共查询到20条相似文献，搜索用时 46 毫秒
1.
The results of recent investigations on the stability limitsof staurolite have been combined together with those of thepresent study to develop a semi-quantitative model of the P–T–fo2–Xrelations of staurolite±quartz±magnetite. Theproblem with respect to the hydroxyl content of staurolite hasbeen analysed; it is concluded that no evidence has yet beenmustered to discount the idealised stoichiometry proposed byNaray-Szabó & Sasvari (1958), at least as a limitingcomposition. The stability limits of staurolite±magnetitehave been calculated from the experimental data for the equilibriainvolving quartz. Also the conditions over which the assemblagecordierite+magnetite+quartz could be stable, as well as a quantitativemodel for the fo2-P stability of almandine ± quartz havebeen deduced theoretically. An analysis is presented of the paragenetic relations of staurolitein common pelitic schists. It is suggested that the formationof staurolite at the expense of either chloritoid or chlorite,rather than the unqualified first appearance of staurolite asproposed by Winkler (1970), should define a ‘staurolite-in’isograd in the range of 500–575 °C. In regional metamorphism,chloritoid, staurolite, and aluminum silicates should, underequilibrium conditions, be unstable relative to almandine ingraphitic pelitic schists involving magnetite (chloritoid/staurolite/Al2SiO6+magnetite+quartzalmandine+O2+H2O).The limits of P-T conditions over which staurolite and cordieritemay coexist in natural assemblages have been deduced; it isrestricted, almost entirely within the field of andalusite,between 500–700 °C, and 2–6 kbars, thus definingthe range of P-T conditions for the ‘low-pressure intermediate’—or ‘Buchan’–type amphibolite facies discussedby Miyashiro (1961). In assemblages involving staurolite andandalusite, cordierite rather than almandine should usuallybe stable; the reverse holds for assemblages involving stauroliteand sillimanite. 相似文献
2.
A high-grade metamorphic terrane in the southern part of theCalabrian massif (South Italy) has been petrographically mappedand the dominant rock types petrologically investigated. Bothmethods of investigation have led to the recognition of a continuoussection through a former lower crust which is 7 km thick. Itslower part consists predominantly of metabasic rocks togetherwith minor felsic granulites, its upper part of metapeliteswith minor metabasic and metacarbonate rocks. The rocks experienced a common two-stage prograde metamorphicevolution in which the second stage occurred after the lastpenetrative deformation. The prograde metamorphism which, accordingto radiometric dates, ended in late Hercynian time, was of themedium-pressure type of Miyashiro (1961), and equilibrationoccurred in the ‘medium-pressure granulite field’(characterized by the instability of olivine-plagioclase aswell as garnet-clinopyroxene-quartz). Estimates of the highestP—T conditions of prograde metamorphism give 7–8kb and approximately 800°C at the base, but 5–6 kband 650–700°C at the top of the section, at whichthe paragenesis staurolite-quartz indicates the transition tothe amphibolite facies. The existence of a metamorphic gradientin the lower crust section is demonstrated by the systematicchange in the compositions of ferro-magnesian minerals in divariantmetapelitic assemblages. The metamorphic evolution during the excavation history of theformer lower crust has been reconstructed using the numerousdisequilibrium reaction textures preserved in most rock types.The highest metamorphic conditions ended with a pressure decreaseof approximately 1.5 to 2 kb, which was followed by a periodof quasi-isobaric cooling in the middle crust. During this cooling,the stability field of the ‘high-pressure granulites’(garnet-clinopyroxene-quartz) was reached. The pressure decrease, which induced the end of the high-temperaturehistory of the lower crust, is interpreted as reflecting theerosion of the uppermost crustal levels as a response to overlappingof large crustal segments during the Hercynian orogeny. Consequently,the deduced P—T path of the upper, i.e. overthrust crustalsegment is thought to have been tectonically controlled. 相似文献
3.
Petrology and Geochemistry of Metabasalts from the 1.95 Ga Jormua Ophiolite, Northeastern Finland 总被引：9，自引：0，他引：9
The Jormua Ophiolite exposes a unique fragment of Red Seatypeoceanic crust formed in a setting related to continental break-up1950 Ma ago. Two distinct types of basalt are represented: the‘early dykes’ and the ‘main basalt suite’.‘Early dykes’ have fractionated (H) REE patterns,OIB-like trace element patterns, low Zr/Nb (6) and ENd(1.95Ga)–0.6, indicative of their derivation from an enrichedsource. The remaining dykes and all lavas belong to the second,E-MORB-like ‘main basalt suite’, which is characterizedby high mg-number and Cr contents, flat REE patterns, Zr/Nb= 6–17, chondritic Th/Ta and only moderately depletedisotopic signatures [END (1.95 Ga)+1.9]. Most ‘main suite’samples cannot be related solely by fractional crystallizationto a common parental magma. Rather, they represent distinctmelt fractions that underwent variable amounts of chromite +olivine plagioclase fractionation during ascent. A significantpart of the compositional diversity of the ‘main basaltsuite’ can be explained by mixing a depleted source witha relatively uniform proportion of an enriched component similarto that represented by the OIB-like ‘early dykes’.It is probable that during the latest stages of continentalrifting the OIB-type melts metasomatized the upper part of thedepleted asthenospheric mantle, which became the source of the‘main basalt suite’ soon after the old continentallithosphere was ruptured. The complete absence of any evidencefor a subduction-related component in the basalts implies thatJormua is not a back-are ophiolite.
*Fax: +358 0 462 205. e-mail: petri.peltonen{at}gsf.fi 相似文献
4.
