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1.
The apparition of Comet C/1996 B2 (Hyakutake) offered an unexpected and rare opportunity to probe the inner atmosphere of a comet with high spatial resolution and to investigate with unprecedented sensitivity its chemical composition. We present observations of over 30 submillimeter transitions of HCN, H13CN, HNC, HNCO, CO, CH3OH, and H2CO in Comet Hyakutake carried out between 1996 March 18 and April 9 at the Caltech Submillimeter Observatory. Detections of the H13CN (4–3) and HNCO (160,16–150,15) transitions represent the first observations of these species in a comet. In addition, several other transitions, including HCN (8–7), CO (4–3), and CO (6–5) are detected for the first time in a comet as is the hyperfine structure of the HCN (4–3) line. The observed intensities of the HCN (4–3) hyperfine components indicate a line center optical depth of 0.9 ± 0.2 on March 22.5 UT. The HCN/HNC abundance ratio in Comet Hyakutake at a heliocentric distance of 1 AU is similar to that measured in the Orion extended ridge— a warm, quiescent molecular cloud. The HCN/H13CN abundance ratio implied by our observations is 34 ± 12, similar to that measured in giant molecular clouds in the galactic disk but significantly lower than the Solar System12C/13C ratio. The low HCN/H13CN abundance ratio may be in part due to contamination by an SO2line blended with the H13CN (4–3) line. In addition, chemical models suggest that the HCN/H13CN ratio can be affected by fractionation during the collapse phase of the protosolar nebula; hence a low HCN/H13CN ratio observed in a comet is not inconsistent with the solar system12C/13C isotopic ratio. The abundance of HNCO relative to water derived from our observations is (7 ± 3) × 10−4. The HCN/HNCO abundance ratio is similar to that measured in the core of Sagittarius B2 molecular cloud. Although a photo-dissociative channel of HNCO leads to CO, the CO produced by HNCO is a negligible component of cometary atmospheres. Production rates of HCN, CO, H2CO, and CH3OH are presented. Inferred molecular abundances relative to water are typical of those measured in comets at 1 AU from the Sun. The exception is CO, for which we derive a large relative abundance of 30%. The evolution of the HCN production rate between March 20 and March 30 suggests that the increased activity of the comet was the cause of the fragmentation of the nucleus. The time evolution of the H2CO emission suggests production of this species from dust grains.  相似文献   

2.
Bockelée-Morvan  D.  Wink  J.  Despois  D.  Colom  P.  Biver  N.  Crovisier  J.  Gautier  D.  Gérard  E.  Lellouch  E.  Moreno  R.  Paubert  G.  Rauer  H.  Davies  J. K.  Dent  W. R. F. 《Earth, Moon, and Planets》1997,78(1-3):67-67
Spectroscopic observations of comet Hale-Boppwere undertaken near perihelion at millimetre wavelengths with the Institut de Radioastronomie Millimétrique (IRAM) telescopes at Plateau de Bure (France)and Pico Veleta (Spain). They resulted in the first detections of HCOOH,SO2, NH2CHO and HCOOCH3 in a comet. HDO was detected through its312–221 line at 225.897 GHz,complementing the observation of the 101–000 line at 464.925 GHz at the James Clerk Maxwell Telescope (Meier et al., 1998,Science 279, 842).Several unidentified lines are present in the spectra. Observations of HC3N, HNCO, OCS, SO, CN, CO+, HCO+, in addition to more ‘classical’species CO, HCN, HNC, CH3CN, CH3OH, H2CO, CS and H2S (Biveret al., this issue) permit us to make out an extensive inventory of the composition of the coma of comet Hale-Bopp at its perihelion. It presents strong analogies with gas-phase abundances measured in interstellar hot cores and bipolar flows, which are believed to reflect the composition of interstellar grains. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

