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1.
Late Holocene paleoceanography and climate variability of the Southeastern Beaufort Sea (Canadian Arctic) have been investigated on the basis of sedimentary cores collected over the Mackenzie Slope. Piston, trigger and box cores were sampled at station 803 in 2004 aboard the CCGS Amundsen at 218 m water depth. The chronology of the piston core is constrained by 4 AMS-14C dates, as the sedimentation rate in the box core is assessed from 210Pb data. We obtain a continuous composite sequence covering the last 4600 years, with a sedimentation rate of ~ 140 cm.kyr? 1. Transfer functions (modern analogue technique) based on dinoflagellate cyst (dinocyst) assemblages were used to reconstruct the evolution of sea-surface conditions over the time period covered by the cores.Palynological data reveal that dinocyst assemblages are dominated by Operculodinium centrocarpum sensu lato (mean of 43.3%) throughout the core, with the accompanying taxa Brigantedinium spp. (19.6%), Islandinium minutum (15.6%) and cysts of Pentapharsodinium dalei (13.7%). Four zones have been established on the basis of dinocyst relative abundances. Dinocyst assemblage zone 1 (D1), from 4600 to 2700 cal years BP, is dominated by O. centrocarpum (mean of 49.0%). In zone D2 (2700–1500 cal years BP), the relative abundances of O. centrocarpum decrease (34.4%) in favour of the opportunistic, heterotrophic taxa Brigantedinium spp. (28.8%) and cysts of Polykrikos sp. var. arctic/quadratus (2.8%). Dinocyst zone D3 (1500–30 cal years BP or 450–1920 AD) is characterised by the high relative abundance of the peridinioid taxa I. minutum (19.9%). The last zone (D4), spanning from 1920 to 2004 AD, is again dominated by O. centrocarpum (44.5%), and shows low relative abundances of Brigantedinium spp. and cf. Echinidinium karaense.Quantitative reconstructions of past sea-surface parameters (August sea-surface temperature: SST, August sea-surface salinity: SSS, and duration of sea-ice cover) indicate relatively stable conditions over the last 4.6 kyr, with episodic cooling events (SST of ~ 1.5 °C below the modern value of 6 °C) that took place between 700 and 1820 AD. We associate the last and the longest of these cooling events (1560–1820 AD) with the Little Ice Age. Reconstructed SSS shows decadal oscillations since 1920 AD that we tentatively associate with the accumulation of freshwater by the Beaufort Gyre and the subsequent Great Salinity Anomalies. Our data suggest that similar salinity anomalies could have occurred ca. 1860 and 1790 AD.Stable isotopic data show a slight increase in δ13C values (from ~?27.1‰ at the base to ~?25.8‰ at the top) over the last 4.6 kyr that we associate with the gradual increase in atmospheric CO2 concentration as recorded by Antarctic ice cores. Variations in the δ15N profile suggest variations in Pacific water influence from 4600 to ~ 1300 cal years BP, associated with centennial scale shifts of the Arctic Oscillation phases.  相似文献   

2.
《Marine Geology》2001,172(3-4):265-285
Studies of latest Quaternary continental slope sediments at two localities on the east Australian margin have revealed markedly different responses to late Quaternary sea level fluctuations. Offshore of Noosa, in the sub-tropics, the sediment is predominantly a mixture of fine metastable carbonate, siliciclastic material, and pelagic carbonate. Important features of the stratigraphy include a siliciclastic-dominated facies deposited relatively slowly during the last glacial lowstand (sedimentation rate ≤8 cm/ka), and a calcareous facies, rich in metastable carbonate, deposited more rapidly during the late post-glacial transgression (sedimentation rates 15–24 cm/ka). Highstand and transgressive sedimentation rates are greater than lowstand rates by a factor of 2.5–6 due to increased shelf carbonate productivity after flooding of the mid-shelf. Off Sydney, in temperate latitudes, continental slope sediment is largely a mixture of fine siliciclastic material and pelagic carbonate. Mean sedimentation rates range from 2 to 5 cm/ka over the last four oxygen isotope stages, with mean glacial/interstadial rates higher than Holocene rates by a factor of ∼1.36. This largely reflects the transfer of siliciclastic mud from the shelf to the slope during sea level regression. In both localities, facies changes on the slope are not related to specific sea level states (e.g. lowstand facies, transgressive facies, etc.), but reflect instead the interaction of changing sea level with shelf morphology.  相似文献   

