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1.
利用甲烷碳同位素研究混合气的混合体积 总被引：5，自引：1，他引：5
自然界不同源天然气的混合是一种普遍现象。混合作用是一种物理过程，混合气中某一组份的含量为该组份在各种来源气中的含量以其体积比例为权的和。因此，根据混合气的碳同位素以及被混合的气的碳同位素丰度可确定出各种被混合的气的比例。文章根据这一原理对廊固凹陷河西务构造带天然气的混合比例进行了计算，结果表明混合气中有２４%～６３%是来自石炭－二叠系的煤成气。在实际应用中，确定典型气的甲烷碳同位素丰度是基础，根据天然气甲烷同位素丰度与其源岩热演化成熟度Ｒｏ有线性关系的原理，可利用研究区源岩的Ｒｏ来确定本区的煤成气或油型气甲烷碳同位素的丰度。 相似文献
2.
中国南方百色盆地浅层生物气组成与成因 总被引：1，自引：1，他引：1
根据30余个气样分析资料,结合地质、地球化学背景,对百色第三系残留型盆地浅层生物气的组成和分布特征进行了深入研究,并探讨了其成因和形成机制。这些浅层气主要以烃类气体为主,一般占90%以上。甲烷和C2+烷烃含量有较大变化范围,分别主要在50%～100%和0～50%之间,取决于热成因气混入生物气的比例。所研究浅层气的一个重要特征是其碳同位素很轻,甲烷的δ13C值主要变化在-55‰～-75‰范围。按照分子和碳同位素组成及轻烃参数,该盆地浅层气可划分为三种成因类型:纯生物气、生物气/热成因气混合气和原油菌解气。它们在时空上呈规律性分布,与邻… 相似文献
3.
根据天然气地球化学基本理论,对柴达木盆地西部（柴西）地区天然气的地球化学特征进行分析。测试和收集该地区18个油气田及含油气构造的83个天然气样品,分析其组分和C同位素数据,结果显示,该区天然气以烃类气体为主,烃类含量介于79.24%~99.81%之间,天然气比重介于0.72~1.36之间,天然气干燥系数（C1/C2+）介于1.04~617.8之间,甲烷C同位素值介于-51.4‰~-24.2‰之间,乙烷C同位素值介于-34.2‰~-17.4‰之间。在此基础上,对该区不同构造带的天然气成因类型进行研究。研究结果表明,柴达木盆地西部地区天然气类型可划分为腐泥型气、腐殖型气、混合气3类,柴西北部天然气主要为腐泥型气和混合气,少量腐殖型气;柴西南部主要为腐泥型气,少量混合气。同时,建立了天然气成因类型的判识指标,对该区的天然气地球化学特征有了较为深入的认识,对今后的天然气勘探具有指导意义。 相似文献
4.
本文根据30余个气样分析资料,结合地质、地球化学背景,对百色第三系残留型盆地浅层生物气的组成和分布特征进行了深入研究,并探讨了其成因和形成机制。这些浅层气主要以烃类气体为主,一般占90%以上。甲烷和烷烃含量有较大变化范围,分别主要在50%～100%和0～50%之间,取决于热成因气混入生物气的比例。所研究浅层气的一个重要特征是其碳同位素很轻,甲烷的δ13C值主要变化在55‰～-75‰范围。按照分子和碳同位素组成及轻烃参数,该盆地浅层气可划分为3种成因类型:纯生物气、生物气-热成因气混合气和原油菌解气。它们在时空上呈规律性分布,与邻… 相似文献
5.
