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1.
江西修水地区震旦纪前后沉积岩的Nd同位素组成和物质来源   总被引:14,自引:1,他引:14  
凌洪飞  刘继顺 《岩石学报》1992,8(2):190-194
本文报导了江西修水地区前震旦系与震旦—寒武系沉积岩的Nd同位素组成。前震旦系浅变质沉积岩:~(143)Nd/~(144)Nd=0.512000~0.512214,ε_(Nd)(t)=-2.57~3.91,t_(DM)=1563~1859Ma;震旦—寒武系沉积岩:~(143)Nd/~(144)Nd=0.511710~0.511902,ε_(Nd)(t)=-8.04~-9.99,t_(DM)=1833~2426Ma。两者之间的显著差异反映了震旦纪前后沉积岩物质来源的不同及沉积构造环境的改变,前震旦纪地壳活动性强,沉积岩中含有较多的幔源物质;震旦纪以后地壳活动性减弱,沉积岩以陆壳再循环碎屑为主。  相似文献   

2.
太华群和登封群变质杂岩的锆石U-Pb定年结果统计表明,华北克拉通中部造山带南段地区在新太古代-古元古代期间存在至少四阶段岩浆活动(2.85~2.72 Ga,2.57~2.48 Ga,2.34~2.30 Ga和2.20~2.07 Ga)。与中部造山带中、北段地区相比,南段地区的新太古代早期的岩浆活动略早,并具有相对较强烈的古元古代早期(~2.3 Ga)岩浆活动。新太古代早期(2.85~2.72 Ga)的TTG质岩石整体具有正的全岩ε_(Hf)(t)和ε_(Nd)(t)值,并且有εHf(t)值偏高的Hf-Nd同位素解耦现象,其源区形成与地幔交代作用相关。新太古代末期-古元古代初期(2.57~2.48 Ga)的TTG质片麻岩主要为正的全岩εHf(t)和εNd(t)值,部分样品具有ε_(Hf)(t)值偏低的Hf-Nd同位素解耦现象,为锆石效应的结果,其岩石成因以初生地壳物质部分熔融为主,存在少量古老地壳物质的再循环作用。古元古代早期(2.34~2.30 Ga)TTG质岩石和古元古代中期(2.20~2.07 Ga)的富钾岩及TTG质岩石的全岩ε_(Hf)(t)和ε_(Nd)(t)值均为负值,并具ε_(Hf)(t)值明显偏低的Hf-Nd同位素解耦现象,均为锆石效应的结果,其岩石成因以古老地壳物质的再循环作用为主。太华群和登封群片麻岩的全岩Hf-Nd同位素解耦主要与其源区形成过程存在地幔交代作用或者锆石效应有关,而与石榴子石效应关系不大,表明各阶段TTG质岩石的高Sr/Y、(La/Yb)_N比值和低重稀土含量等特征不是继承自源区,而确实反映了较大压力深度的岩浆活动过程。总体上,新太古代早期-古元古代初期为华北克拉通中部造山带南段地区主要的地壳生长阶段,而古元古代早-中期主要为地壳再循环阶段。  相似文献   

3.
通过对福建紫金山地区不同岩石样品中岩浆锆石的SIMS U-Pb年龄和Hf、O同位素研究,对该地区岩浆序列以及源区组成、壳幔相互作用等进行初步探讨。结果显示,岩石样品中岩浆锆石的年龄(151~1514 Ma)较为分散,包含了从中元古代、震旦纪、早古生代晚期、晚三叠世到晚侏罗世的5个不同岩浆侵入时期。锆石的二阶段Hf亏损地幔模式年龄(t_(DM2)值)主要分布在古元古代,ε_(Hf)(t)数据也显示主要沿基性地壳演化线分布,指示古元古代时期的新生基性地壳可能是研究区中元古代直至晚侏罗世侵入岩形成的主要源区。锆石δ~(18)O及ε_(Hf)(t)值显示中元古代及震旦纪岩浆作用是幔源岩浆与古元古代基性地壳共同作用的结果;早古生代晚期和晚三叠世岩浆作用以壳源为主;至晚侏罗世,亏损地幔物质对岩浆作用的影响增加。  相似文献   

