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1.
Stability of Temperature and Conductivity Sensors of Argo Profiling Floats   总被引:7,自引:3,他引:7  
After recalibration of the temperature and conductivity sensors of three Argo profiling floats recovered after operations for four to nine months, the results indicate that the floats basically showed no significant drift, either in temperature or salinity, and adequately fulfilled the accuracy requirement of the Argo project (0.005°C for temperature and 0.01 psu for salinity). Only the third float showed a significant offset in salinity of about −0.02 psu, as expected from comparison between the float data and the shipboard conductivity-temperature-depth data. This offset was caused by the operational error of the PROVOR-type float, in which the surface water was pumped immediately after the launch, fouling the conductivity sensor cell. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

2.
An improved method to estimate the time-varying drift of measured conductivity from autonomous CTD profiling floats has been developed. This procedure extends previous methods developed by Wong, Johnson and Owens [2003. Delayed-mode calibration of autonomous CTD profiling float salinity data by θS climatology. Journal of Atmospheric and Oceanic Technology, 20, 308–318] and Böhme and Send [2005. Objective analyses of hydrographic data for referencing profiling float salinities in highly variable environments. Deep-Sea Research Part II, 52, 651–664]. It uses climatological salinity interpolated to the float positions and observed θ surfaces and chooses 10 ‘best’ levels that are within well-mixed mode waters or deep homogeneous water masses. A piece-wise linear fit is used to estimate the temporally varying multiplicative adjustment to the float potential conductivities. An objective, statistical method is used to choose the breakpoints in the float time series where there are multiple drift trends. In the previous methods these breakpoints were chosen subjectively by manually splitting the time series into separate segments over which the fits were made. Our statistical procedure reduces the subjectivity by providing an automated way for doing the piece-wise linear fit. Uncertainties in this predicted adjustment are estimated using a Monte-Carlo simulation. Examples of this new procedure as applied to two Argo floats are presented.  相似文献   

3.
A sighting device, called a “probe sight”, is described which simplifies the measurement, taken, from a helicopter, of the float separations from a deployed expendable surface current probe. The separation distance between the floats (along with a known time release) is a measure of the surface current speed. The sighting device can be used at any altitude. Comparisons of the readings using the probe sight and the “normal” measurements taken from aerial photographs for 180 stations in the Chukchi Sea, show that the difference between the two methods is less than 10% when the current speed is greater than 10 cm sec−1. The largest difference (15%) occurs at those stations where the current speed is less than 10 cm sec−1.  相似文献   

4.
Argo浮标电导率漂移误差检测及其校正方法探讨   总被引:6,自引:0,他引:6  
文章引入位势电导比(potential conductivity ratio)的概念,对一个在西北太平洋上观测时间长达4a的Argo剖面浮标进行了诊断分析,并利用现场CTD资料和简单的误差消除法,对该浮标由电导率传感器漂移所产生的盐度误差进行了校正处理,且与目前同际上公认的WJO方法进行了比较,发现利用现场CTD资料校正Argo浮标长期观测所产生的盐度误差更直观、更简便,其校正结果也是可信的。  相似文献   

5.
ARGO剖面浮标电导率传感器漂移问题探讨   总被引:3,自引:0,他引:3  
ARGO剖面浮标在海上长期工作,其携带的电导率传感器漂移会导致测量数据误差,从而影响观测资料的质量。文章利用误差理论和回归分析、曲线拟合等数理统计方法,检测和处理由ARGO剖面浮标电导率传感器漂移所带来的测量误差,并对太平洋、大西洋和印度洋上已经发现有电导率传感器漂移的ARGO资料进行了校正,取得了比较理想的结果。  相似文献   

6.
Several floats that deployed by different countries during the last years over the global ocean, which served as a contribution to the Array for real time geostrophic oceanography (Argo), are studied in this paper with respect to their uniqueness in the Delayed Mode Quality Control (DMQC) process. Of these floats, issues were found in the temperature-salinity relationships during the DMQC, which would easily be misinterpreted or overlooked. This study lists and summarizes the possible situations of the floats that might confront in their observation life, together with the reasonable explanations. The authors present some thoughts on evaluating the performance of the conductivity sensors and calibrating the float salinity data.  相似文献   

