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1.
-Exchange additivity of binary mixtures of hydrous metal oxides and clay minerals has been studied by investigating the relations of the zinc exchange-pH and the zinc partition coefficients to mixtures. The additive exchange equation is proposed to describe the exchange-pH relationship. The results suggest that zinc exchanges on the components in amorphous iron oxide/montmorrillonite, kaolinite/montmorrillonite, γ-A100H/montmorrillonite, amorphous iron oxide/illite mixtures are additive. But the exchange ofδ-MnO2/montmorrillonite is much less than its additive exchange. It is also shown that in the case of additive exchange the exchange parameters (Kmix{SOH}Tmix) of the mixtures are equal in weight to the sum of those of each component of the solid mixtures.  相似文献   

2.
Zinc exchange isotherms in mixtures of hydrous metal oxides and clay minerals have been reported. The relationship between the isotherms of the mixtures and the isotherms of their components is studied. The isotherms of the mixtures are stepwise. And the formation constants for the zinc exchange in the mixtures are calculated. The results show that the stepwise equilibrium formation constants and the saturation exchange capacities for the zinc exchange in kaolinite/ mon-tmorrillonite, amorphous iron oxide/montmorrillonite and γ-AlOOH/montmorrillonite mixtures are equal in weight to those of their components. The interactions between fresh iron oxyhydroxide and δ-MnOz reduce the metal binding sites of the mixtures, while the stepwise equilibrium constants are not affected by the interactions.  相似文献   

3.
A three-dimensional numerical model in the δ-coordinate system is developed to study the problem of waves. Turbulence effects are modeled by a subgfid-scale (SGS) model with the concept of large eddy simulation (LES). The δ-coordinate transformation is introduced to map the irregular physical domain of the wavy free surface and uneven bottom onto the regular computational domain of the shape of rectangular prism. The operator splitting method, which splits the solution procedure into the advection, diffusion, and propagation steps, is used to solve the modified Navier-Stokes Equation.The model is used to simulate the propagation of solitary wave and wave passing over a submerged breakwater. Numerical results are compared with available analytical solutions and experimental data in terms of velocity profiles, free surface displacement, and energy conservation. Good agreement is obtained. The method is proved to be of high accuracy and efficiency in simulating surface wave propagation and wave-structure interaction. It is suitable for the large and irregular physical domain, and requiring the non-uniform grid system. The present work provides a foundation for further studies of random waves, wave-structure interaction, wave-discharge interaction, etc.  相似文献   

4.
Ferromanganese(Fe-Mn) crusts are potential archives of the Cu and Zn isotope compositions of seawater through time. In this study, the Cu and Zn isotopes of the top surface of 28 Fe-Mn crusts and 2 Fe-Mn nodules were analysed by MC-ICP-MS using combined sample-standard bracketing for mass bias correction. The Zn isotope compositions of the top surface of Fe-Mn crusts are in the range of 0.71‰ to 1.08‰, with a mean δ~(66) Zn value of 0.94‰±0.21‰(2 SD, n=28). The δ~(65) Cu values of the top surface of Fe-Mn crusts range from 0.33‰ to0.73‰, with a mean value of 0.58‰±0.20‰(2 SD, n=28). The Cu isotope compositions of Fe-Mn crusts are isotopically lighter than that of dissolved Cu in deep seawater(0.58‰ vs. 0.9‰). In contrast, the δ~(66) Zn values of Fe-Mn crusts appear to be isotopically heavy compared to deep seawater(0.94‰±0.21‰ vs. 0.51‰±0.14‰). The isotope fractionation between Fe-Mn crusts and seawater is attributed to equilibrium partitioning between the sorption to crusts and the organic-ligand-bound Cu and Zn in seawater. The Cu and Zn isotopes in the top surface of Fe-Mn crusts are not a direct reflection of the Cu and Zn isotopes, but a function of Cu and Zn isotopes in modern seawater. This study proposes that Fe-Mn crusts have the potential to be archives for paleoceanography through Cu and Zn isotope analysis.  相似文献   

