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1.
针对海洋环境条件,重点研究了粉煤灰混凝土的抗冻性和氯离子渗透性能的相互关系.试验分别研究了水胶比、粉煤灰等量取代水泥掺量大小、引气剂掺量等因素对抗冻性和抗氯离子渗透性能的影响,并与普通混凝土进行了对比.结果表明,粉煤灰不增加混凝土的抗海水冻融耐久性;粉煤灰增加混凝土的抗氯离子渗透性能,但是掺量超过30%,抗氯离子渗透性能下降;粉煤灰对混凝土抗冻性和抗氯离子渗透性的耦合影响在30%左右存在一个最佳掺量.为评估混凝土的抗冻性和氯离子扩散性的耦合性能,提出了新的评价方法--冻渗比(R值方法),并进行了试验验证.SEM和MIP微观分析与R值方法评价的结果是吻合的.  相似文献   

2.
海洋潮汐浪溅区混凝土表面氯离子浓度计算模型   总被引:2,自引:0,他引:2       下载免费PDF全文
蔡荣  杨绿峰  余波 《海洋工程》2014,32(5):25-33
海洋混凝土结构的表面氯离子浓度反映了海洋氯化物环境的腐蚀作用强度,是海洋混凝土结构耐久性分析和定量设计的重要参数。本文依据国内外不同地区的大量自然暴露试验数据,通过数理统计和回归分析,确定了各种海洋环境条件下表面氯离子浓度的统计特征值,分析了海洋潮汐浪溅区混凝土中氯离子的传输机理和积聚规律,揭示了水胶比对混凝土表面氯离子浓度的影响规律,进而综合考虑水胶比、胶凝材料种类和时变特性等因素的影响,建立了海洋潮汐浪溅区混凝土表面氯离子浓度的改进计算模型。结合国内外各种表面氯离子浓度经验模型的预测结果和海洋自然暴露试验的实测数据,对比验证了所建立表面氯离子浓度计算模型的有效性和适用性,为海洋氯化物环境下混凝土结构的耐久性设计和服役寿命分析提供了重要边界条件。  相似文献   

3.
对服役12年的华南某跨海大桥典型构件开展碳化性能、氯离子扩散性能等指标的耐久性检测,评估了海水环境下掺粉煤灰的高性能混凝土长期耐久性。研究表明:随高程的增加混凝土碳化深度逐渐增大,其中大气区浪溅区水位变动区,碳化作用对粉煤灰混凝土结构耐久性的影响较小;粉煤灰可显著提升实体结构混凝土抗氯离子侵蚀性能,粉煤灰高性能混凝土的氯离子扩散系数不大于0.40×10-12m2/s,比普通混凝土氯离子扩散系数降低了约6倍;利用规范计算了引桥承台混凝土中氯离子含量计算值,其计算值与实测值吻合较好,可用于实体工程混凝土结构的耐久性评估,评估结果显示采用粉煤灰高性能的桥梁典型构件满足100年设计使用寿命的要求。  相似文献   

4.
海洋潮汐环境下混凝土硫酸盐侵蚀机理研究   总被引:2,自引:0,他引:2  
研究海洋潮汐区侵蚀环境下混凝土中硫酸盐侵蚀机理,对不同配合比混凝土试件在海洋潮汐环境下进行现场暴露试验。同时利用分光光度计法测定不同侵蚀龄期及不同配合比混凝土中硫酸根离子质量分数。试验结果表明:早期海洋暴露环境下,混凝土中总硫酸根离子质量分数随着腐蚀龄期的增加而显著升高,但随着时间增加幅度逐渐降低;混凝土中总硫酸根离子质量分数因水胶比、水泥用量不同而不同;一定比例的矿物掺合料可以有效提高混凝土抗硫酸盐侵蚀性能。  相似文献   

