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冈底斯成矿带西段鲁尔玛斑岩型铜(金)矿床的成矿 物质来源研究 总被引：1，自引：1，他引：0
西藏措勤县鲁尔玛铜(金)矿床为冈底斯成矿带西段新发现的斑岩型矿床,位于中拉萨微陆块的西部,矿体主要呈脉状和不规则状产于含矿斑岩顶部和接触带,矿床形成于晚三叠世(213 Ma)。文章通过研究主成矿阶段硫化物的S-Pb同位素组成特征,并与晚三叠世含矿斑岩体Pb同位素组成进行对比,发现共生硫化物δ34SV-CDT值变化范围较窄(δ34SV-CDT=-2.38‰～1.75‰,极差为4.13‰,均值为-0.64‰),具有深源硫(地幔或下地壳)的特征;共生硫化物(黄铁矿、黄铜矿和毒砂等)Pb同位素(n(206Pb)/n(204Pb)、n(207Pb)/n(204Pb)、n(208Pb)/n(204Pb)分别为18.450～18.903、15.602～15.669、38.637～39.424)和晚三叠世含矿斑岩的Pb同位素(n(206Pb)/n(204Pb)、n(207Pb)/n(204Pb)、n(208Pb)/n(204Pb)分别为18.845～19.560、15.634～15.689、39.273～40.211)具有一致的线性演化曲线,显示出壳幔混合的特征,暗示鲁尔玛铜(金)矿的铅来自于晚三叠世的岩浆活动。研究认为,鲁尔玛铜(金)矿床形成于晚三叠世新特提斯洋壳向北俯冲的环境,成矿物质应源于新生地壳熔融形成的中酸性岩浆。 相似文献
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黔西北赫章天桥铅锌矿床成矿物质来源:S、Pb同位素和REE制约 总被引：15，自引：0，他引：15
赫章县天桥铅锌矿床位于扬子准地台西南缘的黔西北铅锌成矿区中部,是本区已发现的96处中、小型矿(床)点的典型代表。天桥铅锌矿床由三个矿体群组成,其金属资源量(Pb+Zn)超过0.2Mt。本文报道了该矿床矿石硫化物的硫和铅同位素组成及其稀土元素组成特征。矿石硫化物δ34SV-CDT值主要集中在8.4‰～14.4‰之间,总体具有δ34Spyδ34Sspδ34Sga特征,表明成矿流体中硫已达到平衡。该矿床成矿流体中δ34S∑S值与不同时代地层中海相硫酸盐δ34S值(15‰)相近,表明成矿流体中硫来源于不同时代地层,为不同时代地层海相硫酸盐热化学还原(TSR)的产物。铅同位素组成相当均一,n(208Pb)/n(204Pb)值为38.875～39.057(平均38.945),n(207Pb)/n(204Pb)值为15.708～15.763(平均15.728),n(206Pb)/n(204Pb)值范围为18.481～18.544(平均18.516),与碳酸盐地层相近,在n(208Pb)/n(204Pb)—n(206Pb)/n(204Pb)和n(207Pb)/n(204Pb)—n(206Pb)/n(204Pb)图,落入碳酸盐地层范围内,表明铅来源于与矿物铅同位素组成相近的各时代碳酸盐地层。硫化物样品具有低ΣREE(3×10-6)和负的Eu异常(0.13～0.88)特征。在稀土元素球粒陨石标准化配分模式图上,全部样品具有相似特征,且与地层中的黄铁矿(下石炭统大塘组C1d)、地层白云岩及蚀变围岩相比,具有一致的稀土配分模式和Eu负异常特征,表明成矿流体来源围岩及下伏碳酸盐地层。综合S、Pb同位素和REE地球化学特征认为该矿床成矿物质和成矿流体具有多来源特征,各时代地层均不同程度地为成矿提供物质和流体。 相似文献
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滇东南白牛厂多金属矿床铅同位素组成及铅来源新认识 总被引：1，自引：0，他引：1
白牛厂矿床位于滇东南锡多金属成矿带中部,是一个Ag、Pb、Zn、Sn等共生的多金属矿床,但成因争议较大.前人引用早期矿床矿石矿物铅同位素数据得出矿石铅主要来源于基底岩石淋滤,矿床经历了热水沉积+岩浆热液叠加两个成矿阶段的结论.本文采用最新铅同位素数据系统研究了白牛厂矿床的铅同位素组成,其中,白牛厂矿床矿石矿物的铅同位素组成206Pb/204Pb、207Pb/204Pb和208Pb/204Pb分别为17.264～18.537、14.843～15.862和38.481～39.424;薄竹山花岗岩长石铅同位素组成206Pb/204Pb、207Pb/204Pb和208Pb/204Pb分别为18.301～18.387、15.611～15.670和38.677～38.904;薄竹山岩体接触带型矿床(点)矿石矿物铅同位素组成206Pb/204Pb、207Pb/204Pb和208Pb/204Pb分别为18.302～18.417、15.603～15.692和38.596～38.868;区域地层及矿区地层钻孔样品铅同位素组成206Pb/204Pb、207Pb/204Pb和208Pb/204Pb分别为18.307～19.206、15.622～15.809和38.436～39.932.对比四者铅同位素组成特征,白牛厂矿床矿石矿物、薄竹山花岗岩长石、薄竹山岩体接触带型矿床(点)矿石矿物具有一致的铅同位素组成,与地层铅同位素组成相差甚远,表明白牛厂矿床铅主要来自岩浆作用,在侵入的过程中可能受到了地层的轻度混染.矿床地质特征及近期地球化学和年代学研究成果表明,白牛厂矿床的形成主要受岩浆作用影响,沉积成矿作用在白牛厂矿床很可能是不存在的. 相似文献
