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1.
Transformation Trillings in Cordierite 总被引：1，自引：0，他引：1
Cordierite sector trillings, which are found well developedin some A1-rich volcanic rocks and pelitic buchites, are thoughtto have formed initially as hexagonal high cordierite crystals.Subsequent ordering of the (Al, Si) configuration in the crystalstructure would have produced the present orthorhombic modificationand simultaneously the sector trilling, preserving in the processthe hexagonal habit of form. The predominance of the regularsixfold sector pattern in the composition plane configurationof the resulting trilling is best explained by assuming thatits formation is kinetically more advantageous than that ofother configurations because it mimics the hexagonal trend setby the initial crystal. The three orthorhombic orientations in the cordierite trillingshave parallel c-axes and each can be transformed into eitherof the other two by operation of a threefold axis (rotationthrough 120°) parallel to the common c-axis and coincidentwith the main axis of the original hexagonal form. The compositionplanes in the sector trilling pattern are shown to be essentiallyirregular in the present orthorhombic form; they do not belongto {110} or {130}. The traditional explanation that the trillings are multipletwins with repeated twin and composition planes of {110} or{130} is rejected since elementary geometrical considerationsshow that this model is only feasible if (110) (110) of orthorhombiccordierite equals 120°. X-ray work shows conclusively thatthis is not the case. In fact (110) (110) = 120° woulddefine a hexagonal symmetry. 相似文献
2.
Indialite (hexagonal cordierite) has been found in a cordierite vein of polymetamorphosed pelitic rock, a member of the Unazuki
schists in Hida terrane, central Japan. Most of the indialite grains show intergrowth textures with cordierite of orthorhombic
symmetry. This is the second identification of indialite since the first one from a fused sediment in India.
The intergrowth texture was formed by a nucleation-growth process accompanied with the first order transition from the hexagonal
to the orthorhombic form. Characteristic pseudo-twin relation exists among the orthorhombic phases. Chemical compositions
of both hexagonal and orthorhombic forms in the intergrowth have been deter-mined by analytical electron microscopy. The difference
in Fe/(Mg+Fe) at the interfaces between the two forms indicates the existence of a transition loop in the (Mg, Fe)-cordierite.
The transition of the present specimens is estimated to have initiated at about 700° C. A possible phase diagram of (Mg, Fe)-cordierite
has been proposed, based on the result of this investigation. 相似文献
3.
Porphyroblastic schists in the thermal aureole of the Victor Harbor Granite at Petrel Cove, in the southern Adelaide Fold Belt, South Australia, preserve a record of sequential cordierite, andalusite, staurolite, fibrolite, chlorite and muscovite growth (along with biotite+plagioclase+quartz+ilmenite) during progressive deformation. A P–T pseudo‐section appropriate to biotite‐saturated assemblages in KFMASH shows that the sequence of mineral reactions records increasing pressure of at least 1 kbar (from c. 3 to c. 4 kbar) during cooling from around 580 °C. Heating at pressures below c. 3 kbar is inferred for growth of early formed cordierite porphyroblasts, and is attributed in part to the thermal effects of granite emplacement, while the pressure increase is attributed to tectonic burial accruing from ongoing deformation. The ‘anticlockwise’P–T path is consistent with convergent deformation being focussed as a consequence of heating, as to be expected for a lithospheric rheology that is strongly temperature dependent. 相似文献
4.
The H2O and CO2 content of cordierite was analysed in 34 samples from successive contact metamorphic zones of the Etive thermal aureole, Scotland, using Fourier‐transform infrared spectroscopy (FTIR). The measured volatile contents were used to calculate peak metamorphic H2O and CO2 activities. Total volatile contents are compared with recently modelled cordierite volatile saturation surfaces in order to assess the extent of fluid‐present v. fluid‐absent conditions across the thermal aureole. In the middle aureole, prior to the onset of partial melting, calculated aH2O values are high, close to unity, and measured volatile contents intersect modelled H2O–CO2 saturation curves at the temperature of interest, suggesting that fluid‐present conditions prevailed. Total volatile contents and aH2O steadily decrease beyond the onset of partial melting, consistent with the notion of aH2O being buffered to lower values as melting progresses once free hydrous fluid is exhausted. All sillimanite zone samples record total volatile contents that are significantly lower than modelled H2O–CO2 saturation surfaces, implying that fluid‐absent conditions prevailed. The lowest recorded aH2O values lie entirely within part of the section where fluid‐absent melting reactions are thought to have dominated. Samples within 30 m of the igneous contact appear to be re‐saturated, possibly via a magmatically derived fluid. In fluid‐absent parts of the aureole, cordierite H2O contents yield melt–H2O contents that are compatible with independently determined melt–H2O contents. The internally consistent cordierite volatile data and melt–H2O data support the conclusion that the independent P–T estimates applied to the Etive rocks were valid and that measured cordierite volatile contents are representative of peak metamorphic values. The Etive thermal aureole provides the most compelling evidence, suggesting that the cordierite fluid monitor can be used to accurately assess the fluid conditions during metamorphism and partial melting in a thermal aureole. 相似文献
5.