3.
Biver  N.  Bockelée-Morvan  D.  Colom  P.  Crovisier  J.  Germain  B.  Lellouch  E.  Davies  J. K.  Dent  W. R. F.  Moreno  R.  Paubert  G.  Wink  J.  Despois  D.  Lis  D. C.  Mehringer  D.  Benford  D.  Gardner  M.  Phillips  T. G.  Gunnarsson  M.  Rickman  H.  Winnberg  A.  Bergman  P.  Johansson  L. E. B.  Rauer  H. 《Earth, Moon, and Planets》1997,78(1-3):5-11
C/1995 O1 (Hale-Bopp) has been observed on a regular basis since August 1995 at millimetre and submillimetre wavelengths using IRAM, JCMT, CSO and SEST radio telescopes. The production rates of eight molecular species (CO, HCN, CH3OH, H2CO,H2S, CS, CH3CN,HNC) have been monitored as a function of heliocentric distance(rh from 7 AU pre-perihelion to 4 AU post-perihelion. As comet Hale-Bopp approached and receded from the Sun, these species displayed different behaviours. Far from the Sun, the most volatile species were found in general relatively more abundant in the coma. In comparison to other species, HNC, H2CO and CS showed a much steeper increase of the production rate with decreasing rh. Less than 1.5 AU from the Sun, the relative abundances were fairly stable and approached those found in other comets near 1 AU. The kinetic temperature of the coma, estimated from the relative intensities of the CH3OH and CO lines, increased with decreasing rh, from about10 K at 7 AU to 110 K around perihelion. The expansion velocity of the gaseous species, derived from the line shapes, also increased with a law close torh 3. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

4.
Irvine  W. M.  Dickens  J. E.  Lovell  A. J.  Schloerb  F. P.  Senay  M.  Bergin  E. A.  Jewitt  D.  Matthews  H. E. 《Earth, Moon, and Planets》1997,78(1-3):29-35
The abundance ratio of the isomers HCN and HNC has been investigated in comet Hale-Bopp (C/1995 O1) through observations of the J = 4−3 rotational transitions of both species for heliocentric distances 0.93 < r < 3 AU, both pre- and post-perihelion. After correcting for the optical depth of the stronger HCN line, we find that the column density ratio of HNC/HCN in our telescope beam increases significantly as the comet approaches the Sun. We compare this behavior to that predicted from an ion-molecule chemical model and conclude that the HNC is produced insignificant measure by chemical processes in the coma; i.e., for comet Hale-Bopp, HNC is not a parent molecule sublimating from the nucleus. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

5.
M.H. Moore  R.L. Hudson 《Icarus》2003,161(2):486-500
Infrared spectra and radiation chemical behavior of N2-dominated ices relevant to the surfaces of Triton and Pluto are presented. This is the first systematic IR study of proton-irradiated N2-rich ices containing CH4 and CO. Experiments at 12 K show that HCN, HNC, and diazomethane (CH2N2) form in the solid phase, along with several radicals. NH3 is also identified in irradiated N2 + CH4 and N2 + CH4 + CO. We show that HCN and HNC are made in irradiated binary ice mixtures having initial N2/CH4 ratios from 100 to 4, and in three-component mixtures have an initial N2/(CH4 + CO) ratio of 50. HCN and HNC are not detected in N2-dominated ices when CH4 is replaced with C2H6, C2H2, or CH3OH.The intrinsic band strengths of HCN and HNC are measured and used to calculate G(HCN) and G(HNC) in irradiated N2 + CH4 and N2 + CH4 + CO ices. In addition, the HNC/HCN ratio is calculated to be ∼1 in both icy mixtures. These radiolysis results reveal, for the first time, solid-phase synthesis of both HCN and HNC in N2-rich ices containing CH4.We examine the evolution of spectral features due to acid-base reactions (acids such as HCN, HNC, and HNCO and a base, NH3) triggered by warming irradiated ices from 12 K to 30-35 K. We identify anions (OCN−, CN−, and N3−) in ices warmed to 35 K. These ions are expected to form and survive on the surfaces of Triton and Pluto. Our results have astrobiological implications since many of these products (HCN, HNC, HNCO, NH3, NH4OCN, and NH4CN) are involved in the syntheses of biomolecules such as amino acids and polypeptides.  相似文献   

