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The Karoo Basin covers much of South Africa and is an area of prospective shale gas exploration, with the Whitehill Formation the target shale unit. However, the sedimentary succession, including the Whitehill, has been intruded by a series of sills and dykes associated with the Karoo Large Igneous Province (~183 Ma), which are expected to have modified the thermal history of the basin dramatically. Here, we investigate a secondary effect of these intrusions: a series of hydrothermal vent complexes, or breccia pipes, focusing on using O, H, and C isotopes to constrain the origin and evolution of fluids produced during the intrusion of basaltic sills. A cluster of breccia pipes have been eroded down to the level of the Ecca Group at Luiperdskop on the western edge of the Karoo basin; a small isolated pipe of similar appearance crops out 13 km to the east. The Luiperdskop pipes are underlain by a Karoo dolerite sill that is assumed to provide the heat driving fluidization. The pipes consist of fine‐grained matrix and about 8% clasts, on average, of mostly sedimentary material; occasional large rafts of quartzite and dolerite are also present. The presence of clasts apparently from the Dwyka Group is consistent with the depth of formation of the pipes being at, or near, the base of the Karoo Supergroup, between 400 and 850 m below present surface. The presence of chlorite as the dominant hydrous mineral is consistent with an emplacement temperature between 300 and 350°C. The major and trace element, and O‐ and H‐isotope composition of the Tankwa breccias is homogenous, consistent with them being derived from the same source. The δ18O values (vsVSMOW) of the breccias are relatively uniform (7.1‰–8.7‰), and are similar to that of the country rock shale, and both are lower than expected for shale. The water content of the breccia is between 2.7 and 3.1 wt.% and the δD values range from ?109‰ to ?144‰. Calcite in vesicles has δ13C and δ18O (VSMOW) values of ?4.2‰ and 24.0‰, respectively. The low δD value of the breccia rocks does not appear to be due to the presence of methane in the fluid. Instead, it is proposed that low δD and δ18O values are the result of the fluid being derived from the breakdown of clay minerals that formed and were deposited at a time of cold climate at ~290 Ma.  相似文献   
3.
Stable water isotopes δ18O and δ2H are used to investigate precipitation trends and storm dynamics to advance knowledge of precipitation patterns in a warming world. Herein, δ18O and δ2H were used to determine the relationship between extratropical cyclonic precipitation and local meteoric water lines (LMWLs) in the eastern Ohio Valley and the eastern United States. Precipitation volume weighted and unweighted central Ohio LMWLs, created with samples collected during 2012–2018, showed that temperature had the greatest effect on precipitation isotopic composition. HYSPLIT back trajectory modelling showed that precipitation was primarily derived from a mid-continental moisture source. Remnants of major hurricanes were collected as extratropical precipitation during the 2012–2018 sampling period in central Ohio. Extratropical precipitation samples were not significantly different from the samples that created the central Ohio LMWL. Six additional LMWLs were derived from United States Geological Survey (USGS) Atmospheric Integrated Research Monitoring Network (AIRMoN) samples collected in Pennsylvania, Delaware, Tennessee, Vermont, New Hampshire, and Oxford, Ohio. Meteoric water lines describing published samples from Superstorm Sandy, plotted with these AIRMoN LMWLs, showed isotopic composition of Superstorm Sandy precipitation was commonly more depleted than the average isotopic composition at the mid-latitude locations. Meteoric water lines describing the Superstorm Sandy precipitation were not significantly different in slope from LMWLs generated within 300 km of the USGS AIRMoN site. This finding, which was observed across the eastern Ohio Valley and eastern United States, demonstrated a consistent precipitation δ2H–δ18O relationship for extratropical cyclonic and non-cyclonic events. This work also facilitates the analysis of storm development based on the relationship between extratropical event signature and the LMWL. Analysis of extratropical precipitation in relation to LMWLs along storm tracks allows for stronger development of precipitation models and understanding of which climatic and atmospheric factors determine the isotopic composition of precipitation.  相似文献   
4.