5.
Cold seeps are pervasive along the continental margin worldwide,and are recognized as hotspots for elemental cycling pathway on Earth.In this study,analyses of pore water geochemical compositions of one-400 cm piston core(S3) and the application of a mass balance model are conducted to assess methane-associated biogeochemical reactions and uncover the relationship of methane in shallow sediment with gas hydrate reservoir at the Makran accretionary wedge off Pakistan.The results revealed that approximately 77% of sulfate is consumed by the predominant biogeochemical process of anaerobic oxidation of methane.However,the estimated sulfate-methane interface depth is-400 cm below sea floor with the methane diffusive flux of 0.039 mol/(m~2·a),suggesting the activity of methane seepage.Based on the δ~(13)C_(DIC) mass balance model combined with the contribution proportion of different dissolved inorganic carbon sources,this study calculated the δ~(13)C of the exogenous methane to be-57.9‰,indicating that the exogenous methane may be a mixture source,including thermogenic and biogenic methane.The study of pore water geochemistry at Makran accretionary wedge off Pakistan may have considerable implications for understanding the specific details on the dynamics of methane in cold seeps and provide important evidence for the potential occurrence of subsurface gas hydrate in this area.  相似文献   

6.
The surface heat budget of the Arctic Ocean （SHEBA） project has shown that the study of the surface heat budget characteristics is crucial to understanding the interface process and environmental change in the polar region. An arctic single - column model （ARCSCM） of Colorado University is used to simulate the arctic surface radiation and energy budget during the summertime. The simulation results are analyzed and compared with the SHEBA measurements. Sensitivity analyses are performed to test microphysical and radiative parameterizations in this model. The results show that the ARCSCM model is able to simulate the surface radiation and energy budget in the arctic during the summertime, and the different parameterizations have a significant influence on the results. The combination of cloud microphysics and RRTM parameterizations can fairly derive the surface solar shortwave radiation and downwelling longwave radiation flux. But this cloud microphysics parameterization scheme deviates notably from the simulation of surface sensible and latent heat flux. Further improvement for the parameterization scheme applied to the Arctic Regions is necessary.  相似文献   

7.
Monsoon driven water mass exchange between the Bay of Bengal(Bo B) and Arabian Sea(AS) is the common experience. However, it is not yet firmly confirmed that the exchange pathway is either passing through southern tip of Sri Lanka or Palk Strait. Local circulation patterns impact the pathways followed by the East Indian Coastal Currents(EICC) that drive exchange, thereby modulating mixing and water mass transformation in the Bay of Bengal around Sri Lanka. In this study, observations from surface drifters were incorporated with the satellite derived data to understand the monsoonal impact on circulation patterns in the Indian Ocean. This was the first multi-national scientific effort which was conducted in the Bo B and AS during 2013 to 2015 to understand the monsoonal impact on circulation patterns in the complex region. The results indicated that seasonally reversing monsoonal currents of southern Sri Lanka, traced by the wintertime freshwater export pathways of the EICC. The deflection of monsoon currents running along the east coast of Sri Lanka by forming cyclonic and anti-cyclonic eddies, which influence the mixing and stirring associated with these flows. Results further indicate the low salinity cold water flows from the Bo B to AS along the western boundary of the Bo B during northeast monsoon. In the same way, reverses the phenomena during southwest monsoon, transporting high salinity warm water from AS to the Bo B. This maintain the bay status which occurred due to freshwater influx from large rivers and high saline water from AS. However, no evidences were observed for the exchange through Palk Strait during the study.Also, there are some mis-matches in in-situ and remotely sensed measurements which imply the necessity of systematic observation system for the complex region as an alternative approach.  相似文献   