Bands and pods of calc-silicate rock a few centimetres thickare widely distributed throughout the Late Precambrian Moiniansequence in N.W. Scotland. They probably originated as late-diageneticcalcareous concretions and were subsequently affected by greenschistto upper middle amphibolite facies (Barrovian) regional metamorphismduring the Caledonian (s.l.) orogeny. The calc-silicate rocks described here are from Inverness-shirein the Western Highlands of Scotland. Distinctive prograde mineralassemblages define four narrow zones which run broadly north-southand increase in grade eastwards. Plagioclase composition changesprogressively from albite to near anorthite with increasinggrade and, together with the presence or absence of zoisitebiotite, and hornblende, is the basis of the zonal divisions.Zoisite Ca2(Al0.96, Fe0.04)3Si3O12(OH) with biotite is commonin the lower zones and plagioclase ‘jumps’ in compositionfrom calcic andesine to bytownite with the exit of all, or mostof, the zoisite. Similarly biotite-bearing assemblages giveway to those containing ferro-horn-blende and/or pyroxene. Almandinegarnet with approximately 30–40 per cent grossular ispresent throughout and clinozoisite becomes more common in thehigher grade assemblages. Three main episodes of folding (F1–F3) are recognizedin the area, with the calc-silicate assemblages having developedduring the second deformation (MS2) and immediately followingit (MP2). The metamorphic zones (largely of MP2 age) are foldedby major third folds and there is evidence of widespread superimposed‘retrogression’ of probable MP3 age to the east. New analyses of 21 whole rocks by X.R.F., and of 20 mineralsby microprobe, are presented. AI2O3 content varies over a smallrange in the whole rock analyses and aluminium is used as astandard for comparing variations in the other elements. CaO/Al2O3ratios show little variation but a progressive decrease in Na2O/Al2O3and K2O/Al2O3 with increasingly calcic plagioclase composition(as assessed by measurements on separated fractions), and hence with metamorphic grade, isnoted. Coupled with the fact that the metamorphic zones cross-cutpreviously folded stratigraphic boundaries, this suggests thatboth Na2O and K2O have been in part lost from the higher gradecalc-silicate assemblages during progressive metamorphism. Reactions are proposed for the observed mineral changes, andit is concluded that these are most likely achieved by cationexchange through the medium of the pore fluid and result inpartial elimination from the local system of certain elements.No evidence is found that the reaction often quoted as thatresponsible for the exit of zoisite in semi-calcareous rocks,namely 4zo+qtz5an+gross+vap, has taken place. 相似文献
5.
Synmetamorphic High-Density Carbonic Fluids in the Lower Crust: Evidence from the Nilgiri Granulites, Southern India 总被引：4，自引：1，他引：3
High-density CO2 inclusions occur abundantly in granulite fadesrocks (age of metamorphism 2–5b.y.) of the Nilgiri massif,southern India. The chronology of carbonic inclusions in thewidespread enderbitic granulites studied in relation to thedevelopment of micro-textures and mineral assemblages indicatesthat randomly oriented, negative-crystal-shaped CO2 inclusions(4–20 µim) in garnet and quartz grains (qtz I) armouredby garnet entrap syn-peak-metamorphic pore fluids. The moreabundant trail-bound CO2 inclusions in the deformed, polygonized,and partially recrystallized matrix quartz grains (qtz II andIII) and plagioclase grains were formed in connection with astage of compressional deformation and subsequent annealingrelated to the development of the late-Proterozoic Bhavani shearzone. These inclusions resulted from local re-equilibrationof the former peak-granulitic carbonic inclusions and re-entrapmentof released fluids. The presence of pure CO2 in all the inclusionsis confirmed by microthermometric data and laser-excited Ramanmicrospectrome-try. Temperatures of homogenization (liquid phase)are in the range of 50 to +20C, and the corresponding CO2 densitiesare between 1.154 and 0–807 g/cm3. Mineralogical thermobarometry on the enderbitic granulites documentsa continuous gradient of near-peak metamorphic conditions from750C, 9–10 kb in the northern part to 73OC, 7 kb inthe southwestern part of the Nilgiri massif. Uniform P, Testimates(600–650 C, 6–7 kb) for late coronitic garnet +quartz assemblages in enderbites and metadolerites indicatethat differential uplift of the massif to mid-crustal levelswas accomplished before late compressional deformation. In conformity,carbonic inclusions in quartz II and III are characterized byuniformly high density (1.154–1.08 g/cm3). In contrast,early carbonic inclusions in garnet and quartz I preserve thedensity contrast reflecting the regional P, T gradient duringnear-peak metamorphic fluid entrapment. The fluid inclusionsys-tematics indicate ‘near-isochoric’ uplift ofthe northern high-P domain, but near-isobaric cooling of thesouthwestern low-P domain. The carbonic fluids are thought tohave been derived either from internal sources during dehydration-meltingprocesses or from freezing synmetamorphic intrusives into thelower crust. 相似文献
6.