3.
Mass fluxes of diatom opal, planktonic foraminifera carbonate and coccolithophorid carbonate were measured with time-series sediment traps at six sites in the Arabian Sea, Bay of Bengal and Equatorial Indian Ocean (EIOT). The above fluxes were related to regional variations in salinity, temperature and nutrient distribution. Annual fluxes of diatom opal range between 3 and 28 g m−2 yr−1, while planktonic foraminifera carbonate fluxes range between 6 and 23 g m−2 yr−1 and coccolithophorid carbonate fluxes range between 4 and 24 g m−2 yr−1. Annual planktonic foraminifera carbonate to coccolithophorid carbonate ratios range between 0.8 and 2.2 and coccolithophorid carbonate to diatom opal ratios range between 0.5 and 3.3.In the western Arabian Sea, coccolithophorids are the major contributors to biogenic flux during periods of low nutrient concentrations. Coccolithophorid carbonate fluxes decrease and planktonic foraminiferal carbonate and diatom opal fluxes increase when nutrient-rich upwelled waters are advected over the trap site. In the oligotropic eastern Arabian Sea, coccolithophorid carbonate fluxes are high throughout the year. Planktonic foraminiferal carbonate fluxes are the major contributors to biogenic flux in the EIOT. In the northern and central Bay of Bengal, when surface salinity values drop sharply during the SW monsoon, there is a drastic reduction in planktonic foraminiferal carbonate fluxes, but coccolithophorid carbonate and diatom opal fluxes remain steady or continue to increase. Distinctly higher annual molar Sibio/Cinorg (>1) and Corg/Cinorg (>1.5) ratios are observed in the northern and central Bay of Bengal mainly due to lower foraminiferal carbonate production as a result of sharp salinity variations. We can thus infer that the enhanced freshwater supply from rivers should increase oceanic CO2 uptake. Its silicate supply favours the production of diatoms while the salinity drop produces conditions unfavourable for most planktonic foraminifera species.  相似文献   

4.
Previous studies measuring biogenic silica production in the Sargasso Sea, all conducted when no phytoplankton bloom was in progress, have reported a mean rate of 0.4 mmol Si m?2 d?1 and maximum rate of 0.9 mmol Si m?2 d?1, the lowest rates yet recorded in any ocean habitat. During February/March of 2004 and 2005 we studied the effects of late-winter storms prior to seasonal stratification on the production rate, standing stock and vertical export of biogenic silica in the Sargasso Sea. In 2004, alternating storm and stratification events provided pulsed input of nutrients to the euphotic zone. In contrast, nearly constant storm conditions in 2005 caused the mixed layer to deepen to ~350 m toward the end of the cruise. Biogenic silica production rates in the upper 140 m were statistically indistinguishable between years, averaging ~1.0 mmol Si m?2 d?1. In early March 2004, a storm event entrained nutrients into the euphotic zone and, upon stabilization, vertically integrated biogenic silica in the upper 140 m nearly doubled in 2 days. Within 4 days, 75–100% of the accumulated biogenic silica was exported, sustaining a flux to 200 m of ~0.5 mmol Si m?2 d?1 (4× greater than export measured during February and March in the mid-1990s). In 2005, destabilization without stratification increased biogenic silica flux at 200 m up to two-fold above previously measured export in late winter, with little or no increase in water-column biogenic silica. Despite comprising <5% of total chlorophyll, diatoms accounted for an estimated 25–50% of the nitrate uptake in the upper 140 m and 35–97% of the particulate organic nitrogen export from the upper 200 m during both cruise periods. These previously unobserved brief episodes of diatom production and export in response to late-winter storms increase the estimated production and export of diatom-derived material in the Sargasso Sea in late winter by >150%, and increase estimated annual biogenic silica production in this region by ~8%.  相似文献   

