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1.
atu Tara is an active potassic volcano in the eastern Sunda arc. Its leucite-bearing rock suite can be subdivided into two groups, one less evolved with Th<20 ppm, the other more evolved with Th>20 ppm. 87Sr/86Sr, δ18O and trace-element systematics in the less evolved group suggests that existence of parental magmas with different mantle origins. The mantle below Batu Tara is most likely heterogeneous and several source components are involved in magma genesis. Trace element and isotopic compositions of Batu Tara and adjacent volcanoes are consistent with the involvement of a subducted sedimentary/crustal component as well as MORB and OIB mantle, the latter with geochemical characteristics comparable to the mantle underlying Muriah (Java). Melt extraction from this complex mixture is envisioned as a two-stage process: partial melts of the crust-contaminated MORB mantle mix in the mantle wedge with partial melts of OIB domains. Different mixtures of these two melts provide the parental magmas that enter the volcanic plumbing system, where crystallization, hybridization and refilling processes occur. The calcalkaline volcanoes in the arc segment show stronger signatures for a subducted crustal component than Batu Tara, which displays a greater influence from the OIB mantle source. The potassium enrichment can therefore be attributed to contributions both from the enriched mantle and from subducted crustal material. Mantle-type δ18O values of the Batu Tara magmas indicate that the mantle wedge below potassic orogenic volcanoes is not necessarily strongly enriched in 18O.  相似文献   

2.
The Denizli region of the Western Anatolia Extensional Province (WAEP) includes a typical example of intra-plate potassic magmatism. Lamproite-like K-rich to shoshonitic alkaline rocks erupted in the Upper Miocene-Pliocene in a tensional tectonic setting. The absence of Nb and Ta depletion, low Th/Zr and high Nb/Zr ratios and distinct isotopic values (i.e. low 87Sr/86Sr, 0.703523–0.703757; high 143Nd/144Nd, 0.512708–0.512784; high 206Pb/204Pb, 19.079–19.227, 207Pb/204Pb, 15.635–15.682, 208Pb/204Pb, 39.144–39.302) mark an anorogenic geochemical signature of the Denizli volcanics. All of the lavas are strongly enriched in large-ion-lithophile elements (e.g. Ba 1,100–2,200 ppm; Sr 1,900–3,100 ppm; Rb 91–295 ppm) and light rare-earth elements (e.g. LaN?=?319–464), with a geochemical affinity to ocean-island basalts and lack of a recognizable subduction signature or any evidence for crustal contamination. The restricted range of isotopic (Sr, Nd, Pb) ratios in both near-primitive (Mg# 66.7–77.2) and more evolved (Mg# 64.6–68.7) members of the Denizli volcanics signify their evolution from an isotopically equilibrated parental mantle source. Their high Dy/Yb and Rb/Sr values also suggest that garnet and phlogopite were present in the mantle source. Their strong EM-II signature, very low Nd model ages (0.44–049 Ga) and isotopic (Sr-Nd-Pb) values analogous to those of the Nyiragongo potassic basanites and kimberlites from the African stable continental settings, suggest that the parental melts that produced the Denizli volcanics are associated with very young and enriched mantle sources, which include both sublithospheric and enriched subcontinental lithospheric mantle melts. Mantle-lithosphere delamination probably played a significant role in the generation of these melts, and could be related to roll-back of the Aegean arc, lithospheric extension and asthenospheric mantle upwelling.  相似文献   

3.
Mineralogical, major and trace element, and isotopic data are presented for leucite basanite and leucite tephrite eruptives and dykes from the Batu Tara volcano, eastern Sunda arc. In general, the eruptives are markedly porphyritic with phenocrysts of clinopyroxene, olivine, leucite ±plagioclase±biotite set in similar groundmass assemblages. These K-rich alkaline volcanics have high concentrations of large-ion-lithophile (LIL), light rare earth (LRE) and most incompatible trace elements, and are characterized by high 87Sr/86Sr (0.70571–0.70706) and low 143Nd/ 144Nd (0.512609–0.512450) compared with less alkaline volcanics from the Sunda arc. They also display the relative depletion of Ti and Nb in chondrite-normalized plots which is a feature of subalkaline volcanics from the eastern Sunda arc and arc volcanics in general. Chemical and mineralogical data for the Batu Tara K-rich rocks indicate that they were formed by the accumulation of variable amounts of phenocrysts in several melts with different major and trace element compositions. The compositions of one of these melts estimated from glass inclusions in phenocrysts is relatively Fe-rich (100 Mg/(Mg + Fe2+)=48–51) and is inferred to have been derived from a more primitive magma by low-pressure crystal fractionation involving olivine, clinopyroxene and spinel. Mg-rich (mg 90) and Cr-rich (up to 1.7 wt. % Cr2O3) zones in complex oscillatory-zoned clinopyroxene phenocrysts probably also crystallized from such a magma. The marked oscillatory zoning in the clinopyroxene phenocrysts is considered to be the result of limited mixing of relatively evolved with more primitive magmas, together with their phenocrysts, along interfaces between discrete convecting magma bodies.  相似文献   

