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1.
为揭示川西九龙白台花岗岩成因及其与稀有金属成矿的关系,笔者等对白台花岗岩开展了岩相学、岩石地球化学、LA-ICP-MS锆石U-Pb年代学、锆石微量元素地球化学、Hf同位素地球化学测试。结果显示,白台黑云母二长花岗岩具高SiO2(69.01%～70.55%)、高K2O(3.86%～4.99%)、高碱(K2O+Na2O=7.41%～8.18%),低CaO(1.49%～2.2%)、低MgO(0.44%～0.57%)等特征,里特曼指数σ=2.03～2.43,A/CNK=1.07～1.14,为弱过铝质的高钾钙碱性系列岩石;微量元素特征显示相对富集Rb、K等大离子亲石元素,相对亏损Nb、P、Hf等高场强元素;球粒陨石标准化的稀土元素配分模式为明显的轻稀土富集和重稀土亏损的右倾型。白台黑云母二长花岗岩锆石U-Pb年龄为(213～212)Ma,εHf(t)值为-7.4～-1.1,Hf同位素二阶模式年龄TDM2为(1.6～1.2)Ga。研究结果表明,白台花岗岩形成于后碰撞伸...  相似文献   

2.
义敦岛弧带晚中生代侵入岩体目前仍缺乏高精度的年代学数据制约,其成因也存在争论。作者首次在岛弧带中段夏塞银铅锌多金属矿区发现与成矿关系密切的黑云母二长花岗岩。本文对其开展了年代学、地球化学和Hf同位素分析,探讨成因及构造背景。LA-ICP-MS锆石U-Pb定年结果为103±1 Ma(MSWD=0.5),为早白垩世晚期岩浆活动产物。花岗岩属高钾钙碱性岩系,具有高硅、富碱和铁、贫钙和镁特征,Si O2含量为72.94%~74.98%,K2O+Na2O=7.56%~8.08%,铝饱和指数A/CNK=1.06~1.10,属弱过铝质岩石。岩石富集Zr、Hf等高场强元素和U、Th等大离子亲石元素,明显亏损Ba和Sr。REE具有明显的Eu负异常(δEu=0.13~0.25),总体呈较陡右倾的LREE富集和HREE相对亏损特征。岩相学和地球化学显示其为铝质A型花岗岩。Hf同位素组成εHf(t)=–2.7~0.6,二阶段模式年龄TDM2=925~1095 Ma。地球化学及Hf同位素揭示夏塞岩体为软流圈地幔与壳源长英质岩浆混合成因,并经历了斜长石、正长石和褐帘石等矿物的分离结晶。夏塞花岗岩体具有后碰撞花岗岩特征,形成于早白垩世晚期弧-陆碰撞造山后伸展构造背景。  相似文献   

3.
张垚垚  刘凯  何庆成  童珏  邓岳飞  余成华  孙军亮  余廷溪  郭骏瀚  王书训 《地质论评》2023,69(1):2023010013-2023010013
武功山造山带位于华夏地块与扬子地块碰撞缝合带南侧,记录了新元古代以来的多次构造运动。本文对其中的黑云母二长花岗岩和二云母二长花岗岩进行了全面的矿物学、岩石地球化学、锆石U- Pb同位素年代学及Lu—Hf同位素研究。LA- ICP- MS锆石U- Pb同位素年代学研究指示武功山黑云母二长花岗岩和二云母二长花岗岩结晶于早志留世（441. 6~442. 2 Ma）。武功山早志留世花岗岩具有富硅（SiO2含量为67. 43%~73. 06%）、富碱（Na2O+K2O含量为6. 47%~8. 46%）、贫钙（CaO=0. 78%~2. 64%）、贫镁（MgO=0. 46%~1. 61%）等特征,为强过铝质高钾钙碱性花岗岩（A/CNK=1. 09~1. 35）。同时,岩相学和地球化学指示岩石属于亚碱性系列,分异程度较低,ΣREE较低,轻重稀土分异程度较高,为S型花岗岩且岩浆源区物相为角闪石+斜长石+石榴子石。结合花岗岩锆石fLu/Hf 值均小于-0. 9,εHf（t）均为负值（-6. 7到-4. 8）,指示岩浆来源于古元古代古老陆壳物质,形成于陆内造山构造背景下,为武功山地区对武夷—云开造山运动的响应。  相似文献   

