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云南老王寨金矿区煌斑岩的成因：稀土元素研究 总被引：6，自引：0，他引：6
云南老王寨金矿区煌斑岩与金矿化在时间上、空间上密切共生。主要元素分析表明，本区煌斑岩属钾质－富钾质钙碱性煌斑岩；与原始地幔和大洋中脊玄武岩相比，岩石相对富集稀土元素；模拟计算表明，岩石来源于稀土元素相对富集的交代富集地幔；地质发展史、不相容元素分配型式、Ｓｒ、Ｎｄ同位素组成及有关模拟计算表明，俯冲进入地幔楔的地壳物质脱水 流体是引起该区地幔交代作用的主要因素。 相似文献
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分布于攀西及邻近地区的煌斑岩主要为云辉正煌岩-黑云正煌岩、白榴橄榄云辉岩、透辉云煌岩,常量元素特征表明岩石属于碱性系列、钾质钙碱性煌斑岩;过渡元素分配模式为幔源岩石的"W"型、不相容元素分配模式为大离子亲石元素和高场强元素富集的"驼峰"型、稀土元素分配模式为"右倾"的轻稀土富集型,表明该区煌斑岩为交代富集地幔部分熔融的产物.Ta-Nb-Ti负异常分配模式说明源区煌斑岩具有的交代富集地幔可能和板块俯冲有关.源区大地构造环境为活动大陆边缘的陆缘岛弧或陆缘火山弧区. 相似文献
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云南白马寨镍矿区煌斑岩地球化学Ⅰ.主要元素和微量元素 总被引：9，自引：1，他引：9
云南白马寨镍矿区煌斑岩呈岩墙和岩脉穿切矿区各时代地层、基性-超基性岩和矿体，为成矿期后产物；采自矿区不同中段和不同产状的煌斑岩具有相似矿物组合，岩石类型均为云煌岩；岩石化学特征表明岩石均为钾质-富钾质钙碱性煌斑岩；微量元素配分模式为相似的“骆峰型”，与MORB相比，富集LILE和HPSE；REE配分模式为相似的LREE富集型；主要元素和微量元素与镁指数(M值)之间存在一定的相关关系；在La—La／Sm图中样品既有水平分布趋势、也有倾斜分布趋势。总体上，该区煌斑岩为相同岩浆源区的产物，源区地幔部分熔融程度和岩浆结晶分异作用对岩石主要元素和微量元素地球化学性质均有一定的影响。比较老王寨金矿区煌斑岩形成地质背景、岩石类型、主要元素和微量元素地球化学特征，认为两地区煌斑岩地幔源区具有相同或相似、的性质。 相似文献
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目前所知产金刚石的岩石类型包括金伯利岩、钾镁煌斑岩、榴辉岩、蛇绿岩套、碱性超基性杂岩、碱性超基性煌斑岩和橄榄岩类(方辉橄榄岩、纯橄榄岩等) 等偏碱性超镁铁质岩石, 而有经济价值的金刚石原生矿床仅见于金伯利岩和钾镁煌斑岩中, 除此之外的其他岩石类型中仅见有少量微粒金刚石.金伯利岩和钾镁煌斑岩都起源于地幔深部, 就此意义上讲, 二者是同源的, 但其岩石化学成分、主要矿物组成、产出大地构造背景以及同位素资料等, 却存在着比较明显的差异.由此构成了金刚石原生矿床的两个成矿系列: 金伯利岩成矿系列和钾镁煌斑岩成矿系列.金伯利岩成矿系列又可以根据其化学成分划分为3个亚系列, 即: 高Cr, Ti, Mg成矿亚系列, 低Cr, Ti, Mg成矿亚系列和介于二者之间的一种具有复杂化学成分的成矿亚系列.钾镁煌斑岩成矿系列则可以根据其主要矿物组成, 划分出橄榄石钾镁煌斑岩成矿亚系列、白榴石钾镁煌斑岩成矿亚系列以及介于两者之间的白榴石-橄榄石钾镁煌斑岩成矿亚系列共3种次级成矿系列.与此同时, 无论是金伯利岩成矿系列, 还是钾镁煌斑岩成矿系列, 又都可以根据其野外地质产状, 划分为以下3个成矿亚系列(形成时间从早到晚) : (1) 火山沉积凝灰岩成矿亚系列; (2) 火山凝灰角砾岩成矿亚系列; (3) 火山-次火山侵入相成矿亚系列. 相似文献
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甘肃宕昌好梯含上地幔包体和巨晶的碱性超基性火山岩为新生代火山作用的产物。该火山岩的岩相学、矿物学、岩石化学和地球化学特征显示了从碱性基性岩(霞石碱玄岩-碧玄岩)-超基性岩(苦橄岩-玻基辉橄岩)-钾镁煌斑岩之过渡类型岩石的特征。表明好榜火山岩是一种煌斑岩。根据火山岩的岩相学、矿物学、岩石化学和地球化学特征,火山岩的镁铁指数>90,特别是岩石中含一定数量的金云母以及含白榴石、原生方解石、碱性角闪石和碱性辉石的球状分异物等特征,将该火山岩命名为钾质超镁铁煌斑岩。本文还提出该钾质超镁铁煌斑岩代表一种原生煌斑岩浆的标志。 相似文献