4.
Summary Sr, Nd and Pb isotope data are presented for a transitional basalt-peralkaline rhyolite suite, and spatially associated calc-alkaline rhyolites from the D'Entrecasteaux Islands, eastern Papua New Guinea. Both suites have a typical convergent margin geochemical signature (i.e. high Zr/Nb, La/Nb, and low Ta/Yb compared with OIB). The transitional basalt-peralkaline rhyolite suite and calc-alkaline rhyolites have a restricted range of206Pb/204Pb (18.522–18.661),207Pb/204Pb (15.543–15.631), and208Pb/204Pb (38.31–38.63) values which overlap the fields of volcanics from Tonga, Fiji, and Pacific MORB and sediments. The transitional basalt-peralkaline rhyolite suite also displays a restricted range of143Nd/144Nd values (0.513053–0.512984), but a much broader range of87Sr/86Sr (0.703989–0.70585) values. The latter reflects uncertainties in the ages of samples with very high87Rb/86Sr values and the effects of Sr exchange with seawater. The calc-alkaline rhyolites have consistently lower143Nd/144Nd values (0.512923—0.512867), and a more restricted range of87Sr/86Sr values (0.703864–0.704028) compared with the transitional basalt-peralkaline rhyolite suite.The isotopic and trace element data are consistent with the interpretation that the calc-alkaline rhyolites were produced by partial melting of a young arc protocrust, whereas associated calc-alkaline basic and intermediate magmas were derived from a depleted mantle source which previously had been modified by subduction along the Trobriand Trough. The transitional basalt-peralkaline rhyolite suite was produced by extensive magmatic differentiation of a parental transitional basalt magma in a relatively shallow magma chamber. The parent magma was produced by partial melting of either a depleted MORB-source mantle or a less-depleted OIB-type source which previously had been modified by subduction processes. The hy- and ol-normative transitional basalt magmas were probably generated in response to lithospheric thinning at somewhat higher pressures than qz-normative calc-alkaline magmas.The close spatial and temporal relationship between the transitional basalt-peralkaline rhyolite suite and the tale-alkaline volcanics reflects the complex and dynamic tectonic setting of eastern Papua and the D'Entrecasteaux Islands. In particular, the change from calc-alkaline to alkaline magmatism appears to have occurred following a change from compressional to extensional tectonics resulting from the westward propogation of the Woodlark spreading ridge into eastern Papua.
Sr, Nd und Pb Isotopenzusammensetzung saurer kalkalkalischer und peralkalischer Vulkanite der D' Entrecasteaux Inseln, Papua Neuguinea, und ihre tektonische Bedeutung
Zusammenfassung In dieser Arbeit werden Sr, Nd und Pb Isotopendaten transitionaler Basalt-peralkalischer Rhyolithabfolgen und räumlich mit diesen assoziierter kalkalkalischer Rhyolithe der D' Entrecasteaux Inseln im östlichen Papua Neuguinea vorgestellt. Beide Abfolgen zeigen für konvergiernde Plattenränder typische geochemische Signaturen (z.B. hohe Zr/Nb, La/Nb und niedrige Ta/Yb Verhältnisse im Vergleich mit OIB). Die transitionale Basalt-peralkalische Rhyolithabfolge und die kalkalkalischen Rhyolithe zeigen eine geringe Variation in ihren206Pb/204Pb (18.522–18.661),207/204Pb (15.543–15.631) und208Pb/204Pb (38.31–38.63) Verhältnissen, die mit denen von Vulkaniten aus Tonga, Fiji und den pazifischen MOR-Basalten und Sedimenten übereinstimmen. Die transitionale Basalt-peralkalische Rhyolithabfolge zeigt weiters eine geringe Variationsbreite der143Nd/144Nd Verhältnisse (0.513053–0.512984), aber eine größere Streuung der87Sr/86Sr Verhältnisse (0.703989–0.70585). Letztere reflektiern die Unsicherheiten der Alterseinstufung der Proben mit sehr hohen87Rb/86Sr Verhältnissen und die Effekte des Sr-Austausches mit Meerwasser. Die87Sr/86Sr Verhältnisse kalkalkalischer Rhyolithe variieren im Vergleich dazu gerigfügiger (0.703864–0.704028).Isotopen und Spurenelementdaten sind mit der Interpretation, daß die kalkalkalischen Rhyolithe durch partielle Anatexis junger Inselbogen-Protkruste entstanden sind, kompatibel. Die mit ihnen vergesellschafteten basischen bis intermediären klakalkalischen Magmen entstammen einer abgereicherten Mantelquelle, die zuvor durch Subduktionsprozesse entlang des Trobriandgrabens modifiziert wurde. Die transitionale Basalt-peralkalische Rhyolithabfolge entstand durch extensive magmatische Differentiation eines transitionalen basaltischen Stammagmas in einer relativ seicht liegenden Magmenkammer. Das Stammagma wurde durch partielle Aufschmelzung entweder eines abgereicherten MORB-Mantels oder einer weniger stark abgereicherten OIBQuelle, die zuvor durch Subduktionsprozesse modifiziert wurde, gebildet. Die Hyund O1-normativen transitionalen Basaltmagmen wurden wahrscheinlich im Zuge der Ausdünnung von Lithosphäre unter etwas höheren Drucken gebildet als die Quarznormativen kalkalkaischen Magmen.Die enge räumliche und zeitliche Beziehung der transitionalen Basalt-peralkalischen Rhyolithabfolge mit kalkalkalischen Vulkaniten spiegelt die komplexen und dynamischen geotektonischen Vorgänge im östlichen Papua Neuguinea wieder. Der Wechsel von kalkalkalischem zu alkalischem Magmatismus könnte durch die Umstellung von Kompressions- auf Extensionstektonik, die mit der Verlagerung des westlich gelegenen Woodlark Spreadingzenrums in das östliche Papua Neugiunea in Beziehung gebracht wird, erklärt werden.