7.
Mid-depth circulation of the Shikoku Basin was measured by tracking four SOFAR floats drifting at the 1,500 m layer. Two floats were released on 17 April 1988 at 30°N, 135°59E and tracked for 433 days. Another two were released on 3 November 1988 at 29°52N and 133°25E, and tracked for 234 days. Two floats flowed clockwise around the Shikoku Warm Water Mass with a diameter of 400 km centered at 31°N and 136°E and a mean drift speed of 4.5 cm sec–1. One of the floats showed about ten counterclockwise rotations with a period of about 8 days and a maximum speed of 80 cm sec–1 in the sea area west to the Izu Ridge. In the east to Kyushu, a southward flow was observed under the northward flowing Kuroshio. The southward flow of 4 cm sec–1 drift speed was considered to be a part of the counterclockwise circulation at deep layers along the perimeter of the Shikoku Basin. One float remained for 234 days in a limited area of 100 km by 150 km in the western part of the basin.  相似文献   

8.
ROMS with horizontal grid spacing of 3.5 km for the region off Central California was compared to RAFOS float observations and satellite altimetry on meso/submesoscales. The approach introduced and used two new metrics for model-data comparison, as well as suggested how to calculate these metrics for different spatio-temporal scales. The first metric consisted of the first two moments of exit time and was used to compare ROMS against RAFOS float observations at mid-depths (between 300 m and 350 m). Exit time is the time a float launched at a point takes to leave a domain for the first time. The second metric was spectral entropy and was used to estimate how well ROMS reproduced variability of the sea surface height (SSH) anomaly field extracted from an AVISO data set (1992–2007) for specified temporal and spatial scales. Calculations showed that ROMS reproduced the mid-depth mesoscale/submesoscale currents next to the coast in a very accurate manner (low-order exit time statistics of floats were reproduced by ROMS with an accuracy better than 95%); but ROMS overestimated the speed of westward drift of floats by as much as 20–30% at distances greater than 350 km from the coastline. ROMS predicted the variability of the mesoscale (100–400 km) SSH anomaly field for temporal scales of 1–12 months with a reasonable accuracy. A wavelet transform modulus maxima technique applied to the spectral entropy of SSH anomaly also demonstrated good agreement between ROMS and satellite altimetry for mesoscales characterized by singular exponents and multi-fractal spectra for 1–12 month time scales.  相似文献   

9.
Six newly developed floats, which were set to drift on the 26.7 σθ isopycnal surface and to profile temperature, salinity and pressure above 1000 dbar once a week, were deployed in the Oyashio and Kuroshio Extension (KE) in order to examine the circulation, formation site and time scale of newly formed North Pacific Intermediate Water (NPIW). The floats were deployed in February or May 2001, and the data from their deployments to December 2002 are analyzed here. Four of the six floats were deployed near the KE axis at around the first meander crest, and they moved eastward to 157°E–176°W at latitudes of 30°N–45°N. The other two floats deployed in the Oyashio water with low-potential vorticity near the south coast of Hokkaido moved southward to reach the KE front and then moved eastward to the same region as the first four floats. The temperature and salinity at 26.7 σθ measured by the profiling floats indicate that the source waters of NPIW, Oyashio and Kuroshio waters are drastically mixed and modified in the mixed water region west of 160°E. The floats were separated into the three paths east of 160°E between the Kuroshio Extension front and the north of Water-Mass front (nearly subarctic front). New NPIW is judged to be formed along these three paths since the vertical profiles of temperature and salinity are quite smooth, having a salinity minimum at about 26.7σθ along each path. Kuroshio-Oyashio isopycnal mixing ratios of the new NPIW are 7:3, 6:4 and 5:5 at 26.7σθ along the southern, middle and northern paths, respectively. Potential vorticity converges to about 14–15 × 10−11 m−1s−1 along these paths. The time scale of new NPIW formation is estimated to be 1–1.5 years from the merger of Oyashio and Kuroshio waters to the formation of the new NPIW. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

