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Byproduct Formation During the Reduction of TCE by Zero-Valence Iron and Palladized Iron 总被引：4，自引：0，他引：4
Liyuan Liang Nic Korte J.D. Goodlaxson Jay Clausen Quintus Fernando Rosy Muftikian 《Ground Water Monitoring & Remediation》1997,17(1):122-127
Trichloroethene (TCE) was reduced with zero-valence iron and palladized iron in zero-head-space extractors. Progress of the reaction in these batch studies was monitored with purge-and-trap gas chromatography and a flame ionization detector. When a 5 ppm initial concentration of TCF. reacts with zero-valence iron, approximately 140 ppb of vinyl chloride persists for as long as 73 days. The concentration of vinyl chloride (approximately If) ppb) remaining with palladized iron is approximately an order of magnitude less than when zero-valence iron is the reductant. These data suggest that volatile byproducts may be under-represented in oilier published data regarding reduction with zero-valence metals. These results also demonstrate that the reduction of TCE with palladized iron (0.05 percent palladium) is more than an order of magnitude faster than with zero-valence iron. Wilh a 5:1 solution-to-solid ratio the TCE half-life with zero-valence iron is 7.41 hours. but is only 0.59 hours with the palladized iron. 相似文献
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The distributions of dissolved and of particulate iron in the Dead Sea during the period which preceeded its overturn and thereafter (1977–1980) are reported. During 1977–1978, the vertical profiles of the iron phases revealed facets of the mixing pattern: the progressive deepening of the pycnocline, restricted mixing within the upper water mass and penetration of surface waters into the deepest layer. The inventories of particulate iron suggest resuspension of bottom sediments in November 1978 and after the overturn the gradual disappearance from the water column of iron sulfides and iron oxy-hydroxides. Fluxes of iron from and to the lake in the undisturbed meromictic Dead Sea have been estimated: it appears that diffusion of divalent iron from bottom sediments was the major source for the standing crop of iron in the lower water mass. Low settling velocities of solid particles in the dense and viscous Dead Sea is one of the causes for the relatively large concentrations of particulate iron. The rate constant for oxidation of divalent iron in Dead Sea sediment interstitial waters is larger by two orders of magnitude than in other natural waters. 相似文献
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Iron isotope fractionation during planetary differentiation 总被引：4，自引：0，他引：4
Stefan Weyer Ariel D. Anbar Carsten Münker Alan B. Woodland 《Earth and Planetary Science Letters》2005,240(2):251-264
The Fe isotope composition of samples from the Moon, Mars (SNC meteorites), HED parent body (eucrites), pallasites (metal and silicate) and the Earth's mantle were measured using high mass resolution MC-ICP-MS. These high precision measurements (δ56Fe ≈ ± 0.04‰, 2 S.D.) place tight constraints on Fe isotope fractionation during planetary differentiation.Fractionation during planetary core formation is confined to < 0.1‰ for δ56Fe by the indistinguishable Fe isotope composition of pallasite bulk metal (including sulfides and phosphides) and olivine separates. However, large isotopic variations (≈ 0.5‰) were observed among pallasite metal separates, varying systematically with the amounts of troilite, schreibersite, kamacite and taenite. Troilite generally has the lightest (δ56Fe ≈ − 0.25‰) and schreibersite the heaviest (δ56Fe ≈ + 0.2‰) Fe isotope composition. Taenite is heavier then kamacite. Therefore, these variations probably reflect Fe isotope fractionation during the late stage evolution and differentiation of the S- and P-rich metal melts, and during low-temperature kamacite exsolution, rather than fractionation during silicate-metal separation.Differentiation of the silicate portion of planets also seems to fractionate Fe isotopes. Notably, magmatic rocks (partial melts) are systematically isotopically heavier than their mantle protoliths. This is indicated by the mean of 11 terrestrial peridotite samples from different tectonic settings (δ56Fe = + 0.015 ± 0.018‰), which is significantly lighter than the mean of terrestrial basalts (δ56Fe = + 0.076 ± 0.029‰). We consider the peridotite mean to be the best estimate for the Fe isotope composition of the bulk silicate Earth, and probably also of bulk Earth. The terrestrial basaltic mean is in good agreement with the mean of the lunar samples (δ56Fe = + 0.073 ± 0.019‰), excluding the high-Ti basalts. The high-Ti basalts display the heaviest Fe isotope composition of all rocks measured here (δ56Fe ≈ + 0.2‰). This is interpreted as a fingerprint of the lunar magma ocean, which produced a very heterogeneous mantle, including the ilmenite-rich source regions of these basalts.Within uncertainties, samples from Mars (SNC meteorites), HED (eucrites) and the pallasites (average olivine + metal) have the same Fe isotope compositions as the Earth's mantle. This indicates that the solar system is very homogeneous in Fe isotopes. Its average δ56Fe is very close to that of the IRMM-014 standard. 相似文献
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Barry J. Allred 《Ground Water Monitoring & Remediation》2012,32(2):81-95