4.
耿雯  秦江锋  李永飞  赖绍聪 《地质通报》2014,33(9):1333-1341
对张广才岭南部一面坡花岗岩的地质学、岩石学、地球化学及锆石U-Pb年龄研究表明,岩石富硅富铝,属于过铝质岩石(A/CNK=1.04~1.07),全碱(K2O+Na2O)含量为8.24%~8.85%,K2O/Na2O值为1.58~1.68,属于高钾钙碱性系列I型花岗岩。岩石富集LREE、Rb、Th、U、K,相对亏损Nb、Ta、P、Ti,具有明显的Eu负异常,LA-ICP-MS锆石206Pb/238U年龄加权平均值为211Ma±4Ma(MSWD=1.4,2σ),代表了花岗岩的结晶年龄。岩石具有相对亏损的锆石Hf同位素组成(εHf(t)=+1.75~+13.81),TDM2为367~1136Ma。结合区域构造环境分析,认为一面坡晚三叠世花岗岩属于I型花岗岩,可能形成于后碰撞伸展构造环境,是岩石圈伸展阶段新增生下地壳物质发生部分熔融的产物。  相似文献   

5.
对湖南中生代的五峰仙岩体进行了锆石SHRIMP U-Pb定年和岩石学、岩石地球化学分析。该岩体主要由印支期的中粒斑状黑云母二长花岗岩、细粒二云母二长花岗岩组成。本次获得黑云母二长花岗岩的锆石U-Pb年龄(233.5±2.5)Ma,表明形成于晚三叠世;结合已发表的岩体年龄资料,五峰仙岩体侵位于236~233.5 Ma和221.6 Ma,具有多阶段岩浆活动特点。五峰仙花岗岩具有高的w(SiO2)、w(P2O5),含过铝质的白云母,表现为弱铝质、强铝质岩石;微量元素方面,大离子元素Rb、Th、U富集,Nb、Ba、Sr、Ti亏损明显,稀土元素配分模式右倾,轻稀土元素富集,Eu亏损相对明显以及高的Rb/Sr比值,为高成熟度陆壳物质重熔的S型花岗岩。黑云母花岗岩中发育暗色微粒包体,具淬冷结构、含长石捕获晶及呈塑形变等特征的包体为岩浆混合成因,该类花岗岩中锆石Hf同位素εHf(t)值较高,为-4.4~0.7,Hf同位素的两阶段模式年龄TDM2值为1 534~1 216Ma,变化范围较大,可能是受幔源岩浆作用所致。五峰仙岩体是在印支板块向华南板块俯冲碰撞期后(变质基底年龄258~243Ma)及华南板块与华北板块的碰撞期间(超高压变质峰期在238~218Ma)华南内陆由挤压向伸展转换的背景下形成的。  相似文献   

6.
东昆仑造山带东段五龙沟金矿田内首次发现晚志留世A型花岗岩体.对其开展了锆石U-Pb年代学、岩石地球化学、Nd及Hf同位素研究,探讨岩体成因和构造背景.岩体LA-ICP-MS锆石U-Pb定年结果为420±3 Ma,为晚志留世岩浆活动产物.岩石具有高SiO2（76.0%~78.4%）、K2O（4.64%~5.22%）和Na2O（2.93%~3.25%）含量,低FeOT（0.98%~1.45%）、MgO（0.11%~0.22%）和CaO（0.27%~0.79%）含量特征.样品富集大离子亲石元素（Rb、K、La）和LREE,亏损高场强元素（Nb、P、Ti）和HREE,具有强烈的Eu负异常（Eu/Eu*=0.09~0.12）.该岩体104×Ga/Al比值为3.09~3.15,具有A型花岗岩的特征.全岩εNd（t）=-2.5~-2.2,对应的二阶段模式年龄tDM2（Nd）=1 339~1 365 Ma.锆石εHf（t）=-2.8~+2.1,二阶段模式年龄tDM2（Hf）=1 269~1 583 Ma.地球化学、Nd及Hf同位素揭示该岩体为软流圈地幔部分熔融形成的幔源岩浆与其诱发的古老地壳物质混合形成.构造判别图解指示岩体具有A2型花岗岩特征,形成于后碰撞伸展构造环境.结合和勒冈那仁和冰沟A型花岗岩体,认为东昆仑地区至少在晚志留世已进入伸展阶段.   相似文献   