8.
Bifenthrin(BF) is a pyrethroid insecticide that is widely used in agriculture, horticulture, and for residential purposes. However, few studies addressing the reproductive toxicity of BF on fishes are available. The present study was conducted to investigate the effects of BF on testicular development in Sebastiscus marmoratus and to gain insight into its mechanism. After exposure to 1, 10 and 100 ng/L BF for 50 days, there was a reduced number of mature sperm and an abundance of the late stages of spermatocysts in the testes. The levels of 17β-estradiol and testosterone were decreased significantly after BF exposure. The activity of caspase-3 was increased in a dosedependent manner after BF exposure, TUNEL assay indicated that BF exposure resulted in the occurrence of apoptosis in the testes, which might be main reason for the inhibition of spermatogenesis.  相似文献   

9.
The effect of river runoff over the northern Indian Ocean(NIO) especially over the Bay of Bengal(Bo B) has been studied using global Nucleus for European Modelling of the Ocean(NEMO). Two sensitivity experiments, with and without river runoff are conducted and the influence of river runoff on the Indian Ocean hydrography,stratification and circulation features are studied. It is found that due to river runoff surface salinity over the northern Bo B decreases by more than 5 and the East India Coastal Current strengthens by 2 cm/s during post monsoon season. The fresh river water reaches up to 15°N in the Bo B and is the main cause for low salinity there.Sea surface temperature in the northwestern Bo B increases by more than 0.2℃ due to the river runoff in summer monsoon while surface cooling upto 0.2℃ is seen in north-west part of Bo B in winter season. The seasonal mixed layer depth in the region is found to be dependent on river runoff. The effect of vertical shear and Brunt Vaisala frequency on stratification is also examined. The ocean water becomes highly stratified up to 3 035 m due to the river runoff. It is found that the energy required for mixing is high in the northern and coastal Bo B.  相似文献   

10.
Based on the 1st order cnoidal wave theory, the nonlinear wave diffraction around a circular cylinder in shallow water is studied in this paper. The equation of the wave surface around the cylinder is formulated and by using this formula the wave surface elevation on the cylinder surface can be obtained. In this paper, the formula for calculating the cnoidal wave force on a circular cylinder is also derived. For the wave conditions which are often encountered in practical engineering designs, the ratios of the nonlinear wave forces to the linear wave forces are calculated, and the results are plotted in this paper for design purposes. In order to verify the theoretical results, model tests are conducted. After comparing the test results with the theoretical ones, it is concluded that, in shallow water, for the case of T g / d~(1/2) > 8-10 and H / d > 0.3, the cnoidal wave theory should be used to calculate the wave action on a cylindrical pier.  相似文献   

11.
In this paper,by using the ECMWF objective analysed data as well as CAC and NOAA grid point data of 1981 and 1983,the sensible and latent heat fluxes at the air and sea boundary surface within the range of 45°E-75°W, 35°N-35°S over the Pacific and the Indian Ocean are calculated. The purpose is to analyse the different revealing features during the mature stage and at the end of the 1982 -1983 El Nino event and to compare the difference of the features between thd El Nino and the normal. The result shows that the air and sea heat exchange west of the dateline over the central tropical Pacific during the EJ Nino period is more intense than that of the normal. However,the fluxes of the sensible and latent heat on the sea surface with strong warming of SSTneat by and on the south side of the equator east of 170°W are low and even negative,and the patterns of the sensible and latent heat fluxes over the Indian Ocean during the year of 1983 are similer to that of normal. Spatial patterns of the sensible  相似文献   

