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1.
张宏飞  骆庭川 《地球科学》1994,19(2):219-226
对扬子克拉通北缘新古代岛弧花岗岩类成分极性的地球化学研究表明,在SiO2含量相近的条件下,由北向南岩石中K2O、K2O+Na2O,K2O/Na2O逐渐增加,而CaO逐渐降低;从北向南,微量元素Rb,Ba,Th,Zr,Nb,Ta,ΣREE及Rb/Th,Rb/Nb,ΣLREE/ΣHREE(La/Yb)N等逐渐增加或具增加趋势,而Sr,Co,Ni和Sr/Ba具逐渐降低或具降低趋势;同位素组成成由北向南δ  相似文献   

2.
陆琦  周湖云 《矿物学报》1994,14(4):343-347,T001
本文回顾了国内外金伯利岩及其它地幔岩中发现的K、Ba、Ca、REE的Ti-Cr-Fe-Mg氧化物矿物的研究现状,包括沂蒙矿系列、蒙山矿系列及柱红石系列。在此基础上概括性地总结了笔者近一、二年对山东蒙阴金伯利岩中蒙山矿矿物所进行的微区矿物学方向研究取得的最新进展,包括①揭示了K、Ba、Ca、REE等半径较大的元素在蒙山矿中的不均匀分布特点;②首次在金伯利岩中发现了蒙山矿系列矿物的Ca端元-Ca蒙山矿  相似文献   

3.
灵台风尘堆积中钙质结核的地球化学研究   总被引:9,自引:0,他引:9  
孙有斌  周杰  安芷生 《地球化学》2000,29(3):277-282
通过对甘肃灵台风成黄土-古土壤-红粘土序列中钙质结核的野外分布及形态特征观察,并对主元素和微量元素进行化学分析,发现结核中氧化物活动给分和惰性组分含量的比值在剖面中自下而上逐渐变大,反映了结核形成时其上覆土层所经历的淋溶程度逐渐增强;而MgO含量校正后的MgO/Cao比值则逐渐减小,批示结核形成时环境温度逐渐降低。灵台剖面自下而上不同层位结核中Sr/Ba比值及CaCO3含量的变化同氧化物含量及比值  相似文献   

4.
方维萱  黄转莹 《岩石学报》1999,15(3):484-491
本文通过对银硐子特大型银多金属矿床中重晶石岩类的岩石学、矿物学、地球化学等特征研究和总结, 认为本区重晶石岩类是由热水流体同生沉积作用形成的。热水成岩成矿作用方式有两种, 重晶石单矿物岩成分纯度高, Ba S O4 的含量为 7729% ~9937% , 其他成分混入少, 以热水快速化学沉淀的方式同生沉积形成; 重晶石岩类及银多金属矿石中, Ba O(569% ~2906% )、 Si O2、 Al2 O3、 Fe2 O3 、 Fe O、 Na2 O、 S、 Cu、 Pb、 Zn、 Ag 等含量高, 是不同成分、性状热水混合触发的层流体系失稳造成矿质大量骤沉, 热水混合同生沉积作用形成了重晶石岩类及银多金属矿层。  相似文献   

5.
矿物3CaO·3Al_2O_3·BaSO_4形成过程研究   总被引:1,自引:0,他引:1  
eoreanu等[1]研究CaOAl2O3Mx(SO4)Y[M=Mg2+、Sr2+、Ba2+、Zn2+、Fe2+、Fe3+、Al3]系统中,形成类似于矿物3CaO·3Al2O3·CaSO4(硫铝酸钙)的可能性时,报道合成了新矿物3CaO·3Al2O3·BaSO4(简写为3CA·BaSO4);部分学者[2,3]研究过它的胶凝性能等。在有关文献中,研究者制备研究用纯矿物的煅烧条件、获得样品的矿相组成不尽相同。如文献[1]在温度1400℃保温240min,制备的样品包括铝酸钙(CaO·Al2O3…  相似文献   

6.
在大别山菖蒲地区新鲜硬玉石英岩逐步退变为片麻岩的变质作用过程中,其岩相学以及地球化学元素发生了一系列有规律的变化。SiO2,FeO,微量元素Ba,Zr,Ga以及稀土元素La,Ce,Pr,Nd,Sm,Eu逐步升高,而TiO2,Na2O,Fe2O3微量元素Rb,Y,Nb以及稀土元素Gd,Tb,Dy,Ho,Er,Tm,Yb则逐步降低。这反映了矿物晶内的元素的迁移以及外来流体的参与在一定的程度上制约一岩相  相似文献   

7.
颜佳新  伍明 《沉积学报》1998,16(4):79-84
在详细的沉积作用,成岩作研究基础,利用多元统计分析方法重点对湖北省巴东水布垭剖面栖霞组碳酸盐岩地化学特征刊物了分析。研究表明,该组碳盐岩中CaO、Al2O3、K2O、Fe2O3、P、Ba和Mn的含量主要与沉积环境或原岩岩性关。  相似文献   

8.
陆琦  周湖云 《矿物学报》1994,14(3):228-233,T001
在山东蒙阴金伯利岩中,首次发现了沂蒙矿类质同象系列新的富Ti矿物(变)种。理想的晶体化学式可表达为:K(Ti5Fe3Cr2Mg2)12O19(简称K-Ti沂蒙矿)(Ba,K)(Ti5Fe4Mg2Cr)12O19(简称Ba-Ti沂蒙矿)从而与原来确定的沂蒙矿K(Cr5Ti3Fe2Mg2)12O19和钡钛铁铬矿(Ba,K)(Cr4Fe4Ti3Mg)12O19g一起构成了金伯利岩中AM12O19磁铁铅矿  相似文献   

9.
通过4个月实地和近3年的追踪观测,查明拒马矿泉水产于涞源县浮图峪铜矿区的闪长玢岩与夕卡岩接触带中。H_2SiO_3含量25~39mg/L;Sr含量0.40~0.39mg/L,还含有CO_2,I,Br,Li,Zn,Mo,Se,Cu等多种对人体有益的微量元素,是极为宝贵的矿泉水资源。  相似文献   

10.
本文使用PC-1500计算机,选用华亭煤产地主要可采煤层煤_8层原煤煤岩、煤化学指标和α值(煤与二氧化碳分解率),应用R型因子分析方法,讨论影响该煤煤化学活性的内在因素。其分析结果表明:该煤原煤V_(daf)、V+BV、CaO、MgO含量偏高,有利于煤与二氧化碳的热分解反应,而原煤Ad、SiO_2、Al_2O_3、矿物含量偏高,抑制煤与二氧化碳的热分解反应。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

13.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

14.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

15.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

16.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

17.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

18.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

19.
滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.  相似文献   

20.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

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