5.
Fish farming impact on the seasonal biomass, carbon and nutrient (nitrogen and phosphorus) balance of the endemic Mediterranean seagrass Posidonia oceanica was assessed in the Aegean Sea (Greece) in order to detect changes in magnitude and fate of seagrass production and nutrient incorporation with organic loading of the meadows. Phosphorus concentration in the leaves, rhizomes and roots was enhanced under the cages throughout the study. Standing biomass was diminished by 64% and carbon, nitrogen and phosphorus standing stock by 64%, 61% and 48%, respectively, under the cages in relation to those at the control. Seagrass production decreased by 68% and element (C, N, P) incorporation by 67%, 58% and 58%, respectively, under the cages. Leaf shedding was reduced by 81% and loss of elements (C, N, and P) through shedding by 82%, 74% and 72%, respectively, under the cages. Leaf and element (C, N, P) residual loss rate, accounting for grazing and mechanical breakage of leaves, was decreased by 79%, 85%, 100% and 96%, respectively, at the control station. At the control station, 13.98 g C m?2 yr?1, 1.91 g N m?2 yr?1 and 0.05 g P m?2 yr?1 were produced in excess of export and loss. In contrast, under the cages 12.69 g C m?2 yr?1, 0.31 g N m?2 yr?1 and 0.04 g P m?2 yr?1 were released from the meadow. Organic loading due to fish farm discharges transformed the seagrass meadow under the cages from a typical sink to a source of organic carbon and nutrients.  相似文献   

6.
An intra-annual investigation of the fugacity of CO2 (fCO2) has been conducted in surface waters of the north-eastern shelf of the Gulf of Cádiz (SW Iberian Peninsula) in four cruises made in 2006 and 2007. Intra-annual variability of fCO2 was assessed and is discussed in terms of mixing, temperature and biology. In the study area of the shelf, thermodynamic control over fCO2 predominates from early May to late November, and this is opposite and similar in magnitude to the net biological effect. However, biological control over fCO2 predominates during winter. The results suggest that surface waters in the coastal area are under-saturated with respect to atmospheric CO2 during most of the year; therefore they represent a sink for atmospheric CO2 between November and May (? 1.0 mmol m? 2 day? 1), but a weak source in June (1.3 mmol m? 2 day? 1). In contrast, the coastal ecosystems studied (the lower estuary of Guadalquivir Estuary and Bay of Cádiz) acted as a weak sink for atmospheric CO2 during February (? 1.3 mmol m? 2 day? 1) and as a source between May and November (2.6 mmol m? 2 day? 1). The resulting mean annual CO2 flux in the north-eastern shelf of the Gulf of Cádiz was ? 0.07 mol m? 2 year? 1 (? 0.2 mmol m? 2 day? 1), indicating that the area acts as a net sink on an annual basis.  相似文献   

7.
The Lophelia pertusa community at Viosca Knoll (VK826) is the most extensive found to date in the Gulf of Mexico. As part of a multi-disciplinary study, the physical setting of this area was described using benthic landers, CTD transects and remotely operated vehicle observations. The site was broadly characterised into three main habitats: (1) dense coral cover that resembles biogenic reef complexes, (2) areas of sediment, and (3) authigenic carbonate blocks with sparse coral and chemosynthetic communities. The coral communities were dominated by L. pertusa but also contained numerous solitary coral species. Over areas that contained L. pertusa, the environmental conditions recorded were similar to those associated with communities in the north-eastern Atlantic, with temperature (8.5–10.6 °C) and salinity (~35) falling within the known species niche for L. pertusa. However, dissolved oxygen concentrations (2.7–2.8 ml l?1) and density (σΘ, 27.1–27.2 kg m?3) were lower and mass fluxes from sediment trap data appeared much higher (4002–4192 mg m?2 d?1). Yet, this species still appears to thrive in this region, suggesting that L. pertusa may not be as limited by lower dissolved oxygen concentrations as previously thought. The VK826 site experienced sustained eastward water flow of 10–30 cm s?1 over the 5-day measurement period but was also subjected to significant short-term variability in current velocity and direction. In addition, two processes were observed that caused variability in salinity and temperature; the first was consistent with internal waves that caused temperature variations of 0.8 °C over 5–11 h periods. The second was high-frequency variability (20–30 min periods) in temperature recorded only at the ALBEX site. A further pattern observed over the coral habitat was the presence of a 24 h diel vertical migration of zooplankton that may form part of a food chain that eventually reaches the corals. The majority of detailed studies concerning local environmental conditions in L. pertusa habitats have been conducted within the north-eastern Atlantic, limiting most knowledge of the niche of this species to a single part of an ocean basin. Data presented here show that the corals at VK826 are subjected to similar conditions in temperature, salinity, and flow velocity as their counterparts in the north-east Atlantic, although values for dissolved oxygen and density (sigma-theta: σΘ) are different. Our data also highlight novel observations of short-term environmental variability in cold-water coral habitat.  相似文献   