With 13 Figures  相似文献   

5.
本文对中国东南沿海不含幔源包体的中生代玄武岩和含幔源包体的新生代玄武岩进行了微量元素和Nd-Sr-Pb同位素对比研究。中生代玄武岩呈Ta、Nb和Hf负异常,低Ce/Pb、Nb/U比值和高La/Nb比值,与岛弧火山岩和陆壳岩石的微量元素特征相类似,说明在岩浆生成和上升过程中,幔源组分受到了陆壳组分的混染。新生代玄武岩呈Ta、Nb正异常和Pb负异常,高Ce/Pb、Nb/U比值和低La/Nb比值,与海岛玄武岩(OIB)相类似,Nd-Sr同位素成分与夏威夷玄武岩类似,因而它们未受明显的陆壳混染。143Nd/144Nd与206Pb/204Pb之间的负相关关系和87Sr/86Sr与206Pb/204Pb之间的正相关关系说明本区新生代玄武岩起源于中等亏损程度的软流圈地幔,并与EMII富集地幔组分发生了混合。  相似文献   

6.
Recent statistical analyses on the isotopic compositions of oceanic, arc, and continental basalts have revealed that the Earth's mantle is broadly divided into eastern and western hemispheres. The present study aimed to characterize the isotopically defined east–west geochemical hemispheres using trace-element concentrations. Basalt data with Rb, Sr, Nd, Sm, Pb, Th, and U in addition to the isotopic ratios 87Sr/86Sr, 143Nd/144Nd, 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb were selected mostly from the GEOROC and PetDB databases. A total of 4787 samples were used to investigate the global geochemical variations. The results show that the wide trace-element variations are broadly explained by the melting of melt-metasomatized and fluid-metasomatized mantle sources. The larger amount of the fluid component derived from subducted plates in the eastern hemisphere than that in the western hemisphere is inferred from the basalts. These characteristics support the hypothesis that focused subduction towards the supercontinent created the mantle geochemical hemispheres.  相似文献   

7.
Mineralogy,geochemistry and petrogenesis of Kurile island-arc basalts   总被引:1,自引:0,他引:1  
Whole-rock (major- and trace-element) and mineral chemical data are presented for basaltic rocks from the main evolutionary stages of the Kurile island arc, NW Pacific. An outer, inactive arc contains a Cretaceous-Lower Tertiary sequence of tholeiitic, calcalkaline and shoshonitic basalts. The main arc (Miocene-Quaternary) is dominated by weakly tholeiitic, with lesser, alkalic basalts. The mineralogy of Kuriles basalts is characterised by An-rich plagioclases, a continuous transition from chromites to titanomagnetites, pyroxenes with low Fe3+ contents and without strong Fe-enrichment, abundance of groundmass pigeonites and the absence of amphiboles. There is an increase in K2O contents both along-arc (northwards) and towards the reararc side. The basalts show an exceptionally wide but continuous range of K2O contents (0.1–4.7%) which correlate with other LIL element contents. Tholeiitic basalts with low LIL element contents, La/Yb and Th/U, but high K/ Rb, P2O5/La and Zr/Nb were derived from depleted, lherzolitic mantle which had suffered fluid metasomatism by K, Rb, Cs, Sr, Ba, Pb and H2O only. Alkali basalts are also thought to be derived from depleted mantle but melt metasomatism involved addition of all LIL elements to a garnet lherzolite mantle. The Kuriles basalts and their mantle sources range continuously between these two end-member compositions. The metasomatic fluids/melts were probably released by early dehydration and later melting within subducted oceanic lithosphere though the process is not adequately constrained.  相似文献   

