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1.
根据万里副总理关于“从海水中提取碘、溴、钾等,还有海水淡化,是不是应当列为近期项目,应当仔细研究一下”的指示,中国海洋湖沼化学学会于1986年11月初,在连云港召开了“海水资源化学专题讨论会”。与会专家一致认为:海水提溴、提钾、提镁,卤水提碘及海水淡化,可以列为近期的开发项目;海水提碘、提铀,则可列为高技术跟踪计划。  相似文献   

2.
物质海 -气通量计算新建议中将物质海 -气通量计算公式 F=K(CL- b Cg)中的 CL 用CL ( SML ) 代替。本文着重于对公式中质量迁移系数 K的讨论。在测定了海水微表层、次表层水粘度并同时测定了其它一些化学参量基础上 ,得出如下结论 :海水粘度与盐度、碱度有一定相关性 ;微表层与次表层海水的粘度变化小于 3%。因此 ,海水微表层效应影响 K值 ,与海水微表层效应影响物质浓度相比 ,可以不考虑。  相似文献   

3.
于2011年5至6月在东海采集不同深度海水样品,研究了其中溶存氧化亚氮(N2O)的分布并估算其海-气交换通量。结果表明,春季东海表层海水中溶存N2O浓度范围为6.31~11.88 nmol/L,平均值为(9.13±1.45)nmol/L;底层海水中N2O浓度范围为7.53~39.75 nmol/L,平均值为(13.71±7.76)nmol/L。随着深度的增加,N2O浓度逐渐升高。温度是影响春季东海N2O分布的主要因素,N2O浓度与温度呈负相关关系。长江冲淡水和黑潮水是东海N2O的重要来源。东海表层海水中N2O的饱和度范围为92.5%~139.3%,平均值为118.5%±10.3%,绝大多数站位都处于过饱和状态,因此,春季东海是大气N2O的净源。利用LM86公式和W92公式求得东海的海-气交换通量分别为(4.96±6.12)μmol/(m2·d)和(10.25±17.18)μmol/(m2·d),初步估算出东海年释放N2O通量约为0.061~0.127 Tg/a,占全球海洋释放总量的2.0%,远高于其所占的面积比0.2%。  相似文献   

4.
研究201×7、201×4、D201 3种阴离子交换树脂对人工浓海水中的溴离子吸附性能,结果表明,201×7树脂的吸附效果最好。该树脂的静态饱和吸附量达到25.94 mg.g-1,流速为2.3 mL.min-1时的动态饱和吸附量为13.42 mg.g-1,因此选择201×7树脂作为吸附剂。通过静态吸附实验,测得298 K时吸附速率常数k298=1.7×10-3s-1;热焓ΔH=67.75 kJ.mol-1;在解吸过程中,确定了柠檬酸钠溶液作为解吸剂。201×7树脂吸附溴离子的过程符合Freundlich吸附等温式。通过动态吸附实验,研究了海水流速对201×7树脂吸附溴离子的影响。探讨了201×7树脂吸附溴离子的机理,结果表明,溴离子在201×7树脂上的吸附机理主要是Br-与—N+(CH3)3之间的静电作用。  相似文献   

5.
针对舰船烟气脱硫脱硝需求,提出采用光催化/真空紫外(Vacuum Ultraviolet,VUV)辐射协同海水吸收脱硫脱硝一体化技术,强化SO2和NO在海水中的传质吸收过程.基于舰船烟气脱硫脱硝的过程分析机理,设计小试装置模拟舰船的烟气脱硫脱硝系统,开展实验探究液气比、温度、空速、SO2和NO初始浓度等关键参数下的系统...  相似文献   

6.
莱州湾南岸滨海平原地下卤水水化学特征   总被引:1,自引:0,他引:1       下载免费PDF全文
综合运用数理统计分析方法对莱州湾南岸滨海平原地下卤水样品的水化学特征进行分析,结果表明:莱州湾南岸地下卤水水化学总体特征与海水一致,rNa/rCl,rK /rBr和rMg/rCa系数反映出当地地下卤水来源于沉积古海水,并且海水浓缩程度很高,而变质作用较弱;主成分分析中,第一主分量可以用来解释地下卤水形成时的海水浓缩程度...  相似文献   