5.
标准养护和夏季自然养护的内养护混凝土在盐渍土环境中腐蚀不同龄期,测试其抗压强度及氯离子渗透性能。结果表明:无论标准养护还是自然养护,高吸水树脂的掺加均降低了混凝土早期强度,但当高吸水树脂掺量为1kg/m3时可提高混凝土后期强度,且提升幅度对低水胶比混凝土更明显。在盐渍土腐蚀环境中,普通混凝土强度先上升后下降,而内养护混凝土强度先下降后上升。高吸水树脂能够延缓混凝土抗压强度下降的速率,提升混凝土抗氯离子渗透能力。  相似文献   

6.
有氯盐侵蚀的钢筋腐蚀,是钢筋混凝土结构性能劣化的主要原因之一,混凝土构件使用寿命的关键是氯离子的传输速率和使钢筋产生锈蚀的时间。本文以人工鱼礁混凝土构件为研究对象,分析海水氯离子在C30、C35和钢渣复合材料人工鱼礁混凝土中的扩散系数,以混凝土中钢筋锈蚀的临界氯离子浓度为寿命预测的边界条件,利用氯离子扩散模型预测C30、C35和钢渣复合材料人工鱼礁在海水中的腐蚀寿命。研究结果表明,氯离子在混凝土人工鱼礁中的扩散规律基本满足Fick第二定律。通过模型计算得出C30、C35和钢渣复合材料混凝土人工鱼礁的腐蚀寿命分别为51.6,54.8和56.8年。  相似文献   

7.
人工鱼礁在自然海水条件下的腐蚀寿命研究   总被引:1,自引:0,他引:1  
有氯盐侵蚀的钢筋腐蚀,是钢筋混凝土结构性能劣化的主要原因之一,混凝土构件使用寿命的关键是氯离子的传输速率和使钢筋产生锈蚀的时间。本文以人工鱼礁混凝土构件为研究对象,分析海水氯离子在C30、C35和钢渣复合材料人工鱼礁混凝土中的扩散系数,以混凝土中钢筋锈蚀的临界氯离子浓度为寿命预测的边界条件,利用氯离子扩散模型预测C30、C35和钢渣复合材料人工鱼礁在海水中的腐蚀寿命。研究结果表明,氯离子在混凝土人工鱼礁中的扩散规律基本满足Fick第二定律。通过模型计算得出C30、C35和钢渣复合材料混凝土人工鱼礁的腐蚀寿命分别为51.6,54.8和56.8年。  相似文献   

8.
海洋大气及污染海洋大气对典型钢腐蚀的影响   总被引:6,自引:0,他引:6  
对典型钢(碳钢Q235和耐候钢09CuPCrNi)在海洋大气(麦岛)和污染海洋大气(团岛)环境中进行了2年的暴露腐蚀实验,并测试了其环境的大气污染因子。结果显示典型钢在团岛的腐蚀明显地比麦岛重,团岛的氯离子浓度几乎是麦岛氯离子浓度的3倍。讨论了海洋大气和污染海洋大气对典型钢的腐蚀作用的差异。  相似文献   

9.
钢筋混凝土耐久性海洋暴露试验   总被引:4,自引:0,他引:4  
对不同技术条件的钢筋混凝土试件进行长期的海洋暴露腐蚀试验,以了解其服役特性,为钢筋混凝土结构的耐久性设计提供依据。近7年的暴露结果表明:在混凝土中掺加高炉矿渣等活性掺合料,能大大降低氯离子渗透速率,提高钢筋混凝土的耐久性。  相似文献   

10.
表面氯离子含量(C_s)是研究海洋环境条件下混凝土结构耐久性和服役寿命的氯离子扩散方程的边界条件,是海洋混凝土结构耐久性分析和定量设计的重要参数。依据国内外大量自然暴露试验与工程实测数据,通过采用Excel、Origin等数据分析软件进行数据统计和回归分析,确定了海洋混凝土结构表面自由氯离子含量(C_(sf))与表面总氯离子含量(C_(st))之间的相互关系,探讨了海洋混凝土结构的C_(sf)时变规律,建立了C_(sf)与暴露时间之间的关系表达式及其取值范围,并运用可靠度理论和修正氯离子扩散理论分析了C_(sf)时变性对海洋混凝土结构寿命的影响。结果表明:C_(sf)与C_(st)线性相关,且C_(sf)随着暴露时间的延长呈指数或者幂函数的增长关系;采用不同的C_(sf)时变性规律,对海洋混凝土结构寿命具有重大的影响。  相似文献   