8.
Benthic fluxes of dissolved inorganic carbon, total alkalinity, oxygen, nutrients, nitrous oxide and methane were measured in situ at three sites of Río San Pedro salt marsh tidal creek (Bay of Cádiz, SW Spain) during three seasons. This system is affected by the discharges of organic carbon and nutrients from the surrounding aquaculture installations. Sediment oxygen uptake rates and inorganic carbon fluxes ranged respectively from 16 to 79 mmol O2 m? 2 d? 1 and from 48 to 146 mmol C m? 2 d? 1. Benthic alkalinity fluxes were corrected for the influence of NH4+ and NO3? + NO2? fluxes, and the upper and lower limits for carbon oxidation rates were inferred by considering two possible scenarios: maximum and minimum contribution of CaCO3 dissolution to corrected alkalinity fluxes. Average Cox rates were in all cases within ± 25% of the upper and lower limits and ranged from 40 to 122 mmol C m? 2 d? 1. Whereas carbon mineralization did not show significant differences among the sites, Cox rates varied seasonally and were correlated with temperature (r2 = 0.72). During winter and spring denitrification was estimated to account for an average loss of 46% and 75%, respectively, of the potentially recyclable N, whereas during the summer no net removal was observed. A possible shift from denitrification to dissimilatory nitrate reduction to ammonium (DNRA) during this period is argued. Dissolved CH4 and N2O fluxes ranged from 5.7 to 47 μmol CH4 m? 2 d? 1 and 4.3 to 49 μmol N–N2O m? 2 d? 1, respectively, and represented in all cases a small fraction of total inorganic C and N flux. Overall, about 60% of the total particulate organic matter that is discharged into the creek by the main fish farm facility is estimated to degrade in the sediments, resulting in a significant input of nutrients to the system.  相似文献   

9.
We have hypothesized that the weekly/biweekly passage of winter storms in the subtropical open ocean destabilizes the water column leading to pulsed NO3? inputs, resulting in new production that is not accounted for in most annual estimates. This paper presents data on nitrogen and carbon cycling in the Sargasso Sea at approximately daily resolution, during the period prior to seasonal stratification in 2004 and 2005; these data permit us to assess the importance of winter storms for introducing NO3? and the contribution of these inputs to annual new and export production. The two sampling years were in stark contrast to each other with 2004 characterized by periods of relative calm between winter storms, and 2005 characterized by nearly continuous storm activity. As a result, temporal variability in mixed layer depth (MLD) and euphotic zone [NO3?] were very different between years. MLDs in 2004 increased to >150 m in response to the passage of storms and then rapidly shoaled to <100 m leading to the pulsed injection of NO3? (~100 nmol l?1) into the lower half of the euphotic zone, while in 2005 MLDs were consistently >300 m and euphotic zone [NO3?]>100 nmol l?1. Despite the very different [NO3?], rates of daily NO3? uptake were similar from year to year because of significant nocturnal uptake in 2004. Similar rates of new production did not translate into similar rates of particulate nitrogen and carbon export however, as observed export from the upper 200 m was 2–5-fold greater in 2004 than in 2005. Furthermore, the decrease of particulate nitrogen and carbon flux with depth between 200 and 400 m in 2004 was substantially lower than in 2005; this is consistent with the observed biological response in which diatoms and coccolithophores exhibited rapid growth following pulsed NO3? inputs in 2004. A combination of data from the Bermuda Testbed Mooring, which provides a longer temporal record than the cruise, and the observations presented in this study show that in the winter of 2004, there were 8–10 storm events that likely resulted in pulsed NO3? inputs. Summed over all the events, new production prior to seasonal stratification was estimated to be ~0.12–0.18 mol N m?2 or ~14–21% of current annual estimates.  相似文献   