7.
李治华  李碧乐  李鹏 《地质学报》2020,94(12):3625-3642
本文报道了柴北缘滩间山地区独树沟金矿区花岗斑岩的地球化学、锆石U- Pb定年和Hf同位素的研究结果。全岩化学分析显示岩石具有富硅（SiO2=75. 23%~77. 28%）、钠（Na2O/K2O=1. 71~2. 41）,贫铁（TFe2O3=1. 04%~3. 24%）、镁（MgO=0. 28%~0. 39%）、钙（CaO=0. 23%~0. 75%）、铝（Al2O3=13. 09%~13. 73%）的特征;样品富集大离子亲石元素如Rb、K、Th和U,明显亏损高场强元素Nb、Ta、Ti和 P,富集轻稀土元素,亏损重稀土元素,岩石具有较强的Eu负异常（δEu=0. 49~0. 53）,分异指数DI为90. 76~93. 71,指示岩石发生了较强的结晶分异作用,通过与邻区花岗岩进行特征对比,判断独树沟花岗斑岩为高分异I型花岗岩;锆石U- Pb定年显示,独树沟花岗斑岩形成于350. 8±1. 7Ma;锆石Hf同位素显示,独树沟花岗斑岩的锆石εHf( t )值为+1. 82~+9. 19,平均值为+6. 85,二阶段模式年龄（ t DM2）为768~1238Ma,独树沟花岗斑岩的Hf同位素组成变化较大,指示其源区物质组成较为复杂,以新元古代新生地壳物质为主,有中元古代甚至更古老的地壳物质存在。结合柴北缘古生代构造演化历史,认为独树沟花岗斑岩形成于早古生代碰撞造山之后的伸展环境。  相似文献   

8.
中国东南部南岭地区广泛出露以弱过铝质黑云母二长花岗岩和黑云母钾长花岗岩为主的燕山早期花岗质岩石,其成因有待进一步研究。大东山岩体岩性主要为黑云母二长花岗岩和黑云母钾长花岗岩,两个样品的SHRIMP锆石U-Pb 年龄为165±2 Ma 和159±2 Ma,与区域南岭系列的黑云母花岗岩的主要形成时代一致。花岗岩样品以高硅（SiO2 > 72%）、高钾（K2O/Na2O > 1.6）、富碱（K2O + Na2O = 7.36% ~ 9.31%）和弱过铝质（集中于ASI = 1.00 ~ 1.11）为特征。微量和稀土元素组成上,岩体富Rb, Th 和LREE,贫Ba, Nb, Sr, P 和Ti, Eu 负异常显著（δEu = 0.06 ~ 0.34）。多数样品的Zr,Ce, Nb 和Y 含量总和小于350×10-6,10 000 × Ga/Al 值低于典型的A 型花岗岩。同位素组成上,样品具有高I sr（ 0.7123 ~ 0.7193）和低εN（d t）（-9.3~ -11.5）的特点,两阶段Nd 模式年龄为1.70~1.89 Ga ;与全岩εNd（t）不同,岩浆锆石的εHf（t）具有较大的变化范围（-3.5~ -11.8）。矿物学及地球化学结果表明大东山是一个高分异的I 型花岗岩岩体。岩体岩浆很可能是由元古代火成岩石部分熔融形成,并伴随有少量年轻或新生幔源物质的加入,岩浆上升侵位的过程中发生混合、结晶分异作用。  相似文献   