对食品中有机氯农药和多氯联苯的气相色谱-质谱联用(GC-MS)分析方法中三种离子化方式,电子轰击电离(EI)、正化学电离(PCI)和负化学电离(NCI)进行了总结和比较。PCI-MS/MS方法和EI-MS/MS方法都有很高的选择性和较高的灵敏度;PCI方法在分析含硝基、羰基等基团的化合物时有明显优势,EI则在分析狄氏剂、异狄氏剂、硫丹及其代谢物时比PCI表现稍好,而NCI-MS的灵敏度最高,但抗干扰能力稍弱,且不适合分析滴滴涕类和多氯联苯类化合物。在食品安全分析中,三种质谱方法的准确性好,精密度高,检测限较低,都能够满足食品中农残检测的要求,在日常检测工作中可互为补充和替代。同时指出,GC在有机氯化合物分析中仍表现出明显的优越性;常规的GC-MS尤其在EI电离模式下,易受到基质干扰而使谱图变得复杂;新型离子化方式包括高选择性化学电离技术的应用,将是食品安全中GC-MS联用分析的发展方向之一。 相似文献
6.
甲烷动态反应电感耦合等离子体质谱法测定地下水中痕量硒 总被引：2，自引：2，他引：0
地下水中的硒含量一般低于1μg/L,大量氯离子等形成的多原子离子干扰和较低的电离程度,严重影响常规模式ICP-MS测定地下水中痕量硒的准确性,且检出限难以满足实际需要。本文建立了应用动态反应池电感耦合等离子体质谱(DRC-ICP-MS)技术测定地下水中痕量硒的方法,采用乙醇为增感剂,甲烷为反应气,通过实验优化了甲烷流量、乙醇含量、雾化气流速、低质量截取(RPq)、射频发生器(Rf)功率、离子驻留时间等条件对硒不同质量数测定的影响。结果表明:乙醇、甲烷可显著降低Ar等形成的多原子离子干扰,乙醇可明显提高硒的响应强度;在优化实验条件下,除74Se外,各离子的校准曲线线性关系良好(R≥0. 9996),方法检出限为0. 02～0. 03μg/L,低浓度和高浓度样品测试结果的RSD 2%(n=5),平均加标回收率为95. 7%。本方法样品前处理简单,使用设备单一,可满足大批量地下水中痕量硒的测定要求。 相似文献
7.
本文就和田河气田天然气组分组成、碳同位素组成和天然气成因类型进行了分析,着重分析了其东西部差异。研究发现:和田河气田天然气甲烷含量很高,达64.19%～86.86%,平均含量79.36%,C2+含量0～3.75%,干燥系数为95.52～99.4,平均值为97.34,CO2含量高。和田河气田东西部天然气差异明显,其主要表现为多期成藏、TSR反应东西运移的结果。天然气的成因分别是东部为原油裂解气,玛2井为原油裂解气和干酪根裂解气混合气,西部为干酪根裂解气。 相似文献
8.
通过对松南气田营城组与登楼库组火山岩天然气的组成、碳同位素及惰性气体同位素特征分析,天然气烃类组成以甲烷为主,含极少量重烃,干燥系数均在0.99左右,为干气;天然气中CO2含量高,在-20.74%~-25.75%之间,为高含CO2的天然气藏;天然气甲烷同位素偏重为-18.3‰~-26.5‰,并且有δ13C1δ13C2δ13C3负碳同位素序列,表明有无机成因烃类气体混合的特征,营城组的CO2同位素表明为幔源无机成因气,3He/4He的比值高,介于壳源成因与幔源成因之间,也表明有幔源3He/4He的输入,多种参数表明松南地区天然气的有幔源成因的甲烷,也有煤系地层生成的煤型气,营城组的CO2为幔源成因,为煤幔混合气。通过模拟计算,松南气田深层天然气幔源成因的烃类气体占40.62%~100%。煤系成因来源为0~59.38%,加之20%左右的CO2气体均为无机幔源成因,因此该区天然气主要为无机幔源成因的天然气。 相似文献
9.
