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1.
Major, trace-element, and Sr-, Nd-and Pbisotope data are presented for volcanics from 12 active or recently active volcanoes from the islands of Flores, Adonara, Lembata and Batu Tara in the eastern Sunda are. The volcanics vary in composition from low-K tholeiite, through medium-and high-K calcalkaline types to the K-rich leucite basanites of Batu Tara. From the tholeiites to the leucite basanites there are marked increases in the concentrations of LILE (K, Rb, Ba, Sr), LREE and La/Yb, and all the volcanics have high Ba/ Nb, La/Nb and Ba/La compared with mid-ocean ridge and intraplate eruptives. K/Cs values are generally lower than OIB values, and overlap those of other arc volcanics and northeast Indian Ocean sediments. The volcanics exhibit a broad range of 87Sr/86Sr (0.70468–0.70706), 143Nd/144Nd (0.512946–0.512447), and a moderate range in 206Pb/204Pb (18.825–19.143), 207Pb/ 204Pb (15.643–15.760) and 208Pb/204Pb (38.97–39.51). Trace-element and isotopic data suggest that the mantle beneath the eastern Sunda arc is a complex heterogeneous mixture of 3 or 4 major source components: MORB-source or depleted MORB-source, OIB-source and subducted Indian Ocean sediment. The low-K tholeiites were probably formed by relatively large degrees of melting of depleted MORB-source mantle, modified by subduction-related fluids, whereas the trace-element and isotopic characteristics of the K-rich volcanics suggest that they were derived from an OIB source which and been modified by a subduction-related melt component. The source components of the medium-to high-K calcalkaline rocks are more difficult to determine, and probably include mixtures of MORB-source or OIB-source, and melt/fluid derived from subducted oceanic sediment. Minor-and trace-element modelling calculations indicate substantial difficulties in producing the relatively low Ti-contents of arc volcanics by melting OIB-source mantle. Where OIB mantle is considered to be an important component of arc magmas it is suggested that the HFSE are buffered to relatively low concentration by a residual Ti-rich accessory phase.  相似文献   

2.
The composite Meghri–Ordubad and Bargushat plutons of the Zangezur–Ordubad region in the southernmost Lesser Caucasus consist of successive Eocene to Pliocene magmatic pulses, and host two stages of porphyry Cu–Mo deposits. New high-precision TIMS U–Pb zircon ages confirm the magmatic sequence recognized by previous Rb–Sr isochron and whole-rock K–Ar dating. A 44.03 ± 0.02 Ma-old granite and a 48.99 ± 0.07 Ma-old granodiorite belong to an initial Eocene magmatic pulse, which is coeval with the first stage of porphyry Cu–Mo formation at Agarak, Hanqasar, Aygedzor and Dastakert. A subsequent Oligocene magmatic pulse was constrained by U–Pb zircon ages at 31.82 ± 0.02 Ma and 33.49 ± 0.02 Ma for a monzonite and a gabbro, and a late Miocene porphyritic granodioritic and granitic pulse yielded ages between 22.46 ± 0.02 Ma and 22.22 ± 0.01 Ma, respectively. The Oligo-Miocene magmatic evolution broadly coincides with the second porphyry-Cu–Mo ore deposit stage, including the major Kadjaran deposit at 26–27 Ma.Primitive mantle-normalized spider diagrams with negative Nb, Ta and Ti anomalies support a subduction-like nature for all Cenozoic magmatic rocks. Eocene magmatic rocks have a normal arc, calc-alkaline to high-K calc-alkaline composition, early Oligocene magmatic rocks a high-K calc-alkaline to shoshonitic composition, and late Oligocene to Mio-Pliocene rocks are adakitic and have a calc-alkaline to high-K calc-alkaline composition. Radiogenic isotopes reveal a mantle-dominated magmatic source, with the mantle component becoming more predominant during the Neogene. Trace element ratio and concentration patterns (Dy/Yb, Sr/Y, La/Yb, Eu/Eu*, Y contents) correlate with the age of the magmatic rocks. They reveal combined amphibole and plagioclase fractionation during the Eocene and the early Oligocene, and amphibole fractionation in the absence of plagioclase during the late Oligocene and the Mio-Pliocene, consistent with Eocene to Pliocene progressive thickening of the crust or increasing pressure of magma differentiation. Characteristic trace element and isotope systematics (Ba vs. Nb/Y, Th/Yb vs. Ba/La, 206Pb/204Pb vs. Th/Nb, Th/Nb vs. δ18O, REE) indicate that Eocene magmatism was dominated by fluid-mobile components, whereas Oligocene and Mio-Pliocene magmatism was dominated by a depleted mantle, compositionally modified by subducted sediments.A two-stage magmatic and metallogenic evolution is proposed for the Zangezur–Ordubad region. Eocene normal arc, calc-alkaline to high-K calc-alkaline magmatism was coeval with extensive Eocene magmatism in Iran attributed to Neotethys subduction. Eocene subduction resulted in the emplacement of small tonnage porphyry Cu–Mo deposits. Subsequent Oligocene and Miocene high-K calc-alkaline and shoshonitic to adakitic magmatism, and the second porphyry Cu–Mo deposit stage coincided with Arabia–Eurasia collision to post-collision tectonics. Magmatism and ore formation are linked to asthenospheric upwelling along translithospheric, transpressional regional faults between the Gondwana-derived South Armenian block and the Eurasian margin, resulting in decompression melting of lithospheric mantle, metasomatised by sediment components added to the mantle during the previous Eocene subduction event.  相似文献   

