共查询到20条相似文献，搜索用时 147 毫秒
1.
研究了碘化钾-甲基异丁基甲酮（KI—MIBK）萃取-火焰原子吸收分光光度法连续测定地球化学样品中痕量银、镉和铊的主要条件。通过对火焰原子吸收分光光度计气路控制系统及雾化器的改进，较大地改善了萃取-火焰原子吸收分光光度法测定银、镉和铊的稳定性和灵敏度。选择萃取酸度为1．2mol／L HCl、水相和有机相体积配比为3：1～4：1，方法精密度（RSD，n=12）为Ag4．5％～9．6％、Cd1．5％～7．9％、T14．5％～5．4％，检出限（3s）为Ag0．004μg/g、Cd0．007μg／g、T10．011μg/g，符合多目标地球化学调查样品测试及质量监控要求。用国家一级标准物质和密码组合标准物质进行验证，测试结果令人满意。 相似文献
2.
发展了一种可在野外快速测定０．０１０—５０μｇ／ｇ银量的新方法。此法由两个各自独立而又配套的部分组成。一是直接测定０．２５—５０μｇ／ｇ银量的Ａｇ－ＴＭＫ－ＳＤＳ三元络合物光导比色测定法；二是测定０．０１０—０．２５μｇ／ｇ银量的巯基棉分离富集微珠析出比色法。可在同一份试液中依次完成。前者检出限为０．００６μｇ／ｍｌ（Ｋ＝３）；测定铜、铅和锌矿石标样ＧＳＯ－Ｃｕ－１（含银３．８７μｇ／ｇ）、ＧＳＯ－Ｐｈ－１（含银１４．７μｇ／ｇ）和ＧＳＯ－Ｚｎ－１（含银１３．５μｇ／ｇ）中的银，ＲＤＳ（ｎ＝１１）分别为１．６％、３．７％和３．４％；后法可检出５ｎｇ／ｇ银；测定地球化学标样ＧＳＤ－３（含银０．５９μｇ／ｇ）中的银，ＲＳＤ（ｎ＝１１）为６．ｔ％。方法较为简便、快速、准确和灵敏。用光导比色计测定，结果准确度、精度均有较大改善，且与室内原子吸收法相当。故所定方法具有广阔的应用前景。 相似文献
3.
原子荧光光谱法直接测定铜矿中的硒 总被引：6，自引：5，他引：6
采用硫脲抑制铜的干扰，不经分离富集原子荧光光谱法直接测定铜矿中的Se。方法的检出限为0．02μg/g。Se浓度在0～80μg／L与荧光强度呈线性关系。用铜矿石国家一级标准物质GBW 07233(ωSe为5．1μg／g)和GBW 07234(ωSe为0.89μg／g)进行精密度试验，RSD(n=12)为3.44％、8.06％。加标准回收试验结果，Se的回收率为93．2％～104、6％。经铜矿石国家标准物质验证，测定结果与标准值相符，方法适用于铜矿中0～8．0μg／g Se的测定。 相似文献
4.
发射光谱法测定勘查地球化学样品中银硼锡钼铅 总被引：21，自引：13，他引：21
以K2S2O7、NaF、Al2O3和炭粉为缓冲剂，Ge为内标，电弧发射光谱法测定勘查地球化学样品中Ag、B、Sn、Mo、Pb。方法检出限为Ag0．013μg／g、B0．83μg/g、Sn0．23μg／g、Mo0．073μg/g、Pb0．37μg／g。方法精密度（RSD，n=12）为Ag4．2％～11．3％、B3．2％～6．5％、Sn2．6％～7．1％、Mo2．9％～6．3％、Pb1．57％～5．18％。测定了国家一级地球化学标准物质，结果与标准值相符。 相似文献
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本文采用水作载流，盐酸为介质，硼氢化钠3．5%(m／v)，氩气流量0．8L／min，分析试样体积400μl，进样与试剂采用同步注入．样品定容体积50ml，0．5μg砷呈线性关系．本法检出限0．6ng／ml,精密度2．9%．经用国家一级标样测试．RE%≤士10%,准确度符合质量要求. 相似文献
8.