T. H. Green 《Australian Journal of Earth Sciences》2013,60(2):405-418
A Devonian granite complex intrudes Precambrian and Silurian siltstones and sandstones as well as (?) Cambrian volcanics and dunite. Metamorphism of the Precambrian sediments is slight, and an andalusite‐bearing, pelitic hornfels is the only characteristic assemblage. The (?) Cambrian volcanics give rise to a variety of assemblages; (1) lime‐ and ferromagnesia‐rich (hypersthene — cummingtonite — labradorite; diopside — hornblende — labradorite); (2) magnesia‐rich (cordierite — hypersthene; cordierite — anthophyllite); (3) ultrabasic (olivine and/or pleonaste). Biotite (or phlogopite) is an almost invariable component, and garnet may also be present in these groups. No significant metamorphism of the dunite is evident; minor development of veins and segregrations of aragonite, magnetite, phlogopite, brucite, chalcedony and antigorite may result from low‐grade hydrothermal activity Metamorphic assemblages in calcareous Silurian siltstones contain garnet, diopside, calcite and epidote. A characteristic feature of the contact metamorphic aureole is the occurrence of diopside‐rich bodies in granite, volcanic hornfels, quartzite and dunite host rocks. 相似文献
6.
A method of determining the number of Al-O-Al bonds per unit cell from 29Si nuclear magnetic resonance (NMR) data of synthetic cordierites with increasing Si, Al order is described. The number of Al-O-Al bonds is found to vary linearly with the logarithm of the annealing time. This may be correlated with previously published heat of solution data on similar samples (Carpenter et al. 1983) to determine the enthalpy change Δh, associated with a single Al?Si interchange in cordierite. Δh is found to be 8.1 kcal/mole. The NMR data show that the short range Al, Si order cannot be described in terms of twin domains of ordered orthorhombic cordierite. An ordering model derived from group theoretical constraints on possible Al, Si distributions within the hexagonal symmetry of the cordierite is found to provide a better fit to the NMR data. 相似文献
7.
The 2 km wide contact aureole produced from serpentinite bythe intrusion of the Mount Stuart Batholith into the IngallsComplex at Paddy-Go-Easy Pass contains the following ultramaficassemblages, in order of increasing grade: serpentine-forsterite-diopside,serpentine-forsterite-tremolite, forsterite-talc, forsterite-anthophyllite,forsterite-enstatite-anthophyllite, forsterite-enstatite-chlorite,forsterite-enstatite-spinel. Associated metarodingites displayfive metamorphic zones, the diagnostic assemblages of whichare, in increasing grade: grossular-idocrase-chlorite, grossular-diopside-chlorite,epidote-diopside-chlorite, epidotediopside-spinel, plagioclase-grossular-diopside.Mafic hornfels in the aureole contains no orthopyroxene, indicatingthat the conditions of pyroxene hornfels facies were not reached. The breakdown of chlorite is best displayed in aluminous blackwallreaction zones around mafic inclusions in the peridotite. Attemperatures above those of the anthophyllite-out isograd, butwithin the field of forsterite+tremolite, these chlorite-richrocks react to form the assemblage: forsterite-enstatite-spinel.Calculations show that cordierite did not form as a result ofchlorite breakdown in the natural system because impurities,such as iron and chromium, displaced the equilibrium: forsterite+cordierite= enstatite+spinel to much lower pressures than the three kilobarsfound in the pure system. The primary chromite of the peridotite has been altered to chrome-magnetitein the serpentinite. This alteration seems to be isochemicalover the whole rock, as true chromite, formed by metamorphism,occurs at grades above that of the forsterite-enstatite-anthophylliteassemblage. Calcic amphibole in high-grade metaperidotite is tremolite,even in the presence of aluminous chromite, whereas that inmetamorphosed blackwall rock grades from tremolite into hornblende.The pattern of substitution appears to be: Mg2Si3rlhar2;(Na,K)(AlVI)2(AlIV)3. 相似文献
8.