4.
延边地区晚古生代–早白垩世花岗岩的Nd同位素研究显示,该区可以富尔河–古洞河断裂为界划分为南北两个岩区。北区显示亏损、年轻的源区特征(εNd(t)=?0.7~+3.8,tDM2=691~976 Ma),南区可能继承了古老富集端元组分(εNd(t)=–13.6~–0.6,tDM2=1004~2166 Ma)。从二叠纪到白垩纪,北区花岗岩的εNd(t)值随着年龄变新递减,南区的εNd(t)值则随着年龄变新递增,并在早白垩世时两区花岗岩的εNd(t)值达到基本相同。这种Nd同位素组成的变化趋势,说明南北两区深部地壳物质组成随时间变新而趋于均一化,反映了北区和南区先前存在的古亚洲洋型增生地壳和华北克拉通古老再循环地壳,在中生代期间遭受了古太平洋板块俯冲形成的新增生弧地壳的强烈改造和置换,使得两区深部地壳组成在白垩纪时基本一致。该研究结果为深入理解中生代古太平洋俯冲作用对东北地区深部地壳的改造过程提供了可靠的同位素地球化学制约。  相似文献   

5.
测定了黄陵背斜核部被称作"孔兹岩系"的5个全岩样品Ce、Nd同位素组成,5个样品分别代表该岩系不同层位与岩性.其中两个含有石墨的黑云斜长片麻岩和一个含榴黑云石英片岩样品的εCe(t)都是负值(分别为-2.5、-2.1和-1.7),εNd(t)值相对高(分别为-0.5、-1.3和-1.6),揭示了岩石中含有较多幔源组分,原岩沉积环境不稳定;一个石榴石矽线石石英片岩的εCe(t)值为+1.6,εNd(t)值是-2.4,指示原岩的沉积环境符合形成孔兹岩的地质条件;黑云变粒岩的所有特征与基底片麻岩相似,εCe(t)和εNd(t)值分别为+2.2和-7.7,Nd模式年龄为(3169±19)Ma,表明它可能不属于古元古代.总之,黄陵地区古元古代的沉积构造环境并不全是稳定的,在岩系沉积开始阶段和中间某个时期有明显的海底幔源组分活动,因此,符合孔兹岩形成条件的沉积-构造环境只在其中一段时间里存在,另外有一些地层可能属于太古宙.  相似文献   

6.
火山岩及其相关岩石的全岩Sm-Nd等时线年龄测定表明,安徽省歙县—休宁—带广泛分布的海相火山岩形成于12.86亿年前。这一结果证实皖南地区与江南古陆东南缘其它地段一样,也存在两个元古代岛弧系,即位于南部江湾—街口一带的晚元古代岛弧系及位于北部歙县—休宁一带的中元古代岛弧系。Nd同位素特征研究表明,歙县—休宁一带的火山岩的Sm/Nd比值都大于或接近于0.318(球粒陨石的现代标准值),Nd的初始值(~(143)Nd/~(144)Nd)_1=0.51118,ε_(Nd)(t)=+3.9±0.4,位于亏损地幔演化线附近。因此推断,歙县—休宁一带海相火山岩可能来自亏损地幔源。  相似文献   

7.
测定了湘西及邻区晚震旦世—早二叠世25个黑色岩系样品的La-Ce和Sm-Nd同位素数据。它们的εCe(t) 和εNd(t) 值分别变化在- 1.6 ~+ 2.6和- 1.4 ~- 11.0范围内,δCe值为0.28 ~1.68 ,T2 DM 年龄为1358 ~2207 Ma。在εCe(t)-εNd(t) 图上,全部数据点可以分成3个区,不同的分区显示了黑色岩系的不同沉积环境与构造背景。在沉积环境研究中Ce同位素是有用的地球化学示踪器。  相似文献   