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作为最早被识别出的碱性岩石之一,煌斑岩因富含金和金刚石等矿产资源以及对理解深部地球动力学过程的重要作用而受到广泛重视,但是目前对于煌斑岩的成因还存在不同的认识。本文基于近年来对煌斑岩的研究成果,对它们的分类、特征以及岩石成因进行综述。根据国际地科联(IUGS)的分类标准,煌斑岩可以分为超镁铁质煌斑岩、钙碱性煌斑岩和碱性煌斑岩。研究发现,超镁铁质煌斑岩往往是伸展环境下岩浆作用的产物,与金伯利岩和碳酸岩有密切的成因关系;钙碱性煌斑岩通常发育在汇聚或被动大陆边缘环境,其岩石成因可能有多种机制(如基性岩浆的分异、岩浆混合以及交代富集地幔的部分熔融);碱性煌斑岩出露在离散型大陆边缘和板内构造环境,通常和碱性玄武质岩浆作用密切相关。不管岩石的形成环境和过程如何,超镁铁质煌斑岩、钙碱性煌斑岩和碱性煌斑岩被普遍认为是来自于经历了交代富集作用的地幔源区。最后,文章指出了煌斑岩研究过程中存在的一些科学问题,如富集的地幔源区存在的矿物相(金云母和角闪石)对产生钠质还是钾质岩浆的影响,控制岩浆在结晶过程中影响含水矿物斑晶形成的因素以及部分煌斑岩中碳酸岩球粒和钠长石的形成原因等。 相似文献
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云南老王寨金矿区煌斑岩的地球化学 总被引：15，自引：1，他引：15
报道了云南老王寨金矿区与金矿化时空密切共生的煌斑岩的地球化学资料。主要元素研究表明，研究区煌斑岩属钾质－富钾质钙碱性煌斑岩；过渡元素分配模式为典型幔源岩石的“Ｗ”型，岩石富集大离子亲石元素、高场强元素、稀土元素以及相对高＾８７Ｓｒ／＾８６Ｓｒ、低＾１４３Ｎｄ／＾１４４Ｎｄ比值等特征都暗示，该区煌斑岩源于交代富集地幔；地质发展史，不相容元素分配模式，Ｓｒ、Ｎｄ同位素组成及有关模拟计算表明，俯冲进入地 相似文献
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云南马厂箐金矿区煌斑岩地球化学及成因探讨 总被引：8，自引：0，他引：8
广泛分布于云南马厂箐金矿区煌斑岩主要为云煌区，主要元素表明为碱性系列、钾质钙碱性煌斑岩；过渡元素分配模式为慢源岩石的“Ｗ”型、不相容元素分配模式为大离子亲石元素和高场强元素富集的“骆峰”型、稀土元素分配模式为“右倾”的经稀土富集型、以及模拟计算均表明，该区煌斑岩为交代富集地幔部分熔融（熔融程度约为１２％）的产物。新鲜、蚀变、矿化煌斑岩Ａｕ，ＣＯ２，Ｆｅ２Ｏ３，ＦｅＯ等的含量及变化规律，暗示其在金矿 相似文献
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河北省涞源—阜平一带煌斑岩的岩石学研究 总被引：3，自引：0，他引：3
在涞源地区侵入了大量以碱性为主的煌斑岩,这些煌斑岩是一套来自地幔深部的基性岩石。碱性煌斑岩SiO_2<46％,TiO_2≥1.5％,F≥5％;钙碱性煌斑岩SiO_2≥46％,TiO_2<1.5％,F<5％。碱性煌斑岩有棕闪斜煌斑岩、碱云煌岩,碱云斜煌岩、碱闪正煌岩、碱云闪斜煌斑岩、碱云闪正煌岩,这些碱性煌斑岩均以具含钛暗色矿物为特征。钙碱性煌斑岩主要有闪斜煌斑岩、角闪正煌岩,暗色矿物含钛极少或不含钛。本区煌斑岩受地壳的同化混染的影响不大,基本上为原生岩浆。本区无钾镁煌斑岩。 相似文献