9.
新寮岽铜多金属矿是近年来在粤东地区新发现的一个铜矿床。对该矿床中与成矿关系密切的石英闪长岩进行了锆石U-Pb年龄、地球化学、Hf同位素研究,以约束其形成时代和岩石成因。测得石英闪长岩LA-ICP-MS锆石U-Pb年龄为161±1Ma(n=25,MSWD=0.57),被解释为岩体的成岩年龄。地球化学数据显示,石英闪长岩具有碱含量中等(Na2O+K2O=3.99%~5.05%),高镁(Mg O=4.53%~4.91%)的特征,属准铝质钙碱性系列。稀土和微量元素特征表明,其富集轻稀土元素和大离子亲石元素(K、Rb、Ba、Th、U),亏损重稀土元素和高场强元素(Nb、Ta、Ti、P),具弱负Eu异常(δEu=0.68~0.76)。电子探针分析结果表明,石英闪长岩中黑云母为镁质黑云母,具环带结构,斜长石为拉长石。锆石Hf同位素分析结果表明,石英闪长岩εHf(t)为-5.8~2.7,tDM2=1.03~1.58Ga。岩石地球化学和锆石Hf同位素组成特征表明,石英闪长岩源区较复杂,为壳幔混合源,可能为俯冲板片部分熔融并与楔形地幔橄榄岩相互作用形成,且岩浆上侵过程中有古老地壳物质的混染。综合岩石地球化学、矿物化学及Hf同位素特征,结合区域构造演化史和前人研究成果,推测岩体形成于俯冲背景下的活动大陆边缘环境。  相似文献   

10.
辽宁兴城新立屯地区岩浆杂岩主要由4种不同的岩石单元组成,分别为似斑状黑云母二长花岗岩,中细粒石英闪长岩,花岗细晶岩和花岗伟晶岩,前两者分布广泛且为研究区的主要岩石单元,后两者则呈脉状侵入到前两者中。应用LA-ICP-MS锆石U-Pb定年方法,测得似斑状黑云母二长花岗岩,中细粒石英闪长岩及花岗细晶岩的年龄分别为2 496±18 Ma,2 490±19 Ma,2 479±29 Ma,形成于古元古代早期。结合野外地质特征,侵位顺序由早到晚依次为:似斑状黑云母二长花岗岩,中细粒石英闪长岩,花岗细晶岩,花岗伟晶岩。岩石地球化学特征显示,新立屯地区岩浆杂岩主量元素方面具高硅(SiO2=61.38%~74.99%),富碱(Na2O+K2O=6.86%~9.41%),富Mg#(56~70)特征;A/CNK=0.91~1.18,属准铝质-过铝质岩石;微量元素方面,相对富集轻稀土元素,亏损重稀土元素,具有Eu异常(δEu=0.50~0.96);富集大离子亲石元素,亏损高场强元素;锆石Lu-Hf同位素特征εHf(t)值为-1.12~+6.13;TDM2(Hf)介于2 594~2 937 Ma,显示该套岩浆杂岩可能为地幔物质加入新生地壳再造的产物。  相似文献   

11.
Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km2 and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.  相似文献   

12.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations.  相似文献   

13.
The contents of As, Cd, Cu, Cr, Mg, Mn, Ni, Pb and Zn have been determined in sediment and water samples from Valle de las Garzas estuary and Port Manzanillo (Colima, Mexico) using ICP-AES. The concentrations of these elements were used for a comparative study to determine the distribution of heavy metals and to evaluate which elements reflect natural or anthropogenic backgrounds. For this purpose, seven sampling points were selected: Four of them correspond to the lagoon, and three were situated in the port. Statistical analysis of the mineral content was assessed. Initially, data comparison was assessed by statistical tests for each variable. Principal component analysis was then applied considering the influence of all variables at the same time by obtaining the distribution of samples according to their scores in the principal component space. In this way, four studies were carried out: (1) study of sediments collected during the dry season; (2) study of sediments collected during the rainy season; (3) comparative study between sediments from rainy and dry season; and (4) study of water composition collected during rainy season. From the results of the performed analyses, it can be concluded that metals distribution pattern reflected natural and anthropogenic backgrounds (e.g., sediments from the lagoon, situated at the beginning of the rain channel, presented high contents of Zn and Cu, perhaps related to anthropogenic activities or the influence of igneous sediments).  相似文献   

