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1.
胶东金矿集中区金矿成矿年代学研究 总被引：9，自引：0，他引：9
对不同研究者采用蚀变矿物Rb Sr、K Ar和Ar Ar法 ,流体包裹体Rb Sr等时线法 ,石英Ar Ar法和矿石矿物 (黄铁矿 )Rb Sr等时线法等多种同位素定年方法获得的胶东金矿集中区金矿成矿年龄数据进行了方法适用性研究和应用选择 ,筛选后的成矿年龄集中于 15 3 8～ 80 6Ma。综合考虑与金矿床有密切时空关系的花岗岩类侵入体及脉岩的K Ar、Ar Ar及U Pb (SHRIMP)年龄 ,确认胶东金矿集中区金矿主成矿期年龄为 (115± 10 )Ma ,金 银 多金属矿成矿期年龄为 (85± 5 )Ma ,分别为中生代早白垩世晚期 (K21)和晚白垩世早期 (K12 )。 相似文献
2.
硫化物Rb-Sr同位素定年研究进展 总被引：4，自引：0，他引：4
针对金属矿床成矿年代确定混乱的问题,国内外许多矿床学家和同位素地球化学家对金属矿物常规同位素定年方法进行了有益的探索研究,尤其是对于矿石矿物以闪锌矿、方铅矿和黄铁矿为主的铅锌矿床,硫化物矿物Rb-Sr同位素定年方法显示出了其独特的优势。结合近几年开展的工作,总结国内外硫化物Rb-Sr同位素定年研究取得的成果、闪锌矿中Rb、Sr的赋存状态与定年机理以及定年适应性问题。采用闪锌矿Rb-Sr同位素组成数据拟合成等时线源自热液流体与闪锌矿之间Rb和Sr的不同分异作用,但并不是所有的闪锌矿均适合该定年技术。要成功获得年龄,需结合野外地质特征采集代表性的矿石样品,并在镜下鉴定基础上挑选合适的单矿物;在分析测试过程中,需尽可能去除次生包裹体和粘土矿物。 相似文献
3.
闪锌矿流体包裹体Ar-Ar定年研究进展 总被引：1，自引：0，他引：1
各种同位素年代学方法已广泛的应用于矿床成矿年龄的测定,然而,对大多数矿床来说,要准确其成矿年龄还存在一定的困难.对于金属硫化物矿床,由于难于找到既能够代表成矿时代、同时又适合于常规同位素定年方法的测定对象,难以对其进行直接定年.Re-Os和La-Ce法适用面很窄,只有少数的特殊矿物可作为测定对象,Rb-Sr、Sm-Nd和Pb-Pb等时线法常因一组样品同位素组成相近而不能构成等时线.热液矿床中矿物通常含有较丰富的流体包裹体,其中存在着一定量的钾.本文尝试用流体包裹体的40Ar-39Ar测年方法,对金属硫化物矿床进行直接定年分析. 相似文献
4.
粤西河台金矿床富硫化物石英脉Rb-Sr等时线年龄讨论 总被引：8，自引：0，他引：8
河台金矿床产于河台韧性剪切带中 ,成矿作用分为韧性剪切变质成矿期的韧性剪切变质成矿阶段和热液蚀变成矿期金石英脉阶段、金硫化物阶段和方铅矿闪锌矿碳酸盐脉阶段。金的成矿主要发生在金石英脉阶段和金硫化物阶段 ,形成的矿石有蚀变糜棱岩型和富硫化物石英脉型。富硫化物石英脉单矿物石英中富含以富CO2 液相为主的流体包裹体、流体熔融包裹体及熔融包裹体。与以往用流体包裹体热爆法和压碎法提取Rb、Sr的方法不同 ,本文用石英全溶法测得富硫化物石英脉中石英的Rb Sr等时线年龄为 172± 2Ma(1σ) ,初始比值为 0 .72 816± 0 .0 0 0 96 ,对比已有的同位素年龄数据及区域成矿特征 ,认为这一年龄值可能代表了河台金矿床的成矿年龄。 相似文献
5.