3.
The petrogenesis of high-Mg andesites (HMA) in subduction zones involves shallow melting of refractory mantle sources or, alternatively, the interaction of ascending slab-derived melts with mantle peridotite. To unravel the petrogenesis of HMA, we report major, trace element and Sr–Nd–Hf–Pb isotope data for a newly found occurrence of HMA in the New Georgia group, Solomon Islands, SW-Pacific. Volcanism in the Solomon Islands was initiated by subduction of the Pacific plate beneath the Indian–Australian plate until a reversal of subduction polarity occurred ca. 10 Ma ago. Currently, the Indian–Australian plate is subducted northeastwards along the San Cristobál trench, forming the younger and still active southwestern Solomon island arc. However, a fossil slab of Pacific crust is still present beneath the arc. The edifice of the active volcano Simbo is located directly in the San Cristobál trench on top of the subducting Indian–Australian plate. Simbo Island lies on top of a strike-slip fault of the adjacent Woodlark spreading centre that is subducted beneath the Pacific plate. Geochemical and petrological compositions of volcanic rocks from Simbo are in marked contrast to those of volcanic rocks from islands north of the trench (mostly arc basalts). Simbo-type rocks are opx-bearing HMA, displaying 60–62 wt% SiO2 but rather primitive Mg–Ni–Cr characteristics with 4–6 wt% MgO, up to 65 ppm Ni, up to 264 ppm Cr and Mg# from 67 to 75. The compositions of the Simbo andesites are explained by a binary mixture of silicic and basaltic melts. Relict olivine phenocrysts with Fo88–90 and reaction-rims of opx also support a mixing model. The basaltic endmember is similar to back-arc basalts from the Woodlark Ridge. A slab melt affinity of the silicic mixing component is indicated by Gd(N)/Yb(N) of up to 2.2 that is higher if compared to MORB and other arc basalts from the Solomon Islands. 87Sr/86Sr, ɛNd and ɛHf values in the analysed rocks range from 0.7035 to 0.7040, +6.4 to +7.9 and +12 to +14.4, respectively. These values reveal the presence of the Indian–Australian mantle domain beneath Simbo (i.e. the Indian–Australian plate) and also beneath all other volcanic islands of the New Georgia group, which are located north of the San Cristobál trench. 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb values (18.43–18.52, 15.49–15.55 and 18.13–18.34, respectively) confirm the presence of slab melts from the subducted Pacific plate beneath southern Simbo where the highest Gd(N)/Yb(N) ratios are reported. A spatial shift towards an Indian–Australian slab signature is observed when approaching the active San Cristobál trench on northern Simbo, reflecting the decreasing influence of slab melts from the old subducted Pacific plate.  相似文献   

4.
Miocene to Pleistocene calc-alkaline volcanism in the East Carpathianarc of Romania was related to the subduction of a small oceanbasin beneath the continental Tisza–Dacia microlate. Volcanicproducts are predominantly andesitic to dadtic in composition,with rare basalts and rhyodacites (51–l71% SiO2; mg-number0.65–0.26) and have medium- to high-K calcalkaline andshoshonitic affinities. Mg, Cr and Ni are low in all rock-types,indicating the absence of primary erupted compositions. Detailedtrace element and Sr, Nd, Pb and 0 isotope data suggest thatmagmas were strongly crustally contaminated. Assimilation andfractional crystallization (AFC) calculations predict the consumptionof 5–35% local upper-crustal metasediments or sedimentsfrom the palaeo-accretionary wedge. Variations in the isotopiccomposition of the contaminants and parental magmas caused variationsin the mixing trajectories in different parts of the arc Themost primitive isotopic compositions are found in low-K dacitesof the northern Cdlimani volcanic centre and are interpretedas largely mantle derived. A second possible mantle reservoirof lower 149 Nd/144 Nd and lower 206 Pb/204 Pb is identifiedfrom back-arc basic calc-alkaline rocks in the south of thearc Both magmatic reservoirs have elevated isotopic characteristics,owing either to source bulk mixing (between depleted or enrichedasthenosphere and <1% average subducted local sediment) orlower-crustal contamination. KEY WORDS: Carpathians; assimilation; calc-alkaline; Sr-Nd-Pb-0 isotopes; laser flurination  相似文献   

5.
The earliest representatives in the sequence of Tertiary to Recent magmatic rocks on Adak island in the central Aleutians, are the Finger Bay Volcanics and associated small shallow-level gabbroic intrusives. The tholeiitic Finger Bay pluton (gabbro to quartz monzodiorite) is among the least altered representatives of this earliest period. The field relations, mineralogy, and geochemistry of the Finger Bay pluton contrast with the more recent calcalkaline plutons in the arc (e.g. on Adak, Hidden Bay pluton: 33 m.y. and on Kagalaska, Kagalaska pluton: 15 m.y.). Compared with the Hidden Bay pluton, the Finger Bay pluton is smaller (8 km2 versus 100 km2), has a greater proportion of gabbro (84% versus 5%), has a somewhat different mineralogy, and has higher whole rock and mafic mineral FeO/MgO ratios, higher K2O, and higher concentrations of incompatable elements in rocks of equivalent SiO2 (particularly for the more siliceous units). Magmatic amphibole occurs only in the most siliceous units in the Finger Bay pluton, whereas it is common in the calc-alkaline plutons. Except for the size, these differences parallel those between tholeiitic and calc-alkaline volcanic rocks from the active Aleutian volcanic centers. Textural, miner-alogical, and trace element analyses indicate that mixing of magmas and gabbros generated some of the rocks of intermediate (monzodiorite) composition in the Finger Bay pluton. Most of the differences in magmatic trends between the calc-alkaline and tholeiitic plutons are attributed to the physical conditions of magmatic evolution in the crust, rather than to differences in initial magmatic types. This conclusion rests on the similarity of fractionation-independent isotope ratios and trace element ratios in Aleutian magmas of all ages. In particular, compared to magmas of the north Pacific ocean basin (MORB, oceanic islands), Aleutian magmas show excess enrichment of Ba, K, Rb, and U relative to REE and high 207Pb/204Pb ratios for a given 206Pb/204Pb ratio. Recognition of tholeiitic series plutons in the arc provides direct evidence for magmatic conditions accompanying fractionation, and serves to emphasize the diversity of magmatic trends that are found over time and space at convergent plate margins.  相似文献   