煤的加水热模拟气特征对比 总被引：7，自引：0，他引：7
为探讨煤成气的生成特征和演化规律，对两种不同有机质类型煤进行了加水热模拟生气实验研究。认为，有机质类型对于煤的热模拟气生成特征和烃气产率有决定作用。非烃气中的氢气、一氧化碳与二氧化碳含量之间呈负相关，这与水参与反应有关。甲烷的形成与水的作用关系密切。不同的热模拟气在成熟—高成熟演化阶段差异明显，有机质类型越差，热模拟气中甲烷相对越多，干燥系数相对越大，异丁烷／正丁烷越高；反之，甲烷相对越少，干燥系数越小，异丁烷／正丁烷低，区别越明显。演化程度增加时，热模拟气之间的差别减小。总烃气和甲烷的产率随温度升高而增加，而重烃有产率高峰存在，正好对应于生油窗的底界。 相似文献
10.
南海北部天然气水合物钻探区烃类气体成因类型研究 总被引：5，自引：2，他引：3
南海北部天然气水合物钻探区水合物气、顶空气样品和沉积物样品烃类气体组分和甲烷同位素特征测试结果表明,气体样品中烃类气体以甲烷为主,含微量乙烷和丙烷,C1/(C2+C3)值均大于或接近1 000。甲烷的碳同位素值为-54.1‰~-62.2‰,氢同位素值为-180‰~-255‰,属于微生物气或是以微生物气为主的混合气,甲烷由CO2还原生成,由原地提供或侧向运移而来。沉积物样品酸解烃分析显示多数样品甲烷丰度大于90%,含一定量的乙烷、丙烷及少量的丁烷,C1/(C2+C3)值均小于50。甲烷的碳同位素值为-29.8‰~-48.2‰,呈现典型的热解气特征,显示由深部运移而来。 相似文献
11.
Emily Keeble David I. Whiteside Michael J. Benton 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(2):99-119
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco. 相似文献
12.
Gilles Serge Odin 《Comptes Rendus Geoscience》2002,334(6):409-414
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414. 相似文献
13.
The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts 总被引：4，自引：0，他引：4
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species. 相似文献
14.
15.
Muriel Rocher Stéphane Baize Stéphane Jaillet Edward Marc Cushing Yannick Lozac&#x;h Francis Lemeille 《Comptes Rendus Geoscience》2003,335(8):701-708
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003). 相似文献
16.
正20141520 Bo Ying(Key Laboratory of Metallogeny and Mineral Assessment,MLR,Beijing 100037,China);Liu Chenglin Saline Spring Hydrochemical Characteristics and Indicators for Potassium Exploration in Southwestern and Northern Tarim Basin,Xinjiang(Acta Geoscientica Sinica,ISSN1006-3021,CN11-3474/P,34(5),2013,p.594-602,5 illus.,3 tables,28 refs.) 相似文献
17.
正20141243Chen Ge(Hangzhou Research Institute of Petroleum Geology,PetroChina,Hangzhou 310023,China);Si Chunsong Study on Sedimentary Numerical Simulation Method of Fan Delta Sand Body(Journal of Geology, 相似文献
18.
正20142599Chen Sanming(Guangxi Key Laboratory of Concealed Deposits Exploration,Guilin University of Technology,Guilin541004,China);He Yuzhou Block Model and Reserves Estimation of Panzhihua Iron Deposit Based on 3D Geological Modeling(Journal of Guilin University of Technology,ISSN1674-9057,CN45-1375/N,33(4),2013,p.610-615,9illus.,1table,15refs.) 相似文献
19.
正20140594 Bai Daoyuan(Hunan Institute of Geology Survey,Changsha 410016,China);Zhong Xiang Faults in the Jingzhou Basin and Their Tectonic Settings(Geotectonica et Metallogenia,ISSN1001-1552,CN44-1595/P,37(2),2013,p.173-183,6illus.,59refs.)Key words:basin evolution,tectonic setting,South China In the Upper Paleozoic and Jurassic se- 相似文献
20.
正20141912Cao Hui(State Key Laboratory for Continental Tectonics and Dynamics,Institute of Geology,Chinese Academy of Geological Sciences,Beijing 100037,China)Gravitational Collapse and Folding during Orogenesis:A Comparative Study of FIA Trends and Fold Axial Plane Traces(Geology in China,ISSN1000-3657,CN11-1167/P,40(6),2013,p.1818-1828,9illus.,35refs.,with 相似文献