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1.
对乌奴耳地区花岗闪长岩进行的LA-ICP-MS锆石U-Pb测年和岩石地球化学测试结果表明:花岗闪长岩的锆石U-Pb加权平均年龄为332.6±6.9Ma(MSWD=3.1),时代为早石炭世. 岩石地球化学数据显示,花岗闪长岩属准铝质低钾(拉斑)系列.花岗闪长岩总体富集大离子亲石元素,亏损高场强元素. Th、U表现,为明显正异常,Nb、Ta、Zr、Ti表现明显负异常,La、Hf、Lu等富集,δEu值为0.61~0.69,具有负铕异常,与I型花岗岩相似,具有火山弧花岗岩的特征,表明该侵入岩的形成与俯冲作用有关. 综合区域地质特征及本研究认为,花岗闪长岩为早石炭世古亚洲洋俯冲时的产物,可为古亚洲洋及东北地块构造演化研究提供新的约束和佐证实例. 相似文献
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《世界地质》2021,(1)
对跃进山铜金矿床与矽卡岩型矿化有关的花岗闪长岩开展了LA-ICP-MS锆石U-Pb定年、锆石Lu-Hf同位素及岩石地球化学研究。结果表明,花岗闪长岩中26个锆石测点的~(206)Pb/~(238)U加权平均年龄为(118.96±0.77) Ma (MSWD=0.29);岩体中锆石的ε_(Hf)(t)值均为正值(+1.4～+3.2),且具有较年轻的Hf二阶段模式年龄(t_(DM2)=1.09～0.98 Ga);花岗闪长岩表现为富Al、高K和Na以及低Ti、P、Ca的钙碱性I型花岗岩地球化学特征,显示出轻稀土富集、重稀土元素亏损的稀土元素组成特征;样品锆石的ε_(Hf)(t)的值为偏低的正值,表明岩浆物质来源应为壳幔混源。结合岩石地球化学投图以及区域构造背景演化认为,花岗闪长岩和花岗斑岩均属于后碰撞-火山弧花岗岩,研究区的成矿成岩作用与太平洋板块强烈俯冲背景下的下岩石圈地幔拆沉有直接关系。 相似文献
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哈西亚图铁多金属矿位于东昆仑构造带,是区域较为典型的一处矽卡岩型矿床.文章对矿区花岗闪长岩开展了LA-ICP-MS锆石U-Pb同位素测定与岩石地球化学研究,结果表明花岗闪长岩中锆石的年龄为(240.1±0.8)Ma(MSWD=0.62),形成于中三叠世,岩石为准铝高钾钙碱性系列,轻稀土富集,轻重稀土分馏明显,具弱的负铕异常,富集大离子亲石元素(Rb、K等),同时表现出“TNT”(Ta、Nb、Ti)负异常等俯冲带幔源岩石的成分特点.依据岩石学、地球化学特征并结合同时期大地构造背景认为:花岗闪长岩产于中生代岩浆弧环境,区域同时期花岗闪长岩与石英闪长岩有着相同的物质来源与产出背景.在其他具有矽卡岩型矿化潜力的区域,今后找矿工作中应注重花岗闪长岩的成矿作用. 相似文献
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《西北地质》2019,(4)
笔者研究了北祁连中段毛藏寺花岗闪长岩体的岩石学、年代学和地球化学特征。毛藏寺岩体主要岩石类型为花岗闪长岩,锆石SHRIMP U-Pb测年获得花岗闪长岩结晶年龄为(456±3)Ma。花岗闪长岩的SiO_2含量较高,介于65.1%～73.0%,较低的Mg#值(18～32),K_2O/Na_2O介于0.82～1.37,A/NKC=0.9～1.1,总体为高钾钙碱性准铝质花岗岩;岩石微量元素组成具富集LILE元素,亏损HFSE元素,轻重稀土分异明显[(La/Yb)N=11.1～34.1],具弱负Eu异常。综合地球化学特征和区域构造演化表明,花岗闪长岩岩浆源区为下地壳变玄武岩石,形成于同碰撞构造背景。 相似文献
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对南祁连地区日托卡一带花岗闪长岩进行锆石U-Pb定年及全岩分析以确定其形成时代及构造环境.定年结果表明,花岗闪长岩形成于(458±1)Ma,为晚奥陶世.全岩分析,岩石具有偏铝(w(Al2O3)为13.14％～13.79％)和中碱(w(K2O+Na2O)为6.84％～6.93％)特征,属偏铝质钙碱性系列;稀土总量为(397.29～479.89)×10-6,为富集型,L/H值为10.87～12.66,轻稀土富集,重稀土亏损;微量元素Rb、Nb、Sr亏损,Th、Ce富集,表明该岩体的岩浆经历了较强的分异演化.综合花岗闪长岩地质及主微量元素特征,认为花岗闪长岩形成构造环境为由挤压向拉伸转换阶段,属同造山花岗岩. 相似文献
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柴北缘牛鼻子梁地区的花岗闪长岩锆石U-Pb年代学及岩石地球化学研究结果表明,该花岗闪长岩的锆石LA-ICP-MS U-Pb谐和年龄为393.2~395.6Ma,对应的加权平均年龄为(394.4±2.4)Ma,表明该岩石形成于中泥盆世。岩石主量元素具有较高的SiO_2(65.70%~69.22%)和Al_2O_3(14.96%~16.03%)、较低的MgO(1.37%~1.89%)含量,A/CNK值为0.95~0.98,属于钙碱性、准铝质系列,具有I型花岗岩的特征,表明其岩浆起源于下地壳部分熔融。岩石稀土总量较高,无明显的Eu异常(δEu=0.95~1.30),富集轻稀土元素和K、Rb、Ba、U等大离子亲石元素,相对亏损重稀土元素和Nb、Ta、Ti、Th、Zr等高场强元素。综上可知,岩石具有碰撞后花岗岩的地球化学特征属性,结合区内晚泥盆世牦牛山组陆相火山岩和区域构造演化特征,认为牛鼻子梁地区的花岗闪长岩形成于柴达木地块与南祁连地块碰撞后的伸展环境。 相似文献