11.
The interdependence between the seismo-acoustic properties of a marine sediment and its geotechnical/physical parameters has been known for many years, and it has been postulated that this should allow the extraction of geotechnical information from seismic data. Though in the literature many correlations have been published for the surficial layer, there is a lack of information for greater sediment depths. In this article, a desktop study on a synthetic seafloor model illustrates how the application of published near-surface prediction equations to subsurface sediments (up to several tens of meters burial depth) can lead to spurious predictions. To test this further, acoustic and geotechnical properties were measured on a number of sediment core samples, some of which were subjected to loading in acoustically-equipped consolidation cells (oedometers) to simulate greater burial depth conditions. For low effective pressures (representing small burial depths extending to around 10 meters subsurface), the general applicability of established relationships was confirmed: the prediction of porosity, bulk density, and mean grain size from acoustic velocity and impedance appears generally possible for the investigated sedimentary environments. As effective pressure increases through, the observed relationships deviate more and more from the established ones for the near-surface area. For the samples tested in this study, in some instances increasing pressure even resulted in decreasing velocities. There are several possible explanations for this abnormal behavior, including the presence of gas, overconsolidation, or bimodal grain size distribution. The results indicate that an appropriate depth correction must be introduced into the published prediction equations in order to obtain reliable estimates of physical sediment properties for greater subsurface depths.  相似文献   

12.
This article reviews information recently available from existing marine and coastal mining for responses to environmental issues affecting marine mining at different depths. It is particularly but not exclusively concerned with those issues affecting seabed biodiversity impact and recovery. Much information has been gathered in the past 10 years from shallow mining operations for construction aggregate, diamonds, and gold, from coastal mines discharging tailings to shallow and deep water, and from experimental deep mining tests. The responses to issues identified are summarized in a series of eight tables intended to facilitate site-specific consideration. Since impacts can spread widely in the surface mixing layer SML, and can affect the biologically productive euphotic zone, the main issues considered arise from the depth of mining relative to the SML of the sea. Where mining is below the SML, the issue is whether it is environmentally better to bring the extraction products to the surface vessel for processing (and waste discharge), or to process the extraction products as much as possible on the seabed. Responses to the issues need to be sitespecific, and dependent on adequate preoperational environmental impact and recovery prediction. For deep tailings disposal from a surface vessel, there are four important environmental unknowns: (1) the possible growth of "marine snow" (bacterial flocs) utilizing the enormous quantities of fine tailings particles (hundreds or thousands of metric tons per day) as nuclei for growth, (2) the possibility that local keystone plankton and nekton species may migrate diurnally down to and beyond the depth of deep discharge and hence be subjected to tailings impact at depth, (3) the burrow-up capability of deep benthos and their ability to survive high rates of tailings deposition, and (4) the pattern and rate of dispersion of a tailings density current through the deep water column from discharge point to seabed. Actions to obtain relevant information in general and site-specifically are suggested.  相似文献   

13.
Particle fluxes were measured 7 m above the sea bottom during the predisturbance, disturbance, and postdisturbance periods by using time series sediment traps attached to seven deep-sea moorings deployed in the INDEX experiment site in the Central Indian Basin. The predisturbance particle fluxes varied between 22.3 to 55.1 mg m -2 day -1 . Increased and variable particle fluxes were recorded by the sediment traps during the disturbance period. The increase observed was 0.5 to 4 times more than the background predisturbance fluxes. The increases in particle fluxes (~4 times) recorded by the sediment trap located in the southwestern direction (DMS-1) were the greatest, which could be the result of preferential movement of resuspended particles generated during the deep-sea benthic disturbance along the general current direction prevailing in this area during the experimental period. Also, the traps located closer to the disturbance area recorded greater fluxes than did the traps far away, across the Deep Sea Sediment Resuspension System path. This variability in recorded particle fluxes by the traps around the disturbance area clearly indicates that physical characteristics such as grain size and density of the resuspended particles produced during the disturbance had an important effect on particle movement. The postdisturbance measurements during ~5 days showed a reduction in particle fluxes of ~50%, indicating rapid particle settlement.  相似文献   