6.
T.Y Brooke  H.A Weaver  G Chin  S.J Kim 《Icarus》2003,166(1):167-187
High resolution infrared spectra of Comet C/1995 O1 (Hale-Bopp) were obtained during 2-5 March 1997 UT from the NASA Infrared Telescope Facility on Mauna Kea, Hawaii, when the comet was at r≈1.0 AU from the Sun pre-perihelion. Emission lines of CH4, C2H6, HCN, C2H2, CH3OH, H2O, CO, and OH were detected. The rotational temperature of CH4 in the inner coma was Trot=110±20 K. Spatial profiles of CH4, C2H6, and H2O were consistent with release solely from the nucleus. The centroid of the CO emission was offset from that of the dust continuum and H2O. Spatial profiles of the CO lines were much broader than those of the other molecules and asymmetric. We estimate the CO production rate using a simplified outflow model: constant, symmetric outflow from the peak position. A model of the excitation of CO that includes optical depth effects using an escape probability method is presented. Optical depth effects are not sufficient to explain the broad spatial extent. Using a parent+extended-source model, the broad extent of the CO lines can be explained by CO being produced mostly (∼90% on 5 March) from an extended source in the coma. The CO rotational temperature was near 100 K. Abundances relative to H2O (in percent) were 1.1±0.3 (CH4), 0.39±0.10 (C2H6), 0.18±0.04 (HCN), 0.17±0.04 (C2H2), 1.7±0.5 (CH3OH), and 37-41 (CO, parent+extended source). These are roughly comparable to those obtained for other long-period comets also observed in the infrared, though CO appears to vary.  相似文献   

7.
We present a comparative study on molecular abundances in comets basedon millimetre/submillimetre observations made with the IRAM 30-m,JCMT, CSO and SEST telescopes. This study concerns a sample of 24comets (6 Jupiter-family, 3 Halley-family, 15 long-period) observedfrom 1986 to 2001 and 8 molecular species (HCN, HNC, CH3CN,CH3OH, H2CO, CO, CS, H2S). HCN was detected in all comets,while at least 2 molecules were detected in 19 comets. From the sub-sample of comets for which contemporary H2O productionrates are available, we infer that the HCN abundance relative to water variesfrom 0.08% to 0.25%. With respect to other species, HCN is the moleculewhich exhibits the lowest abundance variation from comet to comet. Therefore,production rates relative to that of HCN can be used for a comparative study ofmolecular abundances in the 19 comets. It is found that: CH3OH/HCN varies from ≤ 9 to 64; CO/HCN varies from ≤ 24 to 180; H2CO/HCN varies between 1.6 and 10; and H2S/HCN varies between 1.5 and 7.6. This study does not show any clear correlation between the relative abundancesand the dynamical origins of the comets, or their dust-to-gas ratios.  相似文献   

8.
The bright comet Hale–Bopp provided the first opportunity to follow the outgassing rates of a number of molecular species over a large range of heliocentric distances. We present the results of our observing campaign at radio wavelengths which began in August 1995 and ended in January 2002. The observations were carried out with the telescopes of Nançay, IRAM, JCMT, CSO and, since September 1997, SEST. The lines of nine molecules (OH, CO, HCN, CH3OH, H2CO, H2S, CS, CH3CN and HNC) were monitored. CS, H2S, H2CO, CH3CN were detected up to rh= 3–4 AU from the Sun, while HCN and CH3OH were detected up to 6 AU. CO, which is the main driver of cometary activity at heliocentric distances larger than 3–4 AU, was last detected in August 2001, at rh= 14 AU. The gas production rates obtained from this programme contain important information on the nature of cometary ices, their thermal properties and sublimation mechanisms.Line shapes allow to measure gas expansion velocities, which, at large heliocentric distances, might be directly connected to the temperature of the nucleus surface. Inferred expansion velocity of the gas varied as rh -0.4 within 7 AU from the Sun, but remained close to 0.4 km s-1 further away. The CO spectra obtained at large rhare strongly blueshifted and indicative of an important day-to-night asymmetry in outgassing and expansion velocity. The kinetic temperature of the coma, estimated from the relative intensities of the CH3OH and CO lines, increased with decreasing rh, from about 10 K at 7 AU to 110 K around perihelion.  相似文献   