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西藏仲巴县天宫尼勒矽卡岩型铜金矿床锆石U-Pb年代学和岩石地球化学特征: 对成因及其成矿构造背景的指示 总被引：2，自引：0，他引：2
天宫尼勒铜金矿床位于冈底斯成矿带北部,是与花岗闪长岩关系密切的矽卡岩型矿床。花岗闪长岩锆石ICP-MSU-Pb年龄加权平均值为102.6±1.8Ma,指示该矿床形成于早白垩世。元素地球化学数据表明,花岗闪长岩具有高Al2O3,富Na2O,低TiO2等特点,属于准铝质、钙碱性岩石系列,微量元素富集大离子亲石元素(LILE),亏损高场强元素(HFSE)和重稀土元素,显示Nb和Ta的负异常,具有明显的岛弧型岩石的地球化学特征,岩石成因可能与班公湖-怒江洋壳板片俯冲所诱发的岩浆活动有关。结合区域构造演化,天宫尼勒铜金矿床形成于班公湖-怒江洋向南(即冈底斯地块)俯冲碰撞闭合之前的岛弧环境。 相似文献
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跃进山小型矽卡岩型铜金矿床位于完达山地体西南部,矿体主要赋存于矽卡岩、花岗斑岩及其构造裂隙中,呈扁豆状或脉状。本文对矿区花岗闪长岩和花岗斑岩进行锆石U-Pb年代学和岩石地球化学研究,以了解矿床形成时代、成岩（矿）构造背景及矿床成因。测年结果表明,花岗斑岩和花岗闪长岩成岩年龄分别为（115.8±1.0）Ma和（126.9±1.7）Ma,铜金矿化时代与花岗斑岩成岩时代基本一致,为早白垩世晚期。岩石地球化学研究表明,花岗闪长岩属过铝质钙碱性系列岩石,稀土配分模式图为轻稀土富集,重稀土亏损,具较强的铕负异常,无铈异常,岩浆主要来源于壳源物质;花岗斑岩属过铝质钙碱性系列岩石,轻稀土富集,重稀土亏损,具弱铕负异常,无铈异常,相对富集大离子亲石元素（Rb、Ba、K、Sr）和不相容元素（U、Th）,亏损高场强元素（Ta、Nb、P、Ti）和HREE,岩浆来源于壳幔物质混合源区,形成于碰撞后构造环境,成岩成矿作用与太平洋板块强烈俯冲作用后的伸展体制密切相关。 相似文献
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北祁连西段小柳沟矿区花岗质岩石锆石U-Pb年代学、地球化学及成因研究 总被引：8，自引：2，他引：6
甘肃小柳沟钨钼(铜)矿是一个与花岗岩类有关的斑岩-矽卡岩-石英脉型矿床,小柳沟矿区内花岗质岩石类型主要为二长花岗岩和花岗闪长岩。本文对该岩体进行年代学、地球化学研究以约束其形成时代和岩石成因。LA-ICP-MS锆石UPb测年分别获得二长花岗岩与花岗闪长岩谐和年龄为454.0±2.0Ma和417.7±1.7Ma,属于加里东期岩浆活动的产物,并经历了海西期和燕山期岩浆热事件的改造。地球化学数据显示,小柳沟花岗质岩石具有高硅、富碱的特征,属于过铝质高钾钙碱性系列,富集Rb、Th、U、K、Pb,亏损Ba、Sr、Ti、P,具有明显Eu负异常,尤其是二长花岗岩显示强烈的铕负异常(δEu为0.08～0.19),属于高分异I型花岗岩。锆石Hf同位素分析结果显示,二长花岗岩εHf(t)为-4.45～4.04,t DM2=1176～1714Ma,花岗闪长岩εHf(t)为-4.18～4.43,t DM2=1124～1670Ma,二者可能是由壳幔混合作用形成,其壳源源区很可能来源于古元古代-中元古代古老地壳岩石,花岗闪长岩的源区相对较深,北大河岩群与朱龙关群可能是小柳沟钨矿的初始矿源层。综合研究表明,小柳沟钨钼矿床与二长花岗岩在时间、空间及成因上有密切关系。结合区域构造演化,认为小柳沟二长花岗岩应形成于俯冲背景下的活动大陆边缘环境,花岗闪长岩形成于碰撞造山环境。 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
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Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献
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Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA 总被引：1，自引：0，他引：1
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources. 相似文献
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滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床. 相似文献
20.
岩石密度和超高压岩石折返速率 总被引：1，自引：3，他引：1
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。 相似文献