6.
More than 140 middle-small sized deposits or minerals are present in the Weishan-Yongping ore concentration area which is located in the southern part of a typical Lanping strike-slip and pull-apart basin. It has plenty of mineral resources derived from the collision between the Indian and Asian plates. The ore-forming fluid system in the Weishan-Yongping ore concentration area can be divided into two subsystems, namely, the Zijinshan subsystem and Gonglang arc subsystem. The ore-forming fluids of Cu, Co deposits in the Gonglang arc fluid subsystem have δD values between −83.8‰ and −69‰, δ18O values between 4.17‰ and 10.45‰, and δ13C values between −13.6‰ and 3.7‰, suggesting that the ore-forming fluids of Cu, Co deposits were derived mainly from magmatic water and partly from formation water. The ore-forming fluids of Au, Pb, Zn, Fe deposits in the Zijinshan subsystem have δD values between −117.4‰ and −76‰, δ18O values between 5.32‰ and 9.56‰, and Δ13C values between −10.07‰ and −1.5‰. The ore-forming fluids of Sb deposits have δD values between −95‰ and −78‰, δ18O values between 4.5‰ and 32.3‰, and Δ13C values between −26.4‰ and −1.9‰. Hence, the ore-forming fluids of the Zijinshan subsystem must have been derived mainly from formation water and partly from magmatic water. Affected by the collision between the Indian and Asian plates, ore-forming fluids in Weishan-Yongping basin migrated considerably from southwest to northeast. At first, the Gonglang arc subsystem with high temperature and high salinity was formed. With the development of the ore-forming fluids, the Zijinshan subsystem with lower temperature and lower salinity was subsequently formed. Translated from Mineral Deposits, 2006, 25(1): 60–70 [译自: 矿床地质]  相似文献   

7.
The Neoproterozoic Korab Kansi mafic-ultramafic intrusion is one of the largest (100 km2) intrusions in the Southern Eastern Desert of Egypt. The intrusion consists of Fe-Ti-bearing dunite layers, amphibole peridotites, pyroxenites, troctolites, olivine gabbros, gabbronorites, pyroxene gabbros and pyroxene-hornblende gabbros, and also hosts significant Fe-Ti deposits, mainly as titanomagnetite-ilmenite. These lithologies show rhythmic layers and intrusive contacts against the surrounding granites and ophiolitic-island arc assemblages. The wide ranges of olivine forsterite contents (Fo67.9-85.7), clinopyroxene Mg# (0.57–0.95), amphibole Mg# (0.47–0.88), and plagioclase compositions (An85.8-40.9) indicate the role of fractional crystallization in the evolution from ultramafic to mafic rock types. Clinopyroxene (Cpx) has high REE contents (2–30 times chondrite) with depleted LREE relative to HREE, like those crystallized from ferropicritic melts generated in an island-arc setting. Melts in equilibrium with Cpx also resemble ferropicrites crystallized from olivine-rich mantle melts. Cpx chemistry and its host rock compositions have affinities to tholeiitic and calc-alkaline magma types. Compositions of mafic-ultramafic rocks are depleted in HFSE (e.g. Nb, Ta, Zr, Th and U) relative to LILE (e.g. Li, Rb, Ba, Pb and Sr) due to the addition of subduction-related hydrous fluids (rich in LILE) to the mantle source, suggesting an island-arc setting. Fine-grained olivine gabbros may represent quenched melts approximating the primary magma compositions because they are typically similar in assemblage and chemistry as well as in whole-rock chemistry to ferropicrites. We suggest that the Korab Kansi intrusion crystallized at temperatures ranging from ~700 to 1100 °C from ferropicritic magma derived from melting of metasomatized mantle at <5 Kbar. These hydrous ferropicritic melts were generated in the deep mantle and evolved by fractional crystallization under high ƒO2 at relatively shallow depth. Fractionation formed calc-alkaline magmas during the maturation of an island arc system, reflecting the role of subduction-related fluids. The interaction of metasomatized lithosphere with upwelling asthenospheric melts produced the Fe and Ti-rich ferropicritic parental melts that are responsible for precipitating large quantities of Fe-Ti oxide layers in the Korab Kansi mafic-ultramafic intrusion. The other factors controlling these economic Fe-Ti deposits beside parental melts are high oxygen fugacity, water content and increasing degrees of mantle partial melting. The generation of Ti-rich melts and formation of Fe-Ti deposits in few layered intrusions in Egypt possibly reflect the Neoproterozoic mantle heterogeneity in the Nubian Shield. We suggest that Cryogenian-Tonian mafic intrusions in SE Egypt can be subdivided into Alaskan-type intrusions that are enriched in PGEs whereas Korab Kansi-type layered intrusions are enriched in Fe-Ti-V deposits.  相似文献   