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镜铁山桦树沟铁铜矿区中酸性岩脉地球化学特征、锆石U Pb LA ICP MS年龄及其地质意义 总被引：5，自引：0，他引：5
桦树沟铜矿床是近20年来在北祁连山西段镜铁山矿田铁矿体之下发现的一种新类型铜矿床,其成矿构造环境与形成时代存在较大争议。本文通过对与铜矿床密切共生的闪长玢岩岩脉的主量元素、微量元素、稀土元素以及Sr、Nd、Pb同位素分析,发现闪长玢岩具有明显的板块俯冲岩浆作用特征,大离子不相容元素Rb、Ba、Th、U、K、Pb富集,高场强元素Nb、Ta、Ti亏损,轻重稀土分馏明显,岩石富含放射成因铅,n(206Pb)/n(204Pb)、n(207Pb)/n(204Pb)、n(208Pb)/n(204Pb)比值分别为17.72~18.96、15.497~15.566、37.218~38.674;n(87Sr)/n(86Sr)比值在0.7053~0.7084之间;n(143Nd)/n(144Nd)值为0.5121~0.5122,显示出EMⅡ特征。锆石的U-PbLA-ICP-MS定年结果显示闪长玢岩形成于早古生代早—中奥陶世加里东期。成岩时代为421±24Ma,与铜矿床的成矿年龄一致,且成岩过程中捕获了中元古代1536±370Ma古老地层基底的锆石。 相似文献
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藏北商旭造山型金矿床成矿物质来源探讨：C、S、Pb同位素证据 总被引：1，自引：0，他引：1
西藏双湖县商旭金矿床位于班公湖—怒江缝合带中段。矿床受近东西向断裂控制,赋存于中—下侏罗统木嘎岗日群浅变质增生混杂岩中。本文研究主成矿阶段石英流体包裹体中CO_2的C同位素及共生硫化物的S—Pb同位素组成特征,并与木嘎岗日群、虾别错—木嘎岗日山花岗岩等主要地质体对比。含金石英脉流体包裹体中CO_2的δ~(13)C_(V-PDB)值范围为-17.8‰～-23.1‰,均值为-21.3%,接近沉积岩或者变质岩源有机碳,表明商旭金矿床的成矿流体可能来自于木嘎岗日群的变质流体,而含金石英脉中发育着与虾别错—木嘎岗日山花岗岩同时代的少量岩浆锆石,暗示成矿流体还有岩浆热液的加入。共生硫化物δ~(34)S_(V-CDT)值变化于-4.5‰～4.6‰,均值为-1.6‰,具有深源硫(地幔或下地壳,δ~(34)S_(V-CDT)=-3‰～+3‰)的特征;共生硫化物Pb同位素位素[n(~(206)Pb)/n(~(204)Pb)=18.350～18.690、n(~(207)Pb)/n(~(204)Pb)=15.632～15.700、n(~(208)Pb)/n(~(204)Pb)=38.570～38.980]与早白垩世虾别错—木嘎岗日山花岗岩[n(~(206)Pb)/n(~(204)Pb)=18.558～19.169、n(~(207)Pb)/n(~(204)Pb)=15.616～15.651、n(~(208)Pb)/n(~(204)Pb)=38.838～39.154]基本一致,同时向侏罗统木嘎岗日群[n(~(206)Pb)/n(~(204)Pb)=18.630～18.970、n(~(207)Pb)/n(~(204)Pb)=15.619～15.673、n(~(208)Pb)/n(~(204)Pb)=38.887～39.260]略有漂移,暗示商旭金矿床的Pb可能来源于早白垩世岩浆活动,同时还有部分来自木嘎岗日群中铅的加入。本次研究认为,商旭金矿的成矿物质部分来自深部壳幔岩浆作用,并被成矿热液携带至浅部。木嘎岗日群围岩也贡献了部分成矿物质,被地层中的变质热液携带到成矿流体中。 相似文献
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在自行研制的低成本热电离飞行时间质谱仪(TI-TOF-MS)基础上,开展了应用TI-TOFMS法测定铀矿钻孔样品中铅同位素示踪铀矿勘查的研究。文中介绍了样品的前处理,铅的分离和富集步骤,仪器测量及数据处理等。TI-TOF-MS法测量铅同位素比值~(204)Pb/~(206)Pb、~(207)Pb/~(206)Pb和~(208)Pb/~(206)Pb的精密度分别为0.94%、0.37%和0.14%,可满足铀矿同位素示踪的要求。通过对北方某铀矿钻孔岩心取样的测量结果表明,TI-TOF-MS测量铅同位素的方法能够用于示踪铀矿。 相似文献
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针对分布于豫西南栾川地区的脉状铅锌矿床,进行铅锌矿、地层和岩浆岩的铅同位素数据对比分析研究显示:该区铅锌矿床的铅同位素组成(赤土店矿床206Pb/204Pb=17.005～17.953,207Pb/204Pb=15.414～15.587,208Pb/204Pb=37.948～39.036;冷水北沟矿床206Pb/204Pb=17.602～17.954,207Pb/204Pb=15.458～15.606,208Pb/204Pb=38.208～38.772;百炉沟矿床206Pb/204Pb=17.552～18.426,207Pb/204Pb=15.451～15.5794,208Pb/204Pb=38.264～39.637)与区内燕山期斑岩和地层的铅同位素组成(燕山期斑岩206Pb/204Pb=17.189～17.894,207Pb/204Pb=15.381～15.569,208Pb/204Pb=37.655～39.01;元古界岩石206Pb/204Pb=17.694～19.249,207Pb/204Pb=15.467～15.585,208Pb/204Pb=38.303～41.104)有一定的相似和差别。铅同位素特征值(μ值、ω值)、Δβ-Δγ、206Pb/204Pb-207Pb/204Pb、Δα-Δβ-Δγ等分析研究,揭示铅锌矿床铅与燕山期斑岩和地层铅的来源关系,综合研究,认为栾川地区脉状铅锌床为与燕山中期斑岩侵入有关的岩浆热液充填-交代型矿床,成矿物质存在燕山期岩浆和围岩地层两种来源。 相似文献
