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1.
表面活性剂增敏催化动力学光度法测定水中亚硝酸根   总被引:1,自引:0,他引:1  
陈兰化  马伟 《岩矿测试》2000,19(3):232-234
基于在H2SO4介质中,十二烷基硫酸钠对NO^-2催化KBrO3氧化藏红T褪色反应的增敏作用,建立了测定NO^-2的催化动力学光度法,灵敏度较不加十二烷基硫枰钠的方法提高了5.6倍。测定NO^-2的线性范围为10~140μg/L,检出限为6μg/L。方法用于水样中NO^-2的测定,与格里斯法相符,加标回收率为96%~106%,5次测定的RSD〈5%。  相似文献   

2.
利用实验室含水层物质微环境实验,对地下水中常见有机污染物苯和甲苯在厌氧反硝化条件下的微生物降解进行了研究。通过10种方案实验结果的分析对比,所得重要结论如下:在加强了的反硝化条件下,微生物利用NO-3作为电子受体降解苯和甲苯;降解苯和甲苯的反硝化细菌来自于含水层物质;微生物所需的宏量营养由苯、甲苯和硝酸盐提供,痕量元素来自于含水层物质;环境的酸碱条件对微生物降解具有重要影响,pH值过高或过低均抑制微生物降解作用的产生。  相似文献   

3.
不同植物凋落物对土壤有机碳淋失的影响及岩溶效应   总被引:25,自引:2,他引:23       下载免费PDF全文
以低含量有机碳的岩溶土壤(SOC, 0.89%)为媒介,每150g上添加松针、梧桐叶粉各 7.5g,15g,4个试验土柱号分别为SCC3,SCC5;SBC3,SBC5,接种岩溶土壤微生物群落后,于 恒温室内进行培养淋溶实验。结果表明,土壤淋溶液的电导值受土壤有机质含量多少及性质 的影响。土壤水溶性有机碳(DOC)淋失总量SCC3为540.7mg,SCC5为1522.9mg;SBC3为 383.2mg,SBC5为563.5mg。同时,土壤环境中Ca+的释放总量SCC3为145.7mg,SCC5为 288.7mg; SBC3为170.0mg,SBC5为167.9mg。两者呈正相关,相关系数r=0.85。下伏碳酸 盐岩的溶蚀量排序为SCC5>SBC3>SCC3>SBC5,表明两种不同植物凋落物经微生物分 解,产生不同质和量的DOC,并导致土壤环境中 Ca+释放的差异和不同的岩溶效应。从而初步揭示不同有机碳分解导致DOC淋失的差异性,以及DOC对岩溶动力系统的驱动。这与A.Heyes和T.R.Moore的研究结果一致。  相似文献   

4.
包气带土层防护地下水污染的反硝化测定影响综述   总被引:6,自引:1,他引:5       下载免费PDF全文
施加氮肥是农业增产的有效途径,土壤反硝化作用可使其中的剩余、淋洗氮素得到消散和净化,使地下水免受污染。但影响包气带土层中反硝化测定的因素较复杂,目前还没有较完善的测定方法。文章在论述包气带土层反硝化作用的实质与影响因素基础上,总结了现行反硝化测定方法的影响与不足。结合现有监测技术的发展及对包气带土层中物质、能量的转化和分布认识,探讨分析了适宜于研究包气带土层防护地下水污染的反硝化测定方法,为相关学科研究提供借鉴。  相似文献   

5.
应用溶解氧值确定含煤河水BOD_5稀释倍数丁超美,赵香秀,文志红(阳泉市环境保护监测站)1含煤废水的特殊性BOD5的测定是一种经验的生物实验方法。测定样品的关键是稀释倍数的确定。稀释倍数过大或过小,将使五日需氧量太少或过多,超出耗氧量范围使实验失败。?..  相似文献   

6.
包气带作为防止地下水硝酸盐污染的天然屏障,其反硝化效果通常受到碳源的限制。针对地下水硝酸盐污染防治技术现状,本文采用Ca(OH)2处理的玉米芯作为反硝化的碳源材料,构建包气带强化反应层,用响应曲面法研究硝酸盐浓度、含水量和温度的交互作用对脱氮性能影响,并用硝态氮去除率、亚硝态氮累积、pH值变化以及溶解性有机碳(dissolved organic carbon, DOC)淋失通量综合评价脱氮性能,最后采用高通量测序揭示脱氮层中微生物变化。研究结果表明:温度、含水量以及温度和含水量交互作用对硝态氮去除率影响显著,其中温度是反硝化过程中最关键的因素;系统运行74天后,硝态氮去除率达到50%,亚硝态氮累积量(以N计)大多低于3 mg/L,pH值维持在7.0左右,DOC淋失通量(以C计)介于0.10.2 mg/(cm2·d);高通量测序发现,脱氮层中微生物的丰富度降低,而与反硝化和碳分解有关的微生物相对丰度提高,在碳源的刺激下微生物向有利于脱氮的方向演变。  相似文献   