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Pliocene volcanics on the island of Bequia comprise two interbeddedsuites of basalts and andesites. The isotopically homogeneoussuite (IHS) has a limited range of Sr—Nd—Pb isotopes(87Sr/86Sr 0.7040–0.7046, 143 Nd/144 Nd 0.5130 and 206Pb/204Pb 19.36–19.51), and mantle-like 18O values (5.5in clinopyroxene). The isotopically diverse suite (IDS) is characterizedby much wider ranges of radiogenic isotopes (87 Sr/86Sr 0.7048–0.7077,143 Nd/144 Nd 0.5128–0.5123 and 206 Pb/204 Pb 19.7–20.2),in which all of the Sr and Pb ratios are higher and Nd ratiosare lower than those of the IHS. The IDS is also characterizedby high 18 O values, up to 7.6 in clinopyroxene. The Sr andPb isotope ratios are too high, and the Nd isotope ratios aretoo low in the IDS for any of these lavas to be derived fromunmodified depleted mantle. Both suites are petrologically very similar and their majorelement compositions and phenocryst contents suggest that theywere formed largely by fractional crystallization of a hydroustholeiitic melt at pressures <3 kbar. The isotopic ratiosand enrichments in large ion lithophile elements (LILE), andto some extent light rare earth elements (LREE), as comparedwith mid-ocean ridge basalts (MORB), of the IHS lavas suggestthat they were derived from a depleted mantle source which hadbeen re-enriched by the addition of 1–4% of a subductioncomponent. This component probably comprised a mixture of dehydrationfluids, and perhaps minor siliceous melts, released from subductingsediments and mafic crust. The extreme isotopic ranges, largeenrichments in incompatible elements, more fractionated LREEpatterns and higher 18 O values of the IDS lavas are interpretedas resulting from 10–55% assimilation—fractionalcrystallization of sediments, derived from the Guyana Shield,which are present in the arc crust, by IHS type melts. KEY WORDS: trace elements; radiogenic isotopes; arc lavas; Lesser Antilles
*Corresponding author. 相似文献
12.
