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1.
中条山铜矿峪斑岩型铜矿床位于秦岭造山带北端,矿体主要赋存于变质花岗闪长斑岩、黑云母片岩和变质基性火山岩中。矿区内含铜岩系的全岩地球化学分析显示,主量元素表明矿区的含铜岩系均表现出富钾、富铝的特征;微量元素表明所有样品均显示出相对富集大离子亲石元素(K、Rb、Ba等),亏损高场强元素(P、Y、Ti、Nb、Ta等),反映岩浆源区可能遭受过俯冲带流体的交代作用,具有岛弧玄武岩的地球化学特征;稀土元素特征显示出明显的轻重稀土分馏,轻稀土富集,所有样品都表现出弱的铕负异常。研究认为,变质花岗斑岩、黑云母片岩和绢英岩的原岩初步定为钙碱性玄武岩或拉斑玄武岩,铜矿峪铜矿床形成于挤压与拉张构造环境的转换阶段,其成因类型应属于斑岩型铜矿床。  相似文献   

2.
云南思茅大平掌矿区火山岩的地球化学特征及构造意义   总被引:4,自引:3,他引:4  
大平掌矿区细碧岩-石英角斑岩建造为典型的双峰式火山岩组合,缺失SiO_2为52%~61%之间的中性火山岩。火山岩的TiO_2含量低及其它岩石化学特征、稀土元素地球化学特征均表明这套火山岩很可能形成于岛弧环境。不相容元素N-MORB标准化型式以Ba、Nd、Sm相对富集和Nb、Sr、Ti的相对亏损为特征,其中Ba 富集和Nb亏损更是岛弧火山作用的主要特征之一。大平掌矿区细碧岩具非常低的 Nb/Y(<0.15)和Zr/TiO_2(<0.01)比值,石英角斑岩的低Zr/TiO_2和Nb/Y特征以及Zr/Y比值(3.34~4.23)、(La/Yb)_N比值(0.47~2.50)变化范围都可以反映出火山岩形成于岛弧环境。大平掌火山岩的Sr、Nd同位素特征与世界上典型岛弧火山岩的Sr、Nd特征相似,其岩浆来源于亏损地幔,且经受地壳混染和(或)海水热液蚀变的影响。岩石中富含的放射成因铅也与岛弧环境密切相关。因此,大平掌铜多金属矿床的形成很可能受岛弧环境下的双峰式火山作用控制。  相似文献   

3.
东山铜(金)矿位于新疆准噶尔盆地东南部,哈尔里克古生代复合岛弧带东段,带内矿床成因类型研究程度较低,南北两侧岛弧带内近年均发现较大规模斑岩型铜矿。东山铜金矿体呈脉状、网脉状产于花岗斑岩体边部花岗闪长岩节理裂隙中,矿石矿物主要有黄铜矿、黄铁矿、磁铁矿、赤铁矿等,与典型斑岩型铜矿类似。主要含矿岩体花岗闪长岩SiO_2、Al_2O_3、MgO含量分别为64.3%~68.15%,15.6%~16.6%,1.29%~1.69%。岩体Y和Yb含量低但具较高的Sr值,具埃达克岩特征;岩体大离子亲石元素Rb,Ba,U,K等元素相对富集,高场强元素Nb,Ta,Zr等相对亏损,具明显的Nb,Ta,Ti负异常特征,表明其形成于岛弧环境。埃达克岩和岛弧环境是新疆北部斑岩型铜矿的两个典型特征,本文通过矿床地质特征及含矿岩体地球化学特征研究,对比东山铜(金)矿与新疆北部斑岩型铜矿的成矿特征及构造环境,认为东山铜(金)矿的矿床成因类型应为斑岩型铜金矿床且区内具斑岩型铜矿的成矿潜力。  相似文献   