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大别造山带大陆深俯冲和折返过程中壳-幔相互作用信息--来自大理岩铅同位素的证据 总被引：1，自引：1，他引：0
对大别造山带不同产状大理岩的铅同位素研究表明,红安群王家店和双河大理岩分别经历过高压和超高压变质作用,具有较高的铅同位素变化范围和高的放射性成因铅,反映了上地壳铅同位素的特征;新店大理岩的铅同位素比值和变化范围很小,具有EM1型地幔铅同位素特征,表明有地幔铅同位素特征的记录;而位于剪切带的方高坪大理岩的铅同位素除了n(206Pb)/n(204Pb)值更高外,与新店大理岩的铅同位素特征相似,记录了放射性铅同位素的大量加入或丢失,导致本来具有与双河大理岩类似的铅同位素特征变得不明显.这些结果均表明大陆深俯冲及其折返过程对大理岩铅同位素组成的改造是相当复杂的. 相似文献
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青海锡铁山超大型铅锌矿床产于柴达木盆地北缘早古生代造山带中,发育一套完整的喷流沉积系统,包括管道相、近喷口相与远喷口相以及喷流沉积岩等。对不同对象中硫化物系统的铅同位素测定研究表明,锡铁山矿床铅同位素组成总体较集中,可细分为两组,均呈线性分布:大部分的样品,包括非层状矿、网脉状石英钠长岩、代表供给系统的脉体、基性岩等,以及绝大部分的层状矿体,组成一组,线性回归方程为(207Pb/204Pb)=1.254(206Pb/204Pb)-7.296,相关系数0.997。分布于铅锌矿体及大理岩上盘的含浸染状黄铁矿化的炭质片岩、一个层状矿体样品组成一组,线性回归方程为(207Pb/204Pb)=0.123(206Pb/204Pb)+13.347,相关系数0.902。两条直线交点的同位素组成为206Pb/204Pb=18.253,207Pb/204Pb=15.590,208Pb/204Pb=38.370。结合成矿模型的研究认为,矿床的铅同位素具有造山带与上地壳混合来源的特点,显示喷流成矿过程中铅及成矿金属物质主要由喷流卤水提供,少量物质来自海水;在喷流系统的远端或喷流活动的间歇期,前寒武纪变质岩也可能提供了少量物质。而层状矿体与非层状矿体经历了相同的演化历史,均形成于喷流沉积过程中,非层状矿体属未喷出海底的热液矿体,而不是后期改造的结果。断层沟地区的矿化是后期改造重新定位的,铅同位素组成在改造过程中得到进一步的均一化。 相似文献
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A new approach is suggested for measuring the real U–Pb and Pb–Pb ages of rock-forming metamorphic staurolite. Previously, two approaches have been used for this purpose: (1) measurement of the lead isotopic compositions, uranium and lead contents in leach substance as a product of the step-leaching technique; age is calculated by plotting the Pb–Pb leaching isochron; and (2) lead and uranium isotopic compositions are measured in completely dissolved mineral material without leaching. In both cases, it is assumed a priori that inclusions, overgrowths, secondary phases, and the host mineral are cogenetic. This assumption may lead to errors in the measured age. The technique suggested in this paper uses various reagents (acids) to purify staurolite from the above-mentioned secondary phases while obtaining a staurolite “pure culture,” its subsequent disolution, introduction of the mixed spike, separation of lead and uranium compounds, and, finally, estimation of a real staurolite age using several samples to plot the monomineralic Pb–Pb isochron or by plotting measured Pb/U ratios in the diagram with concordia. The data can be used then to reconstruct the P–T–t evolution of metamorphism. 相似文献