古台山矿床是雪峰弧形构造带中段颇具代表性的石英脉型金锑矿床。矿床位于白马山复式岩体的外接触带,主要赋存于南华系长安组和板溪群五强溪组。本文对古台山矿床载金矿物毒砂流体包裹体氦、氩同位素和含矿石英流体包裹体铷、锶同位素进行了分析。He-Ar同位素分析显示,成矿流体的3He/4He为0.011~0.038 Ra,40Ar/36Ar值为414.4~732.6,表明成矿流体主要为地壳流体,同时有部分大气降水的加入。Sr同位素分析显示,含矿石英流体包裹体87Rb/86Sr变化于0.013~0.956,87Sr/86Sr变化于0.72529~0.73245;利用前人获得的成矿年龄(223.6 Ma)进行了初始锶同位素组成的返算,获得其ISr-223.6变化于0.72360~0.73167,平均0.72744。通过与印支期白马山岩体、板溪群等相关地质体锶同位素组成对比,认为古台山矿床成矿流体不可能单独来源于岩浆,而是岩浆流体运移过程中与来自基底具有高锶同位素比值的碎屑岩水岩相互作用的结果。He-Ar同位素揭示矿区深部及周缘地区板溪群具有更好的资源潜力。 相似文献
6.
《华南地质与矿产》2017,(4)
为了探究Rb、Sr在闪锌矿中的赋存状态及其Rb-Sr定年机理,对挑纯闪锌矿开展了矿物、稀盐酸提取相和硫化物相(王水溶解相)的Rb、Sr、Pb、Zn、Fe、Ca、Mg和Al含量分析。结果表明,挑纯闪锌矿中,79.19%-97.61%(平均90.47%)的Rb与Pb、Zn、Fe主要分布在硫化物相中,而70.30%-98.12%(平均82.92%)的Sr与Ca、Mg主要分布在稀盐酸提取相中,且其中的Sr与Ca+Mg含量之和大致呈正相关,指示硫化物相较之全矿物的Rb/Sr比值变化范围增大和Rb-Sr定年成功率得以提高,是因为通过稀盐酸提取过程去除了方解石、白云石等包裹体中的普通Sr对硫化物相中少量(2.34%-9.79%)放射成因Sr的掩饰作用。上述结果表明,闪锌矿Rb-Sr同位素定年可能是基于硫化物相而非所含流体包裹体和碳酸盐包裹体中的Rb和Sr,从原理上初步证实该定年方法是有意义的。通过条件实验,检验了稀盐酸提取过程可将碳酸盐包裹体中的Sr完全提取出来,且提取酸浓度和浸泡时间对等时线年龄没有影响,验证了闪锌矿分相Rb-Sr体系定年分析流程稳定可靠。 相似文献
7.
流体包裹体RbSr等时线定年的可靠性 总被引：11，自引：0，他引：11
通过对Rb-Sr等时线原理应用的必要条件及流体包裹体样品的成因特点的分析，认为是否可以用流体包裹体Rb-Sr定年在理论上尚需解决以下问题：（1）因矿物中常有不同期次、不同成因的流体包裹体存在，必须保证所选择的各流体包裹体样品具有相同的初始Sr同位素比值；（2）流体包裹中Rb与Sr的分异机理以及分异程度问题，即流体中Rb与Sr之间是否存在分异和分异程度是否可以达到Sr同位素分析的精度分析。已有的流体包裹体的Rb-Sr等时线年龄研究资料和数据的分析检验结果普遍存在以下问题：等时线图上数据点分散；拟合年龄较老；等时线拟合品质参数的MSWD偏大，可靠性低。 相似文献
8.
碧口群铜矿床的成矿时限及其意义 总被引：4，自引：0，他引：4
碧口群铜矿床作为早期同生喷流,后期受变质改造的沉积一变质改造型矿床,其保留有同生沉积的纹层构造和后生叠加改造的脉状构造。脉状硫化物Sr同位素及含矿石英脉的Ar同位素定年分别给出329Ma和211．3Ma,说明脉状硫化物的成矿时限在329－211Ma左右。由于该年龄明显小于矿体围岩的Sin－Nd、Rb－Sr年龄,所以该年龄反映了碧口群矿床的后期叠加成矿的时间。 相似文献
9.