10.
The present paper synthesizes data obtained during a multidisciplinary cruise carried out in June 2004 at the continental margin of the northern Bay of Biscay. The data-set allows to describe the different stages of a coccolithophore bloom dominated by Emiliania huxleyi. The cruise was carried out after the main spring phytoplankton bloom that started in mid-April and peaked in mid-May. Consequently, low phosphate (PO4 < 0.2 μM) and silicate (DSi < 2.0 μM) concentrations, low partial pressure of carbon dioxide (pCO2) and high calcite saturation degree in surface waters combined with thermal stratification, probably favoured the blooming of coccolithophores. During the period of the year our cruise was carried out, internal tides induce enhanced vertical mixing at the continental shelf break leading to the injection of inorganic nutrients to surface waters that probably trigger the bloom. The bloom developed as the water-column stratified and as the water mass was advected over the continental shelf, following the general residual circulation in the area. The most developed phase of the bloom was sampled in a remote sensed high reflectance (HR) patch over the continental shelf that was characterized by low chlorophyll-a (Chl-a) concentration in surface waters (<1.0 μg L?1), high particulate inorganic carbon (PIC) concentration (~8 μmol L?1) and coccolithophore abundance up to 57 × 106 cells L?1. Transparent exopolymer particles (TEP) concentrations ranged between 15 and 75 μg C L?1 and carbon content of TEP represented up to 26% of the particulate organic carbon (POC; maximum concentration of 15.5 μmol L?1 in the upper 40 m). Integrated primary production (PP) ranged between 210 and 680 mg C m?2 d?1 and integrated calcification (CAL) ranged between 14 and 140 mg C m?2 d?1, within the range of PP and CAL values previously reported during coccolithophore blooms in open and shelf waters of the North Atlantic Ocean. Bacterial protein production (BPP) measurements in surface waters (0.3–0.7 μg C L?1 h?1) were much higher than those reported during early phases of coccolithophore blooms in natural conditions, but similar to those during peak and declining coocolithophorid blooms reported in mesocosms. Total alkalinity anomalies with respect to conservative mixing (ΔTA) down to ?49 μmol kg?1 are consistent with the occurrence of biogenic precipitation of calcite, while pCO2 remained 15–107 μatm lower than atmospheric equilibrium (372 μatm). The correlation between ΔTA and pCO2 suggested that pCO2 increased in part due to calcification, but this increase was insufficient to overcome the background under-saturation of CO2. This is related to the biogeochemical history of the water masses due to net carbon fixation by the successive phytoplankton blooms in the area prior to the cruise, hence, the investigated area remained a sink for atmospheric CO2 despite calcification.  相似文献   

11.
Cockle (Cerastoderma edule) population dynamics were studied at the southern limit of the distribution of this marine bivalve in Merja Zerga, Morocco. Parameters such as growth, mortality, and production were compared with those of a population at Arcachon Bay (France) a site in the center of the cockle's range. At each sampling period between two and three cohorts were simultaneously observed at each site and the average total abundance was usually higher at Merja Zerga. Recruitment occurred at both sites in spring when temperature rose above 19 °C, independently of the month. In Merja Zerga, winter recruitment was also observed at one occasion, following high sediment disturbance. The first year (2005–06) at Merja Zerga, the mortality rate was close to nil for juveniles and was Z = 1.5 yr? 1 for adults, providing a high production (64 g dry weight m? 2 yr? 1). At Arcachon during the same period, the juvenile mortality rate was Z = 10.9 yr? 1, the adult mortality rate was 3.4 yr? 1 and production was 26 gDW m?2 yr? 1. The second year (2006–07), mortality after recruitment was much higher (Z = 8.6 yr? 1, for juveniles) and similar to what was observed at Arcachon (Z = 8.4 yr? 1). Mortality rate of adults was higher at Merja Zerga (Z = 3.0 yr? 1) than at Arcachon (Z = 1.5 yr? 1). Production was lower at Arcachon than at Merja Zerga although growth performances were higher at Arcachon. The higher growth performance at Arcachon (Φ′ = 3.3) was mainly due to high asymptotic length (L = 38 mm) and was related to low intraspecific competition compared to Merja Zerga where cockle abundance was higher (Φ′ = 3.1, L = 31 mm). P/B was low in both sites and slightly higher at Arcachon (1.1–1.5 against 1.0–1.1 yr? 1). At Arcachon, recruitment was correlated with temperature, a peak occurring when temperature rose above 19 °C (June–July). At Merja Zerga, recruitment was already 2–3 months earlier but was not significantly correlated to temperature.This study showed that population dynamics of cockles at the southern limit of this distribution fell in the range of what was observed elsewhere in the North-Eastern Atlantic coast. Most factors that were involved in population regulation (intraspecific competition, predation and sediment dynamics) were not strictly dependent on latitude. The direct role of temperature (latitude dependent factor) was not obvious. Variation in temperature could explain the recruitment delay between Arcachon and Merja Zerga and the low maximum shell length at Merja Zerga.  相似文献   