9.
We observed submillimeter lines of H2CO and HCN in comet Hale-Bopp near perihelion. One of our goals was to search for short term variability. Our observations are suggestive, but not conclusive, of temporal and/or spatial changes in the coma's HCN/H2CO abundance ratio of ～25%. If due to spatial variability, the ratio on the sunward side of the coma is enhanced over other regions. If due to temporal variability, we find the bulk ratio in the coma changed in less than 16 hours.  相似文献   

10.
In a recent Icarus note, Podolak et al. (2002, Icarus 160, 208-211) proposed a model, which results in a significant enrichment in the D/H ratio in the coma relative to that in the comet nucleus. This conclusion contradicts to the typical HDO/H2O ice-vapor fractionation, with a smaller or equal D/H in the vapor. It is based on an error in the relationship for sublimation flux, which adversely affects all conclusions of Podolak et al. (2002, Icarus 160, 208-211). Due to the very low diffusion in the H2O ice, the HDO/H2O ratio in the coma should closely match this ratio in the nucleus.  相似文献   

11.
Hofstadter  M. D.  Hartogh  P.  McMullin  J. P.  Martin  R. N.  Jarchow  C.  Peters  W. 《Earth, Moon, and Planets》1997,78(1-3):53-61
We observed submillimeter lines of H2CO and HCN in comet Hale-Bopp near perihelion. One of our goals was to search for short term variability. Our observations are suggestive, but not conclusive, of temporal and/or spatial changes in the coma's HCN/H2CO abundance ratio of ∼25%. If due to spatial variability, the ratio on the sunward side of the coma is enhanced over other regions. If due to temporal variability, we find the bulk ratio in the coma changed in less than 16 hours. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

12.
We have observed C2H2 and HCN rovibrational transitions near 13µm in absorption against GL2591. We also have observed rotational transitions at 0.6-3 mm of CS, HCN, H2CO, and HCO+. Analysis of the rotational lines, which arise in the extended cloud around the source, shows that no single density model can explain all the data. Models with density and temperature gradients do much better; in particular models withn(r) r –1.5 can reproduce the observed pattern of emission line strengths. The abundances show significant depletion compared to models of gas-phase chemistry. The rovibrational data were analyzed in comparison to the absorption line analysis of CO by Mitchellet al. (1989). Our data are consistent with the C2H2 and HCN absorption arising in the same warm (200 K) and hot (1010 K) components seen in CO, but we see little evidence for the cold (38 K) component seen in CO. The rovibrational lines from higher states (J 21) indicate that the hot HCN deviates from LTE, leading to a density of about 3 × 107 cm–3. Comparison of the two data sets shows that the rovibrational absorption of HCN, rather than arising in the extended envelope, must come from a region with a small angular extent. A model in which early-time gas phase abundances are preserved on grain mantles and released at high temperature can explain the data.  相似文献   

13.
The radial distribution of some molecules (CO, H2CO, HNC, …) observed in the coma of some comets cannot be explained only by a direct sublimation from the nucleus, or by the photolysis of a detected parent compound. Such molecules present a so-called extended source in comae. We show in this paper that extended sources can be explained by refractory organic material slowly releasing gas from grains ejected from the cometary nucleus, due to solar UV photons or heat. The degradation products are produced throughout the coma and therefore are presenting an extended distribution. To model this multiphase chemistry we derive new equations, which are applied to Comet 1P/Halley for the case of the production of formaldehyde from polyoxymethylene (POM), the polymer of formaldehyde (-CH2-O-)n. We show that the presence of a few percent of POM on cometary grains (a nominal value of ∼4% in mass of grains is derived from our calculations) is in good agreement with the observed distribution, which so far were not interpreted by the presence of any gaseous parent molecule.  相似文献   