This paper presents the first comprehensive major and traceelement data for 130 abyssal peridotite samples from the Pacificand Indian ocean ridge–transform systems. The data revealimportant features about the petrogenesis of these rocks, mantlemelting and melt extraction processes beneath ocean ridges,and elemental behaviours. Although abyssal peridotites are serpentinized,and have also experienced seafloor weathering, magmatic signaturesremain well preserved in the bulk-rock compositions. The betterinverse correlation of MgO with progressively heavier rare earthelements (REE) reflects varying amounts of melt depletion. Thismelt depletion may result from recent sub-ridge mantle melting,but could also be inherited from previous melt extraction eventsfrom the fertile mantle source. Light REE (LREE) in bulk-rocksamples are more enriched, not more depleted, than in the constituentclinopyroxenes (cpx) of the same sample suites. If the cpx LREErecord sub-ridge mantle melting processes, then the bulk-rockLREE must reflect post-melting refertilization. The significantcorrelations of LREE (e.g. La, Ce, Pr, Nd) with immobile highfield strength elements (HFSE, e.g. Nb and Zr) suggest thatenrichments of both LREE and HFSE resulted from a common magmaticprocess. The refertilization takes place in the ‘cold’thermal boundary layer (TBL) beneath ridges through which theascending melts migrate and interact with the advanced residues.The refertilization apparently did not affect the cpx relicsanalyzed for trace elements. This observation suggests grain-boundaryporous melt migration in the TBL. The ascending melts may notbe thermally ‘reactive’, and thus may have affectedonly cpx rims, which, together with precipitated olivine, entrappedmelt, and the rest of the rock, were subsequently serpentinized.Very large variations in bulk-rock Zr/Hf and Nb/Ta ratios areobserved, which are unexpected. The correlation between thetwo ratios is consistent with observations on basalts that DZr/DHf< 1 and DNb/DTa < 1. Given the identical charges (5+ forNb and Ta; 4+ for Zr and Hf) and essentially the same ionicradii (RNb/RTa = 1·000 and RZr/RHf = 1·006–1·026),yet a factor of 2 mass differences (MZr/MHf = 0·511 andMNb/MTa = 0·513), it is hypothesized that mass-dependentD values, or diffusion or mass-transfer rates may be importantin causing elemental fractionations during porous melt migrationin the TBL. It is also possible that some ‘exotic’phases with highly fractionated Zr/Hf and Nb/Ta ratios may existin these rocks, thus having ‘nugget’ effects onthe bulk-rock analyses. All these hypotheses need testing byconstraining the storage and distribution of all the incompatibletrace elements in mantle peridotite. As serpentine containsup to 13 wt % H2O, and is stable up to 7 GPa before it is transformedto dense hydrous magnesium silicate phases that are stable atpressures of 5–50 GPa, it is possible that the serpentinizedperidotites may survive, at least partly, subduction-zone dehydration,and transport large amounts of H2O (also Ba, Rb, Cs, K, U, Sr,Pb, etc. with elevated U/Pb ratios) into the deep mantle. Thelatter may contribute to the HIMU component in the source regionsof some oceanic basalts. KEY WORDS: abyssal peridotites; serpentinization; seafloor weathering; bulk-rock major and trace element compositions; mantle melting; melt extraction; melt–residue interaction; porous flows; Nb/Ta and Zr/Hf fractionations; HIMU mantle sources 相似文献
7.
FERRY JOHN M.; RUMBLE DOUGLAS III; WING BOSWELL A.; PENNISTON-DORLAND SARAH C. 《Journal of Petrology》2005,46(8):1725-1746
Progress () of the infiltration-driven reaction, 4olivine +5CO2 + H2O = talc + 5magnesite, that occurred during Barrovianregional metamorphism, varies at the cm-scale by a factor of3·5 within an 3 m3 volume of rock. Mineral and stableisotope compositions record that XCO2, 18Ofluid, and 13Cfluidwere uniform within error of measurement in the same rock volume.The conventional interpretation of small-scale variations in in terms of channelized fluid flow cannot explain the uniformityin fluid composition. Small-scale variations in resulted insteadbecause (a) reactant olivine was a solid solution, (b) initiallythere were small-scale variations in the amount and compositionof olivine, and (c) fluid composition was completely homogenizedover the same scale by diffusion–dispersion during infiltrationand subsequent reaction. Assuming isochemical reaction, spatialvariations in image variations in the (Mg + Fe)/Si of the parentrock rather than the geometry of metamorphic fluid flow. Ifinfiltration-driven reactions involve minerals fixed in composition,on the other hand, spatial variations in do directly imagefluid flow paths. The geometry of fluid flow can never be determinedfrom geochemical tracers over a distance smaller than the oneover which fluid composition is completely homogenized by diffusion–dispersion. KEY WORDS: Alpine Barrovian metamorphism; diffusion; metamorphic fluid composition; metamorphic fluid flow; reaction progress 相似文献
8.
High-pressure metamorphic rocks form a coastal belt, 175 kmby 35 km, in northeastern New Caledonia. Metamorphic grade rangesfrom lawsonite-albite schists through glaucophane-epidote schiststo omphacite-garnet-quartz gneisses. In the eclogitic terrane,metabasites, locally containing relict pillow structure andigneous textures, with well-preserved eclogitic mineral assemblages,are intercalated with metasedimentary gneisses containing albite-epidote-garnet? glaucophane and barroisite. Omphacite is partly retrogressedto albite and ferromagnesian minerals in almost every paragneiss.The paragneisses show strong evidence of penetrative foldingand microfracturing and were more permeable to metamorphic fluidsthan were the metabasites. The metabasites are inferred to havebeen relatively ‘dry’ and free of penetrative deformationduring the latter stages of metamorphism and thus were preservedmetastably during uplift, erosion, and cooling. Fe-Mg exchange thermometry between omphacite and garnet suggeststemperatures between 520 and 600 ?C. Omphacite + quartz (molper cent jadeite = 37–43) does not coexist stably withalbite suggesting minimum pressures near 12 kb at 550 ?C. Remnantsof more jadeite-rich pyroxenes in paragneisses (jd50–60)suggest even higher pressure. The stable coexistence of chloritoidalmandine-quartz in paragneisses suggests relatively H2O-rich fluids werein equilibrium with this assemblage. The widespread stable occurrenceof sphene suggests relatively low fco2 during metamorphism.Late stage healed fractures in quartz contain H2O-rich fluidinclusions with relatively low density isochores. Limited geochronologicdata combined with these petrologic data suggest a fairly rapidinitial rate of uplift followed by a much slower rate of uplift 相似文献
9.