7.
SEDBA检索系统(FOXSEDBA3.1)用FoxProZ.5编程.它具有对SEDBA数据库进行查询、检索、打印输出、作图以及应用的工能,是用户对SEDBA进行检索和应用的工具。整个系统由全菜单驱动,并为用户提供了良好的人机对话界面.它不需要具备计算机的知识便易于驱动。系统可以直接在DOS下运行。  相似文献   

8.
陈吉书  徐其亨 《岩矿测试》1999,18(4):288-290
在H3PO4介质中,Ru(Ⅲ)对KIO4氧化二安替比林间溴苯基甲烷(DAmBM)的显色反应有明显的催化作用。基于此,建立了测定痕量钌的催化分光光度分析法,并且测定了一些动力学参数。方法的检出限为2,3μg/L,钌的质量浓度在0 ̄12μg/L符合比尔定律。方法已应用于矿样中痕量钌的测定,5次测定的RSD〈5%,加标回收率在96 ̄101%。  相似文献   

9.
本文通过钢铁工业废水淋溶钢铁工业渗漏区土壤,不同pH值,不同含Ca^2+,F^-浓度与放心水与工业淋溶各种土壤,以及电厂冲灰水淋溶粉煤灰的三种试验,讨论废水中C6H5OH、CN^-AS、Cr,Pb,Zn,H2S,BOD,COD,F^-,Cl^-,SO^2-R,NO^-3,NH^+4,Na^+和硬度等的污染与自净规律,并提出了防治地下水污染的措施。  相似文献   

10.
梅铁  高志 《岩矿测试》1994,13(2):131-133
在PH4.5-6.5条件下,Zn与3,5-diBr-PADAP及SDS形成可溶性紫红色络合物,利用此体系以3,5-diBr-PADAP为指示剂,锌盐回滴法测定铁矿中的Al2O3溶液颜色由亮黄变为紫红,络点突跃敏锐,Fe^3+的黄色不影响终点观察。  相似文献   

11.
International unity is becoming ever stronger in this country owing to an increasing similarity in the development of the cultural environment. This comprises the provision of all the country's republics with a sufficient number of schools, theatres, and other institutions and cultural information media in accordance with the needs of the population. An important part is played by the rise in ‘the general educational level, as well as the level of professional qualifications and skills. Among all the Soviet nations and nationalities, this rise being more rapid among formerly backward peoples. Prominent among the factors of internationalization is the progressive development of the nationalities’ cultural resources, while professional culture is being increasingly brought within the reach of the masses.The implementation of the nationalities policy promotes the all-round development of all Soviet nations and nationalities, their drawing together, the upsurge of the individual capabilities of every Soviet citizen.  相似文献   

12.
The Global Stratotype Section and Point (GSSP) for the base of the Silurian System was defined in 1985. Since that time, a number of researchers have suggested that this section has serious deficiencies for use as a GSSP. As a result, in 2000, the Subcommission on Silurian Stratigraphy (SSS) proposed undertaking a formal restu@ of this GSSP, which was subsequently approved by the International Commission of Stratigraphy (ICS). The result of this restudy was the formal proposal that the current GSSP, at 1.6 m above the base of the Birkhill Shale, at Dob's Linn, Scotland, should be maintained as the same locality and stratigraphic level, but the bios- tratigraphical definition of the boundary should be revised. The previously defined, basal Silurian grapto- lite zone, the Parakidograptus acuminatus Zone, should be subdivided into a lower Akidograptus ascensus Zone and a higher E acuminatus Zone. The base of the A. ascensus Zone, marked by the first appearance of A. ascensus, should be regarded as the biostratigraphic mark for the base of the Silurian. This proposal has now been formally approved by the SSS and ICS, and ratified by International Union of Geological Sciences. This is the first GSSP to undergo formal restudy and redefini- tion, and the proposal also included a recommended procedure for restudy of GSSPs.  相似文献   