8.
The Štěnovice and Čistá granodiorite–tonalite plutons are small (~27 and ~38 km2, respectively) intrusions that are largely discordant to regional ductile structures in the center of the upper-crustal Teplá–Barrandian unit, Bohemian Massif. Their whole-rock and trace-element compositions are consistent with medium-K calc-alkaline magma, generated above a subducted slab in a continental margin arc setting. The U–Pb zircon age of the Štěnovice pluton, newly determined at 375 ± 2 Ma using the laser ablation ICP-MS technique, is within the error of the previously published Pb–Pb age of 373 ± 1 Ma for the Čistá pluton. The two plutons also share other characteristics that are typical of concentrically expanded plutons (CEPs), such as elliptical cross-section in plan view, steep contacts, inferred downward-narrowing conical shape, faint normal zoning, and margin-parallel magmatic foliation decoupled from the regional host-rock structures. We interpret the Štěnovice and Čistá plutons as representing the initial Late Devonian stage of much more voluminous early Carboniferous arc-related plutonism (represented most typically by the Central Bohemian Plutonic Complex) in the upper crust of the central Bohemian Massif. These two plutons are important tectonic elements in that they indicate an overall shift of the arc-related plutonic activity from the ~NW to the ~SE, accompanied with a general compositional trend of the magmas from medium-K calc-alkaline to shoshonitic/ultrapotassic. Such a pattern is compatible with SE-directed subduction of the Saxothuringian Ocean beneath the Teplá–Barrandian overriding plate as a cause of arc-related magmatism in this part of the Bohemian Massif.  相似文献   

9.
atu Tara is an active potassic volcano in the eastern Sunda arc. Its leucite-bearing rock suite can be subdivided into two groups, one less evolved with Th<20 ppm, the other more evolved with Th>20 ppm. 87Sr/86Sr, δ18O and trace-element systematics in the less evolved group suggests that existence of parental magmas with different mantle origins. The mantle below Batu Tara is most likely heterogeneous and several source components are involved in magma genesis. Trace element and isotopic compositions of Batu Tara and adjacent volcanoes are consistent with the involvement of a subducted sedimentary/crustal component as well as MORB and OIB mantle, the latter with geochemical characteristics comparable to the mantle underlying Muriah (Java). Melt extraction from this complex mixture is envisioned as a two-stage process: partial melts of the crust-contaminated MORB mantle mix in the mantle wedge with partial melts of OIB domains. Different mixtures of these two melts provide the parental magmas that enter the volcanic plumbing system, where crystallization, hybridization and refilling processes occur. The calcalkaline volcanoes in the arc segment show stronger signatures for a subducted crustal component than Batu Tara, which displays a greater influence from the OIB mantle source. The potassium enrichment can therefore be attributed to contributions both from the enriched mantle and from subducted crustal material. Mantle-type δ18O values of the Batu Tara magmas indicate that the mantle wedge below potassic orogenic volcanoes is not necessarily strongly enriched in 18O.  相似文献   

10.
We present major and trace element analyses and U–Pb zircon intrusion ages from I-type granitoids sampled along a crustal transect in the vicinity of the Chilas gabbronorite of the Kohistan paleo-arc. The aim is to investigate the roles of fractional crystallization of mantle-derived melts and partial melting of lower crustal amphibolites to produce the magmatic upper crust of an island arc. The analyzed samples span a wide calc-alkaline compositional range (diorite–tonalite–granodiorite–granite) and have typical subduction-related trace element signatures. Their intrusion ages (75.1 ± 4.5–42.1 ± 4.4 Ma) are younger than the Chilas Complex (~85 Ma). The new results indicate, in conjunction with literature data, that granitoid formation in the Kohistan arc was a continuous rather than punctuated process. Field observations and the presence of inherited zircons indicate the importance of assimilation processes. Field relations, petrographic observations and major and trace element compositions of the granitoid indicate the importance of amphibole fractionation for their origin. It is concluded that granitoids in the Kohistan arc are derivative products of mantle derived melts that evolved through amphibole-dominated fractionation and intra crustal assimilation.  相似文献   