Luigi Beccaluva Gianluca Bianchini Massimo Coltorti William Perkins Franca Siena Carmela Vaccaro Marjorie Wilson 《Contributions to Mineralogy and Petrology》2001,142(3):284-297
Peridotite xenoliths entrained in Plio-Pleistocene alkali basalts from Sardinia represent fragments of the uppermost lithospheric mantle, and are characterised by an anhydrous four-phase mineral assemblage. They range in bulk rock composition from fertile spinel-lherzolites to residual spinel-harzburgites. The Sr-Nd isotope and trace element composition of clinopyroxene mineral separates varies between LREE-depleted samples with 87Sr/86Sr as low as 0.70262 and 143Nd/144Nd up to 0.51323 and LREE-enriched samples with 87Sr/86Sr up to 0.70461 and 143Nd/144Nd down to 0.51252. The available data suggest that all the studied peridotite samples suffered variable degrees of partial melting during Pre-Mesozoic times (based on Nd model ages relative to CHUR and DMM). The overprinted enrichment is related to a subsequent metasomatism, induced by fluids rising through the lithosphere that preferentially percolated the originally most depleted domains. Despite the occurrence of orogenic volcanism in the area, preferential enrichment in elements typically associated with slab derived fluids/melts (K, Rb, Sr, Th) relative to LREE has not been detected, and metasomatism seems to be more likely related to the infiltration of highly alkaline basic melts characterised by an EM-like Sr-Nd isotopic composition. Similar 87Sr/86Sr-143Nd/144Nd compositions, characterised by an EM signature, are observed in anorogenic mafic lavas and peridotite xenoliths from widespread localities within the "European" plate, whereas they have not previously been recorded in peridotite xenoliths and associated alkaline mafic lavas from the stable "African" lithospheric domain. 相似文献
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The northeast part of the Czech Republic (Moravia) and the adjoining part of Poland host a 100-km-long and 15- to 25-km-wide belt containing numerous isolated bodies (mainly sills) of lamprophyre of Lower Cretaceous age. The lamprophyres range from mafic (melanocratic) to evolved, feldspar-rich (mesocratic) variants. Mineralogically, they are characterized by compositionally zoned kaersutite phenocrysts, biotite and high Al–Ti salitic to diopsidic clinopyroxene. The lamprophyres are typically alkaline as shown by high contents of P2O5, TiO2, alkalies and incompatible trace elements such as light REE, Zr, Nb, Y, Ba and Sr, and by high Ti/V (>50) and chondrite-normalized (La/Yb)n (8–25) ratios. They resemble alkali basalts, basanites and nephelinites. Major element composition and trace element patterns and Nd–Sr isotopic values (εNd ca. +5.5 to +6.6 and εSr ca. –9.5 to –24.0) indicate that the lamprophyric magma was derived from a mantle source that was compositionally similar to the source of ocean island basalts with HIMU affinities and some continental extension-related alkali basaltic suites. The lamprophyres do not show any subduction imprint. They were generated in the garnet stability field by a variable degree of melting. Evolved lamprophyres were formed by clinopyroxene-dominated fractional crystallization of mafic lamprophyric magma. The lamprophyres are interpreted to have been emplaced along conduits formed during the formation of a basin/graben structure in the Early Cretaceous. 相似文献
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Petrology, Mineral and Isotope Geochemistry of the External Liguride Peridotites (Northern Apennines, Italy) 总被引：9，自引：5，他引：4
RAMPONE E.; HOFMANN A. W.; PICCARDO G. B.; VANNUCCI R.; BOTTAZZI P.; OTTOLINI L. 《Journal of Petrology》1995,36(1):81-105
Mantle peridotites of the External Liguride (EL) units (NorthernApennines) represent slices of subcontinental lithospheric mantleemplaced at the surface during early stages of rifting of theJurassic Ligurian Piemontese basin. Petrological, ion probeand isotopic investigations have been used to unravel the natureof their mantle protolith and to constrain the timing and mechanismsof their evolution. EL peridotites are dominantly fertile spinelIherzolites partly recrystallizfd in the plagiodase Iherzplitestability field Clinopyroxenes stable in thespinel-facies assemblagehave nearly fiat REE patterns (CeN/SmN=06–08) at (10–16)C1and high Na, Sr, Ti and Zr contents. Kaersutitic-Ti-pargasiticamphiboles also occur in the spinel-facies assemblage. TheirLREE-depleted REE spectra and very low Sr, Zr and Ba contentsindicate that they crystallized from hydrous fluids with lowconcentrations of incompatible elements. Thermometric estimateson the spinelfacies parageneses yield lithospheric equilibriumtemperatures in the range 1000–1100C, in agreement withthe stability of amphibole, which implies T<1100C. Sr andNd isotopic compositions, determined on carefully handpickedclinopyroxene separates, plot within the depleted end of theMORB field (87Sr/86Sr=070222–070263; 143Nd/144Nd=0513047–0513205)similar to many subcontinental orogenic spinel Iherzolites fromthe western Mediterranean area (e.g. Ivrea Zpne and Lanzfl N).The interpretation of the EL Iherzolites as subcontinental lithosphericmantle is reinforced by the occurrence of one extremely depletedisotopic composition (87Sr/86Sr=0701736; 143Nd/144Nd=0513543).Sr and Nd model ages, calculated assuming both CHUR and DM mantlesources, range between 24 Ga and 780 Ma. In particular, the12-Ga Sr age and the 780-Ma Nd age can be regarded as minimumages of differentiation. The transition from spinel-to plagioclase-faciesassemblage, accompanied by progressive deformation (from granularto tectonite-mylonite textures), indicate that the EL Iherzolitesexperienced a later, subsolidus decompressional evolution, startingfrom subcontinental lithospheric levels. Sm/Nd isochrons onplagioclase-clinopyroxene pairs furnish ages of 165 Ma. Thisearly Jurassic subsolidus decompressional history is consistentwith uplift by means of denudation in response to passive andasymmetric lithospheric extension. This is considered to bethe most suitable geodynamic mechanism to account for the exposureof huge bodies of subcontinental lithospheric mantle duringearly stages of opening of an oceanic basin.