8.
This study presents Sr and Pb isotopic ratios and Rb, Sr, U, Th, and Pb concentrations of an ultrapotassic basaltic suite and related rocks from the central Sierra Nevada, California. The ultrapotassic suite yields a narrow range of Sr and Pb isotopic compositions (87Sr/86Sr=0.70597–0.70653; 206Pb/ 204Pb=18.862–19.018; 207Pb/204Pb=15.640–15.686; 208Pb/ 204Pb=38.833–38.950). Associated basalts containing ultramafic nodules have less radiogenic Sr (87Sr/86=0.70430–0.70521) and generally higher Rb/Sr ratios than the ultrapotassic suite. Leucitites from Deep Springs Valley, California, contain high 87Sr/86Sr (71141–0.71240) and low 206Pb/204Pb (17.169–17.234) ratios, reflecting contamination by crustal granulite.The isotopic relationships support an origin of the ultrapotassic basaltic suite by partial melting of an enriched upper mantle source. Dehydration of a gently inclined oceanic slab beneath the Sierra Nevada may have provided Ba, K, Rb, Sr, and H2O, which migrated into the overlying upper mantle lithosphere. The end of subduction 10 m.y. ago allowed increased asthenospheric heat flow into the upper mantle lithosphere. The increased heat flow enhanced fluid movement in the upper mantle and contributed towards isotopic homogenization of the upper mantle source areas. Continued heating of the enriched upper mantle caused partial melting and subsequent eruption of the ultrapotassic lavas.  相似文献   

9.
The Quaternary alkaline volcanic field of Southern Turkey is characterized by intra-continental plate-type magmatic products, exposed to the north of the ?skenderun Gulf along a NE-SW trending East Anatolian Fault, to the west of its intersection with the N–S trending Dead Sea Fault zone. The ?skenderun Gulf alkaline rocks are mostly silica-undersaturated with normative nepheline and olivine and are mostly classified as basanites and alkaline basalts with their low-silica contents ranging between 43 and 48?wt.% SiO2. They display Ocean Island Basalt (OIB)–type trace element patterns characterized by enrichments in large-ion-lithophile elements (LILE) and light rare earth element (LREE), and have (La/Yb)N?=?8.8–17.7 and (Hf/Sm)N?=?0.9–1.6 similar to those of basaltic rocks found in intraplate suites. The basanitic rocks have limited variations Sr-Nd isotopic ratios (87Sr/86Sr?=?0.70307–0.70324, 143Nd/144Nd?=?0.512918–0.521947), whereas the alkali basalts display more evolved Sr-Nd isotopic ratios (87Sr/86Sr?=?0.70346-0.70365, 143Nd/144Nd?=?0.512887–0.521896). The ?skenderun Gulf alkaline rocks also display limited Pb isotopic variations with 206Pb/204Pb?=?18.75–19.09 207Pb/204Pb?=?15.61–15.66 and208Pb/204Pb?=?38.65–39.02, indicating that they originated from an enriched lithospheric mantle source. Calculated fractionation vectors indicate that clinopyroxene and olivine are the main fractionating mineral phases. Similarly, based on Sr-Nd isotopic ratios, the assimilation and fractional crystallization (AFC) modeling shows that the alkali basalts were affected by AFC processes (r?=?0.2) and were slightly contaminated by the upper crustal material.The high TiO2 contents, enrichments in Ba and Nb, and depletions in Rb can likely be explained by the existence of amphibole in the mantle source, which might, in turn, indicate that the source mantle has been affected by metasomatic processes. The modeling based on relative abundances of trace elements suggests involvement of amphibole-bearing peridotite as the source material. ?skenderun Gulf alkaline rocks can thus be interpreted as the products of variable extent of mixing between melts from both amphibole-bearing peridotite and dry peridotite.  相似文献   

10.
Neogene (N 1 2 -N 2 1 ?) K-Na alkaline rocks were found in western Kamchatka as a subvolcanic basanite body at Mount Khukhch. The basanites have a microphyric texture with olivine phenocrysts in a fine-grained doleritic groundmass. The olivine contains inclusions of Al-Cr spinel. The microlites consist of clinopyroxene, plagioclase, magnetite, and apatite, and the interstitial phases are leucite, nepheline, and analcime. The Mount Khukhch basanites are characterized by elevated concentrations of MgO, TiO2, Na2O, and K2O, high concentrations of Co, Ni, Cr, Nb, Ta, Th, U, LREE (LaN/YbN = 10.8?12.6, DyN/YbN = 1.4?1.6) at moderate concentrations of Zr, Hf, Rb, Ba, Sr, Pb, and Cu. The values of indicator trace-element ratios suggest that basanites in western Kamchatka affiliate with the group of basaltoids of the within-plate geochemical type: Ba/Nb = 10?12, Sr/Nb = 17?18, Ta/Yb = 1.3?1.6. The basanites of western Kamchatka show many compositional similarities with the Miocene basanites of eastern Kamchatka, basanites of some continental rifts, and basalts of oceanic islands (OIB). The geochemistry of these rocks suggests that the basanite magma was derived via the ~6% partial melting of garnet-bearing peridotite source material. The crystallization temperatures of the first liquidus phases (olivine and spinel) in the parental basanite melt (1372–1369°C) and pressures determined for the conditions of the “mantle” equilibrium of the melt (25–26 kbar) are consistent with the model for the derivation of basanite magma at the garnet depth facies in the mantle. The geodynamic environment in which Neogene alkaline basaltic magmas occur in western Kamchatka was controlled by the termination of the Oligocene—Early Miocene subduction of the Kula oceanic plate beneath the continental margin of Kamchatka and the development of rifting processes in its rear zone. The deep faulting of the lithosphere and decompression-induced magma generation simultaneous with mantle heating at that time could be favorable for the derivation of mantle basite magmas.  相似文献   

