Early solar system aqueous activity: K isotope evidence from Allende     

Yun Jiang  Piers Koefoed  Olga Pravdivtseva  Heng Chen  Chun‐Hui Li  Fang Huang  Li‐Ping Qin  Jia Liu  Kun Wang 《Meteoritics & planetary science》2021,56(1):61-76

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.  相似文献   

含裂隙介质中的视电阻率各向异性变化   总被引：1，自引：0，他引：1       下载免费PDF全文

解滔  卢军 《地球物理学报》2020,63(4):1675-1694

我国50多年的视电阻率连续观测结果表明,大地震前近震中区域的视电阻率呈现出与主压应力方位有关的各向异性变化,即:垂直于主压应力方向观测的变化幅度最大,平行方向最小或不明显,斜交方向介于二者之间.目前我国定点台站视电阻率观测的探测范围主要在浅层沉积层以内,通常含有较多的含水裂隙.本文将地下岩土介质简化为由固体基质和含流体/气体裂隙组成的固液气三相介质,且基质、流体和气体具有标量形式的电阻率,推导出了包含基质和流体电阻率、裂隙率、饱和度和裂隙面积率因子的电阻率张量表达式.以裂隙的扩展/闭合表示应力作用下裂隙的变化,得到了电阻率随裂隙变化的微分形式,电阻率变化对裂隙体积变化放大系数的表达式和裂隙横向变化对纵向电阻率影响的横向权系数的表达式.在此基础上得到了介质电阻率和视电阻率的各向异性变化特征:对于含水裂隙介质,无论裂隙如何变化,均是最小主轴方向电阻率的变化幅度大于其他方向;对于含水孔隙介质,沿孔隙主要变化方向的主轴电阻率变化幅度大于其他方向.对于各向异性变化,视电阻率和介质电阻率存在π/2的方向差异.相较于含水岩石,无水岩石介质电阻率的各向异性变化不显著.本文提出的电阻率表达式可以对实验室和野外实际观测的许多结果做出合理的解释.  相似文献   

基于LocaSpaceViewer的地理信息技术应用教学设计与反思     

陶佳  李青 《地理教学》2020,(2):53-55

本文基于笔者运用LocaSpaceViewer软件完成人教版地理必修3“地理信息技术在区域地理环境研究中的应用”的教学内容,总结反思教学过程中出现的问题,并提出改进的建议和措施。  相似文献   

干旱区地表温度和热岛效应演变研究——以宁夏沿黄城市带为例          下载免费PDF全文

孙灏  马立茹  蔡创创  黄涛  吕林涛  阮琳  陈伟 《干旱区地理》2020,43(3):694-705

宁夏沿黄城市带位于宁夏东北部，不仅是干旱地区地理研究的重点区域，也是宁夏经济发展的核心区域。基于2000—2018年的MODIS地表温度、土地覆盖类型以及植被覆盖率数据，通过计算热岛比例指数 (URI)，利用Mann-Kendall非参数检验及Sen’s斜率估计法，对宁夏沿黄城市带近20 a白天和夜间的地表温度（LST）和热岛效应时间变化进行分析。结果表明：（1） 近20 a来，宁夏沿黄城市带大部分地区[WTBX]LST变化不显著，但在植被覆盖率增加区域，白天LST显著减小而夜间LST显著上升；植被覆盖率减小区域与之相反；夜间LST[WTBZ]变化幅度强于白天。（2） 宁夏沿黄城市带的热岛效应通常在白天较弱、在夜间较强；白天和夜间时刻的城市热岛效应在一年内呈现不同的季节变化特点,白天春冬较强，夜间夏季较强；过去近20 a，宁夏沿黄城市带白天热岛效应呈现稍微减弱趋势，夜间热岛效应呈现稍微增强趋势，但变化趋势均不显著。（3） 从植被覆盖率和地物类型两个影响因素的研究表明，植被覆盖率是影响地表温度变化的重要因素，城建区与郊区主要地物温差的改变是城市热岛强度变化的重要原因。从长时间序列变化的角度详细分析干旱区城市热岛的特征和变化原因，可为干旱区城市热岛带来的环境问题治理提供参考，也为研究干旱区热岛提供了借鉴。  相似文献   