The biotite isograd in pelitic schists of the Waterville Formationinvolved reaction of muscovite + ankerite + rutile + pyrite+graphite + siderite or calcite to form biotite + plagioclase+ ilmenite. There was no single reaction in all pelites; eachrock experienced a unique reaction depending on the mineralogyand proportions of minerals in the chlorite-zone equivalentfrom which it evolved. Quartz, chlorite, and pyrrhotite werereactants in some rocks and products in others. All inferredbiotite-forming reactions involved decarbonation and desulfidation;some were dehydration reactions and others were hydration reactions.P-T conditions at the biotite isograd were near 3500 bars and400 °C. C-O-H-S fluids in equilibrium with the pelitic rockswere close to binary CO2-H2O mixtures with XCO2 = 0.02–0.04.During the biotite-forming reaction, pelitic rocks (a) decreasedby 2–5 percent in volume, (b) performed – (4–11)kcal/liter P-V work on their surroundings, (c) absorbed 38–85kcal/liter heat from their surroundings, and (d) were infiltratedby at least 0.9–2.2 rock volumes H2O fluid. The biotite isograd sharply marks the limit of a decarbonationfront that passed through the terrane during regional metamorphism.Decarbonation converted meta-shales with 6–10 per centcarbonate to carbonate-free pelitic schists. One essential causeof the decarbonation event was pervasive infiltration of theterrane by at least 1–2 rock volumes H2O fluid early inthe metamorphic event under P-T conditions of the biotite isograd.Average shale contains 4–13 per cent siderite, ankerite,and/or calcite, but average pelitic schist is devoid of carbonateminerals. If the Waterville Formation serves as a general modelfor the metamorphism of pelitic rocks, it is likely that worldwidemany pelitic schists developed by decarbonation of shale caused,in part, by pervasive infiltration of metamorphic terranes byseveral rock volumes of aqueous fluid during an early stageof the metamorphic event. 相似文献
10.
Metamorphism in the Adirondacks: II. The Role of Fluids 总被引：6，自引：2，他引：4
VALLEY JOHN W.; BOHLEN STEVEN R.; ESSENE ERIC J.; LAMB WILL 《Journal of Petrology》1990,31(3):555-596
Quantitative estimates of metamorphic fluid speciation, stableisotopic analyses, and studies of fluid inclusions all documentthe local complexity of fluids in the deep crustal rocks exposedin the Adirondack Mountains, NY. Estimates of the activity ofH2O in the granulite facies are substantially lower than inthe amphibolite facies gneisses. The onset of low water activitiesin semi-pelitic gneisses generally correlates with migmatitictextures in the uppermost amphibolite facies, suggesting thatpartial melts absorbed H2O at the peak of metamorphism. In granulitefacies marbles and calc-silicates, conditions varied from extremelyundersaturated in H2O-CO2 fluid to fluid saturated, and H2Oand CO2 show sharp gradients within single outcrops. Low valuesof fO2 and fH2O, or of fCO2, and fH2O indicate fluid-absentconditions for some orthogneisses and marbles, which are inferredto have been ‘dry’ rocks before and during granulitefacies recrystallization. Wollastonite is preserved from earlycontact metamorphism and serves as an index mineral for fluid-absentconditions in granulites where H2O is low. Values offO2 rangefrom near the hematite + magnetite buffer in metamorphosed ironformation to substantially below the quartz + magnetite + fayalitebuffer in some orthogneisses. The anorthosite suite is moreoxidized than some associated granitic gneisses. Halogens (Fand Cl) substitute extensively for OH in micas and amphiboles,extending their stability, although F2, Cl2, HCl, and HF areminor components in any fluid. Oxybiotite-type exchanges involvingO for OH are also important, extending the stability of biotite.Stable isotopic ratios of O and C demonstrate that premetamorphicwhole-rock compositions are commonly preserved whereas mineralcompositions generally reflect equilibration at the peak ofmetamorphism. The Marcy Anorthosite Massif was intruded as ahigh 18O magma. The combination of mineral equilibria, stable isotope data,and fluid inclusions is used to identify and to distinguishamong pre-orogenic contact metamorphic/hydrothermal events,peak metamorphic events, and retrograde/postmetamorphic events.Polymetamorphism is documented at skarn zones adjacent to anorthosite,where large volumes of hydrothermal fluid were channeled duringearly, shallow contact metamorphism and where conditions werefluid poor during subsequent regional metamorphism. Peak metamorphicevents are inferred to have been caused primarily by magmaticprocesses of intrusion and anatexis. Partial melting has causedlow values of H2O in many rocks, but in other cases low valuesof H2O are recorded in orthogneisses derived from H2O-poor magmas.Isotopic studies show that maximum fluid/rock ratios were <0?land possibly 0?0 for infiltrating fluids at the peak of metamorphismin many localities. No evidence of pervasive, regional infiltrationby a fluid at the peak of metamorphism has been substantiatedin the Adirondacks. Fluid inclusions containing high-densityCO2 or CO2 + H2O represent conditions from after the peak ofmetamorphism and document isobaric cooling, in agreement withestimates from garnet zoning. Fine-scale retrograde veins arecommon and are associated with high-density CO2-rich fluid inclusions. 相似文献
11.
Geochemical and Isotopic (O, Nd, Pb and Sr) Constraints on A-type Granite Petrogenesis Based on the Topsails Igneous Suite, Newfoundland Appalachians 总被引：24，自引：2，他引：22
WHALEN JOSEPH. B.; JENNER GEORGE A.; LONGSTAFFE FREDERICK J.; ROBERT FRANCINE; GARIPY CLMENT 《Journal of Petrology》1996,37(6):1463-1489
The voluminous, bimodal, Silurian Topsails igneous suite consistsmainly of ‘A-type’ peralkaline to slightly peraluminous,hypersohnis to subsolvus granites with subordinate syenite,onzonite and diabase, plus consanguineous basalts and highsilicarhyolites. Nd(T) values from the suite range from –1.5to +5.4; most granitoid components exhibit positive Nd(T) values(+1.1 to +3.9). Granitoid initial 87Sr/86Sr and most 18 O valuesare in the range expected for rocks derived from mantle-likeprotoliths (0.701–0.706 and +6 to +80/). Restricted 207Pb/204Pbvariation is accompanied by significant dispersion of 206Pb/204Pband 208Pb/204Pb. Superficially, petrogenesis by either direct(via fractionation from basalt) or indirect (via melting ofjuvenile crust) derivation from mantle sources appears plausible.Remelting of the granulitic protolith of Ordovician are-typegranitoids can be ruled out, because these rocks exhibit negativeNd(T) and a large range in 207Pb/204Pb. Geochemical and isotopicrelationships are most compatible with remelting of hybridizedlithospheric mantle generated during arc-continent collision.A genetic link is suggested among collision-related delaminationor slab break-off events and emplacement of ‘post-erogenic’granite suites. A-type granites may recycle previously subductedcontinental material, and help explain the mass balance notedfor modern arcs. However, they need not represent net, new,crustal growth. KEY WORDS: A-type granites; juvenile crust; isotopes; Newfoundland
*Telephone: (613) 995-4972. Fax: (613) 995-7997. e-mail: jwhalen{at}gsc.emr.ca 相似文献
12.