单个流体包裹体成分LA-ICP-MS分析在精准示踪成矿物质来源和精细刻画成矿过程方面具有独特优势,但已有研究主要聚焦于透明的脉石矿物中的流体包裹体,对用于矿石矿物较少,二者之间有何异同特别是谁更能代表成矿流体组成目前研究薄弱。闪锌矿是岩浆热液矿床和MVT型矿床中常见的矿石矿物,其通常发育流体包裹体并在透射光下具有透明-半透明特征,是研究流体包裹体较为理想的矿石矿物。文章选择南岭新田岭钨矿硫化物阶段的闪锌矿及共生石英为研究对象,开展流体包裹体成分LA-ICP-MS对比分析。分析结果显示,闪锌矿和石英中的流体包裹体组成存在较大差异,前者异常富Cu、Ag和Sn等金属元素,后者富Li、B、Na、K、Rb、Sr、Cs和Pb等元素。结合闪锌矿本身微量元素特征,文章认为元素Cu、Ag和Sn的超常富集与其从寄主矿物扩散进入流体包裹体有关。在基于大离子亲石元素的流体成因类型判别图中,闪锌矿和石英中的流体包裹体组成均能有效示踪成矿流体来源,但后者示踪效果更好。总体而言,共生石英中流体包裹体组成可能更能代表成矿流体组成,闪锌矿因其莫氏硬度较低、金属元素含量高等原因,元素易发生后期扩散/改变,流体包裹体组成可能不能代表真实流体信息。在研究矿石矿物流体包裹体时,需谨慎对待某些元素的超常富集。综合研究脉石矿物流体包裹体和矿石矿物本身元素组成是成矿流体研究更准确的手段。 相似文献
10.
滇西金满铜矿床成矿年龄测定 总被引：11，自引：1，他引：11
采用石英流体包裹体Rb Sr等时线法和磷灰石裂变径迹法对滇西金满铜矿床的成矿时代进行测定。研究结果表明燕山晚期为金满矿床的初始成矿期 ,喜山期是主要成矿时期 ;流体包裹体的Rb Sr法和裂变径迹法测定热液矿床的成矿年龄具有一定的意义 ,但需进一步探讨 ;锶同位素数据为成矿流体来源提供了进一步的证据 相似文献
11.
12.
In unaltered volcanogenic massive sulfide (VMS) ore deposits, variable Rb/Sr ratios in the ore mineral permits application
of the Rb-Sr isotopic method to directly date the time of ore formation. In contrast, post-crystallization deformation and
metamorphism would open the system to metamorphic fluids that would alter elemental ratios. To test whether the Rb-Sr isotopic
systematics in the ore minerals had preserved the formation time in the ∼800 Ma metamorphosed VMS ores within the ∼1 Ga Ambaji-Sendra
arc terrain, Rajasthan, NW India, common sulfides, pyrite and sphalerite from the Pipela Cu-Zn prospect, were analyzed for
their geochemistry and Rb-Sr isotopic systematics. Trace and rare earth elements in these minerals are resident probably at
crystal defects, whereas all inclusions (including those from metamorphic fluids) were removed by a simple crush leach method.
Results of direct dating by the Rb-Sr method to the hydrothermal pyrite yielded an isochron age of 1025±76 Ma with an initial
Sr ratio of 0.7051±0.0006, similar to previously determined zircon U-Pb age of 987 Ma from associated rhyolites. This suggests
the applicability of the crush leach method to date formation time of metamorphosed pyrite ores. 相似文献
13.
