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1.
《Applied Geochemistry》1996,11(5):711-720
The organic matter in 9 recent (not more than 250 years old) and ‘organic-rich’ sediments from the southern Black Sea shelf and upper slope have been characterized semi-quantitatively by Pyrolysis/Gas Chromatography/Mass Spectrometry (PY/GC/MS) and13C Cross Polarization Magic Angle Spinning Nuclear Magnetic Resonance (CPMAS-NMR) spectrometry. The organic matter of 7 of the studied sediments was found to be ligno-carbohydrate with a proteinaceous component, one sediment appeared to contain oxidized coal dust and one contained thiophenes in association with pyrite. The ligno component is derived from grasses and soft wood lignin. Material entrapped in an anoxic environment contained the highest proportions of carbohydrate and protein. All the samples had suffered diagenesis as is generally shown by the attachment of carboxyl groups and the removal of methoxyl groups. The evidence suggests that diagenesis occurred whilst the particles traversed the oxic water column. 相似文献
2.
《地学前缘(英文版)》2016,7(2)
The spatial distribution patterns of surficial sediment samples from different sedimentary domains(shallow to deep-sea regions) of the eastern Arabian Sea were studied using sediment proxies viz.environmental magnetism,geochemistry,particle size and clay mineralogy.Higher concentrations of magnetic minerals(high x_(lf)) were recorded in the deep-water sediments when compared with the shallow water sediments.The magnetic mineralogy of one of the shallow water samples is influenced by the presence of bacterial magnetite as evidenced from the x_(ARM)/x_(lf)~(vs).x_(arm_/x_(fd)biplot.However,the other samples are catchment-derived.The high correlation documented for x_(lf).anhysteretic remanent magnetisation(x_(arm)) and isothermal remanent magnetisation(IRM) with Al indicates that the deep-sea surficial sediments are influenced by terrigenous fluxes which have been probably derived from the southern Indian rivers,the Sindhu(the Indus) and the Narmada-Tapti rivers.A lower Mn concentration is recorded in the upper slope sediments from the oxygen minimum zone(OMZ) but a higher Mn/Al ratio is documented in the lower slope and deep-sea sediments.Clay minerals such as illite(24-48.5%),chlorite(14.1-34.9%),smectite(10.6-28.7%) and kaolinite(11.9-27.5%) dominate the sediments of shallow and deep-sea regions and may have been derived from different sources and transported by fluvial and aeolian agents.Organic carbon(OC) data indicate a low concentration in the shallow/shelf region(well oxygenated water conditions) and deeper basins(increased bottom-water oxygen concentration and low sedimentation rate).High OC concentrations were documented in the OMZ(very low bottom-water oxygen concentration with high sedimentation rate).The calcium carbonate concentration of the surface sediments from the continental shelf and slope regions( 1800 m) up to the Chagos-Laccadive Ridge show higher concentrations(average = 58%) when compared to deep basin sediments(average = 44%).Our study demonstrates that particle size as well as magnetic grain size,magnetic minerals and elemental variations are good indicators to distinguish terrigenous from biogenic sediments and to identify sediment provenance. 相似文献
3.
Sediment samples have been collected during the Donghai 1 cruise in January 1986 in the Chang Jiang estuarine region for which solvent extractable sterols have been analysed by GC and GC/MS and the data examined using Correspondence Factorial Analysis (CFA). The main autochthonous sterols in these sediments were cholesterol, 24-methylcholesta-5,22-dien-3β-ol and 24-methylcholesta-5,24(28)-dien-3β-ol, whereas 24-ethylcholesterol, 24-ethylcholesta-5,22-dien-3β-ol and 24-methylcholesterol were principally allochthonous. Autochthonous sterols prevailed in regions of high primary production observed in summer, and allochthonous ones dominated the sterol distribution in the accumulation region of fine sediments just outside the river mouth and in the reaches of coastal currents. The cholesterol/cholesterol ratio values exhibited higher values close to the river mouth and in the region where the turbidity maximum extends. A comparison between sediment and suspended matter indicated a great difference in the sterol content in regions of high autochthonous production which suggested that sterols have been transformed in the course of sedimentation and at the sediment/water interface. In contrast, sedimentary and suspended sterol concentrations were comparable close to the mouth of the Chang Jiang River and in the region where the turbidity maximum extends, a feature that may be attributable to sediment resuspension episodes and lower production of autochthonous sterols. These results demonstrate the distinct impact of biogeochemical processes on the sediment sterol features in different zones of the estuary. 相似文献
4.