12.
We acquired structural, granulometric and permeability data from a total of 25 extensional fault zones developed in high-porosity sandy sediments of the Crotone basin. Undeformed sediments have mean permeability values in the 103–105 mD range. The studied fault zones have displacement values spanning from a few centimeters to about 100 m, and generally show well-defined narrow fault cores bounded by damage zones on both hangingwall and footwall sides. Fault core rocks developed by progressive comminution and consist of foliated granular material and gouge lenses along indurated and striated slip surfaces. Mean fault core rock permeability broadly ranges between 101 and 104 mD, although we recorded permeability values lower than 10 mD in gouge lenses. Fault damage zones typically consist of closely spaced single to anastomosing cataclastic deformation bands with different degrees of complexity and mean permeability between 102 and 104 mD, i.e. lower than host sands. We obtained empirical relationships between bulk permeability, fault zone thickness, and fault displacement. In particular, both fault cores and damage zones tend to widen with increasing fault displacement, especially in the first ten meters. Most bulk permeability reductions in both fault cores and damage zones occur at sub-seismic scale, and decrease for displacement greater than 25–30 m.  相似文献   

13.
We determined the distributions and fluxes of methyl chloride and methyl bromide in the East China Sea (ECS) and the Southern Yellow Sea (SYS) in November 2007. Methyl chloride and methyl bromide concentrations in the surface waters ranged from 47.1 to 163 pmol L?1 and from 0.70 to 9.82 pmol L? 1, with average values of 87.6 and 2.97 pmol L? 1, respectively. The distributions of the two methyl halides were clearly influenced by the Yangtze (Changjiang) River effluent and Kuroshio water, with high concentrations appearing in the coastal zone and low values occurring in the open waters. A positive linear correlation was observed between methyl chloride and methyl bromide concentration anomalies in the surface waters, suggesting that they may share some origins in this coastal area. However, no correlation was found between the two methyl halide concentration anomalies and chlorophyll a in the surface waters. The vertical profiles of the two methyl halides were characterized by the maxima in the upper mixed layer. Both gases were generally supersaturated in the surface seawater, with mean sea-to-air fluxes of methyl chloride and methyl bromide of 391 and 20.0 nmol m?2 d? 1, respectively.  相似文献   

14.
We examined the bioaccumulation and trophic transfer of mercury in two marine finfish species, striped bass (Morone saxatilis) and tautog (Tautoga onitis), collected from the Narragansett Bay (Rhode Island, USA). For each of these target fish, white muscle tissue was analyzed for total mercury (Hg) and results were evaluated relative to fish age, body size, and Hg content of preferred prey. Dietary and stable isotope analysis was also used to elucidate the effect of trophic processes on Hg concentrations in fish. The Hg content of muscle tissue was positively correlated with fish age and length for both species, although striped bass accumulated Hg faster than tautog. Accelerated Hg bioaccumulation in striped bass is consistent with its high trophic level (trophic level = 4.07) and Hg-enriched prey (forage fish and macrocrustaceans; mean Hg content = 0.03 mg Hg kg wet wt?1). In contrast, tautog maintain a lower trophic status (trophic level = 3.51) and consume prey with lower Hg levels (mussels and crabs; mean Hg content = 0.02 mg Hg kg wet wt?1). Despite differences in Hg bioaccumulation between target fish, the mean Hg concentration of tautog exceeded levels in striped bass (0.24 and 0.16 mg Hg kg wet wt?1, respectively) due to a disparity in age-at-catch between sampled groups (mean age of tautog and bass = 11.3 and 4.3 yr, respectively). Taking into account legal minimum catch lengths further revealed that 75.0% of legal-size striped bass (>70.2 cm TL; n = 4) and 44.8% of tautog (>40.6 cm TL; n = 29) had Hg levels beyond the US EPA regulatory threshold of 0.3 mg Hg kg wet wt?1. Moreover, Hg-length relationships suggest that each target fish meets this threshold near their minimum legal catch length. Our findings reiterate the value of species ecology to improve predictions of fish Hg and permit better management of human contamination by this important dietary source.  相似文献   