流动注射在线离子交换分离富集原子吸收测定地质物料中痕量银 总被引：10，自引：0，他引：10
采用注动注射在线离子交换分离富集技术使通过装填有４１０哌啶树脂的微型柱而被吸附，随后用硫脲梯度洗脱，再用原子吸收法进行测定。每次消耗样品溶液６．６ｍｌ，进样频率为２８次／ｈ时浓集倍率２２。方法检出限０．３μｇ／Ｌ对于含Ａｇ３０μｇ／Ｌ试样进行１２次测定，其平均值为２９．０μｇ／ｌ０，精度为２．９％，方法经地质标样分析验证可靠。 相似文献
9.
La-Ce法岩石标准物质和Ce同位素标准溶液研制 总被引：3，自引：0，他引：3
报道了La-Ce法岩石标准物质的研制结果。标准物质选自峨眉山玄武岩中的新鲜微晶玄武岩（编号EQB）,具有间隐结构,矿物组成相对均一。岩石经粉碎和均一化加工,成为粉末后分装成1000小瓶。经均匀性和稳定性检验合格后,对该岩石标准物质的Ce同位素比值和La、Ce元素含量进行了测定和定值统计,其结果分别表示为：138Ce／142Ce=0．0225755±0．0000003,Ce=（117．4±1．3）μg／g,La=（55．8±0．9）μg／g。对二氧化铈化学试剂进行了溶液制备,以用于Ce同位素分析仪器标准物质。标准溶液编号为CBRICeO2,其138Ce／142Ce比值的测定统计值为0．0225748±0．0000006。为检验所制标准物质分析数据的准确度,对国际标样进行了比对测量,其中JMC304标准溶液的138Ce／142Ce比值测定结果为0．0225762±0．0000015,USGS玄武岩标样BCR-2的La和Ce元素含量测定结果分别为（25．2±0．6）μg／g（2σ）和（54．2±0．8）μg／g（2σ）,所获数值与文献报道值或证书值在误差范围内相符。 相似文献
10.
报道了以NH4H2PO4为基体改进剂，采用悬浮体制样石墨炉原子吸收光谱法直接测定琥珀中微量铅的方法。试验了影响测定的主要因素。在优化实验条件下。方法的检出限为0．038μg／g，Pb的质量浓度为0～80μg／L时，工作曲线线性关系良好。对于ω(Pb)=5．71μg／g样品的测定，相对标准偏差(RSD，n=5)为6．83％。 相似文献
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以29口钻孔的重矿物百分含量数据来分析样本,通过Q型聚类分析、因子分析方法恢复不同物源体系的发育范围及其母岩类型,并以不同物源体系的边界范围为限定条件,结合ZTR指数及其等值线图,对珠江口盆地惠州凹陷M层物源特征进行了系统的研究。研究结果表明：研究区发育3大物源沉积区,分别为东北-北部物源沉积区、西北物源沉积区和东南物源沉积区,且各区重矿物组合特征明显,主次物源分明,整体表现为母岩类型复杂的特征。东北-北部沉积物主要母岩为酸性岩浆岩,次要母岩为变质岩和沉积岩,西北沉积物主要母岩为中性及基性岩浆岩,次要母岩为酸性岩浆岩和变质岩,东南沉积物主要母岩为中性及基性岩浆岩,次要母岩为变质岩。东北-北部物源区和西北物源区为远源沉积的产物,而东南物源区为近源沉积的产物。东北-北部物源区沉积物来自北方和东北方向,而西北物源区和东南物源区沉积物分别来自西北方向和东南方向。 相似文献
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两种煤质分析指标的关联方程组研究 总被引：5，自引：0，他引：5
在综合分析大量文献资料的基础上，采用多元线性回归方法，利用MATLAB对大量煤质分析结果进行了回归分析，推导出了煤质元素分析与工业分析的关联方程组。新方法实现了由工业分析结果求元素分析成分的目的，具有重大的实用意义。 相似文献
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An algorithm andFortran-iv computer program,cabfac, forQ-mode factor analysis is described. The program will accept up to 1500 items and 50 variables on a moderate-size computer. 相似文献
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A piston core from the southern Blake Basin penetrated nine distinct bioclastic carbonate turbidites separated by pelagic terrigenous clay units. X-ray diffraction analysis of the carbonate mineralogy of the graded, laminated, and homogenous units of the individual turbidite units indicated a general loss of unstable carbonates in the homogenous unit beyond that contained in the lower two units. Univariate and multivariate statistical tests were employed to determine the significance of the changes and to determine if different units of a turbidite sequence could be consistently grouped by statistical methods. Principal components, discriminant function, and cluster analysis were used in the multivariate tests. The graded and laminated units were closely related in mineralogy with little significant differences. The mineralogy of the homogenous units was significantly different than that of the other two units except in one example. Cluster analysis generated five groupings of the samples with the end members consisting of graded and laminated units at one end and homogenous units at the other. 相似文献
15.