4.
位于义敦岛弧南端的中甸岛弧已成为我国又一重要的斑岩铜矿产地,其中雪鸡坪中型斑岩铜矿床产于西斑岩带,普朗超大型斑岩铜矿床产于东斑岩带.详细对比研究了这两个斑岩铜矿床矿床地质,含矿斑岩的岩石化学、地球化学以及年代学等特征,认为:①两者的元素组成非常相似,如稀土配分形式均为轻稀土元素富集型,亏损重稀土元素和Y,富集Sr、K、Rb、Ba、Th等大离子亲石元素,亏损Nb、Ta、Zr、Hf、Ti等高场强元素,显示了埃达克岩的地球化学特征,表明它们可能是俯冲的甘孜--理塘洋壳部分熔融的产物,并受到地壳物质的混染;②中甸岛弧的结构及时空演化保持了义敦岛弧的共性,发育完整的沟-弧-盆体系,其中东斑岩带属于外弧,而西斑岩带属于内弧,中斑岩带及零星分布的属都蛇绿混杂岩产于弧间盆地.  相似文献   

5.
位于义敦岛弧南端的中甸岛弧已成为我国又一重要的斑岩铜矿产地,其中雪鸡坪中型斑岩铜矿床产于西斑岩带,普朗超大型斑岩铜矿床产于东斑岩带.详细对比研究了这两个斑岩铜矿床矿床地质,含矿斑岩的岩石化学、地球化学以及年代学等特征,认为:①两者的元素组成非常相似,如稀土配分形式均为轻稀土元素富集型,亏损重稀土元素和Y,富集Sr、K、Rb、Ba、Th等大离子亲石元素,亏损Nb、Ta、Zr、Hf、Ti等高场强元素,显示了埃达克岩的地球化学特征,表明它们可能是俯冲的甘孜--理塘洋壳部分熔融的产物,并受到地壳物质的混染;②中甸岛弧的结构及时空演化保持了义敦岛弧的共性,发育完整的沟-弧-盆体系,其中东斑岩带属于外弧,而西斑岩带属于内弧,中斑岩带及零星分布的属都蛇绿混杂岩产于弧间盆地.  相似文献   

6.
新疆西天山备战铁矿区火山岩地球化学特征与构造环境   总被引:1,自引:0,他引:1  
西天山备战铁矿赋存于以玄武岩、玄武质凝灰岩、安山质凝灰岩、安山岩和英安岩为主的晚石炭世火山岩中,属于高钾钙碱性系列。本文通过对矿区火山岩进行岩石地球化学分析探讨火山岩形成的构造环境。地球化学分析表明,火山岩表现为轻稀土(LREE)相对于重稀土(HREE)富集的配分形式,具有"左陡右缓"的特征;相对富集大离子亲石元素(LILE)Ba、Rb、Th和U等,亏损高场强元素(HFSE)Ta、Nb、Y和Hf等,且具有高LREE/HREE(平均5.2)的特征,类似于大陆边缘岛弧火山岩的特征。在构造环境图解中,火山岩样品落在岛弧火山岩区域内,并显示出偏向富集地幔源区演化的趋势。结合区域地质背景资料,笔者认为矿区内的火山岩应属南天山洋向伊犁-中天山板块俯冲末期大陆边缘岛弧环境的产物。  相似文献   

7.
东天山土屋-延东斑岩铜矿带埃达克岩及其与成矿作用的关系   总被引:45,自引:34,他引:45  
土屋-延东铜矿带位于东天山晚古生代大南湖增生岛弧带,各矿岩石斜长花岗疵岩侵入于岛弧火山岩区通过对容矿围岩化学组成的研究表明,主量元素SiO2、Al2O3和MgO的含量分别为64.37%~72.28%、17.77%~17.7l%和0.55%~1.35%,微量元素Y、Yb和Sr的含量分别为4.42~11.1(μg/g),0.38~0.87(μg/g)和619~738(μg/g),LREE为富集型和Eu为正异常,这些特征反映斜长花岗斑岩为埃达克质岩,本区埃达克岩与铜矿化存在密切的时空关系,铜矿形成时代与埃达克岩相近,形成于早石炭世,而火山岩形成于泥盆纪、铜矿与埃达克宕紧密共生,矿区范围埃达克岩多被蚀变并铜矿化。同位素地球化学特征反映,埃达克质岩浆为成矿提供了主要的物质和流体来源。进一步研究表明,岛弧火山岩与具埃达克岩性质的斜长花岗斑岩形成于不同的地质过程。本区中基性-中酸性的岛弧火山岩是由于大洋板块俯冲到深部,因脱水作用使板片之上的地幔楔发生部分熔融而形成的。而埃达克岩是俯冲到深处具MORB性质的板片在一定的物理化学条件下发生部分熔融后直接侵位于近地表而形成的。  相似文献   