The giant impact hypothesis is the dominant theory explaining the formation of our Moon. However, the inability to produce an isotopically similar Earth–Moon system with correct angular momentum has cast a shadow on its validity. Computer-generated impacts have been successful in producing virtual systems that possess many of the observed physical properties. However, addressing the isotopic similarities between the Earth and Moon coupled with correct angular momentum has proven to be challenging. Equilibration and evection resonance have been proposed as means of reconciling the models. In the summer of 2013, the Royal Society called a meeting solely to discuss the formation of the Moon. In this meeting, evection resonance and equilibration were both questioned as viable means of removing the deficiencies from giant impact models. The main concerns were that models were multi-staged and too complex. We present here initial impact conditions that produce an isotopically similar Earth–Moon system with correct angular momentum. This is done in a single-staged simulation. The initial parameters are straightforward and the results evolve solely from the impact. This was accomplished by colliding two roughly half-Earth-sized impactors, rotating in approximately the same plane in a high-energy, off-centered impact, where both impactors spin into the collision.  相似文献   
5.
The devastating impacts of the widespread flooding and landsliding in Puerto Rico following the September 2017 landfall of Hurricane Maria highlight the increasingly extreme atmospheric disturbances and enhanced hazard potential in mountainous humid-tropical climate zones. Long-standing conceptual models for hydrologically driven hazards in Puerto Rico posit that hillslope soils remain wet throughout the year, and therefore, that antecedent soil wetness imposes a negligible effect on hazard potential. Our post-Maria in situ hillslope hydrologic observations, however, indicate that while some slopes remain wet throughout the year, others exhibit appreciable seasonal and intra-storm subsurface drainage. Therefore, we evaluated the performance of hydro-meteorological (soil wetness and rainfall) versus intensity-duration (rainfall only) hillslope hydrologic response thresholds that identify the onset of positive pore-water pressure, a predisposing factor for widespread slope instability in this region. Our analyses also consider the role of soil-water storage and infiltration rates on runoff generation, which are relevant factors for flooding hazards. We found that the hydro-meteorological thresholds outperformed intensity-duration thresholds for a seasonally wet, coarse-grained soil, although they did not outperform intensity-duration thresholds for a perennially wet, fine-grained soil. These end-member soils types may also produce radically different stormflow responses, with subsurface flow being more common for the coarse-grained soils underlain by intrusive rocks versus infiltration excess and/or saturation excess for the fine-grained soils underlain by volcaniclastic rocks. We conclude that variability in soil-hydraulic properties, as opposed to climate zone, is the dominant factor that controls runoff generation mechanisms and modulates the relative importance of antecedent soil wetness for our hillslope hydrologic response thresholds.  相似文献   
6.
ABSTRACT

In the past, population growth in Australia's Northern Territory, as in other peripheral parts of high-income countries, has been driven by internal labour migration and migration from outside of Australia. These have been contributing to the high population turnover experienced in peripheral areas. Since 2010, the Northern Territory has experienced low (and even negative) population growth, and public policy is currently focused on migration as a lever to reverse this trend. However, the extent to which the characteristics of migrants influence the potential for longer-term population growth is poorly understood. This paper uses a new method to analyse the contributions of various types of migrants to both population turnover and retention. Two major sets of findings emerge: First, the significance of separating newer in-migrants from longer-term residents when analysing migration patterns; and secondly, the contribution of age, gender, Indigenous status, international origin, wages and industry of employment to the Northern Territory's population turnover. The research suggests that current forms of migration favour people who are likely to stay for only short periods, and have high wage demands. The main policy inference is that long-term population growth will likely not eventuate unless new forms of migration can be stimulated.  相似文献   
7.
As part of the secondary school qualification repackaging, the Ministry of Education has requested the geography education community define what constitutes their “critical body of knowledge.” In this article, I discuss three knowledge‐oriented themes focused on: (a) recent assessment trends in geography; (b) the predictive value of NCEA Level 3 geography with 100‐level success and (c) the nature of knowledge as expressed by the New Zealand Curriculum and assessment. Taken together, these themes suggest a need for a serious conversation about knowledge in school geography, as a pre‐cursor to the re‐design of the geography standards matrix.  相似文献   
8.