The terrane in the Panamint Mountains, California, was regionallymetamorphosed under low-pressure conditions and subsequentlyunderwent retrograde metamorphism. Prograde metamorphic isogradsthat mark the stability of tremolite + calcite, diopside, andsillimanite indicate a westward increase in grade. The studywas undertaken to determine the effects of the addition of Caon the types of assemblages that may occur in pelitic schists,to contribute to the understanding of the stability limits inP – T – aH2O – XFe of the pelitic assemblagechlorite + muscovite + quartz, and to estimate the change inenvironment from prograde to retrograde metamorphism. Peliticassemblages are characterized by andalusite + biotite + stauroliteand andalusite + biotite + cordierite. Within a small changein grade, chlorite breaks down over nearly the entire rangein Mg/(Mg + Fe) to biotite + aluminous mineral. Chlorite withMg/(Mg + Fe) = 0.55 is stable to the highest grade, and thegeneralized terminal reaction is chlorite + muscovite + quartz= andalusite + biotite + cordierite + H2O. Calcic schists arecharacterized by the assemblage epidote + muscovite + quartz+ chlorite + actinolite + biotite + calcite + plagioclase atlow grades and by epidote + muscovite + quartz + garnet + hornblende+ biotite + calcite + plagioclase at high grades. Epidote doesnot coexist with any AFM phase that is more aluminous than garnetor chlorite. Lithostatic pressure ranged from 2.3 kb to 3.0kb. During prograde-metamorphism temperatures ranged from lessthan 400° to nearly 700°C, and XH2O (assuming PH2O +PCO3 = Ptotal) is estimated to be 0.25 in siliceous dolomite,0.8 in pelitic schist, and 1.0 in calcic schist. Temperatureduring retrograde metamorphism was 450° ± 50°C,and all fluid were H2O-rich. A flux of H2O-rich fluid duringfolding is believed to have caused retrograde metamorphism.The petrogenetic grid of Albee (1965b) is modified to positionthe (A, Cd) invariant point relative to the aluminosilicatetriple point, which allows the comparison of facies series thatinvolve different chloritoid-reactions. 相似文献
13.
The mutual solubility in the system corundum–hematite[-(Al, Fe3+)2O3] was investigated experimentally using bothsynthetic and natural materials. Mixtures of -Al2O3 and -Fe2O3(weight ratios of 8:2 and 10:1) were used as starting materialsfor synthesis experiments in air at 800–1300°C withrun times of 7–34 days. Experiments at 8–40 kbarand 490–1100°C were performed in a piston-cylinderapparatus (run times of 0·8–7·4 days) usinga natural diasporite consisting of 60–70 vol. % diasporeand 20–30 vol. % Ti-hematite. During the diasporite–corunditetransformation, the FeTiO3 component (12–18 mol %) ofTi-hematite only slightly increased, implying that oxygen fugacitywas maintained at high values. Run products were studied byelectron microprobe and X-ray diffraction (Rietveld) techniques.An essentially linear volume of mixing exists in the solid solutionwith a slight positive deviation at the hematite side. Up to1000°C, corundum contains <4 mol % Fe2O3 and hematite<10 mol % Al2O3; at 1200°C these amounts increase to9·3 and 17·0 mol %, respectively. At 1300°Chematite was no longer stable and coexists with the orthorhombic phase . The present results agree with corundum (solvus) compositions obtained inprevious studies but indicate a larger solubility of Al in hematite.The miscibility gap in the solution can be modelled with anasymmetric Margules equation with interaction parameters (2uncertainties): ; ; ; . Application of the corundum–hematite solution as a solvus geothermometer is limited because of thescarcity of suitable rock compositions. KEY WORDS: corundum; hematite; corundum–hematite miscibility gap; experimental study; Margules model; metabauxite 相似文献
14.
VINCENZO GIANFRANCO DI; ANDRIESSEN PAUL A. M.; GHEZZO CLAUDIO 《Journal of Petrology》1996,37(5):1175-1206
Detailed petrographic and geochemical data and Sr and Nd isotopecompositions of enclaves and host-granite are reported for oneof the largest strongly peraluminous cordierite-bearing intrusionsof the Hercynian Sardinia-Corsica Batholith: the San BasilioGranite. Compared with other peraluminous series, the San BasilioGranite has a ‘non-minimum melt’ composition andshows variations primarily owing to fractionation of early-crystallizedplagioclase, quartz and biotite. Crystallization age is constrainedat 305 Ma, by Rb-Sr whole-rock age [30523 Ma with (87Sr/86Sr)i= 0.711050.00041], and occurred during late Hercynian tectonicevents. Nd(305Ma) values range from –7.8 to –7.5.The San Basilio Granite contains both magmatic and metamorphicenclaves. Magmatic enclaves, similar to mafic microgranularenclaves common in calc-alkaline granitoids, are tonalitic incomposition and show a variation in silica content from 60.3to 67.7 wt % correlating with a variation in (87Sr/86 Sr) (305Ma)and Nd (305 Ma) from 0.7092 to 0.7109 and from –6.6 to–7.4, respectively. Together with petrographic and othergeochemical data, the Sr and Nd isotopic data record differentstages in a complex homogenization process of an unrelated maficmagma with a crustal melt. A process of simple mixing may accountfor the variations of nonalkali elements and, to some extent,of Sr and Nd isotopes, whereas the distribution of alkali elementsrequires diffusioncontrolled mass transfer. Petrographic andmineralogical data on metamorphic enclaves and geochemical modellingfor trace elements in granite indicate melt generation by high-degreepartial melting involving biotite breakdown of a dominantlyquartzo-feldspathic protolith at about T>750–800Cand P>6 kbar leaving a granulite facies garnet-bearing residue,followed by emplacement at 3 kbar. Nd(305Ma) values of thegranite fall within the range defined by the pre-existing metamorphicrocks but (87Sr/86Sr) (305Ma) ratios are lower, indicating involvementof at least two distinct components: a dominant crustal componentand a minor well-mixed mafic end-member. These data point toa decoupling between the Sr-Nd isotope systematics and majorand trace element compositions, suggesting that the effect ofthe mafic component was minor on granite major and trace elementconcentrations, but significant on Sr and Nd isotopes. The studyof the magmatic enclaves and the isotopic evidence demonstratethat unrelated mafic magmas, probably derived from the mantle,had a close spatial and temporal association with the productionof ‘on-minimum melt’ strongly peraluminous granites,and support the proposal that heat from the mafic magma contributedto crustal melting. KEY WORDS: cordierite-bearing granite; enclaves; felsic-mafic interaction; Sardinia-Corsica Batholith; Sr and Nd isotopes
*Corresponding author. 相似文献
15.