11.
Scottish Dinantian transitional to mildly alkaline volcanism is represented by abundant outcrops in the Midland Valley, Southern Uplands and Highlands provinces. Dinantian volcanic rocks from Kintyre in the Scottish Highlands range in composition from basalt through basaltic hawaiite, hawaiite, mugearite and benmoreite to trachyte, the compositions of the evolved types being largely due to differentiation from the basaltic parents.Recent geochemical investigations of Scottish Caledonian granitoids, Siluro-Devonian Old Red Sandstone (ORS) lavas and xenolith suites from numerous vents and dykes of Permo-Carboniferous to Tertiary age have revealed that the Scottish crust and upper mantle both increase in age and are increasingly enriched in incompatible elements towards the north and northwest. The upper mantle and lower crust below the Highlands province are therefore largely considered to be more enriched and in parts older than those below the Midland Valley and Southern Uplands. Dinantian alkali basalts from these latter two provinces have Nd values predominantly in the range +3 to +6, initial 87Sr/86Sr values of 0.7029–0.7041 and 207Pb/ 204Pb values of 15.48–15.60. However, similar basalts from Kintyre and Arran in the Highlands have lower Nd (+0.1 to +3.4) and 207Pb/204Pb (for given 206Pb/204Pb ratios; 15.49–15.51) and slightly higher 87Sr/86Sr (0.7033–0.7046). This regional variation correlates well with the differences seen between Midland Valley and Highland magmas in the ORS calc-alkaline suite (Thirlwall 1986) and it is suggested that both the ORS and Dinantian basic rocks are derived from similar types of mantle, although no lithospheric slab component is present in the later Dinantian suites. Isotopically-distinct portions of mantle therefore appear to have been present below the Highland and Midland Valley-Southern Upland provinces from at least Caledonian to Carboniferous times. The combined incompatible element and Sr-Nd-Pd isotopic evidence from Kintyre and Arran basaltic rocks does not allow unequivocal distinction between a lithospheric mantle and a sublithospheric mantle source. The observed correlation between isotopic composition of Dinantian basalts and the chemical composition of the lithosphere, together with the apparent involvement of long-term separated source reservoirs suggests that Kintyre and Arran lavas were derived largely from a lithospheric mantle source. On the other hand, the isotopic enrichment of Kintyre basaltic rocks is not extreme; trace element and isotopic compositions are still comparable to modem OIB. Sublithospheric mantle could therefore also be a viable source for Kintyre and Arran Dinantian volcanism.  相似文献   

12.
Alkaline lavas were erupted as phonolites and trachytes around Karaburhan (Sivrihisar–Eskisehir, NW Anatolia) within the Izmir–Ankara–Erzincan suture zone. These volcanic rocks were emplaced as domes, close and parallel to the ophiolite thrust line. According to 40Ar/39Ar geochronological analyses of sanidine crystals from the phonolites, the age of the alkaline volcanics is 25 Ma (Late Oligocene–Early Miocene).The flow-textured phonolites are porphyritic and consist mainly of sanidine, clinopyroxene, and feldspathoid crystals. The clinopyroxenes show compositional zoning, with aegirine (Na0.82–0.96Fe+30.68–0.83) rims and aegirine–augite cores (containing calcium, magnesium, and Fe+2). Some aegirine–augites are replaced with sodium-, calcium-, and magnesium-rich amphibole (hastingsite). Feldspathoid (hauyne) crystals enriched with elemental Na and Ca have been almost completely altered to zeolite and carbonate minerals. The fine-grained trachytes with a trachytic texture consist of feldspar (oligoclase and sanidine) phenocrystals and clinopyroxene microphenocrystals within a groundmass made up largely of alkali feldspar microlites.Although there are some differences in their element patterns, the phonolites and trachytes exhibit enrichment in LILEs (Sr, K, Rb, Ba, Th) and LREEs (La, Ce, Pr, Nd) and negative anomalies in Nb and Ta. These geochemical characteristics indicate a lithospheric mantle enriched by fluids extracted from the subduction component. In addition, the high 87Sr/86Sr (0.706358–0.708052) and low 143Nd/144Nd (0.512546–0.512646) isotope concentrations of the alkaline lavas reflect a mantle source that has undergone metasomatism by subduction-derived fluids. Petrogenetic modeling indicates that the alkaline lavas generated from the subduction-modified lithospheric mantle have undergone assimilation, fractional crystallization, and crustal contamination, acquiring high Pb, Ba, Rb, and Sr contents and Pb isotopic compositions during their ascent through the thickened crust in an extensional setting.  相似文献   