14.
This article advances critical geographies of youth through examining the spatiality implicit in the imagined futures of young women in rural India. Geographers and other scholars of youth have begun to pay more attention to the interplay between young people’s past, present, and imagined futures. Within this emerging body of scholarship the role of the family and peer group in influencing young people’s orientations toward the future remain underexamined. Drawing on eleven months of ethnographic fieldwork, my research focuses on a first generation of college-going young women from socioeconomically marginalized backgrounds in India’s westernmost state of Gujarat. I draw on the “possible selves” theoretical construct in order to deploy a flexible conceptual framework that links imagined post-educational trajectories with motivation to act in the present. In tracing the physical movement of these young women as they navigate and complete college, my analysis highlights the ways in which particular kinds of spaces and spatial arrangements facilitate and limit intra- and inter-generational contact, and the extent to which this affects young women’s conceptions of the future. I conclude by considering the wider implications of my research for ongoing debates surrounding youth transitions, relational geographies of age, and education in the Global South.  相似文献   

15.
Partition coefficients of Hf,Zr, and REE between zircon,apatite, and liquid   总被引：25，自引：2，他引：25  
Concentration ratios of Hf, Zr, and REE between zircon, apatite, and liquid were determined for three igneous compositions: two andesites and a diorite. The concentration ratios of these elements between zircon and corresponding liquid can approximate the partition coefficient. Although the concentration ratios between apatite and andesite groundmass can be considered as partition coefficients, those for the apatite in the diorite may deviate from the partition coefficients. The HREE partition coefficients between zircon and liquid are very large (100 for Er to 500 for Lu), and the Hf partition coefficient is even larger. The REE partition coefficients between apatite and liquid are convex upward, and large (D=10–100), whereas the Hf and Zr partition coefficients are less than 1. The large differences between partition coefficients of Lu and Hf for zircon-liquid and for apatite-liquid are confirmed. These partition coefficients are useful for petrogenetic models involving zircon and apatite.  相似文献   

16.
Emilio Biagini 《GeoJournal》1998,44(2):163-165
  相似文献   

17.
《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2.  相似文献   

18.
Models have become so fashionable that many scientists and engineers cannot imagine working without them. The predominant use of computer codes to execute model calculations has blurred the distinction between code and model. The recent controversy regarding model validation has brought into question what we mean by a ‘model’ and by ‘validation.’ It has become apparent that the usual meaning of validation may be common in engineering practice and seems useful in legal practice but it is contrary to scientific practice and brings into question our understanding of science and how it can best be applied to such problems as hazardous waste characterization, remediation, and aqueous geochemistry in general. This review summarizes arguments against using the phrase model validation and examines efforts to validate models for high-level radioactive waste management and for permitting and monitoring open-pit mines. Part of the controversy comes from a misunderstanding of ‘prediction’ and the need to distinguish logical from temporal prediction. Another problem stems from the difference in the engineering approach contrasted with the scientific approach. The reductionist influence on the way we approach environmental investigations also limits our ability to model the interconnected nature of reality. Guidelines are proposed to improve our perceptions and proper utilization of models. Use of the word ‘validation’ is strongly discouraged when discussing model reliability.  相似文献   