CLARKE D. BARRIE; MACDONALD MICHAEL A.; REYNOLDS PETER H.; LONGSTAFFE FRED J. 《Journal of Petrology》1993,34(4):653-679
The South Mountain Batholith is a peraluminous granitic complexranging in composition from biotite granodiorite to muscovite-topaz‘leucogranite’. Leucogranitic rocks (with generally<2% biotite) form a minor part ({small tilde}1•5%) ofthe batholith, and are of two types: (1) ‘associated leucogranites’occurring as relatively small zones in fine-grained leucomonzogranites;and (2) ‘independent leucogranites’ forming generallylarger bodies having no particular spatial association withother rock types. Mean chemical compositions of these two typesof leucogranite are as follows (associated, independent): Na2O(3•46,3•83),K2O(4•40,4•09),andP2O5 (0•26, 0•45)in wt.%;Li(149, 281), F(1199, 2712),Rb (393, 725), U (7•4, 4•4), Nb (12•8, 23•4),Ta (2•9, 7•1), and Zr (52, 31) in ppm. Rare earthelements also differ between the two types (associated, independent):REE (34•1 ppm, 19•9 ppm); and in the degree and variabilityof heavy REE fractionation (GdN/YbN=4•62•2, 2•00•7).In addition, associated leucogranite has REE compositions similarto those of its host rocks. Mean 18O values (associated +ll•21•2,independent +ll•40•5; relative to SMOW) are comparablewith the mean for the entire South Mountain Batholith (+l0•80•7).Radiometric dating (40Ar/39Ar on muscovite) shows that bothtypes of leucogranite have identical ages of 3723 Ma, equivalentto ages determined by other techniques for granodiorite andmonzogranite samples elsewhere in the batholith. Field relationsand geochemistry suggest that the associated leucogranite resultsfrom an open-system interaction between a fluid and its hostleucomonzogranite, whereas the independent leucogranite bodiesare discrete intrusions of highly fractionated melts that underwentclosed-system, late-magmatic to post-magmatic fluid alteration.Where mineralized, the associated leucogranite characteristicallyhosts greisen-type or disseminated polymetallic mineralization,whereas the independent leucogranite hosts pegmatitic or disseminatedpolymetallic mineralization. 相似文献
16.
Phase Equilibria of Amphibolites from the Post Pond Volcanics, Mt. Cube Quadrangle, Vermont 总被引：1，自引：0，他引：1
Amphibolites of the Post Pond Volcanics, south-west corner ofthe Mt. Cube Quadrangle, Vermont, are characterized by a greatdiversity of bulk rock types that give rise to a wide varietyof low-variance mineral assemblges. Original rock types arebelieved to have been intrusive and extrusive volcanics, hydrothermallyaltered volcanics and volcanogenic sediments with or withoutadmixtures of sedimentary detritus. Metamorphism was of staurolite-kyanitegrade. Geothermometry yields a temperature of 535 ± 20°C at pressures of 5–6 kb. Partitioning of Fe and Mg between coexisting phases is systematic,indicating a close approach to chemical equilibrium was attained.Relative enrichment of Fe/Mg is garnet > staurolite >gedrite > anthophyllite cummingtonite hornblende > biotite> chlorite > wonesite > cordierite dolomite > talc;relative enrichment in Mn/Mg is garnet > dolomite > gedrite> staurolite cummingtonite > hornblende > anthophyllite> cordierite > biotite > wonesite > chlorite >talc. between coexisting amphiboles varies as a function ofbulk Fe/Mg, which is inconsistent with an ideal molecular solutionmodel for amphiboles. Mineral assemblages are conveniently divided into carbonate+ hornblende-bearing, hornblende-bearing (carbonate-absent)and hornblende-absent. The carbonate-bearing assemblages allcontain hornblende + dolomite+ calcite + plagioclase (andesineand/or anorthite) + quartz with the additional phases garnetand epidote (in Fe-rich rocks) and chlorite ± cummingtonite(in magnesian rocks). Carbonate-bearing assemblages are restrictedto the most calcic bulk compositions. Hornblende-bearing (carbonate absent) assemblages occur in rocksof lower CaO content than the carbonate-bearing assemblages.All of these assemblages contain hornblende + andesine ±quartz + Fe-Ti oxide (rutile in magnesian rocks and ilmenitein Fe-rich rocks). In rocks of low Al content, cummingtoniteand two orthoamphiboles (gedrite and anthophyllite) are common.In addition, garnet is found in Fe-rich rocks and chlorite isfound in Mg-rich rocks. Several samples were found that containhornblende + cummingtonite + gedrite + anthophyllite ±garnet +chlorite + andesine + quartz + Fe-Ti oxide ±biotite. Aluminous assemblages contain hornblende + staurolite+ garnet ± anorthite/bytownite (coexisting with andesine)± gedrite ± biotite ± chlorite ±andesine ± quartz ± ilmenite. Hornblende-absentassemblages are restricted to Mg-rich, Ca-poor bulk compositions.These rocks contain chlorite ± cordierite ± staurolite± talc ± gedrite ± anthophyllite ±cummingtonite ± garnet ± biotite ± rutile± quartz ± andesine. The actual assemblage observeddepends strongly on Fe/Mg, Ca/Na and Al/Al + Fe + Mg. The chemistry of these rocks can be represented, to a firstapproximation, by the model system SiO2–Al2O3–MgO–FeO–CaO–Na2O–H2O–CO2;graphical representation is thus achieved by projection fromquartz, andesine, H2O and CO2 into the tetrahedron Fe–Ca–Mg–Al.The volumes defined by compositions of coexisting phases filla large portion of this tetrahedron. In general, the distributionof these phase volumes is quite regular, although in detailthere are a large number of phase volumes that overlap otherphase volumes, especially with respect to Fe/Mg ratios. Algebraicand graphical analysis of numerous different assemblages indicatethat every one of the phase volumes should shift to more magnesiancompositions with decreasing µH2O. It is therefore suggestedthat the overlapping phase volumes are the result of differentassemblages having crystallized in equilibrium with differentvalues of µH2O or µCO2 and that the different valuesmay have been inherited from the original H2O and CO2 contentof the volcanic prototype. If true, this implies that eithera fluid phase was not present during metamorphism, or that fluidflow between rocks was very restricted. 相似文献
17.
