳、总氮的关系以及污水输入影响等进行了初步的论述,并提出沉积物中铁结合磷(Fe-P)和铝结合磷(Al-P)可作为判断污染的指标之一。  相似文献   

11.
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

12.
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   

13.
Robert L. Linnen   《Lithos》2005,80(1-4):267-280
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

14.
15.
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).  相似文献   

16.
正20141520 Bo Ying(Key Laboratory of Metallogeny and Mineral Assessment,MLR,Beijing 100037,China);Liu Chenglin Saline Spring Hydrochemical Characteristics and Indicators for Potassium Exploration in Southwestern and Northern Tarim Basin,Xinjiang(Acta Geoscientica Sinica,ISSN1006-3021,CN11-3474/P,34(5),2013,p.594-602,5 illus.,3 tables,28 refs.)  相似文献   

17.
正20141243Chen Ge(Hangzhou Research Institute of Petroleum Geology,PetroChina,Hangzhou 310023,China);Si Chunsong Study on Sedimentary Numerical Simulation Method of Fan Delta Sand Body(Journal of Geology,  相似文献   

18.
正20142599Chen Sanming(Guangxi Key Laboratory of Concealed Deposits Exploration,Guilin University of Technology,Guilin541004,China);He Yuzhou Block Model and Reserves Estimation of Panzhihua Iron Deposit Based on 3D Geological Modeling(Journal of Guilin University of Technology,ISSN1674-9057,CN45-1375/N,33(4),2013,p.610-615,9illus.,1table,15refs.)  相似文献   

19.
正20140594 Bai Daoyuan(Hunan Institute of Geology Survey,Changsha 410016,China);Zhong Xiang Faults in the Jingzhou Basin and Their Tectonic Settings(Geotectonica et Metallogenia,ISSN1001-1552,CN44-1595/P,37(2),2013,p.173-183,6illus.,59refs.)Key words:basin evolution,tectonic setting,South China In the Upper Paleozoic and Jurassic se-  相似文献   

20.
正20141912Cao Hui(State Key Laboratory for Continental Tectonics and Dynamics,Institute of Geology,Chinese Academy of Geological Sciences,Beijing 100037,China)Gravitational Collapse and Folding during Orogenesis:A Comparative Study of FIA Trends and Fold Axial Plane Traces(Geology in China,ISSN1000-3657,CN11-1167/P,40(6),2013,p.1818-1828,9illus.,35refs.,with  相似文献   

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