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1.
粤北帽峰花岗岩体地球化学特征及成因研究   总被引：26，自引：5，他引：26  
帽峰花岗岩体是粤北贵东复式花岗岩体中一个重要的产铀岩体。单颗粒锆石U-Pb定年结果为219．6±0．9Ma, 属于印支期岩浆活动产物。该岩体的主要元素显示富硅、富碱、强过铝质和低CaO／Na2O比值等特征。微量元素富集Rb,Th, U,Ce,Sm和Y而亏损Ba,Sr,P和Ti;LREE轻微富集(LREE／HREE=1．70-9．63,(La／Yb)N=0．41-6．25),Eu亏损明显(δEu=0．02-0．22);具有低的εNd(t)值(-12．3--10．8),变化的δ18O(4．1-11．3‰)、(87Sr／86Sr)i(0．71049- 0．73359)、206Pb／204Pb(18．345-22．019)和207Pb／204Pb(15．646-15．863)以及古老的Nd模式年龄(1879-1996Ma)。以上特征表明,帽峰岩体属于典型的壳源型花岗岩,是在地壳伸展-减薄的构造背景下,通过古元古代成分不均一的泥质变质岩低程度部分熔融的方式形成。  相似文献   

2.
湘东北位于扬子板块东南缘江南造山带中段,出露的新元古代花岗岩有长三背、大围山和葛藤岭等岩体,同属于九岭岩体的一部分。湘东北新元古代花岗岩SiO2含量变化于60%~72%、CaO为0.6%~3%、Na2O为1.98%~3.72%、K2O为2.95%~4.99%之间,A/CNK>1.1,富集K、Rb、Ba等大离子亲石元素(LILE)和轻稀土元素(LREE/HREE=3.1~10.5)、Eu负异常明显(δEu=0.37~0.58),而Nb、Ta、Ti等高场强元素(HFSE)相对亏损。这些特征表明湘东北新元古代花岗岩来源于过铝质熔体,岩石类型上类似于富黑云母过铝花岗岩类(CPG),可能来源于富黑云母的变泥质沉积岩的熔融,如中元古代冷家溪群变质沉积岩等,形成于同碰撞环境,可能与陆壳加厚导致的剪切重熔有关。  相似文献   

3.
对张家岩体乍古田矿床及张家矿床的2件赋矿围岩样品,开展LA-ICP-MS锆石U-Pb同位素定年,获得乍古田矿床赋矿围岩形成年龄为218.0±1.4Ma,张家矿床赋矿围岩形成年龄为226.8±5.7Ma。另外,对张家岩体8件样品的主量、微量元素及Sr-Nd同位素分析测试显示,张家花岗岩富硅(Si O2=74.35%~76.29%)、高铝(Al2O3=12.54%~14.03%)、高碱(Na2O+K2O=6.95%~9.17%)、低镁(Mg O=0.34%~0.45%)、低钙(Ca O=0.68%~1.03%)、低钛(Ti O2=0.106%~0.18%),属高钾钙碱性花岗岩;富集Rb,亏损Ba、Sr,Rb/Sr值高,属于低Ba-Sr花岗岩;轻稀土元素富集,负Eu异常;富U(平均21.5×10-6),Th/U值低(平均1.63),有利于铀矿化;(87Sr/86Sr)i高(约0.7247),低εNd(t)值(平均-13.95),二阶段Nd模式年龄为2.07~2.19Ga。张家花岗岩属于强过铝质S型花岗岩,可能是华夏板块古元古代基底变泥质岩经部分熔融形成的。  相似文献   

4.
华南地区印支期花岗岩按照成因类型可分两类,第一类属强过铝质S型花岗岩,富含过铝质矿物,富SiO2、Al2O3和P2O5,高A/CNK值,微量元素原始地幔标准化分布型式图中富集Rb、U、Ta、Zr、Hf,亏损Ba、Sr、Nb、Ti;稀土元素球粒陨石标准化分布型式图中具显著的负Eu异常,稀土元素总量偏低(ΣREE<80×10-6);第二类属准铝质I型花岗岩,含角闪石等镁铁质矿物,富SiO2、Na2O。总体来说,这两类花岗岩具有高的(87Sr/86Sr)i值(0.710490～0.742118)和低εNd(t)值(-14.42～-4.1),Nd模式年龄(2.09～1.63Ga)指示印支期花岗岩为典型的壳源型花岗岩。CaO/(MgO+FeOT)-Al2O3/(MgO+FeOT)(摩尔比)图解表明这些花岗岩主要来源于变质杂砂岩和变质泥岩的部分熔融,夹杂了少量变质玄武岩和变质英云闪长岩。华南印支期花岗岩形成于挤压加厚的地壳发生局部伸展-减薄时期,推断印支期发生了多期次的岩石圈挤压和拉张,花岗岩侵位于大规模岩石圈挤压后局部减压-伸展的构造环境中。  相似文献   