12.
The Province of Khanh Hoa, Vietnam, is located in the western South China Sea and boasts a shoreline of 385 km and many islands. Previous studies have indicated the extreme diversity and abundance of coral reefs in its waters as compared with other coastal provinces of Vietnam. A study on the resilience of coral reefs against increased surface water temperature and anthropogenic impact is conducted at 19 reef sites in 2015. At each site, a series of parameters (e.g., coral covers, genus diversity, and coral recruitment, substratum heterogeneity, depth, water exchange level, and sediment deposit and water temperature) are measured quantitatively or semi-quantitatively. The measured data are rated based on the relationship between the parameter values and coral susceptibility; the consideration that reef health reflects the biological capability to adapt to environmental changes and the recruitment potential if bleached; and positive or negative influences of physical factors in the mitigation of thermal stress and protecting corals from bleaching. A cumulative analysis enables researchers to divide the studied reefs into four categories based on varying levels of reef health to support resilience, recovery, and vulnerability in the case of increased water temperature. Relevant management interventions for each category and other supporting activities are suggested to enhance management effectiveness and to plan the rehabilitation of coral reefs for biodiversity conservation and touristic development, taking into account the involvement of related stakeholders.  相似文献   

13.
Heavy metal concentrations were measured in the Changjiang Estuary and its adjacent waters. Results from a systematic survey in April 2002 to March 2003 indicate that the ranges of the concentrations of dissolved copper, lead, zinc and cadmium in the study waters are 1.01 - 6.86, 0. 10 - 0.39,3.17 - 9.12 and 0.011 - 0. 049 μg/dm^3 , respectively. Similar to zinc, the behavior of dissolved copper was essentially conservative, but high scatter has been observed for high salinity samples, which can be attributed to the decomposition or mineralization of organic matter by bacteria. Dissolved lead may have active behavior with an addition at high salinity. Overall concentrations of dissolved cadmium increase with salinity. The mean values of these dissolved metals calculated for the surface waters were higher than those for the middle and bottom ones. External inputs of dissolved heavy metals to the surface waters were the likely explanation for these higher values. The maximum seasonal average values of dissolved copper and zinc were found in summer, reflecting higher amounts of riverine input in this season. In contrast, the maximum seasonal average values of dissolved lead and copper were found in winter and the lowest ones in summer, respectively, which might be asso- ciated with a combination of low concentration with heterogeneous scavenging. Concentrations of these dissolved metals found for the Changjiang Estuary fall in the range observed for the other estuaries but are noticeably higher than those from uncontaminated rivers, except for cadmium. Compared with observations for the Changjiang Estuary in the last two decades, it is clear that the Changjiang estuarine waters has been contaminated with copper, lead, zinc and cadmium during China＇ s industrialization, but concentrations of them have decreased in the last few years.  相似文献   

14.
Ocean current forecasting is still in explorative stage of study. In the study, we face some problems that have not been met before. The solving of these problems has become fundamental premise for realizing the ocean current forecasting. In the present paper are discussed in depth the physical essence for such basic problems as the predictability of ocean current, the predictable currents, the dynamical basis for studying respectively the tidal current and circulation, the necessity of boundary model, the models on regions with different scales and their link. The foundations and plans to solve the problems are demonstrated. Finally a set of operational numerical forecasting system for ocean current is proposed.  相似文献   

15.
Laboratory experiments are conducted to study the probability distribution of surface elevation for wind waves and the convergence is discussed of the Gram-Charlier series in describing the surface elevation distribution. Results show that the agreement between the Gram-Charlier series and the observed distribution becomes better and better as the truncated order of the series increases in a certain range, which is contrary to the phenomenon observed by Huang and Long (1980) . It is also shown that the Gram-Charlier series is sensitive to the anomalies in the data set which will make the agreement worse if they are not preprocessed appropriately. Negative values of the probability distribution expressed by the Gram-Charlier series in some ranges of surface elevations are discussed, but the absolute values of the negative values as well as the ranges of their occurrence become smaller gradually as more and more terms are included. Therefore the negative values will have no evident effect on the form of t  相似文献   

16.
An experimental scheme for the generation of directional focusing waves in a wave basin is established in this paper. The effects of the directional range, frequency width and center frequency on the wave focusing are studied. The distrihution of maximum amplitude and the evolution of time series and spectra during wave packet propagation and the variation of water surface parameters are extensively investigated. The results reveal that the characteristics of focusing waves are significantly influenced hy wave directionality and that that breaking criteria for directional waves are distinctly different from those for unidirectional waves.  相似文献   