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Concentrations of total lead as high as 1,600 g/L were detected in gasoline-contaminated and uncontaminated groundwater at three gasoline-release sites in South Carolina. Total lead concentrations were highest in turbid groundwater samples from gasoline-contaminated and uncontaminated wells, whereas lower turbidity groundwater samples (collected using low-flow methods) had lower total lead concentrations. Dissolved lead concentrations in all wells sampled, however, were less than 15 g total lead/L, the current United States Environmental Protection Agency (US EPA) maximum contaminant level (MCL). Because many total lead concentrations exceeded the MCL, the source of lead to the groundwater system at two of the three sites was investigated using a stable lead isotope ratio approach. Plots of the stable isotope ratios of lead (Pb) in groundwater as 207Pb/206Pb versus 208Pb/206Pb, and 208Pb/204Pb versus 206Pb/204Pb were similar to ratios characteristic of lead-based minerals in local rocks of the southeastern US, and were not similar to the stable lead isotopes ratios characteristic of distant lead ore deposits such as Broken Hill, Australia, used to produce tetraethyl lead in gasoline products prior to its phase-out and ban in the United States. Moreover, the isotopic composition of dissolved lead was equivalent to the isotopic composition of total lead in turbid samples collected from the same well, suggesting that the majority of the lead detected in the groundwater samples was associated with sediment particulates of indigenous aquifer material, rather than lead associated with spilled leaded gasoline. The results of this investigation indicate that (1) lead detected at some gasoline-release sites may be derived from the local aquifer material, rather than the gasoline release, and consequently may affect site-specific remediation goals; (2) non-low flow groundwater sampling methods, such as a disposable bailer, may result in turbid groundwater samples and high total lead concentrations, and; (3) stable lead isotopes can be used to clarify the source of lead detected above permissible levels in gasoline-contaminated groundwater systems. 相似文献