13.
It is known from observations that the center of mass of the Moon does not coincide with the geometric center of its figure, and the line connecting these two centers is not aligned with the direction toward the center of the Earth, instead deviating toward the Southeast. This stationary deviation of the axis of the inertia ellipsoid of the Moon to the South of the direction toward the Earth is analyzed. A system of five linear differential equations describing the physical libration of the Moon in latitude is considered, and these equations are derived using a new vector method taking into account perturbations from the Earth and partly from the Sun. The characteristic equation of this system is obtained, and all five oscillation frequencies are found. Special attention is paid to the fifth (zero) frequency, for which the solution of the latitude libration equations are stationary and represents a previously unknown additional motion of the rotational axis of theMoon in a cone with a small opening angle. In contrast to the astronomical precession of the Earth, the rotation of the angular-velocity vector is in the positive direction (counter-clockwise), with the period T 3 = 27.32 days. On this basis, this phenomenon has been named “quasi-precession.” This quasi-precession leads to a stationary inclination of the major axis of the inertia ellipsoid of theMoon to the South (for an observer on Earth), making it possible to explain one component of the observed deviation of the center of mass of the Moon from the direction toward the Earth. The opening angle of the quasiprecession cone is approximately 0.834″.  相似文献   

14.
Important tendencies in development of the world mineral-resources sector at the beginning of the 21st century were an increase in production and consumption of mineral materials differentiated by types of metals and nonmetallic mineral raw materials, by countries and regions, as well as the concentration of the production of mineral raw materials in a small number of countries, and a reduction in industrial reserves of minerals in the world economy, even at the current stage of their extraction. These tendencies should be taken into account in working out a strategy for development of the Russian mineral raw-material base.  相似文献   

15.
Taking the example of W Sudan, an analysis of the climatic incidents leading to the two recent famine disasters is made. On this natural background, the human side is investigated. Focus is directed towards the fragile economic structure of the famine-prone population groups. An early-warning system for famine in the Sahelian Zone is proposed taking grain production and storage, livestock development and the relationship between the prices of livestock and grain as major indicators.  相似文献   

16.
东濮凹陷北部沙三中亚段广泛发育盐岩和烃源岩,这两个看似不能共存的物质却在这里互层共生。该时期研究区沉积特征为多盐韵律与多层烃源岩互层共生、连续沉积,单个盐韵律厚度从几米到十几米,烃源岩有机质丰度高、类型好。平面上,两者在湖盆沉积沉降中心共生;垂向上,高有机质丰度、好干酪根类型与高盐度地层具有较好的对应关系。因而成为恢复古气候和古环境的重要研究对象。通过岩石学、古生物学以及Sr/Ba、B/Ga、(V+Ni+Mn)、Fe/Mn、Sr/Cu、Mg/Ca、V/(V+Ni)、稀土元素含量和氯同位素等方法对凹陷北部沙三中亚段的沉积环境进行研究。结果表明,凹陷北部沙三中亚段为深水沉积的还原环境,古盐度较高,达到半咸水-咸水沉积;微量元素和孢粉化石特征表明研究区沙三中亚段为温暖潮湿的环境。  相似文献   

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19.
郯庐断裂南段研究进展与断裂性质讨论   总被引:13,自引:3,他引:13  
据1:5万区域地质调查和专题研究资料,就郯庐断裂带是否南延与消失的原因,其与大别—苏鲁造山带交截形成的假位错效应,以及与中新生代沉积盆地形成演化的关系等作了新的阐述。在此基础上,讨论了郯庐断裂带是否为巨大的左行平移断层或转换断层。认为郯庐断裂带可能是在“古郯庐带”的基础上于早侏罗世重新活动、白垩纪强烈活动的地堑型枢纽断裂带。  相似文献   

20.
In order to characterise the influence of the heavyrains on the observed landslides during the 1996–1997hydrological cycle, rainfall records for the last 100years are analysed from 104 stations in easternAndalusia. Regarding the amounts of rain recordedbetween October 1996 and March 1997 in the 104stations studied, 31 presented new all-time records;15 presented values that were 80–100% of thepre-1995 record; 49 stations, 80–50%; and 9stations, < 50%. A map has been devised of thesusceptibility of the materials through which thesouth-eastern Andalusian road network crosses,together with an inventory of the damage caused byinstability phenomena on banks and cuttings of theroad network during the winter of 1996–1997. Therelationships between the rainfall during the studyperiod, the damage caused to the road network and thesusceptibility of the materials affected are analysed.The results indicate that there is a clearcorrespondence between the rainfall recorded and thesusceptibility of the materials with the inventorieddamage. It is concluded that the widespread seriousdamage caused in early 1997 to the roads andsurrounding areas in the Alpujarra region and thecoast of the Province of Granada was mainly caused bythe extraordinarily heavy rains. However, considerablyless damage was observed where the susceptibility ofthe terrain is low, thus highlighting the extremeusefulness of terrain-susceptibility maps for riskprevention and territorial planning.  相似文献   

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