Contact aureoles of the anorthositic to granitic plutons of the Mesoproterozoic Nain Plutonic Suite (NPS), Labrador, are particularly well developed in the Palaeoproterozoic granulite facies, metasedimentary, Tasiuyak gneiss. Granulite facies regional metamorphism (MR), c. 1860 Ma, led to biotite dehydration melting of the paragneiss and melt migration, leaving behind biotite‐poor, garnet–sillimanite‐bearing quartzofeldspathic rocks. Subsequently, Tasiuyak gneiss within a c. 1320 Ma contact aureole of the NPS was statically subjected to lower pressure, but higher temperature conditions (MC), leading to a second partial melting event, and the generation of complex mineral assemblages and microstructures, which were controlled to a large extent by the textures of the MR assemblage. This control is clearly seen in scanning electron microscopic images of thin sections and is further supported by phase equilibria modelling. Samples collected within the contact aureole near Anaktalik Brook, west of Nain, Labrador, mainly consist of spinel–cordierite and orthopyroxene–cordierite (or plagioclase) pseudomorphs after MR sillimanite and garnet, respectively, within a quartzofeldspathic matrix. In addition, some samples contain fine‐grained intergrowths of K‐feldspar–quartz–cordierite–orthopyroxene inferred to be pseudomorphs after osumulite. Microstructural evidence of the former melt includes (i) coarse‐grained K‐feldspar–quartz–cordierite–orthopyroxene domains that locally cut the rock fabric and are inferred to represent neosome; (ii) very fine‐ to medium‐grained cordierite–quartz intergrowths interpreted to have formed by a reaction involving dissolution of biotite and feldspar in melt; and (iii) fine‐scale interstitial pools or micro‐cracks filled by feldspar interpreted to have crystallized from melt. Ultrahigh temperature (UHT) conditions during contact metamorphism are supported by (i) solidus temperatures >900 °C estimated for all samples, coupled with extensive textural evidence for contact‐related partial melting; (ii) the inferred (former) presence of osumilite; and (iii) titanium‐in‐quartz thermometry indicating temperatures within error of 900 °C. The UHT environment in which these unusual textures and minerals were developed was likely a consequence of the superposition of more than one contact metamorphic event upon the already relatively anhydrous Tasiuyak gneiss. 相似文献
9.
The time and temperature evolution of twinning in cordierite is simulated using three computer models. The orientation of
walls between twin domains in natural cordierite follows mainly the ferroelastic pattern which minimises the strain energy
of the walls between twin-related domains. Such ferroelastic twinning is simulated in an elastic three-states Potts model
in which each structural six-membered ring is represented by a three state pseudo-spin. The resulting twin pattern in a sample
with 3169 structural rings shows sector trilling and fine scale ferroelastic wall patterns which coarsen with increasing annealing
time. The poorly defined wall directions observed in cordierite were found to be related to twin walls which do not minimise
the strain energy. Instead, these walls are located along the corners of pseudo-hexagonal rings and appear as the consequence
of local rather than global interatomic interactions. Simulations using two-dimensional (38028 atoms) and three-dimensional
(408 228 atoms) structural models show a predominance of these topological walls over the strain walls at early stages in
the ordering process. The domain structure in the simulation is patchy rather than corresponding to repeated stripe structures
found in other ferroelastic and co-elastic materials. In all models, a strong tendency for sector trilling is observed. In
kinetic tweed patterns a novel 60o tweed is found at atomic length scales while the usual strain-mediated 90o tweed appears
at mesoscopic length scales. An unusual surface tension effect in domain formation and ’writhing’, fluid-like motion was found
in the three-dimensional structural model. This motion, along with the existence of non strain-mediated walls may contribute
to cordierite’s poorly defined domain wall directions at the early stages of domain coarsening.
Received: 11 March 1998 / Revised, accepted: 28 August 1998 相似文献
10.