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Nengping Shen Zhengwei Zhang Fuhua You Jiantang Peng Xiaoqing Zhu Jiafei Xiao 《中国地球化学学报》2012,31(4):362-375
The polymetallic(Pb,Zn,Cu,etc) ore belt on the southwestern margin of Tarim is one of the major regions with the greatest prospecting potential in Xinjiang.Reported in this paper are the lead isotope data for 66 sulfide samples(including 50 galena samples,15 chalcopyrite samples and 1 pyrite sample) collected from such representative deposits as Tamu,Tiekelike,Kalangu,Abalieke,etc.in this ore belt.The Pb isotopic ratios of 206 Pb/204 Pb,207 Pb/204 Pb and 208 Pb/204 Pb in the galena samples range from 17.931 to 18.176,15.609 to 15.818 and 38.197 to 38.944,with the average values of 18.017,15.684 and 38.462,respectively.Those in the chalcopyrite samples range from 17.926 to 18.144,15.598 to 15.628 and 38.171 to 38.583,with the average values of 18.020,15.606 and 38.262,respectively.The pyrite sample has the Pb isotopic ratios of 206 Pb/204 Pb,207 Pb/204 Pb and 208 Pb/204 Pb to be 17.980,15.604 and 38.145,respectively.In combination with the previous Pb isotope data for sulfides,it is found that there is only a slight variation in the Pb isotopic composition of galena,chalcopyrite,sphalerite and pyrite in the ore belt.However,there is some difference in Pb isotopic characteristics between galena and chalcopyrite,especially the Pb isotopic composition of galena shows an obvious linear correlation with some other relevant parameters(e.g.β and γ).The comprehensive analysis suggested that lead in galena(maybe including sphalerite and pyrite) was derived principally from wall rocks and underlying basement,and that in chalcopyrite only originated from the basement.The single-stage model ages of these sulfides couldn’t indicate the time limit of metallogenesis(Pb,Zn,Cu,etc.),and the positive linear correlations for the Pb isotopic composition of galena are of no single-stage and two-stage Pb-Pb isochron significance.Furthermore,there are significant differences in Pb isotopic composition characteristics between the genetic type of deposits in this polymetallic ore belt and the Mississippi Valley type(MVT).In addition,the authors also pointed out that there is a phenomenon of differentiation(not paragenesis) for lead and copper elements during the process of metallogenesis in this ore belt. 相似文献
14.