8.
测定了闽西南地区5件基性岩脉的全岩主微量元素,锆石U-Pb年龄和Hf,O同位素。5件岩脉主要为辉绿岩,其全岩SiO_2含量为45%~53%,稀土元素显示轻稀土富集的右倾配分模式。基性岩脉中大部分锆石具明显振荡环带和扇状环带,为典型岩浆结晶锆石特征。锆石U-Pb年龄(96~2 400 Ma)分布较为分散。除少量锆石年龄(96~142 Ma)可能指示岩脉形成年龄外,其余均为捕获锆石。捕获锆石年龄主要分布在4个范围:早元古代(2 467~1 796 Ma),中晚元古代—震旦纪(1 343~647 Ma),志留纪—晚三叠世(427~225 Ma),晚侏罗世(159~140 Ma)。Hf-O同位素显示早元古代锆石来源于接近球粒陨石均一储库的地幔。中晚元古代以后年龄的锆石其Hf-O同位素均具有亏损地幔岩浆与地壳组分混合的特征;志留纪—晚侏罗世锆石主要来源于S型壳源花岗岩的重熔;早白垩世晚期的锆石ε_(Hf)(t)值与δ~(18)O值清晰地显示出亏损地幔与地壳岩浆混合的趋势。闽西南基性岩脉中锆石的二阶段Hf亏损地幔模式年龄(TDM2)峰值主要分布在1.6~1.9 Ga,说明早元古代晚期幔源岩浆作用形成的基性岩地壳可能是形成后期花岗岩的主要源区。  相似文献   

9.
华南地区存在两种类型变质基底。Sm-Nd同位素数据的研究结果表明,它们可分别代表华南两种类型元古代地壳端员。华夏地块区副变质岩代表成熟度较高的(早)元古代地壳端员,~(147)Sm/~(144)Nd=0.1198,~(143)Nd/~(144)Nd=0.511822;江南古岛弧区副变质岩代表成熟度较低的(中—晚)元古代地壳端员,~(147)Sm/~(144)Nd=0.1246,~(143)Nd/~(144)Nd=0.512170。根据上述数据得出了华南元古代地壳Sm-Nd同位素演化域,进而对华南不同时代花岗岩类的物质来源作了进一步的讨论。  相似文献   

10.
天山石炭-二叠纪后碰撞花岗岩的Nd、Sr、Pb同位素源区示踪   总被引:19,自引:2,他引:19  
天山造山带不仅是中亚巨型造山带的组成部分,也是我国西部晚古生代岩浆活动的集中区,蕴含着丰富的古亚洲洋演化的复合地质信息。笔者以探索天山晚古生代花岗岩浆活动的物质来源为目标,采用Sr、Nd、Pb同位素地球化学方法,对该区不同构造单元中具有代表性的花岗岩体进行了全面系统的研究,发现天山不同构造单元中花岗岩Sr、Nd、Pb同位素特征具有明显差异。在与其围岩的同位素特征进行对比研究的基础上,提出了产于不同构造单元石炭-二叠纪花岗岩的可能源区。觉罗塔格石炭-二叠纪裂谷带的晚古生代花岗岩,具有最高的εNd(t)值和最低的(^87Sr/^86Sr)t值,如,以康古尔石英闪长岩为代表的二叠纪花岗岩的源岩可能是早期泥盆纪大南湖岛弧火山岩(新生地壳);博格达地区的晚石炭-二叠纪花岗岩是早期基性火山岩,亦可能是底侵基性岩部分熔融的产物。中新元古代基底晚石炭-二叠纪裂谷带中花岗岩的源岩亦为同期基性火山岩,但在岩浆演化过程中受到古老基底地壳的混染,导致其εNd(t)值低于石炭-二叠纪裂谷带中花岗岩,而(^87Sr/^86Sr)t高于石炭-二叠纪裂谷带花岗岩。南天山东段和前寒武系微地块及其边缘中的晚古生代(含个别早古生代花岗岩)花岗岩分别是类似于库米什斜长角闪岩的古老地壳和西天山元古代古老地壳部分熔融的产物,因此它们均具有负的εNd(t)值和异常高的(^87Sr/^86Sr)t值。上述认识对于了解天山晚古生代区域岩石圈演化及深部过程具有重要意义。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

13.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

14.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

15.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

16.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

17.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

18.
滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.  相似文献   

19.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

20.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

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