Contact Metamorphism of Serpentinite, Chloritic Blackwall and Rodingite at Paddy-Go-Easy Pass, Central Cascades, Washington 总被引：2，自引：2，他引：2
The 2 km wide contact aureole produced from serpentinite bythe intrusion of the Mount Stuart Batholith into the IngallsComplex at Paddy-Go-Easy Pass contains the following ultramaficassemblages, in order of increasing grade: serpentine-forsterite-diopside,serpentine-forsterite-tremolite, forsterite-talc, forsterite-anthophyllite,forsterite-enstatite-anthophyllite, forsterite-enstatite-chlorite,forsterite-enstatite-spinel. Associated metarodingites displayfive metamorphic zones, the diagnostic assemblages of whichare, in increasing grade: grossular-idocrase-chlorite, grossular-diopside-chlorite,epidote-diopside-chlorite, epidote-diopside-spinel, plagioclase-grossular-diopside.Mafic hornfels in the aureole contains no orthopyroxene, indicatingthat the conditions of pyroxene hornfels facies were not reached. The breakdown of chlorite is best displayed in aluminous blackwallreaction zones around mafic inclusions in the peridotite. Attemperatures above those of the anthophyllite-out isograd, butwithin the field of forsterite+tremolite, these chlorite-richrocks react to form the assemblage: forsterite-enstatite-spinel.Calculations show that cordierite did not form as a result ofchlorite breakdown in the natural system because impurities,such as iron and chromium, displaced the equilibrium: forsterite+cordierite=enstatite+spinelto much lower pressures than the three kilobars found in thepure system. The primary chromite of the peridotite has been altered to chrome-magnetitein the serpentinite. This alteration seems to be isochemicalover the whole rock, as true chromite, formed by metamorphism,occurs at grades above that of the forsterite-enstatite-anthophylliteassemblage. Calcic amphibole in high-grade metaperidotite is tremolite,even in the presence of aluminous chromite, whereas that inmetamorphosed blackwall rock grades from tremolite into hornblende.The pattern of substitution appears to be: Mg2Si3(Na,K)(AlVI)2(AlIV)3. 相似文献
11.
Ghislain Trullenque Karsten Kunze Renee Heilbronner Holger Stünitz Stefan M. Schmid 《Tectonophysics》2006,424(1-2):69-97
Microfabrics were analysed in calcite mylonites from the rim of the Pelvoux massif (Western Alps, France). WNW-directed emplacement of the internal Penninic units onto the Dauphinois domain produced intense deformation of an Eocene-age nummulitic limestone under lower anchizone metamorphic conditions (slightly below 300 °C). Two types of microfabrics developed primarily by dislocation creep accompanied by dynamic recrystallisation in the absence of twinning. Coaxial kinematics are inferred for samples exhibiting grain shape fabrics and textures with orthorhombic symmetry. Their texture (crystallographic preferred orientation, CPO) is characterised by two c-axis maxima, symmetrically oriented at 15° from the normal to the macroscopic foliation. Non-coaxial deformation is evident in samples with monoclinic shape fabrics and textures characterised by a single oblique c-axis maximum tilted with the sense of shear by about 15°. From the analysis of suitably oriented slip systems for the main texture components under given kinematics it is inferred that the orthorhombic textures, which developed in coaxial kinematics, favour activity of <10–11> and <02–21> slip along the f and r planes, respectively, with minor contributions of basal-<a> slip. In contrast, the monoclinic textures, which developed during simple shear, are most suited for duplex <a> slip along the basal plane. The transition between the dominating slip systems for the orthorhombic and monoclinic microfabrics is interpreted to be due to the effects of dynamic recrystallisation upon texture development. Since oblique c-axis maxima documented in the literature are most often rotated not with but against the shear sense, calcite textures alone should not be used as unequivocal shear sense indicators, but need to be complemented by microstructural criteria such as shape preferred orientations, grain size estimates and amount of twinning. 相似文献
12.