The redox-sensitive geochemical behavior of uranium permits the use of Th/U ratios as a geochemical proxy for the oxidation state of the atmosphere during deposition. Due to the effects of post-depositional uranium mobility on Th/U ratios during events involving oxygenated fluids, direct measurements of Th/U ratios are often misleading even for drill core samples. Because both of these elements radioactively decay and produce lead isotopes, the Pb isotope composition may reflect the depositional Th/U ratio, although the Th/U ratios induced by changes shortly after deposition may not be distinguished from the true depositional Th/U ratios. In order to effectively evaluate the time-integrated Th/U ratio (κa), values for the initial depositional Pb isotope composition must be determined or accepted from the models for the whole Earth.While the timing for the rise of atmospheric oxygen is reasonably well constrained now, its effect on continental weathering and ocean redox state remains poorly constrained and debated. The ca. 2.15 Ga Sengoma Argillite Formation of Botswana contains organic-rich shales deposited during the Great Oxidation Event. The slope of the 207Pb/204Pb–206Pb/204Pb array of shales from the Sengoma Argillite Formation corresponds to a Pb–Pb age that is within analytical error of the depositional age and is, therefore, inferred to be the time by which the time-integrated thorogenic and uranogenic lead growth started. The time-integrated lead growth corresponds to an average κa of 2.63 (± 0.62, 1σ) for the organic-rich shales of the Sengoma Argillite Formation. This is lower than Th/U ratios measured in Archean shale suites or estimated for the Archean–Proterozoic average upper continental crust [Taylor, S.R. and McLennan, S.M., 1985. The Continental Crust: Its Composition and Evolution. Blackwell, Oxford, 312 pp.], which indicates that these samples were enriched in uranium with respect to thorium (and perhaps lead) at the time of deposition. In the modern ocean, sediments are enriched in uranium under reducing conditions by reduction of the water-soluble uranyl ion, which is delivered to the ocean by oxidative weathering of continental crust. To evaluate the potential mobility of Th, U, and Pb during post-depositional processes, the concentrations of the rare earth elements (REE) were also determined. Interelement ratios of the largely immobile REE (in this study, La/Nd and Gd/Er) can be used as a proxy for the Th/U ratio, as the geochemical behavior of the lanthanide and actinide elements is similar under a variety of conditions. Furthermore, close similarity in the chondrite-normalized REE patterns and small range in La/Nd and Gd/Er ratios in studied samples indicate that variations in κa values are not likely to have been controlled by mixing of one or more REE-, Th-, and U-rich heavy minerals from the multiple detrital sources. Our study of shales from the ca. 2.15 Ga Sengoma Argillite Formation indicates that decoupling of U from Th, most likely related to the oxidative continental weathering, began by 2.15 Ga, at the latest. 相似文献
15.
内蒙古甲乌拉大型Pb-Zn-Ag矿床稳定同位素地球化学研究 总被引：2，自引：0，他引：2
内蒙古甲乌拉银多金属矿床位于大兴安岭成矿带北段,为近年来发现的大型银铅锌多金属矿床。矿床矿体分布完全受到断裂构造的控制,金属矿物组成主要为方铅矿、闪锌矿、黄铜矿、黄铁矿、磁黄铁矿、毒砂、辉钼矿及磁铁矿等。文中重点分析了矿床的硫、氢、氧、碳和铅稳定同位素地球化学特征。研究结果表明：金属硫化物δ34S集中为1.37‰~4.10‰,平均为3.10‰(n=13),极差为2.73‰;石英和方解石δ18Owater的变化范围较大(-18.96‰~+1.08‰) (n=9),均值为-11.36‰;δDV SMOW的变化范围比较集中(-133.6‰~-103.4‰) (n=9);27件样品的铅同位素组成为：206Pb/204Pb=18.228 3~18.758 7、207Pb/204Pb=15.457~15.880和208Pb/204Pb=37.841~39.049,矿床的铅组成基本为正常的放射性成因铅;方解石δ13CV PDB变化范围为-5.2‰~-8.4‰,平均为-6.8‰(n=2)。矿石硫化物的硫同位素及方解石的碳同位素均指示成矿物质可能来源于深部的岩浆活动;石英和方解石的氢氧同位素组成表明成矿流体早期以岩浆流体为主,成矿晚期加入了大量加热补给的大气降水;铅同位素组成表明成矿流体中铅的来源主要为幔源,矿床形成过程中混入少量的壳源铅。矿床稳定同位素组成显示成矿流体主要来源于深部的岩浆热液,特别与燕山晚期的火山次火山热液有较为密切的联系,在流体演化过程中大气降水的加入对矿床成矿元素的聚集和沉淀也起到有利作用。成矿作用的发生是在一种总硫浓度比较低、中等氧化环境、相对开放的非平衡体系中进行的。矿床形成的地球动力学背景为一种岩石圈大规模快速减薄的过程。甲乌拉大型Pb Zn Ag矿床的成因类型属于火山次火山热液脉状银多金属矿床。 相似文献
16.
AG-MP-1M阴离子交换树脂分离-表面热电质谱法测定沉积物中的铅同位素组成 总被引：2，自引：1，他引：1
利用新型阴离子交换树脂分离沉积物中的重金属Pb,采用表面热电离质谱法(TIMS)测定了沉积物样品中的Pb同位素组成。新型树脂为大孔径阴离子树脂AG-MP-1M,淋洗液采用低浓度的盐酸,避免了使用难以纯化的氢溴酸,可有效地降低试剂空白。通过对铅同位素标准物质NIST NBS-981的重复测试,方法的精密度(<0.5%,2s)和准确度均达到了应用研究的要求。对5个实际沉积物样品中的铅同位素组成进行测定,获得了理想的分析效果。 相似文献
17.