The Jinwozi lode gold deposit in the eastern Tianshan Mountains of China includes auriferous quartz veins and network quartz veins that are exemplified by the Veins 3 and 210, respectively. This paper presents H‐, O‐isotope compositions and gas compositions of fluid inclusions hosted in sulfides and quartz, and S‐, Pb‐isotope compositions of sulfide separates collected from the principal Stage 2 ores in Veins 3 and 210. Fluid inclusions trapped in quartz and sphalerite are pseudo‐secondary and primary. They were trapped from the fluids during the successive or alternate precipitation of quartz with sulfides. H‐ and O‐isotope compositions of fluid inclusion of three pyrite and one quartz separates from Vein 210 plot within the field of degassed melt, which is evidence for the incorporation of magmatic fluid as well with some possibility of contribution of metamorphic water to the hydrothermal system since the two datasets show a higher oxygen isotopic ratio than those of degassed melt. However, δD and δ18O values of fluid inclusions hosted in sulfides and quartz from Vein 3 are distinctly lower than those from Vein 210. In addition, salinities of fluid inclusion from Vein 3, approximately 3 to 6 wt% NaCl equivalent, are considerably lower than those from Vein 210, which are approximately 8 to 14 wt% NaCl equivalent. Ore‐forming fluids of Veins 3 and 210 have migrated through the relatively high and low levels in the imbricate‐thrust column where rock deformation is characterized by dilatancy or ductile–brittle transition, respectively. Therefore, the ore‐forming fluid of Vein 3 is interpreted to have mixed with greater amounts of meteoric‐derived groundwater than that of Vein 210. Fluid inclusions hosted in sulfides contain considerably higher abundances of gaseous species of CO2, N2, H2S, and so on, than those hosted in quartz. Many of these gaseous species exhibit linear correlations with H2O. These linear trends are interpreted in terms of mixing between magmatic fluid and groundwater. The relative enrichment of gaseous species in fluid inclusions hosted in sulfides, coupled with the banded ore structure, suggests that the magmatic fluid was involved with the ore‐forming fluid in pulsation. Lead isotope compositions of 21 pyrite and galena separates form a linear trend, suggesting mixing of metallic materials from diverse reservoirs. The δ34S values of pyrite and galena range from +5.6‰ to +7.9‰ and from +3.1‰ to +6.3‰, respectively, indicating sulfur of the Jinwozi deposit has been leached mainly from the granodiorite and partly from the Jinwozi Formation by the circulating ore‐forming fluid. 相似文献
14.
15.
伊利石是一种层状硅酸盐矿物,层间主要为钾离子,可利用K-Ar法、Ar-Ar法和Rb-Sr法等相关的测年方法来分析和限定与自生伊利石有关的地质事件的时代,例如盆地演化历史、热液活动、构造活动和油气运移。本文讨论了利用钾盐矿床中自生伊利石进行蒸发岩地层年代学研究的可能性。虽然多数研究表明温度是控制自生伊利石形成的主要控制因素,即自生伊利石一般形成于温度较高的条件下,但一些研究表明在地表温度的盐湖环境中也可形成自生伊利石,此种环境下控制自生伊利石形成的主要因素为流体成分。这构成了利用自生伊利石定年来研究蒸发岩地层时代的理论基础。然而在实际研究过程中仍存在很多问题,需进行进一步的研究。 相似文献
16.
《International Geology Review》2012,54(5):470-480
Absolute ages of granite magmatism, as well as of tungsten mineralization, are poorly constrained in the Mongolian Altai and adjacent areas. There are no reports focusing on special isotopic investigations of the tungsten deposits. For the deposits in the Achit nuur and the Zagaan-Shibetin tectonic zones, two concepts that are discussed in the literature assume Paleozoic or Mesozoic ages for mineralization and related granite magmatism. We report the first results of a combined Sm-Nd and Rb-Sr isotope investigation of rocks and vein minerals of the Ulaan uul tungsten deposit at Kyzyltau; the results suggest Paleozoic ages for vein mineralization and for albitization of the host granite. The Sm-Nd isotope system, and the structure of vein minerals used for isotopic dating, were only slightly affected by late alteration processes. Sm-Nd mineral isochrons for wolframite and fluorite from the veins define an age of 303 ± 17 Ma (MSWD = 1.8, εNd = +0.9 ± 0.2). The Rb-Sr isotope system of the vein-hosting granite was strongly influenced by alteration processes. The Rb-Sr whole-rock isochron (282.2 ± 2.4 Ma, Sri = 0.70667 ± 0.00032, MSWD = 0.53) is interpreted as a mixing line and the age so defined has no direct geological meaning. Nevertheless, using Rb-Sr model ages and data on the degree of alteration of the samples, an age somewhat below 316 Ma can be estimated for albitization of the vein-hosting granite. This age estimation is in good agreement with the Sm-Nd isochron age for the vein mineralization. High εNd values obtained for wolframite and fluorite from the ore veins indicate an important role for material derived from the upper mantle in the ore formation processes. 相似文献
17.
