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1.
刘斌 《地球化学》1985,(1):90-97
Three thermodynamical equations, for unitary two-phase fluid inclusions have been deduced. (1) The thermodynamical equation for mutual transformation between gas and liquid phases in fluid inclusions. The transformation direction from one phase to the other can be known in terms of the density and filling degree of gas and liquid. (2) The thermodynamical equation for pressure effect on temperature after homogenization of fluid inclusions. The coefficient of P-T variation is directly proportional to the fining degree of gas phase and inversely to the density of gas phase and liquid phase. Equations for homogenization, decrepitation and formation temperatures of fluid inclusions can be inferred from. this equation. (3) The thermodynomical equation for decrepitation temperatures of fluid inclusions. Many factors have effects on the decrepitation temperatures of fluid inclusions.Decrepitation temperature cannot be considered in any case as formation temperature.Thermal and vapor halos produced by decrepitation of minerals of the same kind and the same period from the same locality are worthy of consideration.  相似文献   

2.
Types of polymerized molecular network structure and degree of bond breakdown for glass phases of magmatic inclusions and glassy matrix in volcanic rocks from the Shengli oilfield have been defined by the laser Raman spectroscopic investigation. There are significant differences in types of polymerized molecular network structure and degree of bond 'breakdown of the magmatic glass phases between the non-CO2 and COa gas pools: magmatic glass phases of fluid inclusions and matrix in volcanic rocks from the CO2 gas pool contain more sheet network molecules and have a greater degree of bond beakdown than those from the non-CO2 gas pool; and when gas bubbles occur in evolving magma, magma saturated with volatile components has more sheet network molecules. The results suggest the magma-degassing mechanism of the formation of CO2 gas pools in the Shengli oilfield.  相似文献   

3.
Presented in this paper are the rypes,salinities,homogenization temperatures and organic components of fluid inclusions formed at the four stages of diagenetic authigenesis in the Eogene of the Biyang Depression.The results of cooling experiments on fluid inclusions were used to determine the fluid system and composition of saline aqueous solution in each of the stages .The homogenization temperatures of saline aqueous solution inclusions and hydrocarbon organic inclu-sions have been corrected by two approaches ,and the trapping temperatures and pressures of fluid inclusions at each of the stages have been obtained.This strdy has shed light on the physicochemistry and evolution of diagenetic fluids.The diagentic fluid system is a system which was transformed from a chloride-bearing to a carbonate-bearing system along with the diagenic evolu-tion.The decrease of diagenetic temperature at Stage III of diagenetic authigenesis suggests that the depression would have experiences uplifting at that time.The fluorescent characteristics of fluid inclusions indicate the varieties of organic components in fluid inclusions both in time and in space.  相似文献   

4.
Amino acids have been separated from and identified in the Jilin meteorite No.Ⅰ and Ⅱ by gas-liquid chromatography. Eight kinds of amino acid, i.e., α-alanine,valine, glycine, isoleucine, β-alanine, leucine, proline, and threonine are observed in meteorite No. Ⅰ Ten varieties of amino acids including serine, hydroproline, lysine and etc. are noticed from meteorite No. Ⅱ. A brief diseussion is given to the origin of these acids.  相似文献   

5.
In the Yongjin oilfield of southern Junggar Basin, many wells have been drilled to produce industrial oils. Based on the analysis of fluid inclusions in the reservoirs, in combination with the geological and thermal evolution, the charge history in this area has been studied. The results indicate that the Jurassic Formation and Cretaceous Formation reservoirs contain abundant oil and gas inclusions, and four types of fluid inclusions have been distinguished. According to the homogenization temperatures of the fluid inclusions, the hydrocarbons charged the Cretaceous Formation for two periods, one ranges from the Late Cretaceous period to the Eogene period, and the other ranges from the Neocene period to the present. The oil filling history is correlated with the oil source correlation analysis, which is controlled by the movement of the Che-Mo plaeo uplift. Overall, oil accumulation is characterized by the superposition of two sets of source rocks for two stages in the Shawan depression.  相似文献   