10.
Estimating the average lifetime of floats is very important for Argo, because the total cost of maintaining the monitoring network largely depends on float lifetime. However, the actual lifetime of floats used in Argo is currently unknown. An estimate can be made by examining past float survival, but this is complicated by floats still operating at sea and continuous improvements in float hardware. Because APEX (Autonomous Profiling Explorer) floats are the most widely deployed type of float in the world oceans, in this study we estimate the lifetime of the latest model of APEX powered by alkaline batteries. The expected lifetime is estimated with a statistical method that allows for floats that are still active and that failed because of a known and now fixed hardware fault that should not cause failure in the latest model of floats. As an example, we analyzed the APEX fleets managed by the Japan Agency for Marine-Earth Science and Technology (JAMSTEC), because we have access to a JAMSTEC database in which the causes of float failure have been carefully correlated to known hardware problems. Analysis of the JAMSTEC fleet (n = 571, as of 7 May 2008) indicated that the expected lifetime of the latest model of APEX is 134.6 (127.6–141.5, considering standard errors) cycles, equivalent to 3.7 years of 10-day cycles. We conclude that the annual deployment of 813 (773–859) APEX floats is needed to maintain the Argo observational network of 3000 floats. Floats with different hardware configurations (e.g., lithium batteries) or different mission programs (e.g., shallower profiling, deeper profiling every several cycles) may be expected to have an even longer lifetime.  相似文献   

11.
We deployed two profiling floats in the region south of the Kuroshio Extension in March 2000. Temperature and salinity profiles from a depth of 1500 × 104 Pa to the surface are reported every two and four weeks, respectively. The floats performed very well for first four months after deployment. Later they failed in surfacing for a few months when the sea surface temperature in the region was high. The salinity sensors seemed to suffer from some damage during their failure-in-surfacing period. Despite this trouble, the results clearly demonstrate that the profiling float is a very useful and cost-effective tool for physical oceanographic observation in the open sea. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

12.
Dissolved cadmium and copper concentrations have been determined in 76 surface water samples in coastal and ocean waters around Scotland by anodic stripping voltammetry (ASV). A trace metal/salinity ‘front’ is observed to the west, north and north-east of Scotland separating high salinity ocean water (>35 × 10−3) with low concentrations of dissolved Cd and Cu from lower salinity (<35 × 10−3) coastal water containing higher concentrations of Cd and Cu. Mean Cd concentrations in ocean and coastal waters are 7 ng dm−3 (0·06 n ) and 11 ng dm−3 (0·10 n ) respectively; for Cu the respective levels are 60 ng dm−3 (0·95 n ) and 170 ng dm−3 (2·68 n ). The observed distribution is attributed principally to freshwater runoff and the advection of contaminated Irish Sea water into the study area.  相似文献   

13.
The moored three-float line absorber WEC M4 has been developed to optimise power capture through experiments and linear diffraction modelling. With the progression down wave from small to medium to large floats, the device heads naturally into the wave direction. The bow and mid floats are rigidly connected by a beam and a beam from the stern float is connected to the hinge point above the mid float for power take off (PTO). Increasing the bow to mid float spacing to be more than 50% greater than the mid to stern float spacing has been found to improve power capture. To increase power capture further and potentially reduce electricity generation cost the number of mid floats and stern floats is increased while maintaining a single bow float for mooring connection. The bow and mid floats still form a rigid body while the stern floats may respond independently. A time domain linear diffraction model based on Cummins method has been applied to configurations of 121, 123, 132, 133, and 134 floats where the numbers indicate the number of floats: bow, mid, stern. This shows how power capture is increased while response remains similar. We only consider uni-directional (long-crested) waves with narrow band width typical of swell. By considering scatter diagrams for various offshore sites capacities may range from 3.7 MW to 17.3 MW for the eight float system with a capacity factor of 1/3 while the cost of electricity assuming capital cost to be a fixed multiple of steel cost is reduced from that for the three-float system.  相似文献   

14.
利用Argo剖面浮标分析上层海洋对台风“布拉万”的响应   总被引:9,自引:2,他引:7  
In situ observations from Argo profiling floats combined with satellite retrieved SST and rain rate are used to investigate an upper ocean response to Typhoon Bolaven from 20 through 29 August 2012. After the passage of Typhoon Bolaven, the deepening of mixed layer depth(MLD), and the cooling of mixed layer temperature(MLT) were observed. The changes in mixed layer salinity(MLS) showed an equivalent number of increasing and decreasing because the typhoon-induced salinity changes in the mixed layer were influenced by precipitation, evaporation, turbulent mixing and upwelling of thermocline water. The deepening of the MLD and the cooling of the MLT indicated a significant rightward bias, whereas the MLS was freshened to the left side of the typhoon track and increased on the other side. Intensive temperature and salinity profiles observed by Iridium floats make it possible to view response processes in the upper ocean after the passage of a typhoon. The cooling in the near-surface and the warming in the subsurface were observed by two Iridium floats located to the left side of the cyclonic track during the development stage of the storm, beyond the radius of maximum winds relative to the typhoon center. Water salinity increases at the base of the mixed layer and the top of the thermocline were the most obvious change observed by those two floats. On the right side of the track and near the typhoon center when the typhoon was intensified, the significant cooling from sea surface to a depth of 200×104 Pa, with the exception of the water at the top of the thermocline, was observed by the other Iridium float. Owing to the enhanced upwelling near the typhoon center, the water salinity in the near-surface increased noticeably. The heat pumping from the mixed layer into the thermocline induced by downwelling and the upwelling induced by the positive wind stress curl are the main causes for the different temperature and salinity variations on the different sides of the track. It seems that more time is required for the anomalies in the subsurface to be restored to pretyphoon conditions than for the anomalies in the mixed layer.  相似文献   