Agricultural subsurface drainage waters containing nutrients (nitrate/phosphate) and pesticides are discharged into neighboring streams and lakes, frequently producing adverse environmental impacts on local, regional, and national scales. On‐site drainage water filter treatment systems can potentially prevent the release of agricultural contaminants into adjacent waterways. Zero valent iron (ZVI) and sulfur‐modified iron (SMI) are two types of promising filter materials that could be used within these treatment systems. Therefore, water treatment capabilities of three ZVI and three SMI filter materials were evaluated in the laboratory. Laboratory evaluation included saturated falling‐head hydraulic conductivity tests, contaminant removal batch tests, and saturated solute transport column experiments. The three ZVI and the three SMI filter materials, on average, all had a sufficient hydraulic conductivity greater than 1 × 10–3 cm/s. Batch test results showed a phosphate decrease of at least 94% for all tests conducted with the ZVI and SMI. Furthermore, the three SMI filter materials removed at least 86% of the batch test nitrate originally present, while batch tests for one of the ZVI filter materials exhibited an 88% decrease in the pesticide, atrazine. Saturated solute transport column experiments were carried on the best ZVI filter material, or the best SMI filter material, or both together, in order to better evaluate drainage water treatment effectiveness and efficiency. Results from these column tests additionally document the drainage water treatment ability of both ZVI and SMI to remove the phosphate, the ability of SMI to remove nitrate, and the ability of a select ZVI material to remove atrazine. Consequently, these findings support further investigation of ZVI and SMI subsurface drainage water treatment capabilities, particularly in regard to small‐ and large‐scale field tests. 相似文献
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在分析１９６６年—１９８５年间太原盆地发生的１４起震群序列资料的基础上。叙述了这些震群分布区的新构造特征、空间分布特征、震群活动区特征、震群迁移特征、震群的震源深度、震群所反映的现代局部应力场等。 相似文献
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Prof. Dr. U. Schwertmann L. Carlson H. Fechter 《Aquatic Sciences - Research Across Boundaries》1984,46(2):185-191
Artificial ground water containing 40 mg/l Ca and varying concentrations of Fe(II), Fe(III) and Si were rapidly oxidized with
air. The ferrihydrite forming is similar to those found in natural Finish ground waters. 相似文献
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Séverine Bernardie Jean-Pascal Gilbert François Lebert Hubert Fabriol 《Pure and Applied Geophysics》2007,164(1):177-197
The monitoring of the stability of old mines constitutes an important research objective for our institution, BRGM. The study
reported here shows the contribution of high-frequency (>30 kHz) acoustic emissions to the detection of the damage within
a rock mass, during an experiment within a pilot site of an old flooded iron mine. The experiment consisted of recording all
the hydroacoustic events in a broad frequency band (between 30 Hz and 180 kHz), during 18 months. The monitoring network has
been calibrated by a triggered block fall that made it possible to highlight a relationship between the occurrence of high-frequency/low-frequency
hydroacoustic emissions and rock falls. The events recorded have been associated with the micro-failure of the rock mass near
the roof, prior to the detachment of the blocks. This monitoring showed important high-frequency hydroacoustic activity, which
may be associated with mechanical instabilities generated by the evolution of water pressure during the experiment. In conclusion,
the high-frequency hydroacoustic activity appears to be a good indicator of instability and, therefore, this new technique
constitutes a promising tool for monitoring abandoned underground cavities. 相似文献
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经资料整理与实地调研：老挝已发现铁矿床（点）42处。重要矿床为万象省（P．Vientiane）万荣（Vang—viang）铁矿、川圹省（P．Xiangkhouang）富诺安（Phou．Nhouan）铁矿、万象省（P．Vientiane）帕莱（PhaLek）铁矿、甘蒙省（P．Khammouan）班农洛（BanNonglao）铁矿。重要矿床的矿体呈似层状、脉状产出,矿石质量较好,矿床属接触交代矿床、热液矿床。据地层条件、岩浆岩条件、构造条件、铁矿床（点）的分布情况,老挝划分出琅勃拉邦（Louangphabang）、孟佩（MuangPek）、桑怒（Xam—Nua）3个成矿预测区。 相似文献
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Modeling In Situ Iron Removal from Ground Water 总被引：2，自引：1，他引：1
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Enhanced Degradation of Halogenated Aliphatics by Zero-Valent Iron 总被引：89，自引：0，他引：89
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Chicgoua Noubactep 《洁净——土壤、空气、水》2013,41(7):702-710
Water treatment with metallic iron (Fe0) is still based on the premise that Fe0 is a reducing agent. An alternative concept stipulates that contaminants are removed by adsorption, co‐precipitation, and size‐exclusion in a reactive filtration process. This article underlines the universal validity of the alternative concept. It is shown that admixing non‐expansive material to Fe0 as a pre‐requisite for sustainable Fe0‐based filtration systems. Fe0‐based filters are demonstrated an affordable, appropriate, and efficient decentralized water treatment technology. 相似文献
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Sabine Caré Richard Crane Paolo S. Calabrò Antoine Ghauch Emile Temgoua Chicgoua Noubactep 《洁净——土壤、空气、水》2013,41(3):275-282