14.
海上大直径钢管桩打桩过程中,桩周土体受到强烈扰动而发生强度弱化,掌握桩周土体强度弱化规律对于准确预测打桩过程、保证工程安全具有重要意义。为研究土体强度弱化规律,开展了环剪试验模拟打桩对桩周土体的扰动,测试土体强度随剪切速率的变化规律,建立了描述土体强度弱化规律的拟合公式,引入到打桩分析软件中。研究结果表明:土体的强度折减程度不仅与土体本身的性质有关还受到土体的埋深和剪切速率的影响,埋深越深土体强度折减程度越低,剪切速率越高土体强度折减越高,在打桩分析中可采用这里推荐的线性折减方法来模拟不同深度处土体强度的折减规律。  相似文献   

15.
The advanced piston corer (APC) has been used by the Ocean Drilling Program since 1985 for recovering soft sediments from the ocean floor. The pullout force measured on extracting the core barrel from the sediment is shown to correlate with the average shear strength of the sediment core measured in the ship's laboratory. A simple rule of thumb is derived relating the shear strength of the sediment to the pullout force. Multiple APC holes at individual sites allow the consistency of the pullout measurements to be assessed. The effects of different operational procedures during APC coring are also explored. Although generally applicable, the correlation between pullout force and laboratory measurements of shear strength breaks down for some APC holes, possibly because of the disturbance of some sediment types during the APC coring process. A better understanding of the physical process of APC coring, and its effect on the properties of the sediment both inside and immediately outside the core barrel, would indicate what confidence can be put on the measurement of pullout force as a way of evaluating the in situ shear strength of deep sea sediments.  相似文献   

16.
Specific properties of the interannual sea level variations and annual tides in the Northwestern Pacific were studied. Several tide stations were monitored. The monthly mean sea level for the year of 1995 was analyzed at each tide station. A seismic event in 1995, some tectonic activity around the subject area, and the Kuroshio (the oceanic western boundary current) may possibly contaminate results which would have occurred from the astronomical annual tide alone.  相似文献   

17.
The effect of different fixation and storage protocols on the flow cytometric (FCM) simultaneous analysis of bacterioplankton and phytoplankton in coastal seawater samples (Mediterranean coastal lagoons) was investigated. FCM measurements (cell number, fluorescence and scatter characteristics) were obtained through DAPI staining. Three fixatives [glutaraldehyde (GA), formaldehyde (FA) and paraformaldehyde (PFA)] and two storage (3 months duration) methods (5 °C and −196 °C) were tested. Two dominant populations were detected in studied samples: bacteria and eukaryotic picophytoplankton. Adding fixatives (2% final concentration) appears necessary to obtain FCM exhaustive counts of all the bacteria and phytoplanktonic cells. This was related to the permeation effect of fixatives which allowed a better DAPI staining of the cells. Maximum fluorescence, i.e. optimal staining of the cells was obtained with FA or PFA, and significant lower fluorescences with GA. Fixed samples stored at 5 °C induced rapid cell loss. Only storage in liquid nitrogen of samples fixed with FA or PFA, allows mid-term (≥4 months) preservation of bacteria or picophytoplankton cell numbers, and limited evolution of DAPI-induced fluorescence and scatter characteristics.  相似文献   

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《海洋学报(英文版)》2014,(11):161-F0003
<正>Acta Oceanologica Sinica(AOS)is a comprehensive academic journal edited by the Editorial Committee of Acta Oceanologica Sinica and is designed to provide a forum for important research papers of the marine scientific community which reflect the information on a worldwide basis.The journal publishes scholarly papers on marine science and technology,including physics,chemistry,biology,  相似文献   

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