Little is known about the spatial and temporal variability of peat erosion nor some of its topographic and weather-related drivers. We present field and laboratory observations of peat erosion using Structure-from-Motion (SfM) photogrammetry. Over a 12 month period, 11 repeated SfM surveys were conducted on four geomorphological sites of 18–28 m2 (peat hagg, gully wall, riparian area and gully head) in a blanket peatland in northern England. A net topographic change of –14 to +30 mm yr–1 for the four sites was observed during the whole monitoring period. Cold conditions in the winter of 2016 resulted in highly variable volume change (net surface topographic rise first and lowering afterwards) via freeze–thaw processes. Long periods of dry conditions in the summer of 2017 led to desiccation and drying and cracking of the peat surface and a corresponding surface lowering. Topographic changes were mainly observed over short-term intervals when intense rainfall, flow wash, needle-ice production or surface desiccation was observed. In the laboratory, we applied rainfall simulations on peat blocks and compared the peat losses quantified by traditional sediment flux measurements with SfM derived topographic data. The magnitude of topographic change determined by SfM (mean value: 0.7 mm, SD: 4.3 mm) was very different to the areal average determined by the sediment yield from the blocks (mean value: –0.1 mm, SD: 0.1 mm). Topographic controls on spatial patterns of topographic change were illustrated from both field and laboratory surveys. Roughness was positively correlated to positive topographic change and was negatively correlated to negative topographic change at field plot scale and laboratory macroscale. Overall, the importance of event-scale change and the direct relationship between surface roughness and the rate of topographic change are important characteristics which we suggest are generalizable to other environments. © 2018 John Wiley & Sons, Ltd.  相似文献   
9.
Anatexis of metapelitic rocks at the Bandelierkop Quarry (BQ) locality in the Southern Marginal Zone of the Limpopo Belt occurred via muscovite and biotite breakdown reactions which, in order of increasing temperature, can be modelled as: (1) Muscovite + quartz + plagioclase = sillimanite + melt; (2) Biotite + sillimanite + quartz + plagioclase = garnet + melt; (3) Biotite + quartz + plagioclase = orthopyroxene ± cordierite ± garnet + melt. Reactions 1 and 2 produced stromatic leucosomes, which underwent solid‐state deformation before the formation of undeformed nebulitic leucosomes by reaction 3. The zircon U–Pb ages for both leucosomes are within error identical. Thus, the melt or magma formed by the first two reactions segregated and formed mechanically solid stromatic veins whilst temperature was increasing. As might be predicted from the deformational history and sequence of melting reactions, the compositions of the stromatic leucosomes depart markedly from those of melts from metapelitic sources. Despite having similar Si contents to melts, the leucosomes are strongly K‐depleted, have Ca:Na ratios similar to the residua from which their magmas segregated and are characterized by a strong positive Eu anomaly, whilst the associated residua has no pronounced Eu anomaly. In addition, within the leucosomes and their wall rocks, peritectic garnet and orthopyroxene are very well preserved. This collective evidence suggests that melt loss from the stromatic leucosome structures whilst the rocks were still undergoing heating is the dominant process that shaped the chemistry of these leucosomes and produced solid leucosomes. Two alternative scenarios are evaluated as generalized petrogenetic models for producing Si‐rich, yet markedly K‐depleted and Ca‐enriched leucosomes from metapelitic sources. The first process involves the mechanical concentration of entrained peritectic plagioclase and garnet in the leucosomes. In this scenario, the volume of quartz in the leucosome must reflect the remaining melt fraction with resultant positive correlation between Si and K in the leucosomes. No such correlation exists in the BQ leucosomes and in similar leucosomes from elsewhere. Consequently, we suggest disequilibrium congruent melting of plagioclase in the source and consequential crystallization of peritectic plagioclase in the melt transfer and accumulation structures rather than at the sites of biotite melting. This induces co‐precipitation of quartz in the structures by increasing SiO2 content of the melt. This process is characterized by an absence of plagioclase‐induced fractionation of Eu on melting, and the formation of Eu‐enriched, quartz + plagioclase + garnet leucosomes. From these findings, we argue that melt leaves the source rapidly and that the leucosomes form incrementally as melt or magma leaving the source dumps its disequilibrium Ca load, as well as quartz and entrained ferromagnesian peritectic minerals, in sites of magma accumulation and escape. This is consistent with evidence from S‐type granites suggesting rapid magma transfer from source to high level plutons. These findings also suggest that leucosomes of this type should be regarded as constituting part of the residuum from partial melting.  相似文献   
10.
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