7.
基于聚酰胺(PA)膜-甘露醇(M)-NaCl体系分离机理的研究,以及纳滤(NF)膜处理海带废水的前期实验,采用中试规模的NF膜分离装置,系统地进行海带废水中M的NF提取工艺实验。结果表明,影响NF膜分离的工艺参数主要是料液中的M浓度和NaCl浓度以及操作压力和操作温度。NF分离单组分M水溶液时,渗透通量(J)较高,M截留率(RM)大于80%。NF分离M-NaCl混合物水溶液时,RM值稳定在75%~80%,J值稳定在13L/m2·h。当料液中NaCl浓度(CF,S)分别为0.2wt%和0.8wt%时,NaCl透过率(SNaCl)分别约达50%和70%。比较两支NF膜组件的渗透性和选择性,1#优于2#。实验结果与优先渗透和空间位阻的集成效应传质机理预测的相一致。这种新型的去除NaCl和浓缩M双重效果的NF工艺,可以为NF膜纯化提取海带工业中甘露醇的工程应用提供实践基础。  相似文献   

8.
通过对南海北部2009—2010年获得的浅层、中层和深层时间系列沉积物捕获器的样品分析,发现浮游有孔虫总通量和主要属种Globigerinoidesruber,Globigerinoidessacculifer,Pulleniatinaobliquiloculata和Neogloboquadrinadutertrei的通量和百分含量存在明显的季节性变化,在东北季风和西南季风盛行期出现高值,特别在冬季风期间高值明显,在季风间歇期出现低值,展示出"双峰型"通量模式。浮游有孔虫通量与颗粒总通量、有机碳通量、总碳通量、总氮通量、碳酸钙通量和蛋白石通量变化一致,随叶绿素a浓度和风速大小变化而改变,表明南海北部生源颗粒通量主要受季风影响的表层生产力所控制。浮游有孔虫壳体氧同位素与表层海水温度的季节变化相吻合。壳体δ18 O主要受海水温度变化的影响,不同深度属种的δ18 O变化反映了上层海水温度梯度。此外,壳体碳同位素值总体上在东亚季风强盛期低、季风间期高,与表层海水中叶绿素a浓度和海表风速的变化趋势相反,说明浮游有孔虫δ13 C值反映了水体营养和表层生产力的变化。  相似文献   

9.
测定了15℃和24℃相同温度下己知浓度为K的KCl溶液与标准海水电导率的比值Z_(k,t),Z_(,15),在0.96到1.04之间。发现Z_(N,15)=1的标准浓度(N或K_N)为K_N=32.4356gKCl/kg溶液。测量了在15℃或30℃范围内温度对Z_(N,t)的影响,以Z_(15)的函数和反函数关系给出了KCl浓度的方程,以Z_(24)的函数关系给出了Z_(15)/Z_(24)的方程,(用实验室盐度计对KCl和海水进行比较)和以温度的函数关系给出了Z_(N,t)。  相似文献   

10.
根据2006年7~8月和2007年1月对北黄海进行的大面调查,分析研究了夏冬季表层海水中二甲基硫(DMS)的浓度分布和海-气交换通量.研究表明:表层海水以及大气中DMS浓度季节变化明显,夏季平均值分别是冬季的3.2和3.7倍.相关性分析显示,海水中DMS和Chl a浓度存在明显的相关性,说明浮游植物生物量是影响DMS浓度分布的1个重要因素.利用Liss和Merlivat公式(LM86)估算了北黄海夏冬季DMS的海-气交换通量,其平均值分别为7.31和4.98 μmol·m-2·d-1.另外,根据测定的大气中甲基磺酸盐(MSA)和非海盐硫酸盐(Nss-SO2-4)的浓度及比例,估算出夏冬季北黄海生源硫释放对气溶胶中Nss-SO2-4的贡献比例分别为10.1%和2.8%.此结果表明北黄海大气中Nss-SO2-4主要来源于人为排放.  相似文献   