11.
The island of Salina comprises one of the most distinct calc-alkaline series of the Aeolian arc (Italy), in which calc-alkaline, high-K calc-alkaline, shoshonitic and leucite-shoshonitic magma series are developed. Detailed petrological, geochemical and isotopic (Sr, Nd, Pb, O) data are reported for a stratigraphically well-established sequence of lavas and pyroclastic rocks from the Middle Pleistocene volcanic cycle (430–127 ka) of Salina, which is characterized by an early period of basaltic volcanism (Corvo; Capo; Rivi; Fossa delle Felci, group 1) and a sequence of basaltic andesites, and andesites and dacites in the final stages of activity (Fossa delle Felci, groups 2–8). Major and trace element compositional trends, rare earth element (REE) abundances and mineralogy reveal the importance of crystal fractionation of plagioclase + clinopyroxene + olivine/ orthopyroxene ± titanomagnetite ± amphibole ± apatite in generating the more evolved magma types from parental basaltic magmas, and plagioclase accumulation in producing the high Al2O3 contents of some of the more evolved basalts. Sr isotope ratios range from 0.70410 to 0.70463 throughout the suite and show a well-defined negative correlation with 143Nd/144Nd (0.51275–0.51279). Pb isotope compositions are distinctly radiogenic with relatively large variations in 206Pb/204Pb (19.30–19.66), fairly constant 207Pb/204Pb (15.68–15.76) and minor variations in 208Pb/204Pb ratios (39.15–39.51). Whole-rock δ18O values range from +6.4 to +8.5‰ and correlate positively with Sr isotope ratios. Overall, the isotopic variations are correlated with the degree of differentiation of the rocks, indicating that only small degrees of crustal assimilation are overprinting the dominant evolution by crystal–liquid fractionation (AFC-type processes). The radiogenic and oxygen isotope composition of the Salina basalts suggests derivation from primary magmas from a depleted mantle source contaminated by slab-derived fluids and subducted sediments with an isotopic signature of typical upper continental crust. These magmas then evolved further to andesitic and dacitic compositions through the prevailing process of low-pressure fractional crystallization in a shallow magma reservoir, accompanied by minor assimilation of crustal lithologies similar to those of the Calabrian lower crust. Received: 29 November 1999 / Accepted: 16 April 2000  相似文献   

12.
The magmatic arc of the Fuegian Andes is composed mostly of Upper Mesozoic to Cenozoic calc-alkaline plutons and subordinated lavas. To the rear arc, however, isolated mid-Cretaceous monzonitic plutons and small calc-alkaline dykes and sills crop out. This calc-alkaline unit (the Ushuaia Peninsula Andesites, UPA) includes hornblende-rich, porphyritic quartz meladiorites, granodiorites, andesites, dacites and lamprophyres. Radiometric dating and cross-cutting relationships indicate that UPA is younger than the monzonitic suite. The geochemistry of UPA is medium to high K, with high LILE (Ba 500–2000 ppm, Sr 800–1400 ppm), HFSE (Th 7–23 ppm, Nb 7–13 ppm, Ta 0.5–1.1 ppm) and LREE (La 16–51 ppm) contents, along with relatively low HREE (Yb 1.7–1.3 ppm) and Y (9–19 ppm). The similar mineralogy and geochemistry of all UPA rocks suggest they evolved from a common parental magma, by low pressure crystal fractionation, without significant crustal assimilation. A pure Rayleigh fractionation model indicates that 60–65% of crystal fractionation of 60% hornblende + 34% plagioclase + 4% clinopyroxene + 1% Fe-Ti oxide, apatite and sphene (a paragenesis similar of UPA mafic rocks) can explain evolution from lamprophyres to dacites. The UPA has higher LILE, HFSE and LREE, and lower HREE and Y than the calc-alkaline plutons and lavas of the volcanic front. The HREE and Y are lower than in the potassic plutons as well. High concentrations of Th, Nb, Ta, Zr, Hf, LREE and Ce/Pb, and low U/Th, Ba/Th ratios in UPA, even in the least differentiated samples, suggest contributions from subducted sediments to the mantle source. On the other hand, relatively low HREE and Y, high LREE/HREE (La/Yb 11–38) ratios and Nb-Ta contents can be interpreted as mantle metasomatism by partial melts of either subducted garnetiferous oceanic sediment or basalt as well. Additionally, high LILE content in UPA, similar to the potassic plutons, suggests also a mantle wedge previously metasomatized by potassic parental magmas in their route to crustal levels. Therefore, UPA represents a unique suite in the Fuegian arc generated in a multiple hybridized source. UPA generation is related to a transition from normal to flat subduction which additionally caused the widening and landward migration of the magmatic arc, as well as crustal deformation. Rear-arc magmatism endured ca. 22 m.y.; afterwards, calc-alkaline magmatism remained at the volcanic front.  相似文献   

13.
郭荣荣  刘树文  白翔  张立飞  王伟  胡方泱  阎明 《岩石学报》2014,30(10):2885-2904
冀东双山子群是一套出露于青龙县东部变质程度较低的火山沉积地层,其中火山岩地层主要由变质玄武岩、安山岩和英安岩-流纹岩组成。全岩地球化学分析表明变玄武岩呈现拉斑玄武岩的地球化学特征,起源于尖晶石二辉橄榄岩12%~25%的部分熔融,变质安山岩与变质英安岩-流纹岩形成于弧下地幔部分熔融,该熔体受到地壳物质混染。LA-ICPMS锆石U-Pb定年表明本群变质安山岩形成于2514±16Ma,而变质流纹岩形成于2522±8Ma,二者均受到~2450和~2300Ma的后期热事件扰动。结合本群变质火山岩的岩石组合、地球化学特征和岩石成因,该套岩石可能形成于活动大陆边缘弧相关构造背景。  相似文献   