19.
Materials and energy are the interdependent feedstocks of economic systems, and thermodynamics is their moderator. It costs energy to transform the dispersed minerals of Earth's crust into ordered materials and structures. And it costs materials to collect and focus the energy to perform work — be it from solar, fossil fuel, nuclear, or other sources. The greater the dispersal of minerals sought, the more energy is required to collect them into ordered states.But available energy can be used once only. And the ordered materials of industrial economies become disordered with time. They may be partially reordered and recycled, but only at further costs in energy. Available energy everywhere degrades to bound states and order to disorder — for though entropy may be juggled it always increases. Yet industry is utterly dependent on low entropy states of matter and energy, while decreasing grades of ore require ever higher inputs of energy to convert them to metals, with ever increasing growth both of entropy and environmental hazard.Except as we may prize a thing for its intrinsic qualities — beauty, leisure, love, or gold — low-entropy is the only thing of real value. It is worth whatever the market will bear, and it becomes more valuable as entropy increases. It would be foolish of suppliers to sell it more cheaply or in larger amounts than their own enjoyment of life requires, whatever form it may take. For this reason, and because of physical constraints on the availability of all low-entropy states, the recent energy crises is only the first of a sequence of crises to be expected in energy and materials as long as current trends continue.The apportioning of low-entropy states in a modern industrial society is achieved more or less according to the theory of competitive markets. But the rational powers of this theory suffer as the world grows increasingly polarized into rich, over-industrialized nations with diminishing resource bases and poor, supplier nations with little industry. The theory also discounts posterity, the more so as population density and percapita rates of consumption continue to grow. A new social, economic, and ecologic norm that leads to population control, conservation, and an apportionment of low-entropy states across the generations is needed to assure to posterity the options that properly belong to it as an important but voiceless constituency of the collectivity we call mankind.
Zusammenfassung Rohstoffe und Energie sind die Grundlagen unseres ökonomischen Systems, das von den Gesetzen der Thermodynamik bestimmt wird. Es kostet Energie, um die auf der Erde verteilten Rohstoffe diesem System zuzuführen. Andererseits braucht man Rohstoffe, um die Energie nutzbar zu machen.Die verfügbare Energie kann nur einmal genutzt werden und das Material verbraucht sich. Verbrauchtes Material kann teilweise zur weiteren Nutzung zurückgeführt werden, das kostet wiederum Energie. Die verfügbare Energie nimmt überall ab, und einmal geschaffene Ordnung gerät wieder in Unordnung — das heißt, die Entropie des Systems nimmt ständig zu. Die Industrie ist jedoch abhängig von einem niedrigen Entropiezustand sowohl der Materie als auch der Energie.Je ärmer die Erze sind, um so höher wird die Energie sein, um sie in Metalle umzuwandeln, wobei die Entropie und die Belastung der Umwelt ständig zunimmt.Außer den Dingen, die wir wegen höherer ideeller Werte schätzen, ist eine niedrige Entropie der einzige realistische Wertmaßstab, und der wirkliche Wertzuwachs ist nur an einer höheren Entropie zu messen. Es ist unverantwortlich, Dinge, die eine höhere Entropie bedingen, billiger zu verkaufen oder in größerer Menge zu erzeugen, als unbedingt notwendig ist. Da wir dies heute in unserem Handeln nicht berücksichtigen, ist die derzeitige Energiekrise nur der Anfang einer Folge von Krisen, die Energie und Rohstoffe betreffen, solange wir nicht umdenken.Die Verteilung von niedriger Entropie in einer modernen Industriegesellschaft wird mehr oder weniger nach dem Prinzip der konkurrierenden Märkte erreicht. Das selbstregulierende System gerät jedoch mit zunehmender Polarisierung in reiche Industrienationen mit abnehmenden Ressourcen und armen Nationen mit geringer Industrialisierung in Unordnung. Dieses Prinzip berücksichtigt auch nicht die Nachwelt, vor allem wenn die Bevölkerungsdichte stetig zunimmt und die Konsumbedürfnisse anwachsen. Es sind neue soziale, ökonomische und ökologische Normen notwendig, die zur Populationskontrolle, zur Erhaltung der Umwelt und zu einem Zustand niedriger Entropie für zukünftige Generationen führen. Die nach uns kommenden Menschen haben ein Anrecht darauf.