11.
In order to assess the impact of deep-sea mining on the in situ benthic life, we measured the microbial standing stock and concentration of organic nutrients in the deep-sea sediments of the Central Indian Ocean Basin in the Indian pioneer area. Sediments were collected using box core and grab samples during September 1996. The total bacterial numbers ranged from 10 10 -10 11 cells per g -1 dry weight sediment. There was a marginal decrease in the number of bacteria from surface to 30 cm depth, though the subsurface section registered a higher number than did the surface. The highest numbers were encountered at depths of 4-8 cm. The retrievable number of bacteria were two orders less in comparison with the direct total counts of bacteria. An almost homogeneous distribution of bacteria, total organic carbon, living biomass, and lipids throughout the depth of cores indicates active microbial and benthic processes in the deep sea sediments. On the other hand, a uniform distribution of total counts of bacteria, carbohydrates, and total organic carbon in all the cores indicates their stable nature and suggests that they can serve as useful parameters for long-term monitoring of the area after the benthic disturbance. Further studies on temporal variability in this region would not only verify the observed norms of distribution of these variables but would also help to understand restabilization processes after the simulated benthic disturbance.  相似文献   

12.
海上大直径钢管桩打桩过程中,桩周土体受到强烈扰动而发生强度弱化,掌握桩周土体强度弱化规律对于准确预测打桩过程、保证工程安全具有重要意义。为研究土体强度弱化规律,开展了环剪试验模拟打桩对桩周土体的扰动,测试土体强度随剪切速率的变化规律,建立了描述土体强度弱化规律的拟合公式,引入到打桩分析软件中。研究结果表明:土体的强度折减程度不仅与土体本身的性质有关还受到土体的埋深和剪切速率的影响,埋深越深土体强度折减程度越低,剪切速率越高土体强度折减越高,在打桩分析中可采用这里推荐的线性折减方法来模拟不同深度处土体强度的折减规律。  相似文献   

13.
An acoustic inversion method using a wide-band signal and two near field receivers is proposed and applied to multiple layered seabed models including a manganese sediment. The inversion problem can be formulated into a probabilistic model comprised of signals, a forward model, and additive noise. The forward model simulates wide-band signals, such as chirp signals, and is chosen to be the source-waveletconvolution plane wave modeling method. The wavelet matching technique, using weighted least-squares fitting, estimates the sediment sound-speed and thickness on which determination of the possible numerical ranges for a priori uniform distribution is based. The genetic algorithm is applied to a global optimization problem to find a maximum a posteriori solution for determined a priori search space. Here the object function is defined by an L 2 norm of the difference between measured and modeled signals. Not only the marginal pdf but also its statistics are calculated by numerical evaluation of integrals using the samples selected during importance sampling process of the genetic algorithm.  相似文献   

14.
This article reviews information recently available from existing marine and coastal mining for responses to environmental issues affecting marine mining at different depths. It is particularly but not exclusively concerned with those issues affecting seabed biodiversity impact and recovery. Much information has been gathered in the past 10 years from shallow mining operations for construction aggregate, diamonds, and gold, from coastal mines discharging tailings to shallow and deep water, and from experimental deep mining tests. The responses to issues identified are summarized in a series of eight tables intended to facilitate site-specific consideration. Since impacts can spread widely in the surface mixing layer SML, and can affect the biologically productive euphotic zone, the main issues considered arise from the depth of mining relative to the SML of the sea. Where mining is below the SML, the issue is whether it is environmentally better to bring the extraction products to the surface vessel for processing (and waste discharge), or to process the extraction products as much as possible on the seabed. Responses to the issues need to be sitespecific, and dependent on adequate preoperational environmental impact and recovery prediction. For deep tailings disposal from a surface vessel, there are four important environmental unknowns: (1) the possible growth of "marine snow" (bacterial flocs) utilizing the enormous quantities of fine tailings particles (hundreds or thousands of metric tons per day) as nuclei for growth, (2) the possibility that local keystone plankton and nekton species may migrate diurnally down to and beyond the depth of deep discharge and hence be subjected to tailings impact at depth, (3) the burrow-up capability of deep benthos and their ability to survive high rates of tailings deposition, and (4) the pattern and rate of dispersion of a tailings density current through the deep water column from discharge point to seabed. Actions to obtain relevant information in general and site-specifically are suggested.  相似文献   