Microstructures and quartz c-axis fabrics were analyzed in five quartzite samples collected across the eastern aureole of the Eureka Valley–Joshua Flat–Beer Creek composite pluton. Temperatures of deformation are estimated to be 740±50 °C based on a modified c-axis opening angle thermometer of Kruhl (J. Metamorph. Geol. 16 (1998) 142). In quartzite layers located closest (140 m) to the pluton-wall rock contact, flattened detrital grains are plastically deformed and partially recrystallized. The dominant recrystallization process is subgrain rotation (dislocation creep regime 2 of Hirth and Tullis (J. Struct. Geol. 14 (1992) 145)), although grain boundary migration (dislocation creep regime 3) is also evident. Complete recrystallization occurs in quartzite layers located at a distance of 240 m from the contact, and coincides with recrystallization taking place dominantly through grain boundary migration (regime 3). Within the quartzites, strain is calculated to be lowest in the layers closest to the pluton margin based on the aspect ratios of flattened detrital grains.The c-axis fabrics indicate that a slip operated within the quartzites closest to the pluton-wall rock contact and that with distance from the contact the operative slip systems gradually switch to prism [c] slip. The spatial inversion in microstructures and slip systems (apparent “high temperature” deformation and recrystallization further from the pluton-contact and apparent “low temperature” deformation and recrystallization closer to the pluton-contact) coincides with a change in minor phase mineral content of quartzite samples and also in composition of the surrounding rock units. Marble and calc-silicate assemblages dominate close to the pluton-wall rock contact, whereas mixed quartzite and pelite assemblages are dominant further from the contact.We suggest that a thick marble unit located between the pluton and the quartzite layers acted as a barrier to fluids emanating from the pluton. Decarbonation reactions in marble layers interbedded with the inner aureole quartzites and calc-silicate assemblages in the inner aureole quartzites may have produced high XCO2 (water absent) fluids during deformation. The presence of high XCO2 fluid is inferred from the prograde assemblage of quartz+calcite (and not wollastonite)+diopside±K-feldspar in the inner aureole quartzites. We suggest that it was these “dry” conditions that suppressed prism [c] slip and regime 3 recrystallization in the inner aureole and resulted in a slip and regime 2 recrystallization, which would normally be associated with lower deformation temperatures. In contrast, the prograde assemblage in the pelite-dominated outer part of the aureole is biotite+K-feldspar. These “wet” pelitic assemblages indicate fluids dominated by water in the outer part of the aureole and promoted prism [c] slip and regime 3 recrystallization. Because other variables could also have caused the spatial inversion of c-axis fabrics and recrystallization mechanisms, we briefly review those variables known to cause a transition in slip systems and dislocation creep regimes in quartz. Our conclusions are based on a small number of samples, and therefore, the unusual development of crystal fabrics and microstructures in the aureole to the EJB pluton suggests that further study is needed on the effect of fluid composition on crystal slip system activity and recrystallization mechanisms in naturally deformed rocks. 相似文献
13.
C. Yakymchuk M. Brown C. Clark F. J. Korhonen P. M. Piccoli C. S. Siddoway R. J. M. Taylor J. D. Vervoort 《Journal of Metamorphic Geology》2015,33(2):203-230
In this study, in situ U–Pb monazite ages and Lu–Hf garnet geochronology are used to distinguish mineral parageneses developed during Devonian–Carboniferous and Cretaceous events in migmatitic paragneiss and orthogneiss from the Fosdick migmatite–granite complex in West Antarctica. SHRIMP U–Pb monazite ages define two dominant populations at 365–300 Ma (from cores of polychronic grains, dominantly from deeper structural levels in the central and western sectors of the complex) and 120–96 Ma (from rims of polychronic grains, dominantly from the central and western sectors of the complex, and from monochronic grains, mostly from shallower structural levels in the eastern sector of the complex). For five paragneisses and two orthogneisses, Lu–Hf garnet ages range from 116 to 111 Ma, c. 12–17 Ma older than published Sm–Nd garnet ages of 102–99 Ma from three of the same samples. Garnet grains in the analysed samples generally have Lu‐enriched rims relative to Lu‐depleted cores. By contrast, for three of the same samples, individual garnet grains have flat Sm concentrations consistent with high‐T diffusive resetting. Lutetium enrichment of garnet rims is interpreted to record the breakdown of a Lu‐rich accessory mineral during the final stage of garnet growth immediately prior to the metamorphic peak, and/or the preferential retention of Lu in garnet during breakdown to cordierite in the presence of melt concomitant with the initial stages of exhumation. Therefore, garnet is interpreted to be part of the Cretaceous mineral paragenesis and the Lu–Hf garnet ages are interpreted to record the timing of close‐to‐peak metamorphism for this event. For the Devonian–Carboniferous event, phase equilibria modelling of the metasedimentary protoliths to the paragneiss and a diatexite migmatite restrict the peak P–T conditions to 720–800 °C at 0.45–1.0 GPa. For the Cretaceous event, using both forward and inverse phase equilibria modelling of residual paragneiss and orthogneiss compositions, the P–T conditions after decompression are estimated to have been 850–880 °C at 0.65–0.80 GPa. These P–T conditions occurred between c. 106 and c. 96 Ma, determined from Y‐enriched rims on monazite that record the timing of garnet and biotite breakdown to cordierite in the presence of melt. The effects of this younger metamorphic event are dominant throughout the Fosdick complex. 相似文献
14.