14.
The Dexing porphyry copper deposit, part of the circum-Pacific porphyry copper ore belt, is the largest porphyry copper deposit in China. We present new LA–ICP–MS zircon U–Pb and molybdenite Re–Os dating, bulk-rock elemental and Sr–Nd–Pb isotopic as well as in situ zircon Hf isotopic geochemistry for these ore-bearing porphyries, in an attempt to better constrain their petrogenesis. LA–ICP–MS zircon U–Pb dating shows that the Dexing porphyries were emplaced in the early Middle Jurassic (～171 Ma); molybdenite Re–Os dating indicates that the associated Cu–Mo mineralization was contemporaneous (～171 Ma) with the igneous intrusion. The rocks are mainly high-K calc-alkaline and show adakitic affinities, including high Sr and low Y and Yb contents, high Sr/Y and La/Yb ratios, and high Mg# (higher than pure crustal melts). These porphyries have initial 87Sr/86Sr ratios of 0.7044?0.7047, ?Nd(T) values of –1.5 to?+0.6, and ?Hf(T) (in situ zircon) values of?+2.6 to?+4.6. They show unusually radiogenic Pb isotopic compositions with initial 206Pb/204Pb ratios up to 18.41 and 207Pb/204Pb up to 15.61. These isotopic compositions are distinctly different from either Pacific MORB or Yangtze lower crust but are similar to the subducting sediments in the western Pacific trenches. Detailed elemental and isotopic data suggest that the Dexing porphyries were emplaced in a continental arc setting coupled with westward subduction of the palaeo-Pacific plate. Partial melting involved the subducted slab (mainly the overlying sediments), with generated melts interacting with the lithospheric mantle wedge, thereby forming the investigated high-K calc-alkaline porphyry magmas.  相似文献   

15.
We report major and trace element abundances and Sr, Nd andPb isotopic data for Miocene (16·5–11 Ma) calc-alkalinevolcanic rocks from the western segment of the Carpathian arc.This volcanic suite consists mostly of andesites and dacites;basalts and basaltic andesites as well as rhyolites are rareand occur only at a late stage. Amphibole fractionation bothat high and low pressure played a significant role in magmaticdifferentiation, accompanied by high-pressure garnet fractionationduring the early stages. Sr–Nd–Pb isotopic dataindicate a major role for crustal materials in the petrogenesisof the magmas. The parental mafic magmas could have been generatedfrom an enriched mid-ocean ridge basalt (E-MORB)-type mantlesource, previously metasomatized by fluids derived from subductedsediment. Initially, the mafic magmas ponded beneath the thickcontinental crust and initiated melting in the lower crust.Mixing of mafic magmas with silicic melts from metasedimentarylower crust resulted in relatively Al-rich hybrid dacitic magmas,from which almandine could crystallize at high pressure. Theamount of crustal involvement in the petrogenesis of the magmasdecreased with time as the continental crust thinned. A strikingchange of mantle source occurred at about 13 Ma. The basalticmagmas generated during the later stages of the calc-alkalinemagmatism were derived from a more enriched mantle source, akinto FOZO. An upwelling mantle plume is unlikely to be presentin this area; therefore this mantle component probably residesin the heterogeneous upper mantle. Following the calc-alkalinemagmatism, alkaline mafic magmas erupted that were also generatedfrom an enriched asthenospheric source. We propose that bothtypes of magmatism were related in some way to lithosphericextension of the Pannonian Basin and that subduction playedonly an indirect role in generation of the calc-alkaline magmatism.The calc-alkaline magmas were formed during the peak phase ofextension by melting of metasomatized, enriched lithosphericmantle and were contaminated by various crustal materials, whereasthe alkaline mafic magmas were generated during the post-extensionalstage by low-degree melting of the shallow asthenosphere. Thewestern Carpathian volcanic areas provide an example of long-lastingmagmatism in which magma compositions changed continuously inresponse to changing geodynamic setting. KEY WORDS: Carpathian–Pannonian region; calc-alkaline magmatism; Sr, Nd and Pb isotopes; subduction; lithospheric extension  相似文献   

16.
In the Northern Andes of Ecuador, a broad Quaternary volcanic arc with significant across-arc geochemical changes sits upon continental crust consisting of accreted oceanic and continental terranes. Quaternary volcanic centers occur, from west to east, along the Western Cordillera (frontal arc), in the Inter-Andean Depression and along the Eastern Cordillera (main arc), and in the Sub-Andean Zone (back-arc). The adakite-like signatures of the frontal and main arc volcanoes have been interpreted either as the result of slab melting plus subsequent slab melt–mantle interactions or of lower crustal melting, fractional crystallization, and assimilation processes. In this paper, we present petrographic, geochemical, and isotopic (Sr, Nd, Pb) data on dominantly andesitic to dacitic volcanic rocks as well as crustal xenolith and cumulate samples from five volcanic centers (Pululagua, Pichincha, Ilalo, Chacana, Sumaco) forming a NW–SE transect at about 0° latitude and encompassing the frontal (Pululagua, Pichincha), main (Ilalo, Chacana), and back-arc (Sumaco) chains. All rocks display typical subduction-related geochemical signatures, such as Nb and Ta negative anomalies and LILE enrichment. They show a relative depletion of fluid-mobile elements and a general increase in incompatible elements from the front to the back-arc suggesting derivation from progressively lower degrees of partial melting of the mantle wedge induced by decreasing amounts of fluids released from the slab. We observe widespread petrographic evidence of interaction of primary melts with mafic xenoliths as well as with clinopyroxene- and/or amphibole-bearing cumulates and of magma mixing at all frontal and main arc volcanic centers. Within each volcanic center, rocks display correlations between evolution indices and radiogenic isotopes, although absolute variations of radiogenic isotopes are small and their values are overall rather primitive (e.g., εNd = +1.5 to +6, 87Sr/86Sr = 0.7040–0.70435). Rare earth element patterns are characterized by variably fractionated light to heavy REE (La/YbN = 5.7–34) and by the absence of Eu negative anomalies suggesting evolution of these rocks with limited plagioclase fractionation. We interpret the petrographic, geochemical, and isotopic data as indicating open-system evolution at all volcanic centers characterized by fractional crystallization and magma mixing processes at different lower- to mid-crustal levels as well as by assimilation of mafic lower crust and/or its partial melts. Thus, we propose that the adakite-like signatures of Ecuadorian rocks (e.g., high Sr/Y and La/Yb values) are primarily the result of lower- to mid-crustal processing of mantle-derived melts, rather than of slab melts and slab melt–mantle interactions. The isotopic signatures of the least evolved adakite-like rocks of the active and recent volcanoes are the same as those of Tertiary ”normal” calc-alkaline magmatic rocks of Ecuador suggesting that the source of the magma did not change through time. What changed was the depth of magmatic evolution, probably as a consequence of increased compression induced by the stronger coupling between the subducting and overriding plates associated with subduction of the aseismic Carnegie Ridge.  相似文献   