13.
Whole-rock geochemical and radiogenic data are combined with in situ trace and isotopic analyses of amphibole grains to characterize the source and the emplacement mechanisms of the magmas of the Sunda arc in the Batu Hijau district, Sumbawa, Indonesia. The low-K calc-alkaline magmatic suite in the area is characterized by a distinctively juvenile signature (143Nd/144Nd ~0.5130). Whole-rock trace element and Pb isotopic data (207Pb/204Pb ~15.603) suggest the involvement of a minimal (<0.1%) sediment component in arc petrogenesis. During the petrogenesis of the calc-alkaline plutons, the involvement of fluids that were not entirely derived from the dehydration of a subducting slab is reflected in the mineral chemistry of the primary hydrous magmatic amphiboles, which contain very low B and Li concentrations. We argue that the B- and Li-poor fluids implicated in the petrogenesis of the calc-alkaline melts were at least partially derived from dehydration of uprising asthenospheric mantle. The δD values of selected hydrous magmatic amphibole grains range between ca. −70‰ and 0‰, consistent with an original mantle-derived signature, which was subsequently modified due to a de-hydrogenation process. We put forward the hypothesis that in the Batu Hijau district an arc-transverse fault system facilitated the rise of asthenosphere-derived melts above a kink, or tear, in the subducting Indian Ocean Plate that underlies the Sunda arc. The melts ascended to upper-crustal levels and underwent fractionation while interacting with the arc crust or metasomatized lithospheric mantle wedge. As a result of this study, we emphasize the significance of crustal-scale faults as conduits that connect the mantle to upper-crustal levels in arc settings. The de-hydrogenation process that the tonalite plutons underwent in the Batu Hijau district may have been crucial to the genesis of associated Cu–Au porphyry mineralization and the development of the Pliocene Batu Hijau deposit. Consequently, we argue that deep structures may facilitate the efficient release of mineralizing fluids at high crustal-levels.  相似文献   

14.
Post-3Ma volcanics from the N Luzon arc exhibit systematic variations in 87Sr/86Sr (0.70327–0.70610), 143Nd/144Nd (0.51302–0.51229) and 208Pb*/206Pb* (0.981–1.035) along the arc over a distance of about 500 km. Sediments from the South China Sea west of the Manila Trench also exhibit striking latitudinal variations in radiogenic isotope ratios, and much of the isotopic range in the volcanics is attributed to variations in the sediment added to the mantle wedge during subduction. However, Pb-Pb isotope plots reveal that prior to subduction, the mantle end-member had high 8/4, and to a lesser extent high 7/4, similar to that in MORB from the Indian Ocean and the Philippine Sea Plate. Th isotope data on selected Holocene lavas indicate a source with unusually high Th/U ratios (4.5–5.5). Combined trace element and isotope data require that three end-members were implicated in the genesis of the N Luzon lavas: (1) a mantle wedge end-member with a Dupal-type Pb isotope signature, (2) a high LIL/HFS subduction component interpreted to be a slab-derived hydrous fluid, and (3) an isotopically enriched end-member which reflects bulk addition (<5%) of subducted S China Sea terrigenous sediment. The 87Sr/86Sr ratios in the volcanics show a restricted range compared with that in the sediments, and this contrasts with 143Nd/144Nd and 208Pb*/206Pb*, both of which have similar ranges in the volcanics and sediments. Such differences imply that whereas the isotope ratios of Nd, Pb and Th are dominated by the component from subducted sediment, those of Sr reflect a larger relative contribution from the slab-derived fluid.  相似文献   

15.
New geochemical and isotopic data are reported for calc-alkaline (CA) volcanics of the Aeolian arc. Three main groups are recognized: the Alicudi and Filicudi volcanics in the western part of the arc; the Panarea, Salina and Lipari (henceforth termed PSL) volcanics in the central part of the arc and the Stromboli suite which makes up the eastern part of the arc. Each group is characterized by distinctive isotopic ratios and incompatible element contents and ratios. 87Sr/86Sr values (0.70352–0.70538) increase from west to northeast, and are well correlated with 143Nd/144Nd (Nd from +4.8 to -1.5). Pb isotope ratios are fairly high (6/4=19.15–19.54; 7/4=15.61–15.71; 8/4=38.97–39.36), with a general increase of 7/4 and 8/4 values from Alicudi to PSL islands and Stromboli. LILE contents and some incompatible element ratios (e.g. Ba/La, La/Nb, Zr/Nb, Rb/Sr) increase from the western to the central part of the arc, whereas HFSE and REE abundances decrease. Opposite variations are often observed in the volcanics toward the north-east from PSL islands. To account for these features and the decoupling observed between isotopic compositions and incompatible element abundances and ratios, it is suggested that a mantle source with affinities to the MORB source is metasomatized by slab-derived, crustal components. The proportion of crustal material entrained in the mantle source increases from Alicudi to Stromboli, according to the Sr and Nd isotope variations. It is also proposed that slab derived hydrous fluids play an important role, but which is variable in different sectors of the arc. This is attributed to the metasomatizing agent having variable fluid/melt ratios, reflecting different types of mass transfer from the subducted contaminant (probably pelagic sediments) to the mantle wedge. Thus, it is suggested that the slab derived end-member has a high hydrous fluid/melt ratio in the PSL mantle source and a correspondingly lower ratio in the Alicudi and Stromboli sources.  相似文献   