*Corresponding author. Present address: Dipartimento di Stienze della Terra, Univenit di Geneva, Corso Europa 26,16132 Genova, Italy 相似文献
15.
VINCENZO GIANFRANCO DI; ANDRIESSEN PAUL A. M.; GHEZZO CLAUDIO 《Journal of Petrology》1996,37(5):1175-1206
Detailed petrographic and geochemical data and Sr and Nd isotopecompositions of enclaves and host-granite are reported for oneof the largest strongly peraluminous cordierite-bearing intrusionsof the Hercynian Sardinia-Corsica Batholith: the San BasilioGranite. Compared with other peraluminous series, the San BasilioGranite has a ‘non-minimum melt’ composition andshows variations primarily owing to fractionation of early-crystallizedplagioclase, quartz and biotite. Crystallization age is constrainedat 305 Ma, by Rb-Sr whole-rock age [30523 Ma with (87Sr/86Sr)i= 0.711050.00041], and occurred during late Hercynian tectonicevents. Nd(305Ma) values range from –7.8 to –7.5.The San Basilio Granite contains both magmatic and metamorphicenclaves. Magmatic enclaves, similar to mafic microgranularenclaves common in calc-alkaline granitoids, are tonalitic incomposition and show a variation in silica content from 60.3to 67.7 wt % correlating with a variation in (87Sr/86 Sr) (305Ma)and Nd (305 Ma) from 0.7092 to 0.7109 and from –6.6 to–7.4, respectively. Together with petrographic and othergeochemical data, the Sr and Nd isotopic data record differentstages in a complex homogenization process of an unrelated maficmagma with a crustal melt. A process of simple mixing may accountfor the variations of nonalkali elements and, to some extent,of Sr and Nd isotopes, whereas the distribution of alkali elementsrequires diffusioncontrolled mass transfer. Petrographic andmineralogical data on metamorphic enclaves and geochemical modellingfor trace elements in granite indicate melt generation by high-degreepartial melting involving biotite breakdown of a dominantlyquartzo-feldspathic protolith at about T>750–800Cand P>6 kbar leaving a granulite facies garnet-bearing residue,followed by emplacement at 3 kbar. Nd(305Ma) values of thegranite fall within the range defined by the pre-existing metamorphicrocks but (87Sr/86Sr) (305Ma) ratios are lower, indicating involvementof at least two distinct components: a dominant crustal componentand a minor well-mixed mafic end-member. These data point toa decoupling between the Sr-Nd isotope systematics and majorand trace element compositions, suggesting that the effect ofthe mafic component was minor on granite major and trace elementconcentrations, but significant on Sr and Nd isotopes. The studyof the magmatic enclaves and the isotopic evidence demonstratethat unrelated mafic magmas, probably derived from the mantle,had a close spatial and temporal association with the productionof ‘on-minimum melt’ strongly peraluminous granites,and support the proposal that heat from the mafic magma contributedto crustal melting. KEY WORDS: cordierite-bearing granite; enclaves; felsic-mafic interaction; Sardinia-Corsica Batholith; Sr and Nd isotopes
*Corresponding author. 相似文献
16.