A statistical analysis of the distribution of cordierite and biotite in hornfels from the Bugaboo contact aureole: implications for the kinetics of porphyroblast crystallization 
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下载免费PDF全文 The three‐dimensional disposition of cordierite and biotite crystals in a hornfels from the contact aureole of the Bugaboo Batholith is quantified using high‐resolution X‐ray micro‐computed tomography and global as well as scale‐dependent pattern statistics. The results demonstrate a random distribution of cordierite and biotite crystal sizes for all scales across the entire rock volume studied indicative of interface‐controlled prograde metamorphic reaction kinetics. The reaction considered responsible for the mineral assemblage and the formation of cordierite and biotite in the hornfels is Ms + Chl + Qtz = Crd + And + Bt + . Rock‐specific phase equilibria point to metamorphic conditions of ~520 –550 °C and 3 kbar for this reaction. The common approach to approximate the shape of crystals as spherical underestimates the influence of the Strauss hard‐core process on rock texture and may be misinterpreted to reflect ordering of crystal sizes by inhibition of nucleation and growth commonly associated with diffusion‐controlled reaction kinetics. According to our findings, Strauss hard‐core ordering develops at length scales equal to and less than the average major axis of the crystal population. This is significantly larger than what is obtained if a spherical crystal geometry would be assumed, and increases with deviation from sphericity. For the cordierite and biotite populations investigated in this research, Strauss hard‐core ordering developed at length scales of up to ～2.2 and 1.25 mm, respectively, which is almost 1 mm longer than the scales that would be obtained if a spherical geometry would have been assumed. Our results highlight the importance of a critical assessment of the geometrical model assumptions commonly applied in the three‐dimensional analysis of crystal size distributions, and underline the need for a quantitative understanding of interface processes in order to appreciate their role in the kinetics of contact metamorphic reactions and rock texture formation. 相似文献
15.
The deformation history of a monophase calcite marble shear zone complex on Thassos Island, Northern Greece, is reconstructed by detailed geometric studies of the textural and microstructural patterns relative to a fixed reference system (shear zone boundary, SZB). Strain localization within the massive marble complex is linked to decreasing P–T conditions during the exhumation process of the metamorphic core complex. Solvus thermometry indicates that temperatures of 300–350°C prevailed during part of the shear zone deformation history. The coarse-grained marble protolith outside the shear zone is characterized by symmetrically oriented twin sets due to early coaxial deformation. A component of heterogeneous non-coaxial deformation is first recorded within the adjacent protomylonite. Enhanced strain weakening by dynamic recrystallization promoted strong localization of plastic deformation in the ultramylonite of the calcite shear zone, where high strain was accommodated by non-coaxial flow. This study demonstrates that both a pure shear and a simple shear strain path can result in similar crystallographic preferred orientations (single c-axis maximum perpendicular to the SZB) by different dominant deformation mechanisms. Separated a-axis pole figures (+a- and −a-axis) show different density distributions with orthorhombic texture symmetry in the protolith marble and monoclinic symmetry in the ultramylonite marble consistently with the observed grain fabric symmetry. 相似文献
16.
Silica depleted melting of pelites. Petrogenetic grid and application to the Susqueda Aureole, Spain 总被引：2，自引：0，他引：2
Metapelitic rocks in the low pressure contact metamorphic aureole around the Susqueda igneous complex, Spain show a number of features that make them an ideal testing ground for the modelling of silica‐undersaturated melting. Rocks in the aureole experienced localized depletion in silica by the segregation of quartz veins during a pre‐anatectic, regional cordierite‐andalusite grade metamorphic event. These rocks were then intruded by gabbroic to dioritic rocks of the Susqueda igneous complex that formed a migmatitic contact metamorphic aureole in the country rocks. This migmatisation event caused quartz‐saturated hornfels and restite formation in rocks that had experienced no quartz vein segregation in the previous regional metamorphic event, but silica‐undersaturated melting in those rocks that were previously depleted in silica. Silica‐undersaturated melting is investigated using a new petrogenetic P–T projection and equilibrium pseudosections calculated in the KFMASH and NCKFMASH systems, respectively. The grid considers quartz absent equilibria and a range of phases that form typically in silica‐undersaturated bulk compositions, for example corundum. It is shown that the quartz‐rich precursors in the Susqueda contact aureole produced about 10% melt during contact metamorphism. However, most of this melt was extracted leaving behind rocks with restitic bulk compositions and minor leucosome segregation. It is suggested that the melt mixed with the host igneous rocks causing an apparent magmatic zoning from diorite in the centre of the complex to tonalite at the margins. In contrast, the quartz‐poor precursors (from which the quartz veins segregated) melted in the silica‐undersaturated field producing a range of assemblages including peritectic corundum and spinel. Melting of the silica‐undersaturated rocks produced only negligible melt and no subsequent melt loss. 相似文献
17.