游客-环境互动视角下旅游者目的地环境恢复性效应     

朱芳  苏勤  陶云  沈惊宏 《热带地理》2020,40(4):636-648

日常生活环境和旅游目的地环境都可以为个体提供恢复的机会，不同环境的属性特征导致不同程度的恢复。为了探究环境类型与恢复性效应之间的关系及停留时间的调节作用，文章采用问卷调查方式，利用配对样本t检验和混合设计方差分析相结合的方法，探讨游客在不同环境中的恢复性效应，并对这一现象提供心理上的解释。结果表明：1）恢复体验的4个维度（放松体验、心理脱离、掌握体验、控制体验）在旅游目的地环境中的得分均高于日常生活环境。2）掌握和控制体验维度在城市旅游目的地中的变化程度高于乡村旅游目的地，两种类型目的地的放松和心理脱离维度差异较小。3）随着在目的地停留时间的延长，乡村旅游目的地放松体验和心理脱离维度变化程度高于城市旅游目的地，两种类型目的地环境恢复性效应会相互靠近。因此，游客的环境恢复性效应不仅受到环境和目的地类型的影响，同时还与游客的适应程度有关，且受到其停留时间的调节作用。  相似文献   

Salinivibrio sp.YH4胞外丝氨酸蛋白酶EYHS耐盐性及生物信息学分析          下载免费PDF全文

武翠玲  宋英达  高慧芳  张廉芸  任晨霞 《盐湖研究》2020,28(1)

摘要：目的 探讨菌株Salinivibrio sp.YH4分泌的丝氨酸蛋白酶EYHS的耐盐性及结构特征。方法 明胶底物酶谱法分析EYHS的耐盐性。应用生物信息学手段对EYHS及6种耐盐的S8家族丝氨酸蛋白酶结构特征进行分析。结果 EYHS在4 mol/L的NaCl溶液中仍具有活性，属于耐盐蛋白酶。EYHS及6种S8家族丝氨酸蛋白酶分子表面的loop区等无规则卷曲所占比例较高，α-螺旋与β-片层则主要位于酶分子内部。EYHS分子表面酸性氨基酸含量较高，且具有弱疏水内核。多序列比对发现蛋白酶的催化三联体两侧存在高度保守的基序和保守的极性氨基酸及芳香族氨基酸，并存在多个保守的Gly与Ala。同源模建和表面电荷分布显示，α螺旋和β片层围成了蛋白酶的催化腔，EYHS活性中心包含由Asp32、His65与Ser215组成的催化三联体，且催化位点区域表面静电势为负。结论 上述结构特征可能有助于耐盐丝氨酸蛋白酶EYHS在高盐环境下维持其稳定性和适度柔性，并有助于其催化功能的发挥，为深入研究耐盐丝氨酸蛋白酶的高盐环境适应性提供了一定的理论依据。  相似文献   

Correspondence between the large volcanic eruptions and ENSO events over AD 1525–2000     