The effects of intrusive thermal stress have been studied on a number of Pleistocene sediment samples obtained from Leg 64 of the DSDP-IPOD program in the Gulf of California. Samples were selected from Sites 477, 478 and 481 where the organic matter was subjected to thermal stress from sill intrusions. For comparison purposes, samples from Sites 474 and 479 were selected as representative of unaltered material.The GC and GC-MS data show that lipids of the thermally unaltered samples were derived from microbial and terrestrial higher-plant detritus. Samples from sill proximities were found to contain thermally-derived distillates and those adjacent to sills contained essentially no lipids. Curie point pyrolysis combined with GC and GC-MS was used to show that kerogens from the unaltered samples reflected their predominantly autochthonous microbial origin. Pyrograms of the altered kerogens were much less complex than the unaltered samples, reflecting the thermal effects. The kerogens adjacent to the sills produce little or no pyrolysis products since these intrusions into unconsolidated, wet sediments resulted in in situ pyrolysis of the organic matter.Examination of the kerogens by ESR showed that spin density and line width pass through a maximum during the course of alteration but ESR g-values show no correlation with maturity. Stable carbon isotope (δ13C) values of kerogens decrease by 1–1.5‰ near the sills at Sites 477 and 481 and the atomic N/C decreases slightly with proximity to a smaller sill at Site 478. Differences in maturation behavior between Site 477 and 481 and Site 478 are attributed to dissimilarities in thermal stress and to chemical and isotopic heterogeneity of Guaymas Basin protokerogen. 相似文献
5.
地表松散沉积物中不同粒级的颗粒蕴含着不同的信息,这种差异与其物质来源、搬运和沉积过程中的分选作用以及沉积后的风化作用等有关。因此,可根据沉积物中不同粒级颗粒地球化学特征与矿物组成的差异,进行沉积物物源追踪或沉积环境重建。选择青藏高原在气候和地貌方面具有典型意义的柴达木盆地、错那湖、雅鲁藏布江流域作为研究区,分别采集了这几个地区的沙丘沙、黄土、湖积物、冲积物、洪积物、残坡积物等地表松散沉积物样品,用干筛法将沉积物样品分为两个部分,粗颗粒部分粒径范围为≥75~500 μm,细颗粒部分粒径<75 μm。对上述粗、细颗粒分别进行稀土与微量元素、Sr-Nd同位素、轻矿物组成的实验室分析测试,并对沉积物中粗、细颗粒的测试结果采用古典多维尺度方法进行相似性分析。结果表明：青藏高原松散沉积物中粗、细颗粒在轻矿物组成、微量和稀土元素含量、稀土特征、元素参数等方面存在差异;细颗粒部分蕴含了更多的环境信息,富含容易受化学风化影响的黏土矿物以及硬度较小、容易被磨蚀的方解石等矿物。在物源示踪中不同气候区的沉积物细颗粒不宜进行直接比较,应根据样品的粒度分布情况优先选择合适的粗颗粒组分进行物源示踪。 相似文献
6.
Kersten Löwen Guido Meinhold Arzu Arslan Talip Güngör Jasper Berndt 《International Geology Review》2020,62(4):389-414
ABSTRACTSiliciclastic sediments from the Upper Palaeozoic Konya Complex and its Mesozoic cover were studied by a multi-method approach combining thin-section petrography, bulk-rock geochemistry, mineral chemistry of rutile, and U–Pb geochronology of detrital zircons. Provenance sensitive data of samples from the Upper Palaeozoic Hal?c? Formation indicate sediment supply from mainly low- to medium-grade metamorphosed sedimentary rocks of felsic character, while the contribution from volcanic rocks was rare. The detrital zircon record of sediments from the Hal?c? Formation documents sediment supply from different sources and excludes a similar provenance. Some samples show great similarities with Palaeozoic sandstones from the cover sequence of the Saharan Metacraton and the Arabian–Nubian Shield, while the other samples indicate a provenance that must be sought in units with a southern Eurasian affinity. The upper limit for sediment deposition in the Hal?c? Formation is mostly constrained by Early Palaeozoic zircon populations; however, sediment accumulation in Pennsylvanian–Cisuralian time is more likely, contemporaneously with the Upper Palaeozoic succession on the Karaburun Peninsula (western Turkey). The provenance of sediments from the Upper Triassic Ard?çl? Formation remains enigmatic, but the source should be sought nonetheless in units close to the depositional site. In any case, detrital zircon age spectra and compositional data exclude recycling of underlying rock units (i.e. Hal?c? Formation). Overall, our new provenance data reveal great similarities between the Konya Complex and comparable units (Chios, Karaburun) but also highlight distinct differences in terms of sediment composition and provenance. 相似文献
7.