The King Island Scheelite Mine lies in the contact aureole of a granodiorite stock. Its open cut and numerous drill cores expose a contact metamorphosed and metasomatized series of finely interbedded argillaceous and calcareous sediments, with interleaved flows of picrite‐basalt and basic pyroclastics, the scheelite ore being limited to two limestone horizons. The range and gradation in composition of the original rocks has resulted in an unusual variety of metamorphic rocks, including forsterite‐phlogopite‐spinel‐tremolite hornfels, antho‐phyllite‐cordierite hornfels, biotite hornfels, actinolite hornfels, a variety of calc‐flinta, and marbles. The original sedimentation gave rise to a rapid alternation of limestone and shale, many times repeated, and during metamorphism these rocks reacted with each other to produce narrow bands of calc‐flinta. Subsequent pyrometasomatism selectively converted the greater part of the marble beds to scheelite‐bearing andradite skarn, leaving the various hornfels and calc‐flinta very little affected. The replacement of the marble was a volume for volume process, and the conversion of 1,000,000 tons of marble to average grade ore involved the introduction of about 350,000 tons of SiO2, 250,000 tons of Fe2O3, 55,000 tons A12O3, 30,000 tons of H2O and 82,500 tons of CaO. The temperature of the contact metamorphism attained over 500° C., and the rocks cooled to about 400° C. before the pyrometasomatism occurred. The rocks giving rise to the various hornfels underwent varying degrees of contraction during metamorphism, whereas the limestones probably expanded during metamorphism, and became more permeable to solutions. 相似文献
18.
S. Wyhlidal W. F. Th?ny P. Tropper R. Kaindl C. Hauzenberger V. Mair 《Mineralogy and Petrology》2012,106(3-4):173-191
The Brixen Granodiorite is part of the Permian calc-alkaline plutonic association (Brixen Granodiorite, Ifinger Granite, Kreuzberg Granite, Cima d’Asta Granitoid) that intruded the Variscan Southalpine metamorphic basement. The Brixen Granodiorite is located to the south of the Periatriatic Lineament in the eastern part of the Southalpine basement complex and comprises a series of tonalitic, granitic and granodioritc intrusions, which were emplaced during the Permian (280?Ma) into the country rocks of the Brixen Quarzphyllites. The depth of these Southalpine granodioritic intrusions was less than 10?km (P?≤?0.3?GPa) and solidus temperatures were 670–720?°C (Visona, Mem Sci Geol 47:111–124, 1995; Acquafredda et al., Miner Petrogr Acta XL:45–53, 1997; Wyhlidal et al., Austr J Earth Sci 102:181–192, 2009). Only a small, about 200?m wide, contact aureole formed at the southern rim of the Brixen Granodiorite near the village Franzensfeste/Fortezza (South-Tyrol, Italy). Within the contact aureole four different zones can be distinguished based upon mineralogical, mineral chemical and textural features. Approximately 200?m from the granite contact zone I occurs. The rocks from this zone are macroscopically still quartzphyllites and are characterized by two texturally and chemically different generations of micas (muscovite, biotite) and the appearance of cordierite. Zone II is characterized by quartzphyllites containing pseudomorphs of cordierite + biotite after garnet. The inner contact aureole (zone III) starts approximately 50?m from the granite contact and shows already typical hornfels textures. This zone is characterized by the first occurrence of andalusite. In the innermost area (zone IV), ca 10?m from the granite contact, spinel and corundum occur. Geothermometry (two-feldspar-, Ti-in-biotite) yielded an increase in temperature from 540?°C in the outermost aureole (zone I) to <740?°C in the innermost aureole (zone IV). Pseudosection modelling of hornfelses from zones III and IV also resulted in similar P-T conditions of <0.28?GPa and <620?°C. This contact aureole represents one of the few well-developed remaining areas of Permian contact metamorphism in the Southalpine domain, which are otherwise mostly obliterated by late-stage hydrothermal alteration in the course of the Alpine tectonic overprint. 相似文献
19.