6.
Isoprenoid compounds in the Jilin meteorite are isolated and identified by a combined chromatography-mass spectrometry. In the chromatographic part of this instrumentation, the open glass capillary is coated with SE^30 carrier. Chromatographic and mass spectrometric evidence of the existance of pristane and phytane in the Jilin meteorite has been presented and the possible origin of these compounds briefly discussed  相似文献   

7.
Terrigenous clastic reservoir rocks are widespread in China,and nearly all the industrial oil and gas accumulations in eastern China occur in the clastic rocks.The study shows that organic inclusions are mostly distributed in the secondary fissures and pores which were ormed in the process of oil-rock interaction,rather than in the cements or secondary enlargements. The organic inclusions are dominantly organic gas-rich or are composed of pure hydrocarbons.Homogenization temperatures range mainly from 120℃ to 130℃，which shows a relatively high maturity of organic matter.Vertical and horizontal temperature changes provide the grounds for the investigation of basin evolution and thermal fluid-kinetics-model.Fluorescence spectral characteristics o the organic inclusions indicate that oils and gases in the area studied probably have experienced two-stage or two-time migration.Micro-fluorescence rescearch is one of the effective approaches to oil/source correlation and oil migration-stage determination.The abundance and occurrence of organic inclusions is one of the indicators of oil and gas abundance and accumulation in rock layers.With the help of other informatio,organic inclusions can provide the basis for the prospective assessment of oil and gas in clastic reservoir rocks.  相似文献   

8.
Tectonic movements since the Neogene have been the major developmental and evolutional stages of the latest global crustal deformation and orogenic movements. China is located in a triangular area bounded by the Indian landmass, the West Siberian landmass and the Pacific Plate, characterized by relatively active tectonic movements since the Neogene, and in this region, natural gas would have been very easy to dissipate, or difficult to preserve. Therefore, the characteristics of post-Neogene tectonic movements offer important geological factors in researching the formation and preservation of gas reservoirs in China. Summarizing the reservoiring history of gas fields in China, although there are some differences between various basins, they are all affected by the tectonic  相似文献   

9.
Conditions for the Formation of oil and gas pools in Tertiary volcanics in the western part of the Huimin sag, Shandong and then (?)stribution have been studied based on the geological, seismic and well-logging information. In this paper, the types and lithofacies of the volcanic rocks in the western part of the Huimin sag are described; the relationship between rocks and electrical properties, the seismic reflection structures, the development and distribution of the volcanic rocks are expounded; and the fourfold role of the volcanic activities in the formation of the oil and gas pools is also dealt with. It is considered by the authors that the volcanic activities were not destructive to the formation of oil and gas pools but a factor favourable to the accumulation of organic matters and their conversion to hydrocarbon. The volcanic rocks might have served as reservoir rocks and cap rocks, or as a synsedimentary anticline. The prerequisites and important factors for the formation of oil and gas pools and their distribution are pointed out in the paper.  相似文献   

10.
The Chinese landmass, as a composite region, consists of multiple small continental blocks, such as Sino-Korea, Yangtze, Tarim, etc., and orogenic belts. Because of its distinctive tectonosedimentary evolution, China’s oil/gas-bearing regions differ remarkably from that elsewhere in the world. For instance, in comparison to the Middle East oil/gas-bearing regions which are characterized by Mesozoic-Cenozoic marine oil/gas-bearing beds, early oil and gas discoveries in China are distributed mainly in Mesozoic-Cenozoic continental sedimentary basins. Generation of oil from terrestrial organic matter, or terrestrial oil generation, and the formation of large oil/gas fields in continental sedimentary basins were previously the major characteristics of petroleum geology of China. However, in the past 20 years, a series of major oil and gas discoveries from marine strata have been made. Marine oil/gas fields in China are mainly distributed in the Tarim, Sichuan, and Ordos basins, which are tectonically stable and covered with Mesozoic-Cenozoic deposits. In these basins, hydrocarbon-bearing strata are of old age and the oil/gas fields are commonly deeply-buried. Cumulatively, 995 oil/gas fields have been found so far, making China the fourth largest oil-producing country and the sixth largest gas-producing country in the world. In terms of petroleum and natural gas geology, theories of hydrocarbon generation from continental strata, such as terrestrial oil generation and coal-generated hydrocarbons, etc., have been established. Significant progress has been made in research on the sequence stratigraphy of continental strata, formation mechanisms of ultra-deep clastic reservoirs, and hydrocarbon accumulation in the continental subtle reservoir. Regarding research on the marine petroleum geology of China, with respect to the major characteristics, such as deeply-buried reservoirs, old strata, and multiple phases of transformation, important advances have been made, in areas such as the multiple-elements of hydrocarbon supply, formation of reservoirs jointly controlled by deposition, tectonic activities, and diagenetic fluid-rock reactions, and oil/gas reservoirs formed through superimposed multi-stage hydrocarbon accumulation. As more and more unconventional hydrocarbon resources are discovered, unconventional oil and gas reservoirs are under study by Chinese petroleum geologists, who endeavor to come up with new discoveries on their formation mechanisms.  相似文献   