15.
Short-lived radionuclides (210Pb and 137Cs) were used to document sedimentation regime changes over the last ~100 years, from analysis of a single sedimentary sequence collected in the coastal zone of the Gulf of Tehuantepec, South Pacific of Mexico. Sedimentation rates found in the core Tehua II-21 varied from 0.03 to 0.21 cm yr?1, whereas mass accumulation rates ranged from 0.05 to 0.29 g cm?2 yr?1. 137Cs data validate results obtained from 210Pb measurements and confirm significant changes in the sedimentation regime between 1950 and 1970. We associate these alterations to land use changes, including deforestation for agriculture development and industrialization, as well as the regimentation of the Tehuantepec River from the early 1960s to the late 1970s. This interval has been marked by a major demographic expansion that followed the industrial development of the area.  相似文献   

16.
The hypothesis that benthic foraminifera are useful proxies of local methane emissions from the seafloor has been verified on sediment core KS16 from the headwall of the Ana submarine landslide in the Eivissa Channel, Western Mediterranean Sea. The core MS312 from a nearby location with no known methane emissions is utilised as control. The core was analysed for biostratigraphy, benthic foraminiferal assemblages, Hyalinea balthica and Uvigerina peregrina carbon and oxygen stable isotope composition, and sedimentary structures. The upper part of the core records post-landslide deglacial and Holocene normal marine hemipelagic sediments with highly abundant benthic foraminifera species that are typical of outer neritic to upper bathyal environment. In this interval, the δ13C composition of benthic foraminifera indicates normal marine environment analogous to those found in the control core. Below the sedimentary hiatus caused by the emplacement of the slide, the foraminiferal assemblages are characterised by lower density and higher Shannon Index. Markedly negative δ13C shifts in benthic foraminifera are attributed to the release of methane through the seabed. The mean values of the 13C anomaly in U. peregrina are ? 0.951 ± 0.208 in the pre-landslide sediments, and ? 0.269 ± 0.152 in post-slide reworked sediments deposited immediately above the hiatus. The δ13C anomaly in Hyalinea balthica is ? 2.497 ± 0.080 and ? 2.153 ± 0.087, respectively. To discard the diagenetic effects on the δ13C anomaly, which could have been induced by Ca–Mg replacement and authigenic carbonate overgrowth on foraminifera tests, a benthic foraminifera subsample has been treated following an oxidative and reductive cleaning protocol. The cleaning has resulted, only in some cases, in a slight reduction of the anomaly by 0.95% for δ13C and < 0.80% for δ18O. Therefore, the first conclusion is that the diagenetic alteration is minor and it does not alter significantly the overall carbon isotopic anomaly in the core. Consequently, the pre-landslide sediments have been subject to pervasive methane emissions during a time interval of several thousand years. Methane emissions continued during and immediately after the occurrence of Ana Slide at about 61.5 ka. Subsequently, methane emissions decreased and definitely ceased during the last deglaciation and the Holocene.  相似文献   

17.
North Atlantic sediment drifts are valuable archives for paleoceanographic reconstructions spanning various timescales. However, the short-term dynamics of such systems are poorly known, and this impinges on our ability to quantitatively reconstruct past change. Here we describe a high-resolution 319-day time-series of hydrodynamics and near-bottom (4 m) particulate matter flux variability at a 2600 m deep site with an extremely high sediment accumulation rate on the southern Gardar Drift in the North Atlantic. We compare our findings with the actual deposits at the site. The total annual particle flux amounted to ~360 g m?2 yr?1, varied from ~0.15 to >5.0 g m?2 day?1 and displayed strong seasonal compositional changes, with the highest proportion of fresh biogenic matter arriving after the spring bloom in June and July. Flux variability also depended on the changing input of lithogenic matter that had been (re)suspended for a longer time (decades). Active focussing of material from both sources is required to account for the composition and the magnitude of the total flux, which exceed observations elsewhere by an order of magnitude. The enhanced focussing or increased delivery appeared to be positively related to current velocity. The intercepted annual particle flux accounted for only 60% of the sediment accumulation rate of 600±20 g m?2 yr?1 (0.20±0.07 cm yr?1), indicating higher intra- and inter-annual variability of both the biogenic and lithogenic fluxes and/or advection of additional sediment closer to the seafloor (i.e. <4 m). This temporal variability in the composition and amount of material deposited highlights intra-annual changes in the flux of lithogenic material, but also underscores the importance of (reworked) sediment focussing and seasonality of the biogenic flux. All should be taken into account in the interpretation of the paleorecord from such depositional settings.  相似文献   