Fabric development during shear deformation in the Main Central Thrust Zone, NW-Himalaya, India 总被引：2，自引：0，他引：2
Quartz microfabrics and associated microstructures have been studied on a crustal shear zone—the Main Central Thrust (MCT) of the Himalaya. Sampling has been done along six traverses across the MCT zone in the Kumaun and Garhwal sectors of the Indian Himalaya. The MCT is a moderately north-dipping shear zone formed as a result of the southward emplacement of a part of the deeply rooted crust (that now constitutes the Central Crystalline Zone of the Higher Himalaya) over the less metamorphosed sedimentary belt of the Lesser Himalaya. On the basis of quartz c- and a-axis fabric patterns, supported by the relevant microstructures within the MCT zone, two major kinematic domains have been distinguished. A noncoaxial deformation domain is indicated by the intensely deformed rocks in the vicinity of the MCT plane. This domain includes ductilely deformed and fine-grained mylonitic rocks which contain a strong stretching lineation and are composed of low-grade mineral assemblages (muscovite, chlorite and quartz). These rocks are characterized by highly asymmetric structures/microstructures and quartz c- and a-axis fabrics that indicate a top-to-the-south sense that is compatible with south-directed thrusting for the MCT zone. An apparently coaxial deformation domain, on the other hand, is indicated by the rocks occurring in a rather narrow belt fringing, and structurally above, the noncoaxial deformation domain. The rocks are highly feldspathic and coarse-grained gneisses and do not possess any common lineation trend and the effects of simple shear deformation are weak. The quartz c-axis fabrics are symmetrical with respect to foliation and lineation. Moreover, these rocks contain conjugate and mutually interfering shear bands, feldspar/quartz porphyroclasts with long axes parallel to the macrosopic foliation and the related structures/microstructures, suggesting deformation under an approximate coaxial strain path.On moving towards the MCT, the quartz c- and a-axis fabrics become progressively stronger. The c-axis fabric gradually changes from random to orthorhombic and then to monoclinic. In addition, the coaxial strain path gradually changes to the noncoaxial strain path. All this progressive evolution of quartz fabrics suggests more activation of the basal, rhomb and a slip systems at all structural levels across the MCT. 相似文献
20.
F. J. KORHONEN M. BROWN M. GROVE C. S. SIDDOWAY E. F. BAXTER J. D. INGLIS 《Journal of Metamorphic Geology》2012,30(2):165-192
The Fosdick migmatite–granite complex in West Antarctica records evidence for two high‐temperature metamorphic events, the first during the Devonian–Carboniferous and the second during the Cretaceous. The conditions of each high‐temperature metamorphic event, both of which involved melting and multiple melt‐loss events, are investigated using phase equilibria modelling during successive melt‐loss events, microstructural observations and mineral chemistry. In situ SHRIMP monazite and TIMS Sm–Nd garnet ages are integrated with these results to constrain the timing of the two events. In areas that preferentially preserve the Devonian–Carboniferous (M1) event, monazite grains in leucosomes and core domains of monazite inclusions in Cretaceous cordierite yield an age of c. 346 Ma, which is interpreted to record the timing of monazite growth during peak M1 metamorphism (～820–870 °C, 7.5–11.5 kbar) and the formation of garnet–sillimanite–biotite–melt‐bearing assemblages. Slightly younger monazite spot ages between c. 331 and 314 Ma are identified from grains located in fractured garnet porphyroblasts, and from inclusions in plagioclase that surround relict garnet and in matrix biotite. These ages record the growth of monazite during garnet breakdown associated with cooling from peak M1 conditions. The Cretaceous (M2) overprint is recorded in compositionally homogeneous monazite grains and rim domains in zoned monazite grains. This monazite yields a protracted range of spot ages with a dominant population between c. 111 and 96 Ma. Rim domains of monazite inclusions in cordierite surrounding garnet and in coarse‐grained poikiloblasts of cordierite yield a weighted mean age of c. 102 Ma, interpreted to constrain the age of cordierite growth. TIMS Sm–Nd ages for garnet are similar at 102–99 Ma. Mineral equilibria modelling of the residual protolith composition after Carboniferous melt loss and removal of inert M1 garnet constrains M2 conditions to ～830–870 °C and ～6–7.5 kbar. The modelling results suggest that there was growth and resorption of garnet during the M2 event, which would facilitate overprinting of M1 compositions during the M2 prograde metamorphism. Measured garnet compositions and Sm–Nd diffusion modelling of garnet in the migmatitic gneisses suggest resetting of major elements and the Sm–Nd system during the Cretaceous M1 overprint. The c. 102–99 Ma garnet Sm–Nd ‘closure’ ages correspond to cooling below 700 °C during the rapid exhumation of the Fosdick migmatite–granite complex. 相似文献