11.
Low-mature gases and their resource potentiality   总被引：1，自引：0，他引：1  
In the 80’s of last century, based on the advances in natural gas exploration practice, the concepts of bio-thermocatalytic transitional-zone gas and early thermogenetic gas were proposed, and the lower limit Ro values for the formation and accumulation of thermogenetic natural gases of industrial importance have been extended to 0.3%–0.4%. In accordance with the two-stage model established on the basis of carbon isotope fractionation involved in the formation of coal-type natural gases, the upper limit Ro ...  相似文献   

12.
comparatively evident chondritie structure is observed in the Jilin meteorite. Chondrules range from 0.2 to 3mm in diameter, averaging 0.6mm. Chondrules can be divided into the following types according to the principal minerals crystallized and structure-texture characteristics: (1) Olivine chondrules. In terms of their structure they can be subdivided into prophyritic, grated, barred, sub swirlling internal flow and granular chondrulcs; (2) Orthopyroxene ahondrules. Textural types found are fan-like, radial,parallel fibrous, porphyritic and irregular; (3) Olivineorthopyroxene chondrules; (4)Glass or devitrified chondrules; (5) Ni-Fe chondrules and (6) Troilite-olivine chondrules. Among them, porphyritic and granular olivine chondrules and various kinds of radial orthopyroxene chondrules are most common. In addition, also have been recognized the overlapping of two or more chondrules and chondrules coated with glassy crust. The structure and texture of chondrules indicate that they were originated from molten silicate droplets through rapid cooling prior to the formation of the meteorite parent body. Rapid fusion may be induced on the surface of a few solidified chondrules by solar impulse wave or nebula lightning and, if rapid cooling followed, this would give rise to the appearance of glassy crust. Collision between chondrulcs may result in a variety of chondrule fragments and crystal debris. In some cases, collision is also considered to be responsible for the entrench, inclusion and overlapping textures in ehondrules. After the formation of the meteorite parent body recrystallization of chondrules may take place as a result of thermal metamorphism.  相似文献   

13.
In this paper some new advances in the study of fluid inclusions of the Yinshan deposit in Jiangxi Province,China,are presented.The fluid inclusions of the deposit can be divided into four types:1) gas-rich inclusions;2)liquid-rich inclusions;3)salt-saturated H2O inclusions;and 4)single-phase or multiphase CO2-rich inclusions.Homogenization temperatures of the fluid inclusions range from 100 to 520℃,aminly in the range 120-400℃.The daughter crystal-bearing multiphase inclusions present in quartz porphyries(including Nos.13 and 4 dikes)have been observed.In ore veins,some daughter crystal-bearing multiphase inclusions have been observed.too.On the basis of the results of fluid inclusion research,the authors suggest that the ore-forming fluid must have a close genetic relation to magmatic hydrothermal solution.The ore-forming fluid was dominantly originated from the depth and the mixing of magmatic solution with meteoric water was enhanced during ascending of the fluid,accompanying immiscibility and boiling of fluid.Teher may be a conceales igneous body at the depth of the Yinshan deposity,which furnishes the scientific basis for metallogenic prognosis at th depth of the Yinshan deposit.  相似文献   