14.
Womack  M.  Homich  A.  Festou  M. C.  Mangum  J.  Uhl  W. T.  Stern  S. A. 《Earth, Moon, and Planets》1997,77(3):259-264
On-the-Fly maps of emission from the HCO+ J = 3-2 transition at 267.6 GHz were obtained of C/1995 O1 (Hale-Bopp) on 1997 Mar 15.6 UT using the NRAO 12-m telescope with high spatial resolution. Unlike the relatively symmetric and centralized maps of the neutral species CO, HCN and H2CO, the spatial extent of HCO+ emission is very diffuse with a complex structure characterized by at least two physically different regions. The bulk of the HCO+ emission peaks in intensity ∼175,000 km anti-sunward from the nuclear position. This peak emission does not fall directly along the anti-sunward direction, but is rotated by ∼10 degrees toward the east from the anti-sunward direction. A substantial void, or decrease, of HCO+ emission is observed within ∼ 55,000 km of the nucleus. The HCO+ emission in this void is roughly half the intensity of the emission observed 100,000 km away. This decrease of HCO+ emission near the nucleus may indicate that production or excitation of HCO+ is inhibited, or perhaps that HCO+ is easily destroyed in the inner coma, especially within ∼50,000 km of the nucleus. This void roughly coincides with the approximate location and size of the so-called “diamagnetic cavity” in the coma and may mark a significant transition region in the inner coma of Hale-Bopp This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

15.
We present new observations of the molecular gas distribution in the merging system Arp 299. The first observation set was obtained with the Canada–France–Hawaii Telescope near-IR camera Redeye and the second set comes from the IRAM Plateau de Bure interferometer (combined with short spacings observed at the IRAM 30 m Telescope). In the near IR, H2 ν=1→0 S(1) and Brγ line maps are globally identical: there is bright emission not only at the two galaxy nuclei but also in numerous extranuclear star forming regions. Moreover, there is weaker emission localized in filaments between and around the two nuclei. These filaments correspond to a dust lane observed in optical images from HST. 12CO(1→0), 13CO(1→0) and HCN(1→0) maps are also presented. The structure of the12CO(1→0) map is very close to the NIR observations: the same bright galaxy nuclei and star-forming regions, the same filaments, but half of the total flux is found in weak extended emission. Strong HCN emission is observed in the nucleus A indicating the presence of a large amount of dense gas. Nucleus B1 is weak in 12CO(1→0) emission while nucleus A and star-forming regions C-C′ show more normal 13CO/12CO ratios. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

16.
The HCN emission features near 3 μm recently detected by Geballe et al. (2003, Astrophys. J. 583, L39) are analyzed with a model for fluorescence of sunlight in the ν3 band of HCN. The emission spectrum is consistent with current knowledge of the atmospheric temperature profile and the HCN distribution inferred from millimeter-wave observations. The spectrum is insensitive to the abundance of HCN in the thermosphere and the thousand-fold enhancement relative to photochemical models suggested by Geballe et al. (2003, Astrophys. J. 583, L39) is not required to explain the observations. We find that the spectrum can be matched with temperatures from 130 to 200 K, with slightly better fits at high temperature, contrary to the temperature determination of 130±10 K of Geballe et al. (2003, Astrophys. J. 583, L39). The HCN emission spectrum is sensitive to the collisional de-excitation probability, P10, for the ν3 state and we determine a value of 10−5 with an accuracy of about a factor of two. Analysis of absorption lines in the C2H2ν3 band near 3 μm, detected in the same spectrum, indicate a C2H2 mole fraction near 0.01 μbar of 10−5 for P10=10−4. The derived mole fraction, however, is dependent upon the value adopted for P10 and lower values are required if P10 at Titan temperatures is less than its room temperature value.  相似文献   

17.
Many new cometary molecules — both parents and daughters — were detected in the exceptionally productive comet C/1995 O1 (Hale-Bopp).The space distribution of several of these species could be investigated from radio interferometry or from long-slit spectroscopy in the infrared. The distinction between parent species — directly sublimated from nucleus ices — and secondary species — resulting from chemical processing in the coma or produced by a secondary source — is not always clear. It is important to assess whether or not observed minor species (HCOOCH3, HCOOH...) could be synthesized by chemical reactions favoured by the high density of the coma of comet Hale-Bopp. Chemical modelling by Rodgers and Charnley suggests that this is notthe case. CO and H2CO are abundant cometary species which partly come from distributed sources. The nature of these sources is still a mystery. A special case, now well documented, is that of HNC, for which the abundance evolution with heliocentric distance could be observed in comet Hale-Bopp and which was observed in several much less productive comets.  相似文献   