18.
We have measured the metal composition and estimated the excretion rate of trace elements (Ag, Cd, Co, Cu, Ni, Pb, V and Zn) by Antarctic krill (Euphausia superba) in three locations (two located within a submarine hydrothermal vent field and one away from it) along the Antarctic Peninsula region of the Southern Ocean. Results indicated that krill excreted large amounts of Ag, Cu, Pb and Zn, (range: 1.9–41.2 pmol Ag g DW? 1 h? 1, 15.3–26.8 nmol Cu g DW? 1 h? 1, 308.7–1118.3 pmol Pb g DW? 1 h? 1 and 24.4–76.5 nmol Zn g DW? 1 h? 1), compared with the non-significant or undetectable release rates of Cd, Co, Ni and V. The metal composition of the excreted material from krill collected in the area of hydrothermal activity was similar to the metal composition reported for suspended particles emitted from those vents. Our results suggest that krill recycling of Ag, Cu, Pb and Zn could potentially influence trace metal concentrations in the water column of the Bransfield region of the Southern Ocean, and that the original source of metals to these waters may be hydrothermal vents.  相似文献   

19.
Since 2000 long-term measurements of vertical particle flux have been performed with moored sediment traps at the long-term observatory HAUSGARTEN in the eastern Fram Strait (79°N/4°E). The study area, which is seasonally covered with ice, is located in the confluence zone of the northward flowing warm saline Atlantic water with cold, low salinity water masses of Arctic origin. Current projections suggest that this area is particularly vulnerable to global warming. Total matter fluxes and components thereof (carbonate, particulate organic carbon and nitrogen, biogenic silica, biomarkers) revealed a bimodal seasonal pattern showing elevated sedimentation rates during May/June and August/September. Annual total matter flux (dry weight, DW) at ~300 m depth varied between 13 and 32 g m?2 a?1 during 2000 and 2005. Of this total flux 6–13% was due to CaCO3, 4–21% to refractory particulate organic carbon (POC), and 3–8% to biogenic particulate silica (bPSi). The annual flux of all biogenic components together was almost constant during the period studied (8.5–8.8 g m?2 a?1), although this varied from 27% to 67% of the total annual flux. The fraction was lowest in a year characterized by the longest duration of ice coverage (91 and 70 days for the calendar year and summer season, May–September, respectively). Biomarker analyses revealed that organic matter originating from marine sources was present in excess of terrigenious material in the sedimented matter throughout most of the study period. Fluxes of recognizable phyto- and protozooplankton cells amounted up to 60×106 m?2 d?1. Diatoms and coccolithophorids were the most abundant organisms. Diatoms, mainly pennate species, dominated during the first years of the investigation. A shift in the composition occurred during the last year when numbers of diatoms declined considerably, leading to a dominance of coccolithoporids. This was also reflected in a decrease in the sedimentation of bPSi. The sedimentation of biogenic matter, however, did not differ from the amount observed during the previous years. Among the larger organisms, pteropods at times contributed significantly to both the total matter and CaCO3, fluxes.  相似文献   

20.
The first carbon budget constructed for the Barents Sea to study the fluxes of carbon into, out of, and within the region is presented. The budget is based on modelled volume flows, measured dissolved inorganic carbon (DIC) concentration, and literature values for dissolved organic carbon (DOC) and particulate organic carbon (POC) concentrations. The results of the budget show that ~5600±660×106 t C yr?1 is exchanged through the boundaries of the Barents Sea. If a 40% uncertainty in the volume flows is included in the error calculation it resulted in a total uncertainty of ±1600×106 t C yr?1. The largest part of the total budget flux consists of DIC advection (~95% of the inflow and ~97% of the outflow). The other sources and sinks are, in order of importance, advection of organic carbon (DOC+POC; ~3% of both in- and outflow), total uptake of atmospheric CO2 (~1% of the inflow), river and land sources (~0.2% of the inflow), and burial of organic carbon in the sediments (~0.2% of the outflow). The Barents Sea is a net exporter of carbon to the Arctic Ocean; the net DIC export is ~2500±660×106 t C yr?1 of which ~1700±650×106 t C yr?1 (~70%) is in subsurface water masses and thus sequestered from the atmosphere. The net total organic carbon export to the Arctic Ocean is ~80±20×106 t C yr?1. Shelf pumping in the Barents Sea results in an uptake of ~22±11×106 t C yr?1 from the atmosphere which is exported out of the area in the dense modified Atlantic Waters. The main part of this carbon was channelled through export production (~16±10×106 t C yr?1).  相似文献   

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