15.
Particle fluxes were measured 7 m above the sea bottom during the predisturbance, disturbance, and postdisturbance periods by using time series sediment traps attached to seven deep-sea moorings deployed in the INDEX experiment site in the Central Indian Basin. The predisturbance particle fluxes varied between 22.3 to 55.1 mg m -2 day -1 . Increased and variable particle fluxes were recorded by the sediment traps during the disturbance period. The increase observed was 0.5 to 4 times more than the background predisturbance fluxes. The increases in particle fluxes (~4 times) recorded by the sediment trap located in the southwestern direction (DMS-1) were the greatest, which could be the result of preferential movement of resuspended particles generated during the deep-sea benthic disturbance along the general current direction prevailing in this area during the experimental period. Also, the traps located closer to the disturbance area recorded greater fluxes than did the traps far away, across the Deep Sea Sediment Resuspension System path. This variability in recorded particle fluxes by the traps around the disturbance area clearly indicates that physical characteristics such as grain size and density of the resuspended particles produced during the disturbance had an important effect on particle movement. The postdisturbance measurements during ~5 days showed a reduction in particle fluxes of ~50%, indicating rapid particle settlement.  相似文献   

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A set of 27 marine planktonic bacteria isolated from the polar regions was characterized by 16S rDNA sequencing and physiological and biochemical testing. More than half of these bacteria were positive for caseinase, gelatinase and 13-glucosidase, and could utilize glucose, maltose or malic acid as carbon source for cell growth. Twelve isolates expressed nitrate reduction activities. Except for one antarctic isolate BSwlO175 belonging to Actinobacteria phylum, these isolates were classified as γ-Proteobacteria, suggesting that γ-Proteobacteria dominated in cultivable marine bacterioplankton at both poles. Genus Pseudoalteromonas was the predominant group in the Chukchi Sea and the Bering Sea, and genus ShewaneUa dominated in cultivable bacterioplankton in the Prydz Bay. With sequence similarities above 97%, genus Psychrobacter was found at both poles. These 27 isolates were psychrotolerant, and significant 16S rDNA sequence similarities were found not only between arctic and antarctic marine bacteria ( 〉 99% ), but also between polar marine bacteria and bacteria from other aquatic environments ( ≥ 98.8% ), including temperate ocean, deep sea, pond and lake, suggesting that in the polar oceans less temperature-sensitive bacteria may be cosmopolitan and have a bipolar, even global, distribution at the species level.  相似文献   

19.
The advanced piston corer (APC) has been used by the Ocean Drilling Program since 1985 for recovering soft sediments from the ocean floor. The pullout force measured on extracting the core barrel from the sediment is shown to correlate with the average shear strength of the sediment core measured in the ship's laboratory. A simple rule of thumb is derived relating the shear strength of the sediment to the pullout force. Multiple APC holes at individual sites allow the consistency of the pullout measurements to be assessed. The effects of different operational procedures during APC coring are also explored. Although generally applicable, the correlation between pullout force and laboratory measurements of shear strength breaks down for some APC holes, possibly because of the disturbance of some sediment types during the APC coring process. A better understanding of the physical process of APC coring, and its effect on the properties of the sediment both inside and immediately outside the core barrel, would indicate what confidence can be put on the measurement of pullout force as a way of evaluating the in situ shear strength of deep sea sediments.  相似文献   

20.
Oedometer tests have been carried out on 70 undisturbed surficial clays (at approximately 250 mm below the mudline), mostly collected by free-fall corers from sites widely scattered throughout the deep-sea North Atlantic. Acoustic measurements were also made, initially on contiguous samples and ultimately on the same sample using a geophysically instrumented oedometer which also collected electrical resistivity data. Apart from those quiescent areas below the carbonate compensation depth, such as north of the West Indies where very fine clays exist, most of the samples are silty clays whose geotechnical-geophysical properties are dependent on the type of clay minerals present (and their ability to take in moisture), the sand-size fraction, and the quantity of carbonate present. Thus the pure clays have high compressibilities which decrease on the addition of coarse particles, while the converse is true for the acoustic parameters, these increasing with the sand fraction. Using the notion of the intrinsic compression line for all samples, and comparison to it of the measured compression curves, it is clear that, contrary to some previously held ideas, most deep-sea clays are normally consolidated; the addition of carbonate has the effect of creating an open, stronger sediment skeleton. Interestingly, where information is available, the variation with depth of a sample's acoustic velocity follows the void ratio pressure relationship of the compression curve. This allows the construction of an in-situ sediment compression curve using the in-situ geophysical observations.  相似文献   

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