Ibsen Chivatá Cárdenas 《Georisk: Assessment and Management of Risk for Engineered Systems and Geohazards》2019,13(1):53-65
In this paper, we report on the use of Bayesian networks, BNs, learnt from data generated by physical and numerical models, to overcome to a certain degree a number of complications in traditional slope stability analyses that jointly consider the mechanical and hydraulic properties of soils. Discrete Bayesian networks resulted to be useful and efficient to acquire knowledge from simulated data and to identify significant factors by the combined use of backward inference and global sensitivity analysis. Further, BNs enable decision thresholds to be estimated quickly. Along with this, backward inference and global sensitivity analysis are performed in BNs at low computation costs. Moreover, under conditions in which knowledge is scarce, we show how a practitioner can be better informed using the proposed approach. All these previously under-reported modelling features in the specialised literature encourage the further application of the proposed approach to enhance slope stability analysis. 相似文献
16.
以有限元结构矩阵分析为理论基础，结合应力应变测试和现场实际使用情况，利用计算机结构分析程序，对ＺＴ－Ａ系列三个不同高度钻塔的天梁、塔腿和绷绳做了结构应力分析，弄清了Ａ形塔在承受垂直荷载、水平荷载以及偏载条件下，组成钻塔的各构件的荷载及应力分布；对钻塔设计提出了改进意见；并从整体角度分析了绷绳的作用；对在不同荷载条件下有无绷绳时钻塔的结构应力从量上做了对比；最后提出了应当如何布置提升系统才会使钻塔处 相似文献
17.
Paul F. Czeglédy 《Mathematical Geology》1972,4(4):291-305
On the basis of samples taken from a known topographic surface, the parameters of two types of linear models are estimated. The first category is defined by polynomials or trigonometric functions, whose parameters are simultaneously computed from available data. In the second category a set of local centers is defined, and in the neighborhood of each center a fixed-degree polynomial is developed. An approximative resemblance index is calculated, and contour maps corresponding to various models are compared with the topographic map. It is found that with an increasing number of grid points, maps of local polynomials are converging both in continuity and in resemblance. For a sufficient number of grid points, this resemblance is always higher than those produced by models of the first category. 相似文献
18.
Finite element limit analysis with plane strain condition is employed to determine the upper and lower bound solutions of the undrained limiting pressure behind soil gaps and the lateral force acting on a pile per unit length in a contiguous pile wall. Computed bound solutions confirm serious limitations of existing studies in predicting these two solutions. Predicted failure mechanisms and the arching effect behind soil gaps are discussed. A closed-form equation of the limiting pressure factor is proposed for a convenient and accurate prediction of the lateral force acting on a pile in contiguous pile walls in practice. 相似文献
19.
Ulf Grenander 《Mathematical Geology》1975,7(3):267-278
A deformation mechanism is described and analyzed. It is intended for height patterns exposed to erosion and tectonic activity.
A simulation experiment is carried out for this model. Closedform expressions are derived for the covariance field, the properties
of spectral estimates, and for the optimal retrospective reconstruction of earlier, unknown height patterns. For obvious reasons
the author is in no position to make claims about the verisimilitude of the model. It is offered as an example of a potential
application to geology of the theory of patterns developed by the author and his coworkers in recent years. It is hoped that
those more qualified than the author in the subject matter area can extend and modify the analysis to make it closer to geological
reality.
supported by NSF grant GJ-3100X. 相似文献