15.
In the Neil Brown Instruments' MKIIIB-CTD (conductivity-temperature-depth profiler), the system's digital outputs for the three basic measurements of temperature, conductivity and pressure typically show some small amplitude deviations from smooth calibrations which should be corrected for to achieve high accuracies, as required, e.g. within the Hydrographic Program (WHP) of the current World Ocean Circulation Experiment (WOCE). These deviations show up as (i) a strong nonlinearity or even discontinuity of several mK close to 0°C in temperature output leading to too high subzero temperatures; (ii) a jump of order 0.002 mS cm−1 in conductivity output when passing the half-range value 32.768 mS cm−1, which causes jumps in the relation of potential temperature and salinity; and (iii) errors in pressure measurements of up to 4 dbar due to mechanical hysteresis and both static and dynamic responses to temperature changes. The existence of these effects is demonstrated, and methods to reduce the associated errors are suggested.  相似文献   

16.
The effect of ionic interactions on the kinetics of disproportionation of HO2, and the oxidation of Fe(II) and Cu(I) has been examined. The interactions of O2 with Mg2+ and Ca2+ ions in seawater increases the lifetime by 3–5 times compared to water. The effect of OH on the oxidation of Fe(II) in water and seawater shows a second degree dependence from 5 to 45°C. The effect of salinity on the oxidation of Fe(II) was found to be independent of temperature, while the effect of temperature was found to be independent of salinity. The energy of activation for the overall rate constant was found to be 7 ± 0.5 kcal mol−1.The effect of pH, temperature, salinity and ionic composition on the oxidation of Cu(I) has also been examined. In NaCl solutions from 0.5 to 6 M, the log k for the oxidation was a linear function of pH (6–8) with a slope of 0.2 ± 0.05. The reaction was strongly dependent on the Cl concentration with variation of from 0.3 to 340 min from 0.5 to 6 M Cl. The rates of oxidation of Cu+ and CuCl0 responsible for these effects are dependent upon ionic strength. The energy of activation for the reaction was 8.5–9.9 kcal mol−1 from 0.5 to 6 M. Studies of the oxidation in various NaX salts (X = I, Br and Cl) give rates in the order Cl > Br > I as expected, due to complex formation of Cu+ with X.  相似文献   

17.
The effect of a sudden increase in salinity from 10 to 37 in porewater concentration and the benthic fluxes of ammonium, calcium and dissolved inorganic carbon were studied in sediments of a small coastal lagoon, the Albufera d'Es Grau (Minorca Island, Spain). The temporal effects of the changes in salinity were examined over 17 days using a single diffusion-reaction model and a mass-balance approach. After the salinity change, NH4+-flux to the water and Ca-flux toward sediments increased (NH4+-flux: 5000–3000 μmol m−2 d−1 in seawater and 600/250 μmol m−2 d−1 in brackish water; Ca-flux: −40/−76 meq m−2 d−1 at S=37 and −13/−10 meq m−2 d−1 at S=10); however, later NH4+-flux decreased in seawater, reaching values lower than in brackish water. In contrast, Ca-flux presented similar values in both conditions. The fluxes of dissolved inorganic carbon, which were constant at S=10 (55/45 mmol m−2 d−1), increased during the experiment at S=37 (from 30 mmol m−2 d−1 immediately after salinity increase to 60 mmol m−2 d−1 after 17 days).In brackish conditions, NH4+ and Ca2+ fluxes were consistent with a single diffusion-reaction model that assumes a zero-order reaction for NH4+ production and a first-order reaction for Ca2+ production. In seawater, this model explained the Ca-flux observed, but did not account for the high initial flux of NH4+.The mass balance for 17 days indicated a higher retention of NH4+ in porewater in the littoral station in seawater conditions (9.5 mmol m−2 at S=37 and 1.6 mmol m−2 at S=10) and a significant reduction in the water consumption at both sites (5 mmol m−2 at S=37; 35/23 mmol m−2 at S=10). In contrast, accumulation of dissolved inorganic carbon in porewater was lower in seawater incubations (−10/−1 meq m−2 at S=37; 50/90 meq m−2 at S=10) and was linked to a higher efflux of CO2 to the atmosphere, because of calcium carbonate precipitation in water (675/500 meq m−2). These results indicate that increased salinity in shallow coastal waters could play a major role in the global carbon cycle.  相似文献   