17.
The subduction system in southern Patagonia provides direct evidence for the variability of the position of an active continental arc with respect to the subducting plate through time, but the consequences on the arc magmatic record are less well studied. Here we present a geochemical and geochronological study on small plutons and dykes from the upper crust of the southern Patagonian Andes at ~?51°S, which formed as a result of the subduction of the Nazca and Antarctic plates beneath the South American continent. In situ U–Pb geochronology on zircons and bulk rock geochemical data of plutonic and dyke rocks are used to constrain the magmatic evolution of the retro-arc over the last 30 Ma. We demonstrate that these combined U–Pb and geochemical data for magmatic rocks track the temporal and spatial migration of the active arc, and associated retro-arc magmatism. Our dataset indicates that the rear-arc area is characterized by small volumes of alkaline basaltic magmas at 29–30 Ma that are characterized by low La/Nb and Th/Nb ratios with negligible arc signatures. Subsequent progressive eastward migration of the active arc culminated with the emplacement of calc-alkaline plutons and dikes?~?17–16 Ma with elevated La/Nb and Th/Nb ratios and typical subduction signatures constraining the easternmost position of the southern Patagonian batholith at that time. Geochemical data on the post-16 Ma igneous rocks including the Torres del Paine laccolith indicate an evolution to transitional K-rich calc-alkaline magmatism at 12.5?±?0.2 Ma. We show that trace element ratios such as Nb/Ta and Dy/Yb systematically decrease with increasing SiO2, for both the 17–16 Ma calc-alkaline and the 12–13 Ma K-rich transitional magmatism. In contrast, Th/Nb and La/Nb monitor the changes in the source composition of these magmas. We suggest that the transition from the common calc-alkaline to K-rich transitional magmatism involves a change in the source component, while the trace element ratios, such as Nb/Ta and Dy/Yb, of derivative higher silica content liquids are controlled by similar fractionating mineral assemblages. Analysis of a global compilation of Nb/Ta ratios of arc magmatic rocks and simple geochemical models indicate that amphibole and variable amounts of biotite exert a major control on the low Dy/Yb and Nb/Ta of derivative granitic liquids. Lastly, we suggest that the low Nb/Ta ratio of silica-rich magmas is a natural consequence of biotite fractionation and that alternative models such as amphibolite melting in subduction zones and diffusive fractionation are not required to explain the Nb/Ta ratio of the upper continental crust.  相似文献   

18.
Quaternary lavas from the NE Japan arc show geochemical evidenceof mixing between mantle-derived basalts and crustal melts atthe magmatic front, whereas significant crustal signals arenot detected in the rear-arc lavas. The along-arc chemical variationsin lavas from the magmatic front are attributable almost entirelyto geochemical variations in the crustal melts that were mixedwith a common mantle-derived basalt. The mantle-derived basaltshave slightly enriched Sr–Pb and depleted Nd isotopiccompositions relative to the rear-arc lavas, but the variationis less pronounced if crustal contributions are eliminated.Therefore, the source mantle compositions and slab-derived fluxesare relatively uniform, both across and along the arc. Despitethis, incompatible element concentrations are significantlyhigher in the rear-arc basalts. We examine an open-system, fluid-fluxedmelting model, assuming that depleted mid-ocean ridge basalt(MORB)-source mantle melted by the addition of fluids derivedfrom subducted oceanic crust (MORB) and sediment (SED) hybridsat mixing proportions of 7% and 3% SED in the frontal- and rear-arcsources, respectively. The results reproduce the chemical variationsfound across the NE Japan arc with the conditions: 0·2%fluid flux with degree of melting F = 3% at 2 GPa in the garnetperidotite field for the rear arc, and 0·7% fluid fluxwith F = 20% at 1 GPa in the spinel peridotite field beneaththe magmatic front. The chemical process operating in the mantlewedge requires: (1) various SED–MORB hybrid slab fluidsources; (2) variable amounts of fluid; (3) a common depletedmantle source; (4) different melting parameters to explain across-arcchemical variations. KEY WORDS: arc magma; crustal melt; depleted mantle; NE Japan; Quaternary; slab fluid  相似文献   