16.
Pliocene to recent volcanic rocks from the Bulusan volcanic complex in the southern part of the Bicol arc (Philippines) exhibit a wide compositional range (medium- to high-K basaltic-andesites, andesites and a dacite/rhyolite suite), but are characterised by large ion lithophile element enrichments and HFS element depletions typical of subduction-related rocks. Field, petrographic and geochemical data indicate that the more silicic syn- and post-caldera magmas have been influenced by intracrustal processes such as magma mixing and fractional crystallisation. However, the available data indicate that the Bicol rocks as a group exhibit relatively lower and less variable 87Sr/86Sr ratios (0.7036–0.7039) compared with many of the other subduction-related volcanics from the Philippine archipelago. The Pb isotope ratios of the Bicol volcanics appear to be unlike those of other Philippine arc segments. They typically plot within and below the data field for the Philippine Sea Basin on 207Pb/204Pb versus 206Pb/204Pb and 208Pb/204Pb versus 206Pb/204Pb diagrams, implying a pre-subduction mantle wedge similar to that sampled by the Palau Kyushu Ridge, east of the Philippine Trench. 143Nd/144Nd ratios are moderately variable (0.51285–0.51300). Low silica (<55 wt%) samples that have lower 143Nd/144Nd tend to have high Th/Nd, high Th/Nb, and moderately low Ce/Ce* ratios. Unlike some other arc segments in the Philippines (e.g. the Babuyan-Taiwan segment), there is little evidence for the involvement of subducted terrigenous sediment. Instead, the moderately low 143Nd/144Nd ratios in some of the Bicol volcanics may result from subduction of pelagic sediment (low Ce/Ce*, high Th/Nd, and high Th/Nb) and its incorporation into the mantle wedge via a slab-derived partial melt.  相似文献   

17.
The volcanic rocks of the South Atlantic Ocean islands of Fernando de Noronha and Trindade comprise a diverse magmatic series ranging from nephelinites and basanites to phonolites and, on Fernando de Noronha, trachytes. All rock types are highly silica undersaturated with the exception of Fernando de Noronha trachytes_, and have high abundances of incompatible trace elements and strongly LREE (light rare earth element)-enriched REE patterns. Crystal fractionation of parental basanitic magmas produced evolved phonolites and trachytes which display severe trace-element fractionation, even among trace elements (Nb, Ta, Zr, Hf) which normally behave highly incompatibly during crystallisation of alkaline magmas. Moderately to highly evolved compositions develop strongly MREE (middle REE)-depleted REE patterns, and become increasingly depleted in elements such as Nb and, in particular, Ta. Ratios of Nb/Ta and Zr/Hf are highly fractionated in phonolites (60–65, 64–77 respectively in Fernando de Noronha phonolites) compared to ratios in basanites (14, 45 respectively). The compatibility of Nb, Ta, and the REE, and the strong fractionation of Nb/Ta and Zr/Hf ratios and the MREE, during crystallisation from basanite to phonolite are attributable to the crystallisation of small amounts (<5%) of sphene. Trace-element behaviour is relatively insensitive to the major phenocryst phases, and is controlled by minor phases in highly undersaturated alkaline suites. Incompatible trace-element ratios (e.g. La/Nb, Th/Ta) in nephelinites and basanites from Fernando de Noronha and Trindade are generally comparable with those in basaltic and hawaiitic OIB (ocean island basalt) lavas from other South Atlantic islands, but are distinct from those of Gough and Tristan da Cunha OIB. The mantle source for the highly undersaturated volcanism on Fernando de Noronha and Trindade is similar in trace-element characteristics to the typical OIB source which produces alkaline lavas with significant relative enrichment in Nb and Ta compared to other trace elements (as expressed by low La/Nb, Ba/Nb and Th/Ta ratios). The highly undersaturated nature of the magmas and the slight fractionation of some incompatible-element ratios (elevated Ba/Nb, Ba/Rb, Ba/Th etc.) is consistent with a smaller degree of melting of a typical OIB source, but with residual phlogopite in the source to account for significant K depletion and LIL-element fractionation.  相似文献   

18.
Cold Bay and Amak Island, two Quaternary volcanic centers in the eastern Aleutians, are orthogonal relative to the trench and separated by ~50 km. Sr, Nd and Pb isotopic compositions of the calc-alkaline andesite magmas show no sign of contamination from continental crust (average 87Sr86Sr = 0.70323, 143Nd144Nd = 0.51301, 206Pb204Pb = 18.82, 207Pb204Pb = 15.571). These samples plot within the mantle arrays for Sr-Nd and for Pb and are similar to arcs such as the Marianas and New Britain (Sr-Nd) and Marianas and Tonga (Pb). Incompatible element ratios for the Aleutian andesites (K/Rb ~ 332, K/Cs ~ 10,600, K/Sr ~ 22.4, K/Ba ~ 18.3, Ba/La ~ 60) are within the range reported for arc basalts, despite the difference in degree of fractionation.Average K content, K/Rb, K/Ba and K/Sr are approximately the same for basalts from arcs and from oceanic islands (OIB); K/Cs is a factor of 4 lower and Ba/La almost 3 times higher in arcs. Abundance ratio correlations indicate that arcs are enriched in Cs and depleted in La relative to OIB, with other incompatible element abundances very similar. Histograms of Sr and Nd isotopic compositions for MORB, OIB, and intraoceanic arcs show remarkably similar peaks and distribution patterns for intraoceanic arcs and OIB.A “plum pudding” model for the upper mantle best accommodates a) geochemical coherence of OIB and IAV, b) the existence of mantle plumes at some oceanic islands, and c) the presence of a MORB-type source at back arc spreading centers. In this model, OIB plums are imbedded in a MORB matrix; small degrees of melting generate OIB-type magmas while larger degrees of melting dilute the OIB magma with MORB matrix melts.OIB plums are merely less robust lower mantle plumes (i.e., blobs) which are distributed throughout the upper mantle by convection. The existence of at least two types of OIB, as indicated by Sr, Nd, and Pb isotopes, suggests that nuggets of recycled oceanic lithosphère may coexist with lower-mantle plums and that both may be tapped in arcs and intraplate environments.  相似文献   