Fang  Xiuqi  Zheng  Xue  Zhang  Xing 《地理学报(英文版)》2020,30(1):103-118

ENSO is an interannual mode which may be affected by external forcing, such as volcanic eruptions. Based on the reconstructed volcanic eruptions chronology and ENSO sequences, both 195 large volcanic eruptions(VEI≥4) and 398 ENSO(El Ni?o and La Ni?a) events were extracted from 1525 to 2000. An analysis of the correspondence between the large volcanic eruptions and ENSO events was performed by matching the large volcanic eruptions with the types and magnitudes of ENSO events present in the 0–2 years after the eruptions. The results show the following:(1) The percentages of ENSO events within the 3 years after the large eruptions had increased to 68.3% from 31.7% compared with those with no-eruptions in the previous 0–2 years. In addition, the ratio of El Ni?o to La Ni?a events turned from 2:3 to 1:1, and more El Ni?o events occurred in the 0 year after eruptions in the low-latitudes of the Northern Hemisphere and in the tropics but more La Ni?a events occurred in the 0 year after in the high-latitudes of the Northern Hemisphere and the Southern Hemisphere.(2) After the eruptions, the weak(W) El Ni?o events had increased by 8 percentage points and the very strong(VS) El Ni?o events had decreased by 10 percentage points; conversely, there was a decrease by 15 percentage points of the weak La Ni?a events and an increase by 11.4 percentage points of the very strong La Ni?a events. Specifically, the percentages of strong La Ni?a events increased to a peak at 1(+1) year after the eruptions.(3) The percentage of eruptions followed by single-year ENSO was the greatest. The percentage of ENSO events that occurred in the consecutive 2 years following an eruption was approximately equal to the percentage of events that occurred consecutively 3 years following an eruption, and both sets of ENSO magnitudes showed a decreasing trend.  相似文献   

地理大数据挖掘——目标、内涵与研究问题     

裴韬  宋辞  郭思慧  舒华  刘亚溪  杜云艳  马廷  周成虎 《地理学报(英文版)》2020,30(2):251-266

  相似文献   

城镇化与生态环境耦合的动态模拟——研究进展与展望     

崔学刚  方创琳  刘海猛  刘晓菲  李咏红 《地理学报(英文版)》2020,30(2):333-352

Urbanization and eco-environment coupling is a research hotspot.Dynamic simulation of urbanization and eco-environment coupling needs to be improved because the processes of coupling are complex and statistical methods are limited.Systems science and cross-scale coupling allow us to define the coupled urbanization and eco-environment system as an open complex giant system with multiple feedback loops.We review the current state of dynamic simulation of urbanization and eco-environment coupling and find that:(1)The use of dynamic simulation is an increasing trend,the relevant theory is being developed,and modeling processes are being improved;(2)Dynamic simulation technology has become diversified,refined,intelligent and integrated;(3)Simulation is mainly performed for three aspects of the coupling,multiple regions and multiple elements,local coupling and telecoupling,and regional synergy.However,we also found some shortcomings:(1)Basic theories are inadequately developed and insufficiently integrated;(2)The methods of unifying systems and sharing data are behind the times;(3)Coupling relations and the dynamic characteristics of the main driving elements are not fully understood or completely identified.Additionally,simulation of telecoupling does not quantify parameters and is not systemically unified,and therefore cannot be used to represent spatial synergy.In the future,we must promote communication between research networks,technology integration and data sharing to identify the processes governing change in coupled relations and in the main driving elements in urban agglomerations.Finally,we must build decision support systems to plan and ensure regional sustainable urbanization.  相似文献   

Acoustic reflection well logging modeling using the frequency-domain finite-element method with a hybrid PML     

Bing Wang  Zhang Kuo  Tao Guo  Liu He  Xiao-Liang Zhang 《应用地球物理》2018,15(1):35-45

In this paper, we propose a hybrid PML (H-PML) combining the normal absorption factor of convolutional PML (C-PML) with tangential absorption factor of Mutiaxial PML (M-PML). The H-PML boundary conditions can better suppress the numerical instability in some extreme models. and the computational speed of finite-element method and the dynamic range are greatly increased using this HPML. We use the finiteelement method with a hybrid PML to model the acoustic reflection of the interface when wireline and well logging while drilling (LWD), in a formation with a reflector outside the borehole. The simulation results suggests that the PS- and SP- reflected waves arrive at the same time when the inclination between the well and the outer interface is zero, and the difference in arrival times increases with increasing dip angle. When there are fractures outside the well, the reflection signal is clearer in the subsequent reflection waves and may be used to identify the fractured zone. The difference between the dominant wavelength and the model scale shows that LWD reflection logging data are of higher resolution and quality than wireline acoustic reflection logging.  相似文献