Over the past 30 years the literature has burgeoned with in situ approaches for groundwater remediation. Of the methods currently available, the use of metallic iron (Fe0) in permeable reactive barrier (PRB) systems is one of the most commonly applied. Despite such interest, an increasing amount of experimental and field observations have reported inconsistent Fe0 barrier operation compared to contemporary theory. In the current work, a critical review of the physical chemistry of aqueous Fe0 corrosion in porous media is presented. Subsequent implications for the design of Fe0 filtration systems are modeled. The results suggest that: (i) for the pH range of natural waters (>4.5), the high volumetric expansion of Fe0 during oxidation and precipitation dictates that Fe0 should be mixed with a non‐expansive material; (ii) naturally occurring solute precipitates have a negligible impact on permeability loss compared to Fe0 expansive corrosion; and (iii) the proliferation of H2 metabolizing bacteria may contribute to alleviate permeability loss. As a consequence, it is suggested that more emphasis must be placed on future work with regard to considering the Fe0 PRB system as a physical (size‐exclusion) water filter device. 相似文献
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Carmen Lourdes Yupanqui Zaa Joan E. McLean R. Ryan Dupont Jeanette M. Norton Darwin L. Sorensen 《Ground Water Monitoring & Remediation》2010,30(1):46-57
Dehalorespiration bioremediation has been considered for chlorinated compound removal from two trichloroethene contaminated groundwater plumes in the OU 5 area of Hill Air Force Base, Utah. The distributions and population densities of the 16S rRNA genes of Bacteria, Dehalococcoides ethenogenes, Desulfuromonas michiganensis, Geobacter spp. and Rhodoferax ferrireducens -like bacteria, as well as the functional genes trichloroethene reductive dehalogenase ( tce A) and vinyl chloride reductase ( vcr A) were determined in contaminated aquifer material samples. The influence of aquifer physical and chemical properties, including iron availability, on these distributions was evaluated. Twenty aquifer cores were collected. DNA was extracted and analyzed using real-time quantitative polymerase chain reaction (RT-qPCR) to quantify the gene densities. Dehalococcoides population densities were low and unevenly distributed. D. michiganensis was found in 12 cores while Geobacter spp. were found in 8 cores. Rhodoferax ferrireducens -like bacteria were widely distributed. The vcr A gene distribution was relatively uniform and broad but the tce A gene was detectable in only 2 cores. Gene distribution was not related to core clusters derived from physical/chemical characteristics. 相似文献
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Although intensive research on Fe(0) permeable reactive barriers (PRB) for in situ groundwater remediation has been conducted and multiple applications have been installed in the past two decades, some properties of reactive materials in use have not been fully considered and discussed yet. In the present investigation, a typical granular cast iron has been characterized with different techniques. The grain size distribution not only has an influence on the resulting pore geometry and the surface area but material properties significantly differ between fine and coarse grains. Metallographic analyses revealed large differences in both graphite inclusions and microstructures that likely influence the reactivity. Both graphite and cementite proved to be more resistant toward acidic dissolution compared to Fe0. The intrinsic material characteristics described here have not been covered in the existing PRB literature. 相似文献
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《Ground Water Monitoring & Remediation》2008,28(3):56-64
Core samples taken from a zero-valent iron permeable reactive barrier (ZVI PRB) at Cornhusker Army Ammunition Plant, Nebraska, were analyzed for physical and chemical characteristics. Precipitates containing iron and sulfide were present at much higher concentrations in native aquifer materials just upgradient of the PRB than in the PRB itself. Sulfur mass balance on core solids coupled with trends in ground water sulfate concentrations indicates that the average ground water flow after 20 months of PRB operation was approximately twenty fold less than the regional ground water velocity. Transport and reaction modeling of the aquifer PRB interface suggests that, at the calculated velocity, both iron and hydrogen could diffuse upgradient against ground water flow and thereby contribute to precipitation in the native aquifer materials. The initial hydraulic conductivity ( K ) of the native materials is less than that of the PRB and, given the observed precipitation in the upgradient native materials, it is likely that K reduction occurred upgradient to rather than within the PRB. Although not directly implicated, guar gum used during installation of the PRB is believed to have played a role in the precipitation and flow reduction processes by enhancing microbial activity. 相似文献
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M. V. Martynova 《Water Resources》2010,37(4):488-496
Data on the occurrence forms and concentrations of crystalline, amorphous, and organic Fe in the solid phase of silts in lakes
and reservoirs, as well as data on concentrations of Fe forms in the pore solution of deposits are analyzed. The major mechanisms
of Fe compound transformations are briefly considered. 相似文献