粤北大宝山多金属矿床矿物包裹体特征研究及应用 总被引：11，自引：0，他引：11
粤北大宝山多金属矿床位于曲仁盆地南侧,大东山—贵东东西向构造带与雪山嶂北北东向隆起带的复合部位。本文拟据大宝山矿床包裹体温压地球化学特征和氢、氧同位素以及矿物流体包裹体Rb-Sr等时线年龄的系统研究,认为成矿物质主要来源于岩浆期后含矿热液,其成因应属于燕山早期岩浆期后热液矿床。 相似文献
18.
Yu. A. Shukolyukov O. V. Yakubovich A. G. Mochalov A. B. Kotov E. B. Sal’nikova S. Z. Yakovleva S. I. Korneev B. M. Gorokhovskii 《Petrology》2012,20(6):491-505
A new method of isotope geochronology was proposed for dating native platinum minerals on the basis of the ??-decay of the natural isotope 190Pt. The analysis of the thermal desorption of helium in the crystal lattice of native metals, including platinum, allowed us to predict a very high thermal stability (retentivity) of radiogenic 4He in native platinum minerals up to their melting temperatures. In order to validate the proposed 190Pt-4He method, direct isotopic dating was performed for isoferroplatinum from the Galmoenan dunite-clinopyroxenite and Kondyor alkaline ultramafic massifs. The results of dating obtained by this method for primary ore platinum from the Galmoenan Massif (70 ± 5 Ma) are consistent with geological observations and mean Sm-Nd and Rb-Sr isotopic age estimates. The 190Pt-4He age obtained for placer isoferroplatinum from the Kondyor Massif (112 ± 7 Ma) also agrees with geological observations and is close to the K-Ar and Rb-Sr ages of koswites (phlogopite-magnetite pyroxenites, gabbros, nepheline syenites, and metasomatic rocks after dunites). Our experimental data demonstrated that the 190Pt-4He method is a promising tool for dating native platinum minerals. 相似文献
19.
皖南东至兆吉口铅锌矿床成矿时代的厘定及其找矿指示意义 总被引：1，自引：0，他引：1
皖南东至兆吉口铅锌矿床是近年来在江南过渡带西段新发现的一个规模达中型的中-低温热液型矿床。目前揭露的铅锌矿体均赋存于东至断裂带及其西侧次级张(扭)性断裂及裂隙中。文章选取了该矿床主要矿石矿物闪锌矿以及与主成矿阶段金属硫化物紧密共生的石英,分别采用流体包裹体Rb-Sr法和40Ar-39Ar法进行同位素地质年龄测定。4件闪锌矿样品获得流体包裹体Rb-Sr等时线年龄为(128±1)Ma;2件石英样品获得流体包裹体40Ar-39Ar坪年龄分别为(128.74±3.02)Ma和(128.19±1.98)Ma,等时线年龄分别为(128.81±5.25)Ma和(128.30±3.47)Ma,反等时线年龄分别为(128.82±5.24)Ma和(128.31±3.47)Ma。同位素地质年龄测试结果基本一致,表明兆吉口铅锌矿床形成于128 Ma左右,成矿时代为早白垩世。该成矿年龄与赋矿闪长玢岩的形成时间((129.0±2.3)Ma~(128.4±2.7)Ma)一致,也与东至断裂燕山晚期的活动年龄((126.3±2.2)Ma)相近,表明该矿床成矿与燕山晚期的构造-岩浆活动密切相关,此时区域构造背景为强烈挤压后的伸展环境。这一矿化事件在成矿时代上明显晚于长江中下游成矿带中的断隆区(如铜陵、安庆-贵池等矿集区)的铜金多金属矿床和皖南成矿带中的钨钼多金属矿床(136 Ma),而与长江中下游成矿带断坳区的玢岩铁矿床的成矿时间(135~127 Ma)相近,指示长江中下游成矿带与皖南成矿带之间的江南过渡带中发育有燕山晚期较晚阶段(128 Ma左右)的铅锌矿化事件,为今后在该区开展铅锌多金属矿床找矿勘探提供了重要依据。 相似文献