19.
The volcanic rocks of the Xiong'er Group are situated in the southern margin of the North China Craton(NCC).Research on the Xiong er Group is important to understand the tectonic evolution of the NCC and the Columbia supercontinent during the Paleoproterozoic.In this study,to constrain the age of the Xiong'er volcanic rocks and identify its tectonic environment,we report zircon LA-ICP-MS data with Hf isotope,whole-rock major and trace element compositions and Sr-Nd-Pb-Hf isotopes of the volcanic rocks of the Xiong'er Group.The Xiong'er volcanic rocks mainly consist of basaltic andesite,andesite.dacite and rhyolite,with minor basalt.Our new sets of data combined with those from previous studies indicate that Xiong'er volcanism should have lasted from 1827 Ma to 1746 Ma as the major phase of the volcanism.These volcanics have extremely low MgO.Cr and Ni contents,are enriched in LREEs and LILEs but depleted in HFSEs(Nb,Ta,and Ti),similar to arc-related volcanic rocks.They are characterized by negative zircon ε_(Hf)_(t) values of-17.4 to 8.8,whole-rock initial ~(87)Sr/~(86)Sr values of 0.7023 to 0.7177 andε_(Nd)(t) values of-10.9 to 6.4.and Pb isotopes(~(206)Pb/~(204)Pb =14.366-16.431,~(207)Pb/~(204)Pb =15.106-15.371,~(208)Pb/~(204)Pb= 32.455-37.422).The available elemental and Sr-Nd-Pb-Hf isotope data suggest that the Xiong'er volcanic rocks were sourced from a mantle contaminated by continental crust.The volcanic rocks of the Xiong'er Group might have been generated by high-degree partial melting of a lithospheric mantle that was originally modified by oceanic subduction in the Archean.Thus,we suggest that the subduction-modified lithospheric mantle occurred in an extensional setting during the breakup of the Columbia supercontinent in the Late Paleoproterozoic,rather than in an arc setting.  相似文献   

20.
There are large areas of Permian basaltic rocks in the Tarim basin (PBRT) in northwestern China. Precise Ar–Ar dating of these rocks revealed an eruption age span of 262 to 285 Ma. Most of the PBRT is composed of alkaline basaltic rocks with high TiO2 (2.43%–4.59%, weight percent), high Fe2O3 + FeO (12.63%–17.83%) and P2O5 (0.32%–1.38%) contents. Trace elements of these rocks have affinities with oceanic island basalts (OIB), as shown in chondrite normalized rare earth elements (REE) diagrams and primitive mantle normalized incompatible elements diagrams. The rocks show complex Sr–Nd isotopic character based on which they can be subdivided into two distinct groups: group 1 has relatively small initial (t = 280 Ma)87Sr/86Sr ratio ( 0.7048) and positive εNd(t) (3.42–4.66) values. Group 2 has relatively large initial 87Sr/86Sr ratio (0.7060–0.7083) and negative εNd(t) (from − 2.79 to − 2.16) values. Lead isotopes are even more complex with variations of (206Pb/204Pb)t, (207Pb/204Pb)t and (208Pb/204Pb)t ranging from 17.9265 to 18.5778, 15.4789 to 15.6067 and 37.2922 to 38.1437, respectively. Moreover, these two groups have different trace elements ratios such as Nb/La, Ba/Nb, Zr/Nb, Nb/Ta and Zr/Hf, implying different magmatic processes. Based on the geochemistry of basaltic rocks and an evaluation of the tectonics, deformation, and the compositions of crust and lithospheric mantle in Tarim, we conclude that these basaltic rocks resulted from plume–lithosphere interaction. Permian mantle plume caused an upwelling of the Tarim lithosphere leading to melting of the asthenospheric mantle by decompression. The magma ascended rapidly to the base of lower crust, where different degrees of assimilation of OIB-like materials and fractionation occurred. Group 1 rocks formed where the upwelling is most pronounced and the assimilation was negligible. In other places, different degrees of assimilation and fractionation account for the geochemical traits of group 2.  相似文献   

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