The weathered surface expression of the Lady Loretta lead-zinc-silver deposit outcrops almost continuously over a distance of about 4 km. Lead isotope ratios have been determined for samples, some of which contain > 4000 ppm Pb, from geochemically anomalous areas in order to assign drilling priorities to the anomalies.Twelve of the 43 samples analyzed contain isotopically homogeneous lead with ratios (207Pb/206Pb 0.9532–0.9549) similar to the expected targets for major ore deposits in the Mount Isa-McArthur River metallogenic province (207Pb/206Pb 0.955–0.962). Three main zones of interest can be outlined on the basis of lead isotopic data. The top priority is assigned to a 100-m-long section of the ironstone which coincides with the known outcrop of the ore. Lower priority for drilling is given to the two other zones which outcrop over smaller areas and have more radiogenic lead in their immediate surroundings. Several samples with anomalously high lead contents (> 1000 ppm) contain more radiogenic lead (207Pb/206Pb < 0.950) which was most likely derived from the weathering country rocks by supergene leaching and redeposition. Of the 22 samples containing ≥ 380 ppm Pb, lead isotopic analyses would have reduced the number deserving further attention to 10. Lead isotopic analyses in the early stages of exploration could have assisted in minimizing exploration expenditure at Lady Loretta. 相似文献
18.
19.
位于浙西北安吉港口的铅锌银(钼)多金属矿床,是新近在钦杭成矿带东北缘发现的一个产于大陆环境且具较好前景的矿床.文章通过对矿区坞山关杂岩体三套岩性单元、细粒花岗岩和方铅矿铅同位素的全面对比研究,探讨了矿床的铅物源岩浆岩.矿区中的方铅矿为含较高放射性成因铅的J-型铅,在铅同位素的V1-V2和△γ-Δβ图解中,本次研究的样品分别落入华南和岩浆作用上地壳混合地幔铅范围,显示出方铅矿与华南地球化学省壳幔混合岩浆作用的密切关系.矿区铅锌矿体的方铅矿铅同位素比值显示其具有共同的物质来源,并基本保持了细粒花岗岩206Pb/204Pb值的特征,而207Pb/204Pb值具有坞山关杂岩体和细粒花岗岩混合的特征,208Pb/204Pb和208Pb/206Pb值则仅显示出与细粒花岗岩最相近.方铅矿铅同位素比值特征和比值等值线分布形式显示,铅主要来源于细粒花岗岩,杂岩体对铅成矿贡献了少量的206Pb和207Pb,矿区地层对铅成矿贡献了一定的208Pb.安吉矿区进一步针对铅的找矿工作围绕细粒花岗岩展开,取得成果的可能性更大. 相似文献
20.
The role of pollution versus natural geological sources for lead enrichment in recent lake sediments and surface forest soils 总被引：3，自引：0，他引：3
M.-L. Brännvall H. Kurkkio R. Bindler O. Emteryd I. Renberg 《Environmental Geology》2001,40(9):1057-1065
This paper assesses the role of airborne pollution and natural geological sources for lead enrichment in lake sediments and in surface soils of boreal forests. This assessment is based on analyses of stable lead isotopes (206Pb and 207Pb) and lead concentrations in sediment cores (>30 lakes), ombrotrophic peat and soil samples in Sweden. The 206Pb/207Pb ratio and concentration profiles in the sediment cores change synchronously over the last 3,000 years in different lakes, temporal concentration changes in sediments and peat deposits are very consistent, and these temporal concentration changes coincide well with the history of lead production in Europe. The 206Pb/207Pb ratio is almost the same in all soil mor samples (1.152ǂ.009; n=94), and similar to values recorded in aerosols, despite very high and different 206Pb/207Pb ratio of the mineral soil in the C-horizon (1.3-1.7). This study provides evidence that lead enrichment in recent sediments and peat, and in the mor layer are caused by deposition of pollution lead and not natural processes. 相似文献