Résumé Matériaux et énergie sont les sources des systèmes économiques et sont régis par les lois de la thermodynamique. Il faut de l'énergie pour transformer les ressources minérales dispersées dans la croûte terrestre en matériaux et structures ordonnancées. Et il faut des matériaux pour receuillir et concentrer l'énergie, qu'elle soit solaire ou atomique, ou provienne de combustibles fossiles ou d'autres sources. Plus les minéraux recherchés sont dispersés et plus est côuteuse l'énergie pour leur donner une ordonnance.Or l'énergie disponsible ne peut être utilisée qu'une seule fois. Et les matériaux ordonnancés des économies industrielles se dégradent avec le temps. Ils peuvent être remis partiellement en état et recyclés, mais pour cela il faut de nouveau de l'énergie. Partout l'énergie disponible se dégrade et l'ordre devient désordre; -malgré toutes les jongleries possibles l'entropie augmente toujours.L'industrie dépend clairement d'états de basse entropie tant en ce qui concerne les matériaux que l'énergie, tandis que plus pauvres sont les minerais, plus; élevée est l'énergie à mettre en jeu pour en extraire les métaux, avec toujours augmentation à la fois de l'entropie et de la degradation des milieux.A l'exception de ce que nous apprécions pour leur valeur intrinsèque — la beauté, le loisir, l'amour ou l'or — la basse entropie est la seule chose de réelle valeur. Son prix est réglé par le marché, et sa valeur augmente au fur et à mesure que l'entropie s'accroît. Ceux qui en disposent seraient insensés de la vendre à bas prix ou en quantité supérieure à ce qu'exige leur propre niveau de vie. Pour cette raison, et à cause des contraintes physiques liées à la disponibilité en états de basse entropie, la récente crise d'énergie n'est, en ce qui concerne les matières premières et l'énergie, que la première d'une série de crises auxquelles il faut s'attendre aussi longtemps que se poursoit la marche actuelle des étènements.Dans les sociétés industrielles modernes, les approvisionnement en basse entropie s'effectuent plus ou moins conformément à la théorie de la concurrence des marchés. Cependant la rationalité de cette théorie se ressent de l'accentuation croissante de la polarisation, à l'échelle du monde, en nations riches, surindustrialisées, à ressources de base décroissantes, et en nations pauvres, sous-industrialisées, mais fournisseurs de resources-naturelles. De plus cette théorie ne tient pas compte de notre postérité, et ce, en face d'une densité de population et d'un taux de la consommation par tête d'habitant en augmentation continue.Nous avons donc besoin de nouvelles normes sociales, économiques et écologiques qui conduisent au contrôle de la population, à la conservation et à la répartition des états de basse entropie à travers les générations pour assurer à notre postérité les options qui leur riviennent de droit comme une constituante importante, mais encore muette, de la collectivité que nous appelons l'Humanité.
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Dedicated with appreciation to Nicholas Georgescu-Roegen, distinguished economist, realist among cornucopians  相似文献   

20.
The shape of sedimentary particles may carry important information on their history. Current approaches to shape classification (e.g. the Zingg or the Sneed and Folk system) rely on shape indices derived from the measurement of the three principal axes of the approximating tri-axial ellipsoid. While these systems have undoubtedly proved to be useful tools, their application inevitably requires tedious and ambiguous measurements, also classification involves the introduction of arbitrarily chosen constants. Here we propose an alternative classification system based on the (integer) number of static equilibria. The latter are points of the surface where the pebble is at rest on a horizontal, frictionless support. As opposed to the Zingg system, our method relies on counting rather than measuring. We show that equilibria typically exist on two well-separated (micro and macro) scales. Equilibria can be readily counted by simple hand experiments, i.e. the new classification scheme is practically applicable. Based on statistical results from two different locations we demonstrate that pebbles are well mixed with respect to the new classes, i.e. the new classification is reliable and stable in that sense. We also show that the Zingg statistics can be extracted from the new statistics; however, substantial additional information is also available. From the practical point of view, E-classification is substantially faster than the Zingg method.  相似文献   

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