The metabasites within the Tokoro belt of eastern Hokkaido,Japan, suffered pervasive high–P/ Tetamorphism. Mineralassemblages and compositions of more than 400 metabasites fromthe Saroma–Tokoro district were investigated. The metabasites are divided into six metamorphic zones basedon mineral assemblages. The laumontite (Lm) zone is definedby the presence of laumontite. The prehnite–pumpellyite(Pr–Pp) zone is characterized by the association of prehnite+ pumpellyite. The lawsonite–sodic. pyroxene (Lw–Napx)zone is defined by the assemblage lawsonite + pumpellyite +sodic pyroxene + chlorite. The epidote–sodic pyroxene(Ep–Napx)(1) and (2) zones are charecterized by the assemblage epidote+ pumpellyite + sodic pyroxene + chlorite. The former is characterizedby the absence of aragonite, sodic amphibole, and winchite,as well as the presence of jadeite–poor sodic pyroxene(maxJd mol% = 13), whereas these minerals occur in the Ep–Napx(2)zone, together with jadeite–rich sodic pyroxene (max.Jd mol % = 34). In the epidote–actinolite (Ep–Act)zone, the most common assemblages contain epidote+ actionolite+ pumpellyite + chlorite. The Lm zone corresponds to the zeolite facies (150–200?Cand 1–2 kb) and the Pr–Pp zone is equivalent tothe prehnite–pumpellyite facies (200–250?C and 2–2–5kb). The Ep–Napx(I) zone appears to be stable at 200–250?C and 2? 5?3?5 kb. The pressure conditions in the Lw–Napx,Ep-Napx(2), and Ep–Act zones appear to range from 5 to6 kb, and the temperatures are estimated to be 200–230,230–270, and 270–300? C, respectively. The sequenceof the metamorphic zones is charaterized by the curved P–Tpath. The stability field of pumpellyite+ sodic+ pyroxene+ chloritein Fe3+ bearing metabasites is located in the lower–temperatureand higher–pressure part of the pumpellyite–actionolitefacies. On the basis of Schreinmaker's method, the stabilityfield of the assemblage is bounded by a high–pressurereaction Pp+ Napx+ Chl+ Ab+ Qz+ H2O= Lw+ Gl, and by a high-temperaturereaction Pp Napx+ Chl+ Ab+ Qz = Ep + Gl + H2O. 相似文献
18.
Wollastonite--Scapolite Assemblages as Indicators of Granulite Pressure-Temperature-Fluid Histories: The Rauer Group, East Antarctica 总被引：4，自引：0，他引：4
Mid-Proterozoic ( 1000 Ma) granulite facies calc-silicates fromthe Rauer Group, East Antarctica, contain grossular-wollastonite-scapolite-dinopyroxene( + quartz or calcite) assemblages which preserve symplectiteand corona textures typically involving the growth of secondarywollastonite. The textures include (1) wollastonite rims betweenquartz and calcite; (2) wollastonite-plagioclase rims and intergrowthsbetween quartz and scapolite; (3) wollastonite-scapolite-clinopyroxeneinter-growths replacing grossular; and (4) wollastonite-plagioclasesymplectites replacing grossular or earlier symplectites (3). Reactions between grossular, scapolite, wollastonite, calcite,quartz, anorthite, and vapour, have been modelled in the CaO-Al2O3SiO2-H2O-CO2and more complex systems using the internally consistent data-setof Holland & Powell (1990). Reactions producing scapoliteand wollastonite consume vapour as temperature increases (i.e., carbonation), in agreement with the results of Moecher &Essene (1990). These calc-silicates can therefore behave asfluid sinks under high-grade conditions. Conversely, they maybe important fluid sources on cooling and contribute to theformation of post-metamorphic CO2rich fluid inclusions in isobaricallycooled granulites. P-T-CO2 diagrams calculated for typical phase compositions (e.g., garnet, scapolite) demonstrate that the observed texturesare a record of near-isothermal decompression at 800–850 C, consistent with P—rpath determinations based on otherrock types from the Rauer Group. For example, texture (2) resultsfrom crossing the reaction Scapolite + Quartz = Wollastonite + Plagioclase + V on decompression, at 6. 5–7 kb, 820 C, and aCO2 of0–4–0–5. Furthermore, correlations betweenmodes of product phases (e. g., wollastonitexlinopyroxene) andreactant garnet composition preclude open-system behaviour inthe formation of these textures, consistent with post-peak vapour-absentreactions such as Grossular + Calcite + Quartz = Wollastonite + Scapolite occurring on decomposition at high temperatures (>800C). Reaction textures developed in calc-silicates from other granuliteterranes often involve the formation of grossular ( + quartz calcite) as rims on wollastonite-scapolite, or replacementof wollastonite by calcite-quartz. These textures have developedprincipally in response to cooling below 780–810 C andmay be signatures of near-isobaric cooling. Infiltration ofhydrous fluid is not a necessary condition for the productionof garnet coronas in wollastonite-scapolite granulites. *Present address: Department of Earth Sciences, University ofMelbourne, Parkville, Victoria 3052, Australia 相似文献
19.