P.A. Cranwell 《Organic Geochemistry》1986,10(4-6)
Esters of phytol or related isoprenoid acids and fatty acid esters of pentacyclic triterpenoid alcohols and sterols have been isolated from lacustrine sediments varying in age from contemporary to c. 50,000 years old. The esters were analysed by C-GC-MS and identified by GC retention data and mass spectral interpretation based on comparison with authentic compounds.In surface sediment of a productive lake, phytyl and steryl esters are biochemical markers of input from algal and Zooplankton sources. Esters of pentacyclic triterpenols detected in an older, peat-derived sediment may reflect constituents of peat-forming plant species. In sediments derived mainly from terrestrial organic matter, steryl esters containing the same acyl group showed a lower stanol/Δ5-stenol ratio than did the corresponding free sterols. 相似文献
8.
《Applied Geochemistry》1997,12(5):593-605
The impact of sediment type on stream water geochemistry was studied in a catchment in Finland affected by sulphidic fine-grained sediments. Stream water samples for general characterisation of water quality (pH, electrical conductivity) were taken at the basin outlet during various hydrological conditions, while samples for detailed geochemical analysis were collected at 119 sites in the catchment on one single occasion during high-water flow in autumn. The occurrence of sulphidic fine sediments was estimated based on data from an airborne electromagnetic survey carried out by the Geological Survey of Finland.Growing-symbol maps, which were prepared for each of the studied variables in water, and statistical calculations including factor analysis and Spearman correlations show that the concentrations of Al, Ga, U and Tl, all the lanthanides and several alkali and alkaline earth metals (K, Mg, Na, Li, Ca, Rb, Sr), transition metals (Cd, Co, Cu, Zn, Sc, Mn, Ni, Y, Hf) and non-metals (S, Br, I, Si) increase in water when the proportion of the catchment cover of sulphidic fine sediments increases. It is therefore argued that these elements are released and mobilised in considerable amounts by the oxidation and subsequent acidification and weathering of this type of sediment. Other elements are either slightly depleted in streams in areas of sulphidic fine sediments (V, Nb, Pb, Zr), have a distribution unrelated to sediment type (Fe, Cr, Cs, Mo), or are only weakly impacted by the occurrence of sulphidic sediments in the catchment (As, Ti, Ba). It is argued that these elements are not leached extensively from the oxidising sulphidic sediments, and that their distributions at least partly may be controlled by the contents of dissolved humic material and/or suspended organic and inorganic phases in the water. 相似文献
9.
《China Geology》2019,2(3):325-332
Based on the 39 surface sediment samples collected in the flood season and the dry season in 2012 respectively and the measured hydrological data in October 2012, the sediment grain size characteristics has been analyzed and the response mechanism of surface sediments to estuarine hydrodynamics was revealed by calculating the range of waves and tidal currents. The results show that: (1) The grain size of the surface sediment samples decreased gradually from land to sea in the flood season. The fine sediment was redistributed under marine hydrodynamics in the dry season and the sediments showed coarser tendency ingeneral; (2) tidal current stirring sediment was very obvious in Dagu River estuary area, and wave stirring sediments mainly occurred in the tidal flat area and estuary sand bar area; (3) in the flood season, surface sediment sat the estuary were transported towards south and southeast. In the dry season, surface sediments were transported towards southwest at the north area of Jiaozhou Bay Bridge, and sediments were transported towards northeast area at the south of Jiaozhou Bay Bridge. 相似文献
10.