Origin of Archean lamprophyre dykes,Superior Province,Canada: rare earth element and Nd−Sr isotopic evidence 总被引：1，自引：0，他引：1
Hornblende- and clinopyroxene-phyric lamprophyre dykes exposed in the Roaring River Complex, Superior Province are alkaline, nepheline-normative, basaltic compositions (>50 wt% SiO2), that range from primitive to fractionated [Mg/(Mg + total Fe)=0.66–0.40; Ni=200–35 ppm], and which have high abundances of light rare earth elements (REE) [(Ce/Yb)n=16–26, Cen=60–300; n = chondrite normalized], Sr (870–1,800 ppm), P2O5 (0.4–1.3 wt%), and Ba (150–900 ppm). Crystal fractionation of the lamprophyres produced coeval gabbro and clinopyroxenite cumulate bodies. A whole-rock Sm–Nd isochron for lamprophyres and gabbro-pyroxenite yields a crystallization age of 2,667±51 Ma Ma (I=0.50929±0.0004;
Nd = + 2.3 0.7). Whole-rock Sr isotope data are scattered, but suggest an initial 87Sr/86Sr ratio of 0.7012, similar to bulk Earth. The elevated levels of light REEs and Sr in the lamprophyres were not due to crustal contamination or mixing with contemporaneous monzodioritic magmas, but a result of partial melting of a mantle source which was enriched in these and other large-ion-lithophile elements (LILEs) shortly before melting. The lamprophyres were contemporaneous with mantle-derived, high-Mg, LILE-enriched monzodiorite to granodiorite of the Archean sanukitoid suite. Both suites have concave-downward light REE profiles, suggesting that depleted mantle was common to their source regions, but the higher light REE abundances, higher Ba/La ratios, and lower
Nd values (+1.3±0.3) of the parental monzodiorites suggest a more enriched source. The lamprophyres and high-Mg monzodiorites were derived from a mineralogically and compositionally heterogeneous, LILE-enriched mantle lithosphere that may have been part of a mantle wedge above a subducting plate in an arc environment. 相似文献
17.
Geochemistry of lamprophyres from the Western Alps,Italy: implications for the origin of an enriched isotopic component in the Italian mantle 总被引：3，自引：0，他引：3
Jennifer Paige Owen 《Contributions to Mineralogy and Petrology》2008,155(3):341-362
Cenozoic lamprophyres (minettes, spessartites, kersantite) from the Western Alps, northern Italy, represent small volume,
mafic melts with high Mg#s and high Ni and Cr contents. All the lamprophyres show light REE enrichment, high incompatible
element contents, and Ta, Ti and Nb troughs on chondrite-normalized diagrams. Age-corrected 87Sr/86Sr isotopic ratios (assuming t = 30 Ma) are highly variable and range from 0.70590 to 0.71884; 143Nd/144Nd ratios range from 0.51203 to 0.51242. Pb isotopic ratios are: 206Pb/204Pb = 18.669–18.895, 207Pb/204Pb = 15.605–15.689 and 208Pb/204Pb = 38.224–39.134. 87Sr/86Sr ratios show a negative correlation with 143Nd/144Nd, and a positive correlation with K, Ba, and Rb as well as with Ti, Th, Ta, Nb and Zr abundances. The primitive nature of
the lamprophyres, coupled with their enriched incompatible trace element and isotopic signatures, suggest derivation from
a metasomatized upper mantle source. Linear arrays in isotope space and elemental data plots suggest mixing between two distinct
end-members in the Italian mantle; an enriched end-member that is isotopically similar to pelagic sediments, and a significantly
less enriched end-member that approaches Bulk Earth values. New isotopic data indicate that the mantle source(s) of the lamprophyres
from the Western Alps contain a very high proportion of the enriched end-member. The geochemical signature of the enriched
end-member is attributed to fluids or melts derived from pelagic sediments subducted during the closure of the Tethyan Ocean
in the late Cretaceous to early Tertiary. 相似文献
18.