18.
The European Space Agency (ESA) Rosetta spacecraft (Schulz, R., Alexander, C., Boehnhardt, H., Glassmeier, K.H. (Eds.) [2009]. “ROSETTA - ESA”) will encounter Comet 67P/Churyumov-Gerasimenko in 2014 and spend the next 18 months in the vicinity of the comet, permitting very high spatial and spectral resolution observations of the coma and nucleus. During this time, the heliocentric distance of the comet will change from ∼3.5 AU to ∼1.3 AU, accompanied by an increasing temperature of the nucleus and the development of the coma. The Microwave Instrument for the Rosetta Orbiter (MIRO) will observe the ground-state rotational transition (110-101) of H216O at 556.936 GHz, the two isotopologues H217O and H218O and other molecular transitions in the coma during this time (Gulkis, S. et al., [2007]. MIRO: Microwave Instrument for Rosetta Orbiter. Space Sci. Rev. 128, 561-597).The aim of this study is to simulate the water line spectra that could be obtained with the MIRO instrument and to understand how the observed line spectra with various viewing geometries can be used to study the physical conditions of the coma and the water excitation processes throughout the coma. We applied an accelerated Monte Carlo method to compute the excitations of the seven lowest rotational levels (101, 110, 212, 221, 303, 312, and 321) of ortho-water using a comet model with spherically symmetric water outgassing, density, temperature and expansion velocity at three different heliocentric distances 1.3 AU, 2.5 AU, and 3.5 AU. Mechanisms for the water excitation include water-water collisions, water-electron collisions, and infrared pumping by solar radiation.Synthetic line spectra are calculated at various observational locations and directions using the MIRO instrument parameters. We show that observations at varying viewing distances from the nucleus and directions have the potential to give diagnostic information on the continuum temperature and water outgassing rates at the surface of the nucleus, and the gas density, expansion velocity, and temperature of the coma as a function of distance from the nucleus. The gas expansion velocity and temperature affect the spectral line width and frequency shift of the line from the rest frequency, while the gas density (which is directly related to the outgassing rate) and the line excitation temperature determine the antenna temperature of the absorption and emission signal in the line profile.  相似文献   

19.
Weaver  H. A.  Brooke  T. Y.  Chin  G.  Kim  S. J.  Bockelée-Morvan  D.  Davies  J. K. 《Earth, Moon, and Planets》1997,78(1-3):71-80
High resolution (λ/δλ ∼ 20,000) spectra of comet C/1995 O1 (Hale-Bopp) in the 2–5 μm region were obtained during UT 2–5 March 1997 using CSHELL at the NASA Infrared Telescope Facility (IRTF) on Mauna Kea. The heliocentric and geocentric distances of the comet were ∼1.1 AU and ∼1.5 AU,respectively. We detected emission lines of the gas-phase molecules H2O, 4, C2H6, C2H2, HCN, and CO and derived absolute production rates and relative abundances for all species. We also used the 2-dimensional nature of the CSHELL data to investigate the spatial distribution of the molecules and find evidence that CO was derived at least partly from an extended source in the coma. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

20.
On the origin of HNC in Comet Lee   总被引：1，自引：0，他引：1  
We have modelled the chemistry occurring in the coma of Comet Lee and have critically evaluated the possible routes leading to HNC. We show that the observed levels of HNC cannot be produced by ion–molecule chemistry, or by reactions of energetic H atoms with HCN. Rather, it appears that HNC is injected into the coma following the photodestruction of an unknown precursor. We discuss the possible nature of the parent of HNC and conclude that photofragmentation of large HCN polymers, such as polyaminocyanomethylene (PACM), is responsible. The degradation of hydrogen cyanide polymers may constitute a common source of HNC in comets, accounting for HNC/HCN ratios in the range measured in Lee and Hyakutake (≈ 0.06–0.12). The high HNC/HCN ratio measured in Hale–Bopp (≈0.2) and its heliocentric variation may, however, require an additional source.  相似文献   

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