8.
位于义敦岛弧南端的中甸岛弧已成为我国又一重要的斑岩铜矿产地,其中雪鸡坪中型斑岩铜矿床产于西斑岩带,普朗超大型斑岩铜矿床产于东斑岩带。详细对比研究了这两个斑岩铜矿床矿床地质,含矿斑岩的岩石化学、地球化学以及年代学等特征,认为:①两者的元素组成非常相似,如稀土配分形式均为轻稀土元素富集型,亏损重稀土元素和Y,富集Sr、K、Rb、Ba、Th等大离子亲石元素,亏损Nb、Ta、Zr、Hf、Ti等高场强元素,显示了埃达克岩的地球化学特征,表明它们可能是俯冲的甘孜—理塘洋壳部分熔融的产物,并受到地壳物质的混染;②中甸岛弧的结构及时空演化保持了义敦岛弧的共性,发育完整的沟-弧-盆体系,其中东斑岩带属于外弧,而西斑岩带属于内弧,中斑岩带及零星分布的属都蛇绿混杂岩产于弧间盆地。  相似文献   

9.
东天山土屋-延东斑岩铜矿围岩的同位素年代和地球化学研究   总被引:23,自引:12,他引:23  
东天山土屋-延东大型斑岩铜矿的成岩成矿时代及其构造背景还存在很大争议。本文报道了铜矿远矿围岩—企鹅山群的同位素年代和地球化学研究结果。研究表明,企鹅山群安山岩中锆石 SHRIMP U-Pb 谐和年龄值336.5±6.6Ma,玄武岩的透辉石、斜长石和全岩 Sm-Nd 内部等时线年龄值334±36Ma,两个结果一致地表明企鹅山群形成于早石炭世。元素地球化学研究表明,企鹅山群玄武岩样品属于岛弧拉斑玄武岩系列,其稀土元素配分模式显示轻稀土相对富集,重稀土相对亏损的右倾模式,与洋中脊玄武岩相比,具有大离子亲石元素相对富集、高场强元素相对亏损的特征,具有俯冲带岛弧火山岩的典型特征。构造环境判别图解也指示企鹅山群形成于俯冲带环境。本研究对土屋-延东大型斑岩铜矿的成岩成矿作用时代及其构造背景问题提供了重要制约。  相似文献   

10.
位于义敦岛弧南端的中甸岛弧已成为我国又一重要的斑岩铜矿产地,其中雪鸡坪中型斑岩铜矿床产于西斑岩带,普朗超大型斑岩铜矿床产于东斑岩带。详细对比研究了这两个斑岩铜矿床矿床地质,含矿斑岩的岩石化学、地球化学以及年代学等特征,认为:①两者的元素组成非常相似,如稀土配分形式均为轻稀土元素富集型,亏损重稀土元素和Y,富集Sr、K、Rb、Ba、Th等大离子亲石元素,亏损Nb、Ta、Zr、Hf、置等高场强元素,显示了埃达克岩的地球化学特征,表明它们可能是俯冲的甘孜-理塘洋壳部分熔融的产物,并受到地壳物质的混染;②中甸岛弧的结构及时空演化保持了义敦岛弧的共性,发育完整的沟-弧-盆体系,其中东斑岩带属于外弧,而西斑岩带属于内弧,中斑岩带及零星分布的属都蛇绿混杂岩产于弧间盆地。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

13.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

14.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

15.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

16.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

17.
18.
Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km2 and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.  相似文献   

19.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

20.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).  相似文献   

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