稳定湖相沉积物和风成黄土粒度判别函数的建立及其意义 总被引：10，自引：2，他引：8
沉积物粒度变化主要受搬运介质、搬运方式、沉积环境和气候等多种因素的控制,通过粒度分析可判别沉积物的成因类型,推断其形成的沉积环境,解释环境演变。利用统计学方法对典型稳定湖相沉积物（罗布泊湖相样品２８２块,岱海湖相样品１２３块）和典型风成黄土（甘肃兰州榆中样品２６３块）粒度参数进行定量化分析,并经稳定湖相和风成沉积物验证,获得稳定湖相与风成沉积物的判别公式:Ｆ（湖相、风成沉积物） ＝２０．３６３Ｍｚ－５６．３７１Ｓｄ－６７．９２２Ｓｋ＋２３．５１６Ｋｇ－５５．６２６,若Ｆ＞０,为稳定湖相沉积物,反之,Ｆ＜０,则为风成沉积物。这为研究地史中稳定湖泊与风成环境 沉积物的鉴别提供粒度分析定量化判别方法,它对陆相古环境、干旱化事件和尘暴事件等研究具有十分重要的借鉴价值。 相似文献
11.
《International Geology Review》2012,54(2):145-165
Two sediment cores from the inner continental shelf of SW India, SK‐148/13 (4.66 m long; from 50 m water depth) and SK‐148/14 (5.37 m long; from 22 m water depth), were studied for provenance and palaeomonsoonal implications. Sediment layers at different depth intervals in these cores were estimated for clay minerals and organic matter content. Five surface sediment samples from the nearby Kali River estuary of the adjacent hinterland were also analysed for clay mineral contents. In both cores and Kali River sediments, smectite is the dominant clay followed by illite, and kaolinite or chlorite. Based on the similarities of the abundances of clay minerals and their relative wt‐% in the inner shelf sediment cores and in surface sediments of the estuary as demonstrated by significance tests, Al‐rich illite, and negligible contribution of clay from the deep‐sea and aeolian sources, it can be inferred that the sediments of the two inner continental shelf cores were derived from the adjacent hinterland. Application of statistical discordancy and significance tests on the down‐core variations in the crystallinity index (CI) of illite and organic matter content in the sediment cores indicates intense monsoonal (high rainfall) conditions at the adjacent hinterland during about 4300–6200 and 9300–10,400 years BP. These inferences are comparable to those from other well‐established palaeomonsoonal indicators such as sedimentation rates and mineral magnetic properties. The CI of illite, an easily determinable and climatically sensitive parameter, can thus be a reliable palaemonsoonal indicator for inner shelf sediment cores. The statistical methodology used in this work highlights the advantages of a quantitative interpretation of the data instead of the conventional qualitative visual examination. 相似文献
12.
湖泊沉积物中DNA提取与PCR扩增 总被引：2，自引：0，他引：2
对湖泊沉积物中保存的生物大分子—DNA进行研究分析,以探讨湖泊生态系统随环境改变而演变的过程。根据前人对土壤和海洋沉积物DNA的提取方法,针对湖泊沉积物的特点进行改进,在此基础上对太湖梅梁湾湖泊沉积岩芯进行DNA提取和扩增。结果表明：不同深度湖泊沉积物均能获得DNA,且纯度较高,OD260/ OD280均大于1.4、OD260/ OD230大于1.1,可直接用于PCR（polymerase chain reaction ）扩增。对微囊藻的16S rRNA基因进行PCR扩增,结果发现在前5个沉积物样品中,均得到了200 bp左右的微囊藻16S rRNA基因片段,表明微囊藻或已降解的微囊藻基因片段存在于这5个层位的湖泊沉积物中。这为利用湖泊沉积物中的生物分子来推断历史湖泊生物群落结构,判断湖泊生态演变的历史提供了新的研究思路。 相似文献
13.