Sediment mixing and recycling through a subduction zone canbe detected in lead isotopes and trace elements from basaltsand sediments from the Kermadec-Hikurangi Margin volcanic arcsystem and their coupled back-arc basins. Sr, Nd and Pb isotopesfrom the basalts delineate relatively simple, almost overlapping,arrays between back-arc basin basalts of the Havre Trough-NgatoroBasin (87Sr/86Sr = 0.70255; Nd=+9.3; 206Pb/204Pb = 18.52; 208Pb/204Pb= 38.18), island arc basalts from the Kermadec Arc togetherwith basalts from Taupo Volcanic Zone (87Sr/86Sr 0.7042; Nd= +5; 206Pb/204Pb= 18.81; 208Pb/204Pb = 38.61), and sedimentsderived from New Zealand's Mesozoic (Torlesse) basement (87Sr/86Sr 0.715; Nd —4; 206Pb/204Pb 18.86; 208Pb/204Pb 38.8).Basalts from the arc front volcanoes have high Cs, Rb, Ba, Th,U and K, and generally high but variable Ba/La, Ba/Nb ratios,characteristic of subduction-related magmas, relative to typicaloceanic basalts. These signatures are diluted in the back-arcbasins, which are more like mid-ocean ridge basalts. Strongchemical correlations in plots of SiO2 vs CaO and loss on ignitionfor the sediments (finegrained muds) are consistent with mixingbetween detrital and biogenic (carbonate-rich) components. Otherdata, such as Zr vs CaO, are consistent with the detrital componentcomprising a mixture of arc- and continent-derived fractions.In chondrite-normalized diagrams, most of the sediments havelight rare earth element enriched patterns, and all have negativeEu anomalies. The multielement diagrams have negative spikesat Nb, P and Ti and distinctive enrichments in the large ionlithophile elements and Pb relative to mantle. Isotopic measurementsof Pb, Sr and Nd reveal restricted fields of Pb isotopes butwide variation in Nd and Sr relative to other sediments fromthe Pacific Basin. Rare K-rich basalts from Clark Volcano towardthe southern end of the oceanic Kermadec Island Arc show unusualand primitive characteristics ( 2% K2O at 50% SiO2, Ba 600p.p.m., 9–10% MgO and Ni > 100 p.p.m.) but have highlyradiogenic Sr, Nd and Pb isotopes, similar to those of basaltsfrom the continental Taupo Volcanic Zone. These oceanic islandarc basalts cannot have inherited their isotope signatures throughcrustal contamination or assimilation—fractional crystallizationtype processes, and this leads us to conclude that source processesvia bulk sediment mixing, fluid and/or melt transfer or somecombination of these are responsible. Although our results showclear chemical gradients from oceanic island arc to continentalmargin arc settings (Kermadec Arc to Taupo Volcanic Zone), overlapbetween the data from the oceanic and continental sectors suggeststhat the lithospheric (crustal contamination) effect may beminimal relative to that of sediment subduction. Indeed, itis possible to account for the chemical changes by a decreasenorthward in the sediment flux into the zone of magma genesis.This model receives support from recent sediment dispersal studiesin the Southern Ocean which indicate that a strong bottom current(Deep Western Boundary Current) flows northward along the easterncontinental margin of New Zealand and sweeps continental derivedsediment into the sediment-starved oceanic trench system. Thetrace element and isotopic signatures of the continental derivedcomponent of this sediment are readily distinguished, but alsodiluted in a south to north direction along the plate boundary. KEY WORDS: subduction zone basalts; sediments; Sr-, Nd-, Pb-isotopes; trace elements
*Present address: School of Earth Sciences, University of Melbourne, Parkville, Vic. 3052, Australia. 相似文献
19.