Frezzotti Maria Luce; Ferrando Simona; Dallai Luigi; Compagnoni Roberto 《Journal of Petrology》2007,48(6):1219-1241
Minerals, fluid inclusions and stable isotopes have been studiedin ultrahigh-pressure (UHP) OH-rich topaz–kyanite quartzitesfrom Hushan (west of Dongai), in southern Sulu (China). Thequartzites underwent a metamorphic evolution characterized bya peak stage (3·5 GPa and 730–820°C) with theanhydrous assemblage coesite + kyanite I, followed by an earlynear-isothermal decompression stage (2·9 GPa and 705–780°C)with growth of kyanite II, muscovite, and OH-rich topaz, andby decompression-cooling stages, represented by paragonite (1·9GPa and 700–780°C) and pyrophyllite (0·3 GPaand 400°C) on kyanite (I and II) and OH-rich topaz, respectively.These rocks may exhibit unusually low 18O and D values acquiredbefore undergoing UHP metamorphism. Five distinct fluid generationsare recognized. Type I: concentrated peak solutions rich inSi, Al, and alkalis, present within multiphase inclusions inkyanite I. Type II: CaCl2-rich brines present during the growthof early retrograde OH-rich topaz. Type III, IV, and V: lateaqueous fluids of variable salinity, and rare CO2 present duringamphibolite- and late greenschist-facies conditions. A numberof conclusions may be drawn from these relationships that havean effect on fluid evolution in deeply subducted continentalrocks. (1) At a pressure of about 3·5 GPa alkali–alumino-silicateaqueous solutions, with compositions intermediate between H2Ofluid and melt (H2O > 25 and 50 wt %) evolved from quartzites,probably generated by dehydration reactions. (2) During earlydecompression stages, at the transition from UHP to high-pressure(2·9 GPa) conditions, brines of external origin withhigher water contents (82 wt % H2O) initiated the growth ofOH-rich topaz and muscovite. (3) The subsequent decompression,at P <2 GPa, was defined by a limited circulation of NaClaqueous fluids, and CO2 infiltration. Overall, fluid inclusionsand stable isotopes highlight a metamorphic fluid–rockinteraction characterized by internally derived intermediateaqueous solutions at UHP, followed by infiltration of Cl-richbrines with higher water activities. KEY WORDS: ultrahigh-pressure metamorphism; OH-rich topaz; fluid inclusions; stable isotopes; supercritical liquids 相似文献
20.
Compositional Layering and Syn-eruptive Mixing of a Periodically Refilled Shallow Magma Chamber: the AD 79 Plinian Eruption of Vesuvius 总被引：4，自引：1，他引：3
CIONI RAFFAELLO; CIVETTA LUCIA; MARIANELLI PAOLA; METRICH NICOLE; SANTACROCE ROBERTO; SBRANA ALESSANDRO 《Journal of Petrology》1995,36(3):739-776
A detailed study of the pyroclastic deposits of the AD 79 ‘Pompei’Plinian eruption of Vesuvius has allowed: (1) reconstructionof the thermal, compositional and isotopic (87Sr/86Sr) pre-eruptivelayering of the shallow magma chamber; (2) quantitative definitionof the syn-eruptive mixing between the different magmas occupyingthe chamber, and its relationships with eruption dynamics; (3)recognition of the variability of mafic magma batches supplyingthe chamber. During the different phases of the eruption 25–30%of the magma was ejected as white K-phonolitic pumice, and 70–75%as grey K-tephri-phonolitic pumice. The white pumice resultsfrom the tapping of progressively deeper magma from a body (T= 850–900%C) consisting of two distinct layers mainlyformed by crystal fractionation. The grey pumice results fromsyn-eruptive mixing involving three main end-members: the phonolitic‘white’ magmas (salic end-member, SEM), mafic cumulates(cumulate end-member, CEM) and a crystal-poor ‘grey’phono-tephritic magma (mafic end-member, MEM), which was nevererupted without first being mixed with ‘white’ magma.Evidence is provided that mixing occurred within the chamberand was characterized by a transition with time from physicalmixing at a microscopic scale to chemical hybridization. TheMEM magma had a homogeneous composition and constant 87Sr86Srisotopic ratio, possibly as a result of sustained convection.No unambiguous liquidus phases were found, suggesting that theMEM magma was superheated (T = 1000–1100C); its verylow viscosity was a main cause in the establishment of a physicaldiscontinuity separating the white and the grey magmas. Thewhite-grey boundary layer possibly consisted of a multiply diffusiveinterface, periodically broken and recreated, supplying thephonolitic body through mixing of moderate amounts of fractionatedgrey melts with the overlying white magma. The presence of alarge overheated mass indicates the young, growing stage ofthe AD 79 chamber, whose main engine was the periodic arrivalof hot mafic magma batches. These were characterized by K-tephriticto K-basanitic compositions, high temperatures (>1150C),high volatile contents (20–25% H2O +Cl+F+S), low viscosities[(1+2 102 poises)] and relatively low densities (2500–2600kg/m3). The birth of the Pompei chamber followed the repeatedarrival of these batches (on average characterized by 87Sr/86Sr070729)into a reservoir containing a tephriticphonolitic, crystal-enriched,magma, a residue from the preceding ‘Avellino’ Plinianeruption (3400 BP).In fact, about half of magma ejected duringthe AD 79 eruption could have been inherited from pre-Avellinotimes. KEY WORDS: Vesuvius; magma chamber; magma mixing; compositional layering phonolites; magma supply; potassic magmas
*Correponding author 相似文献