The sediments of the estuaries and offshore Tuticorin along the southern coast of Tamil Nadu were studied for their textural variation. Ninety sediment samples were collected from three sectors (river, estuary, offshore) on the basis of prevailing energy conditions and oceanographic parameters. Frequency curves show unimodal to bimodal in nature. Offshore samples also fall in bimodal with medium and fine sand where sediment is additionally deposited by the Tamiraparani River. The mean values ranging from 1.69 to 2.01 φ with medium to fine sand. The fine sand in the riverine region indicates the depositional nature of the sediments. In pre-monsoon, the standard deviation ranges from 0.29 to 0.81 φ, which falls in the very well sorted to moderately well sorted. Estuary ranges from 0.63 to 1.30 φ, with moderately sorted, whereas in the marine sediments ranges from 0.4 to 1.01 φ, with moderately to moderately well- sorted and some patches of poorly sorted is observed. In both monsoons, the grain size variations are mostly influenced in river and offshore samples compared to the estuaries. The CM pattern indicates the deposition of sediments in graded suspension. In estuary, the sediments are medium sand with moderately to poorly sorted, fine skewed which are indicative of denudation processes taking place there. In marine, the sediments are medium-to-fine, moderately-to-well sorted, and fine skewed to very fine skewed sediments, probably as a result of the influence of palaeo-sediments deposited by rivers from inland as well as by waves and currents from offshore. Further, the marine samples also highlight depositional processes. 相似文献
14.
中国海域拥有宽广的大陆架，同时还有陆坡和深海盆，有众多河流入海并输入巨量的陆源物质，沉积物记录了海陆变迁、环流变化、海平面升降、物质输送和气候变化等环境信息。沉积物的粒度特征可以反映沉积动力、物质来源和搬运距离等，可以通过沉积物粒度组成、参数及各种图解来研究沉积环境的变化。前人对中国海域表层沉积物的粒度分布特征展开了大量的研究，取得了丰富的研究成果，但这些研究多集中在某一海域或区域，缺乏对整个中国海域的表层沉积物类型的宏观系统认识。本文基于中国地质调查局“1：100万海洋区域地质调查项目”获取了中国海域4300个海底表层沉积物样品，通过沉积物粒度分析，结合前人已发表资料，对中国海域表层沉积物的沉积类型特征、物质来源和运移模式等开展了系统的研究。本文把浅海和半深海沉积物按照含砾石和不含砾石主要划分出5个和7个沉积物类型，深海沉积物主要划分了9个沉积类型，研究结果表明：中国海域表层沉积物沉积类型多样、来源复杂，主要受控于物质来源、水动力条件和地形地貌的变化，在东部海域总体呈现“大江大河-宽缓陆架-残留慢速沉积”的条带状沉积分异模式，而在南部海域呈现的是“短源性河流-多类型陆架-重力流快速沉积”的环带状沉积分异模式。本文的结果对研究中国海域沉积物的宏观分布规律提供了基础资料，对理解海洋沉积动力过程具有重要意义，同时沉积物粒度的特征对海底砂矿分布也具有指示意义。 相似文献
15.
Sediment cores from Sagamore Lake and Woods Lake in New York State's Adirondack Park, an area remote from industrial activities, were analyzed for polynuclear aromatic hydrocarbons (PAH) by high resolution gas chromatography/mass spectrometry (GC/MS). Their composition and distribution with depth in the sediment indicate that the parental PAH in the surface sediments are primarily produced by anthropogenic combustion of fossil fuels. Perylene in deep sediments is apparently transformed from natural precursors in the reducing environment, however, the exact precursors remain unknown. The rather even sediment distributions of the non-parental PAH differ from the parental, suggesting biogenic origins. Based on their chemical structures, retene and alkylated and partially hydrogenated phenanthrenes are believed to be biogenically converted from abietic acid; hydrochrysenes and hydropicenes, from pentacyclic triterpenes. 相似文献
16.
Core and surface sediments from the Tonalli River, a tributary of the artificial lake, Lake Burragorang, in the Blue Mountains National Park, New South Wales, Australia, were studied to evaluate the spatio-temporal distribution of pollutants from the Yerranderie silver-lead-zinc mine site, abandoned in the late 1920s. A sediment core was collected in the mouth of the Tonalli River, at its junction with Lake Burragorang, and surface sediment samples were collected in the Tonalli River and its tributaries. The concentrations of Pb, As, Zn, Cu, Cd, Hg and Ag in the sediments were determined by ICP-MS and ICP-AES techniques. Temporal variability of metal concentrations was established through 210Pb dating of the core sediments and compared with published historical records, rainfall records and bushfire data. Metal concentrations in core sediments showed an overall increase around the year 1950 as well as increases coincident with heavy rainfall. Spatially, metal concentrations were up to 400 times the guideline limit around mine sites but decreased rapidly with distance downstream of the mines. 相似文献
17.