Constraints on the Source Components of Lavas Forming the Hawaiian North Arch and Honolulu Volcanics 总被引：4，自引：1，他引：4
Hawaiian volcanoes, dominantly shields of tholeiitic basalt,form as the Pacific Plate migrates over a hotspot in the mantle.As these shields migrate away from the hotspot, highly alkaliclavas, forming the rejuvenated stage of volcanism, may eruptafter an interval of erosion lasting for 0·25–2·5Myr. Alkalic lavas with geochemical characteristics similarto rejuvenated- stage lavas erupted on the sea floor north ofOahu along the Hawaiian Arch. The variable Tb/Yb, Sr/Ce, K/Ce,Rb/La, Ba/La, Ti/Eu and Zr/Sm ratios in lavas forming the NorthArch and the rejuvenated-stage Honolulu Volcanics were controlledduring partial melting by residual garnet, clinopyroxene, Fe–Tioxides and phlogopite. However, the distinctively high Ba/Thand Sr/Nd ratios of lava forming the North Arch and HonoluluVolcanics reflect source characteristics. These characteristicsare also associated with shield tholeiitic basalt; hence theyarise from the Hawaiian hotspot, which is interpreted to bea mantle plume. Inversion of the batch melting equation usingabundances of highly incompatible elements, such as Th and La,requires enriched sources with 10–55% clinopyroxene and5–25% garnet for North Arch lavas. The 87Sr/86Sr and 143Nd/144Ndratios in lavas forming the North Arch and Honolulu Volcanicsare consistent with mixing between the Hawaiian plume and adepleted component related to mid-ocean ridge basalts. Specifically,the enrichment of incompatible elements coupled with low 87Sr/86Srand high 143Nd/144Nd relative to bulk Earth ratios is best explainedby derivation from depleted lithosphere recently metasomatizedby incipient melt (<2% melting) from the Hawaiian plume.In this metasomatized source, the incompatible element abundances,as well as Sr and Nd isotopic ratios, are controlled by incipientmelts. In contrast, the large range of published 187Os/188Osdata (0·134–0·176) reflects heterogeneitycaused by various proportions of pyroxenite veins residing ina depleted peridotite matrix. KEY WORDS: Hawaiian plume; Honolulu Volcanics; North Arch; plume–lithosphere interaction; rejuvenated stage; trace element geochemistry; alkalic lavas 相似文献
20.
Avanzinelli Riccardo; Elliott Tim; Tommasini Simone; Conticelli Sandro 《Journal of Petrology》2008,49(2):195-223
We present new U-series isotope, 87Sr/ 86Sr, 143Nd/ 144Nd andtrace element data for a set of mafic, K-rich rocks from volcanoesin Central–Southern Italy. These shoshonitic to ultrapotassiclavas display strongly depleted high field strength element(HSFE) abundances with respect to other incompatible trace elementstogether with high but variable 87Sr/ 86Sr and low but variable143Nd/ 144Nd values. Such characteristics are thought to bedue to addition of subducted crust of variable amount and compositionto their mantle sources prior to magma genesis. Rocks from thenorthernmost region (i.e. Tuscan Magmatic Province and NorthernRoman Magmatic Province) display (230Th/ 238U) activity ratiosclose to radioactive equilibrium, suggesting that metasomatismof their sources occurred before 400 ka and recent melting tookplace at shallow depths, in the absence of garnet. A 238U excessof up to 27% has been measured in rocks from the NeapolitanDistrict. The occurrence of significant U excesses is a featureof arc magmas, but is typically seen in depleted lavas ratherthan in highly enriched rocks such as these (20 ppm Th). Thissignature requires a recent addition of a U-rich component tothe already strongly enriched mantle wedge beneath this regionof Italy. We suggest that a supercritical liquid, from deeplysubducted carbonate-rich sediments of the still-active Ionianslab, is responsible for generating a high-U, low-Th component,which produces the observed disequilibria. A 30% 230Th excessmeasured in a single unaltered sample from the Lucanian MagmaticProvince, along with a less marked negative HFSE anomaly, suggeststhe contribution of a deeper, garnet-bearing component in thegenesis of these magmas, plausibly related to the upwellingof asthenospheric mantle around the corner of the Ionian slab. KEY WORDS: U/Th disequilibria; potassic and ultrapotassic rocks; subduction: metasomatism; mantle melting; Central and Southern Italy 相似文献