18.
Measurement of dissolved oxygen using optodes in a FerryBox system   总被引:2,自引:0,他引:2  
Optode sensors can provide detailed information on concentrations of dissolved oxygen, which in turn may be used to quantify variations in net primary productivity. Throughout 2005 and 2006 the performance of commercially available oxygen optodes was examined, one in each year. The optode was part of an autonomous measurement system (FerryBox) on a ferry operating between Portsmouth (UK) and Bilbao (Spain). On crossings during which water samples were collected manually, the optode outputs were compared to measurements of dissolved oxygen made by Winkler titrations. The optodes maintained good stability with no evidence of instrumental drift during the course of a year. Over the observed concentration range (230–330 mM m−3) the optode data were approximately 2% low in both years. By fitting the optode data to the Winkler data the median difference between the optode and Winkler measurements is reduced to less than 1 mM m−3 (0.3%) in both years. The most appropriate calibration factor for 2005 was corrected O2 = Optode O2 × 1.018 and for 2006 the corresponding equation is corrected O2 = Optode O2 × 0.884 + 36.8. The standard deviation (95%) of the difference between the individual Winkler measurements was 5 mM m−3 and 3 mM m−3 in 2005 and 2006 respectively.Calculation of the oxygen saturation anomaly is required for calculation of the air sea exchange of oxygen and net biological production. This calculation requires the use of both salinity and temperature data. Salinity is measured to better than 0.1 so the corresponding error in anomaly is less than 0.2 mM m−3. Distortion of the temperature data is present due to warming of the water pumped to the optode. In winter this warming at the optode may be as great as 0.4 °C. The difference in the pumped water temperature can be corrected for by reference to other measurements of sea surface temperature reducing the error to less than 1 mM m−3.  相似文献   

19.
Self-diffusion coefficients of five major ions have been determined by a radioactive tracer method (capillary tube method) in seawater of salinity 34.86 at 25°C. Data are presented for Na+, Ca2+, Cl, SO42, and HCO3, which constitute about 95% by weight of sea salt. The influence of temperature and salinity on these coefficients has been studied for Na+ and Cl which are the major components of sea salt: self-diffusion coefficients of these two ions have been measured in seawater, at different temperatures for a salinity of 34.86 and at different salinities for a temperature of 25°C. Diffusion coefficients of the same ions have been determined at 25°C by using another radioactive tracer method (quasi-steady cell method). In this experiment, seawater ions were allowed to diffuse from natural seawater into dilute seawater. Data have been obtained at 25°C for Na+, Ca 2+, Cl, SO42− and HCO3, corresponding to different salinity gradients.  相似文献   

20.
The suspension-feeding gastropod Crepipatella dilatata occurs in estuaries in southern Chile that experience considerable fluctuations in salinity, driven by tidal and atmospheric forces. In the Quempillén estuary salinities as low as 9 psu may occur after severe rainstorms, and persist for several hours. In this study salinity was the major factor influencing the clearance rate of C. dilatata. At salinities below 20 psu, filtration ceased, whereas at high salinities (>22 psu) mean clearance rate was 0.24 l h−1 standard animal−1 (S.D. 0.18) for actively filtering individuals. This was confirmed by laboratory experiments under controlled conditions. Endoscopic observations were consistent with measurements of clearance rate, and showed that at salinity 25–30 psu the rate of transport along the gill filaments of particulate material embedded in mucus was 759 μm s−1 (S.D. 480), but particle transport ceased at and below salinity 20 psu. Complete or partial isolation of the mantle cavity from the environment may be a mechanism to protect soft tissues and/or incubated egg capsules from osmotic stress.  相似文献   

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