The Xiangxi River is the first middling tributary of the Changjiang River near the Three Gorges Dam. The River is subject
to phosphorus pollution mainly from industrial wastewater. As the water quality of the Xiangxi River could directly influence
the water quality of the Three Gorges Reservoir, the research on phosphorus levels and its change in the sediment profile
of the Xiangxi River could provide useful information in the dynamic changes in the system, thereby offering options for mitigative
measures. Water and sediment samples from lower reaches of Xiangxi River were collected and the different forms of phosphorus
in sediments of the Xiangxi River were studied. The concentrations of total phosphorus in sediment ranged from 757.67 to 1438.54 mg/kg.
Inorganic phosphorus concentrations ranged from 684.63 to 1055.58 mg/kg. Phosphorus contamination was serious in some parts
of the Xiangxi River. With an average concentration of 635.17 mg/kg, calcium-bound phosphorus is the main form among different
inorganic phosphorus forms. Labile phosphorus and iron/aluminum-bound phosphorus measured 3.40, 0.05and 35.28 mg/kg, respectively.
The mobilization potential of phosphorus of sediments was studied through adsorption and release experiments. The equilibrium
concentration of phosphorus adsorption and release was around 0.1 mg/L. The initial concentrations of phosphorus in the overlying
water and the sediments have obvious effect on phosphorus mobilization potential. In addition, the release rate of phosphorus
in sediment increased with water depth. 相似文献
18.
Lake Houston is a man-made reservoir located northeast of Houston, Texas. The purpose of this investigation was to document
suspended sediment transport, sedimentation, and resuspension in the lake with a view towards estimating the influence of
sedimentation on water quality. Sediment traps were placed in strategic locations in the lake to collect suspended sediments.
Samples were analyzed for bulk density, grain size, organic carbon, and a number of trace elements. These data were analyzed
along with meteorological data to examine those factors which regulate suspended sediment input and dispersal, and the role
of suspended sediments in controlling water quality within the lake.
Sediment input to the lake depends primarily on the intensity of rainfall in the watershed. Sediment movement within the lake
is strongly influenced by wave activity, which resuspends sediments from shallow areas, and by wind-driven circulation. The
increased residence time of suspended sediments due to resuspension allows greater decomposition of organic matter and the
release of several trace elements from sediments to the water column.
Virtually all samples from sediment traps suspended between 1 and 5 m above the lake bottom contain medium to coarse silt,
and even some very fine sand-sized material. This implies that circulation in Lake Houston is periodically intense enough
to transport this size material in suspension. During winter, northerly winds with sustained velocities of greater than 5
m/sec provide the most suitable condition for rapid (<1 d) transport of suspended sediment down the length of the lake.
Fluctuations in current velocities and the subsequent suspension/deposition of particles may explain variations in the abundance
of coliform bacteria in Lake Houston. 相似文献
19.
20.
渤海东部晚更新世以来的沉积物地球化学特征 总被引：1，自引：0，他引：1
为探讨渤海东部晚更新世以来的元素地球化学特征及控制因素,对渤海东部DLC70-1孔157个沉积物样品进行了化学成分、粒度及测年分析。结果表明,晚更新世以来研究区沉积物的物质来源与沉积环境较为稳定;根据DLC70-1孔沉积物地球化学特征,钻孔岩芯可划分为6层,反映了末次间冰期（暖期）晚期以来渤海东部沉积物物源的变化以及海面波动。Al2O3、MgO、TFe2O3、MnO、TiO2、Cu、Zn、Pb、Cr和Rb等元素与细粒沉积物呈正相关,SiO2、Na2O与粗粒沉积物呈正相关,K2O、Sr和Ba分布与沉积物粒度无明显正或负的相关性;R-型因子分析得出三种主要组合类型,以Mg、Sr和Ba为代表,分别对应陆源细粒物质输入与黄河物质、海河物质和滦河物质的影响。运用Ba/Al2O3与Sr/Al2O3、MgO/Al2O3与K2O/Al2O3离散图分析了DLC70-1孔的物质来源,结果表明沉积物主要来源于黄河,该孔中上部32.30~49.00 m和9.30~23.20 m沉积物受到了滦河和海河物质的影响。 相似文献