14.
Three new carbonaceous chondrites (GRV 020025,021579 and 022459) collected from the Grove Mountains (GRV), Antarctica, have been classified as the CM2, CO3 and CV3 chondrites, respectively. A total of 27 Ca- and Al-rich inclusions have been found in the three meteorites, which are the earliest assemblages formed in the solar nebula. Most of the inclusions are intensively altered, with abundant phyllosilicates in the inclusions from GRV 020025 and FeO enrichment of spinel in those from GRV 022459. Except for one spinel-spherule in each of GRV 020025 and  相似文献   

15.
The Hetai ductile shear zone-hosted gold deposit occurs in the deep-seated fault mylonite zone of the Sinian-Silurian metamorphic rock series. In this study there have been discovered melt inclusions, fluid-melt inclusions and organic inclusions in ore-bearing quartz veins of the ore deposit and mylonite for the first time. The homogenization temperatures of the various types of inclusions are 160℃, 180 - 350℃, 530℃ and 870℃ for organic inclusions, liquid inclusions, two-phase immiscible liquid inclusions and melt inclusions, respectively. Ore fluid is categorized as the neutral to basic K+ -Ca2+ -Mg2+ -Na+ - SO2- 4-HCO3-Cl- system. The contents of trace gases follow a descending order of H2O＞CO2＞CH4＞(or ＜ ) H2＞CO＞C2H2＞C2I-I6＞O2＞N2.The concentrations of K , Ca2 + ,SO2-4,HCO3-,Cl- H2O and C2H2 in fluid inclusions are related to the contents of gold and the Au/Ag ratios in ores from different levels of the gold deposit. This is significant for deep ore prospecting in the region. Daughter minerals in melt inclusions were analyzed using SEM. Quartz, orthoclase, wollastonite and other silicate minerals were identified. They were formed in different mineral assemblages.This analysis further proves the existence of melt inclusions in ore veins. Sedimentary metamorphic rocks could form silicate melts during metamorphic anatexis and dynamic metamorphism, which possess melt-solution characteristics. Ore formation is related to the multi-stage forming process of silicate melt and fluid.  相似文献   

16.
A huge gypsum miarolitic cavity has been found locatedin an antimony mineralized layer. It is an interformational bleb. Four crystallization steps are recognized for mineral crystals in the miarolitic cavity. Gypsum crystals seem to have been formed through two forms of crystallization. The data on fluid inclusions and hydrogen isotopes.show that this cavity is the product of hypergenic process, the orebeariug solution is derived from meteorie water, and the compositional material comes from the oxidized ore zone. During the formation of the miarolitic cayity, the pH-value was within the range of 4--5, i.e., weakly acidic solution, and the formation temperature less than 50℃. It can be clearly seen from the crystallization behaviour of gypsum cyrstals and mineral association that there have taken place significant changes in the pH-value of mineralization solution.  相似文献   

17.
Fluid inclusions have recorded the history of degassing in basalt. Some fluid inclusions in olivine and pyroxene phenocrysts of basalt were analyzed by micro-thermometry and Raman spectroscopy in this paper. The experimental results showed that many inclusions are present almost in a pure CO2 system. The densities of some CO2 inclusions were computed in terms of Raman spectroscopic characteristics of CO2 Fermi resonance at room temperature. Their densities change over a wide range, but mainly between 0.044 g/cm3 and 0.289 g/cm3. Their micro-thermometric measurements showed that the CO2 inclusions examined reached homogenization between 1145.5℃ and 1265℃ . The mean value of homogenization temperatures of CO2 inclusions in basalts is near 1210℃. The trap pressures (depths) of inclusions were computed with the equation of state and computer program. Distribution of the trap depths makes it know that the degassing of magma can happen over a wide pressure (depth) range, but mainly at the depth of 0.48 km to 3.85 km. This implicates that basalt magma experienced intensive degassing and the CO2 gas reservoir from the basalt magma also may be formed in this range of depths. The results of this study showed that the depth of basalt magma degassing can be forecasted from CO2 fluid inclusions, and it is meaningful for understanding the process of magma degassing and constraining the inorganogenic CO2 gas reservoir.  相似文献   