17.
The low-frequency variance of the surface wave in the area of the Antarctic Circumpolar Current (ACC) and its correlation with the antarctic circumpolar wave (ACW) are focused on. The analysis of the series of 44 a significant wave height (SWH) interannual anomalies reveals that the SWH anomalies have a strong periodicity of about 4-5 a and this signal propagates eastward obviously from 1985 to 1995, which needs about 8 a to complete a mimacircle around the earth. The method of empirical orthogonal function (EOF) is used to analyze the filtered monthly SWH anomalies to study the spatio-temporal distributions and the propagation characteristics of the low-frequency signals in the wave field. Both the dominant wavenumber-2 pattern in space and the propagation feature in the south Pacific, the south Atlantic and the south Indian ocean show strong consistency with the ACW. So it is reasonable to conclude that the ACW signal also exists in the wave field. The ACW is important for the climate in the Southern Ocean, so it is worth to pay more attention to the large-scale effect of the surface wave, which may also be important for climate studies.  相似文献   

18.
Stress intensity factors (SIFs) for the cracked circular disks under different distributing surface tractions are evaluated with the scaled boundary finite element method (SBFEM). In the SBFEM, the analytical advantage of the solution in the radial direction allows SIFs to be directly determined from its definition, therefore no special crack-tip treatment is necessary. Furthermore anisotropic material behavior can be treated easily. Different distributions of surface tractions are considered for the center and double-edge-cracked disks. The benchmark examples are modeled and an excellent agreement between the results in the present study and those in published literature is found. It shows that SBFEM is effective and possesses high accuracy. The SIFs of the cracked orthotropic material circular disks subjected to different surface tractions are also evaluated. The technique of substructure is applied to handle the multiple cracks problem.  相似文献   

19.
In this study, 13 groups of silicon and oxygen isotopes and major elements of the basalts near the East Pacific Rise 13°N are used to study the fractionation of silicon and oxygen isotopes. Among these data, δ30Si values of basalts vary from -0.4%o to 0.2%o with a mean value of δ30Si of （-0.18±0.22）%o. The δ180 values range from 4.1%o to 6.4%o with a mean δ180 value of （＋5.35±0.73） %0. Since the δ30Si values increase in the series of basalt-basaltic andesite- andesite, and δ180 values display a positive correlation with the SiO2 content, we propose that the fractionation of silicon and oxygen isotopes is influenced by the SiO2 content in igneous rocks. Compared with the igneous rocks from Manus Basin with clinopyroxene as their dominant mineral phase, MORBs in this study containing olivine and plagioclase as primary minerals have lower δ180 and δ30Si values, indicating that the fractionation of silicon and oxygen isotopes is also affected by different Si-O bridges in silicate minerals. Furthermore, our samples from the EPR are defined as E-MORB based on K/Ti ratios. Probably, the difference in δ30Si and δ30O between our samples and a normal MORB are cause by the enriched components in E-MORBs.  相似文献   

20.
Based on the fluid motion equations, the physical meaning of eddy viscosity coefficient and the rationality of the Boussinesq hypothesis are discussed in this paper. The effect of the coefficient on numerical stability is analyzed briefly. A semi-enclosed rectangular sea area, with an orthogonal spur dike, is applied in a 2-D numerical model to study the effect of horizontal eddy viscosity coefficient (AH). The computed result shows that AH has little influence on the tidal level and averaged flow velocity, but has obvious influence on the intensity and the range of return flow around near the spur dike. Correspondingly, a wind-driven current pool and an annular current are applied in a 3-D numerical model respectively to study the effect of vertical eddy viscosity coefficient (Av). The computed result shows that the absolute value of Av is inversely proportional to that of horizontal velocity, and the vertical gradient value of Av determines the vertical distribution of horizontal velocity. The distrib  相似文献   

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