19.
Summary Telluride-bearing gold deposits of the Pingyi area, western Shandong, China, are located on the southeastern margin of the North China Craton. There are two main types of deposits: (i) mineralized cryptoexplosive breccia, e.g., Guilaizhuang; and (ii) stratified, finely-disseminated mineralization hosted in carbonate rocks, e.g., Lifanggou and Mofanggou deposits. In Guilaizhuang, the cryptoexplosive breccia is formed within rocks of the Tongshi complex and Ordovician dolomite. The mineralization is controlled by an E–W-trending listric fault. Stratified orebodies of the Lifanggou and Mofanggou deposits are placed along a NE-trending, secondary detachment zone. They are hosted within dolomitic limestone, micrite and dolomite of the Early-Middle Cambrian Changqing Group. The mineralization in the ore districts is considered to be related to the Early Jurassic Tongshi magmatic complex that formed in a continental arc setting on the margin of the North China Craton. The host rocks are porphyritic and consist predominantly of medium- to fine-grained diorite and pyroxene (hornblende)-bearing monzonite. SHRIMP U–Pb zircon dating of diorites give a 206Pb/238U weighted mean age of 175.7 ± 3.8 Ma. This is interpreted as representing the crystallization age of the Tongshi magmatic complex. Considering the contact relationships between the magmatic and host sedimentary rocks, as well as the genetic link with the deposits, we conclude that this age is relevant also for the formation of mineralization in the Pingyi area. We hence consider that the deposits formed in the Jurassic. The principal gold minerals are native gold, electrum and calaverite. Wall-rock alteration comprises pyritization, fluoritization, silicification, carbonatization and chloritization. Fluid inclusion studies indicate that all the analyzed inclusions are of two-phase vapor–liquid NaCl–H2O type. Homogenization temperatures of the fluid inclusions vary from 103 °C to 250 °C, and the ice melting temperatures range from −2.5 °C to −13.5 °C, corresponding to a salinity range of 4.65 to 17.26 wt.% NaCl equiv. The δ34S values of pyrite associated with gold mineralization exhibit a narrow range of −0.71 to + 2.99‰, implying that the sulfur was probably derived from the mantle and/or dioritic magma. The δ13CPDB values of the fluid inclusions in calcite range from −7.3 to 0.0‰. The δ18OSMOW values of vein quartz and calcite range from 11.5 to 21.5‰, corresponding to δ18Ofluid values of −1.1 to 10.9‰; δD values of the fluid inclusions vary between −70 and −48‰. The isotope data for all three deposits suggest mixing of ore-forming fluids derived from the mantle and/or magma with different types of fluids at shallow levels. Pressure release and boiling of the fluids, as well as fluid-rock interaction (Lifanggou and Mofanggou) and mixing of magmatically-derived fluids with meteoritic waters (Guilaizhuang) played an important role in the ore-forming processes.  相似文献   

20.
Middle to Late Jurassic plutonic rocks in the central Mojave Desert represent the continuation of the Sierran arc south of the Garlock fault. Rock types range from calc-alkaline gabbro to quartz monzonite. Chemical and isotopic data indicate that petrologic diversity is attributable to mixing of crustal components with mantle melts. Evidence for magma mixing is scarce in most plutons, but emplacement and injection of plutons into preexisting wallrocks (e.g. pendants of metasedimentary rocks) suggests that assimilation may be locally important. Field and petrographic evidence and major and trace element data indicate that the gabbros do not represent pure liquids but are, at least partly, cumulates. The cumulate nature of the gabbros coupled with field evidence for open-system contamination means that trace element contents of gabbros cannot be used to fingerprint the Jurassic mantle source, nor can isotopic data be unequivocally interpreted to reflect the isotopic composition of the mantle. Correlation of Sr and Nd isotropic composition with bulk composition allows some constraints to be placed on the mantle isotopic signature. Gabbros and mafic inclusions from localities north of Barstow, CA have the most depleted mantle-like isotopic signatures (Sr ( i )≈0.705 and ɛNd (t)=≈0 to +1). However, these rocks have likely seen some contamination as well, so the mantle source probably has an even more depleted character. Gabbros with the lowest Sr( i ) and highest ɛNd (t) are also characterized by the highest 207Pb/204Pb and 206Pb/204Pb in the entire data set. This may be a feature of the mantle component in the Jurassic arc indicative of minor source contamination with subducted sediment as has been observed in modern continental arcs. Locally exposed Precambrian basement and metasedimentary rocks have appropriate Sr, Nd and Pb isotopic signatures for the crustal end members and are possible contaminants. Incorporation of these components through combined anatexis and assimilation can explain the observed spread in isotopic composition. Evidence for a depleted mantle component in these gabbros contrasts with the enriched subcontinental mantle component in Jurassic arc plutons further to the east and suggests there may have been a major mantle lithosphere boundary between the two areas as far back as the Late Jurassic. Crustal boundaries and isotopic provinces defined on the basis of initial isotopic composition (Sr( i )=0.706 isopleth) are difficult to delineate because of the correlation of bulk composition with Sr and Nd isotopic composition and because values may differ depending on the age of the rocks sampled within a given area. Data from plutons intruded into rocks known or inferred to be Precambrian are, however, shifted dramatically (highest Sr( i ) and lowest ɛNd(t)) toward Precambrian values. The least isotopically evolved rocks (lowest Sr( i ) and highest ɛNd(t)) occur within the eugeoclinal belt of the Mojave Desert. This zone has been previously identified as a Precambrian rift zone but more likely represents a zone where mantle magmas have been intruded into isotopically similar crustal rocks of the eugeocline with minor input from old Precambrian crust. Received: 12 August 1993/Accepted: 8 July 1994  相似文献   

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