18.
Abundant organic inclusions are present in the Qinglong antimony deposit. However, the source rocks of these organic matters have not been reliably identified. Recently, a paleo–oil reservoir was found in the Qinglong antimony deposit. In view of similar components of gaseous hydrocarbon, we propose that the organic matters observed in inclusions in Qinglong antimony deposit would come from this paleo–oil reservoir. We used the Re–Os dating method to determine the age of the bitumen from this paleo–oil reservoir, and obtained an isochron age of 254.3±2.8 Ma. The age indicates that the oilgeneration from source rock occurred in the early Late Permian, earlier than the Sb mineralization age(~148±8.5 Ma) in the Qinglong antimony deposit area. After oil generation from Devonian source rock, first and secondary migration, the crude oil have probably entered into the fractures and pores of volcanic rocks and limestone and formed a paleo–oil reservoir in the western wing of Dachang anticline. As burial process deepened, the crude oil has turned into natural gas, migrates into the core of Dachang anticline and formed a paleo–gas reservoir. The hydrocarbons(including CH_4) in the reservoirs can serve as reducing agent to provide the sulfur required for Sb mineralization through thermal chemical reduction of sulfates. Therefore, the formation of oil–gas in the area is a prerequisite for the Sb mineralization in the Qinglong antimony deposit.  相似文献   

19.
The shale gas resources in China have great potential and the geological resources of shale gas is over 100×1012m3,which includes about 20×1012m3 of recoverable resources.Organic-rich shales can be divided into three types according to their sedimentary environments,namely marine,marine-continental transitional,and continental shales,which are distributed in 13 stratigraphic systems from the Mesoproterozoic to the Cenozoic.The Sichuan Basin and its surrounding areas have the highest geological resources of shale gas,and the commercial development of shale gas has been achieved in the Upper Ordovician Wufeng Formation-Lower Silurian Longmaxi Formation in these areas,with a shale gas production of up to 20×109m3 in 2020.China has seen rapid shale gas exploration and development over the last five years,successively achieving breakthroughs and important findings in many areas and strata.The details are as follows.(1)Large-scale development of middle-shallow shale gas(burial depth:less than 3500 m)has been realized,with the productivity having rapidly increased;(2)breakthroughs have been constantly made in the development of deep shale gas(burial depth:3500-4500 m),and the ultradeep shale gas(burial depth:greater than 4500 m)is under testing;(3)breakthroughs have been made in the development of normal-pressure shale gas,and the assessment of the shale gas in complex tectonic areas is being accelerated;(4)shale gas has been frequently discovered in new areas and new strata,exhibiting a great prospect.Based on the exploration and development practice,three aspects of consensus have been gradually reached on the research progress in the geological theories of shale gas achieved in China.(1)in terms of deep-water fine-grained sediments,organic-rich shales are the base for the formation of shale gas;(2)in terms of high-quality reservoirs,the development of micro-nano organic matter-hosted pores serves as the core of shale gas accumulation;(3)in terms of preservation conditions,weak structural transformation,a moderate degree of thermal evolution,and a high pressure coefficient are the key to shale gas enrichment.As a type of important low-carbon fossil energy,shale gas will play an increasingly important role in achieving the strategic goals of peak carbon dioxide emissions and carbon neutrality.Based on the in-depth study of shale gas geological conditions and current exploration progress,three important directions for shale gas exploration in China in the next five years are put forward.  相似文献   

20.
Opaque minerals in the Jilin meteorite inelude kamacite, taenite troilite, chromite, ilmenite, schreibersite, pyrite, pyrrhotite, chalcopyrite, sphalerite and graphite.Five of the above-mentioned minerals have been discussed in more detail in terms of optical and physical properties, chemical composition, coexisting relationship, and the order of crystallization. It is indicated from this study that, with the exception of a small amount of Ni-Fe cbondrules, silicate minerals are the first to erystallize followed by chromite, ilmenite at the early stage of nebula condensation, while Ni-Fe phase in the matrix is considered to be of a more later erigin. At the late stage of nebula condensation troilite resulted from the reaction of Ni-Fe metal with residual H2S vapor. As indicated by the occurrence of coarse grained Ni-Fe metal, the recrystallization of troilite and the apparent Neumann lines in kamaeite, it is expected that opaque minerals in the Jilin metevrite have undergone different degrees of thermal and impact metamorphisms.  相似文献   

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