5.
粤北笋洞花岗岩的形成时代、地球化学特征与成因   总被引：25，自引：10，他引：25  
笋洞花岗岩体是粤北贵东复式花岗岩体的一个重要组成部分。锆石U-Pb年龄为189.1±0.7Ma,是燕山早期岩浆活动产物。该岩体的主要元素显示富硅、富碱、强过铝质和低 CaO/Na_2O比值等特征;微量元素方面,富集Rb,Th,U,Ce,Sm,Y,亏损 Ba,Sr,P,Ti;LREE轻微富集(LREE/HREE=6.6～8.8,(La/Yb)_N=6.44～10.74),Eu亏损明显(δEu=0.14～0.31);它具有低的ε_(Nd)(t)(-11.4～-9.3),高的δ~(18)O(10.2～12.7‰)、(~(87)Sr/~(86)Sr);(0.72949～0.74923)、~(206)Pb/~(204)Pb(18.180～18.488)、~(207)Pb/~(204)Pb(15.655～15.661)和古老的Nd模式年龄(1762～1933Ma)。上述这些特征表明,笋洞岩体属于典型的壳源型花岗岩,是在地壳伸展-减薄的构造背景下,通过以泥质成分为主的古-中元古代变质沉积岩部分熔融的方式形成。  相似文献   

6.
马拉山花岗岩位于特提斯喜马拉雅的西部,其主要矿物组成为石英、钾长石、白云母和黑云母。锆石LA-MC-ICP-MS U-Pb定年表明,花岗岩的发育记录了(28.0±0.5)Ma和(18.4±0.3)Ma两期深熔作用,(18.4±0.3)Ma代表了最终的结晶时间。全岩地球化学分析结果显示,样品具有高的SiO_2(72.36%~72.51%)、Al_2O_3(15.22%~15.37%)和CaO(1.64%~1.66%)含量,高的K_2O/Na_2O值(0.97-1.05)和A/CNK值(1.15-1.20),显示高钾钙碱性过铝质的特征;岩石富集Rb、Th、U和K,亏损Ba、Nb、Sr和Zr、Eu负异常不明显(δEu=0.80~0.89),轻重稀土分馏较强[(La/Yb)_N=7.09~19.68]。马拉山花岗岩具有较低的Rb/Sr值(0.90-1.10)和较高的CaO/Na_2O值(0.44~0.46),指示岩浆源区物质成分可能以页岩为主;样品(~(87)Sr/~(86)Sr)_i和ε_(Nd)(t)分别为0.742 522~0.744 097和-14.5~-13.7,与大喜马拉雅结晶杂岩中变质沉积岩成分一致,表明其来自变质沉积岩的部分熔融。岩石具有较低的(~(87)Sr/~(86)Sr);和较高的Sr含量,且随着Ba含量的增加,Rb/Sr值基本不变,表明马拉山花岗岩是水致白云母部分熔融的产物,部分熔融可能与南北向裂谷的东西向伸展关系密切。  相似文献   

7.
赣东南富城杂岩体的地球化学和年代学研究   总被引：7，自引：11，他引：7  
富城杂岩体出露于赣东南,与闽西南的红山岩体共同构成富城-红山花岗质杂岩。富城杂岩主要由富城黑云母巨斑粗粒二长花岗岩、粗石坝中粒二云母花岗岩和珠长洞含红柱石细粒花岗岩三个单元组成。富城花岗岩含较低的 SiO_2、Rb、Nb 和较高的 Al_2O_3、Ba、Sr、Zr、REE 含量,岩石的 ACNK>1.10,K_2O/Na_2O>1.60。粗石坝花岗岩以高 SiO_2、K_2O,低 CaO、P_2O_5和富 Al(ACNK=1.13～1.20)为特征;岩石含较高的 Rb、Nb 和低的 Ba、Sr、Zr、REE 含量,并具有相对低的 K/Rb 和δ(Eu)比值。珠长洞含红柱石花岗岩的地球化学特征相似于富城花岗岩,除了更高的 ACNK 值(1.22～1.36)和 Rb、Nb 含量以及稍低的 Sr、Ba、Zr、REE 含量。富城单元的~(84)Sr/~(86)Sr 初始比值是0.7135～0.7196,ε_(Nd)(t)是-9.4～-10.2,Nd 模式年龄是1.78Ga 到1.84Ga,其中的锆石 Hf 模式年龄是1.70～1.89Ga,与 Nd 同位素一致;粗石坝单元具有与之相似的 Nd-Hf 同位素组成;珠长洞单元的~(87)Sr/~(86)Sr 初始比值更高(0.7214),ε_(Nd)(t)更低(-16.9),而 Nd 模式年龄达2.37Ga。这些地球化学特征表明富城杂岩体的源岩都是由古老物质组成的沉积岩,其中富城和粗石坝单元起源于具晚古元古代模式年龄的基底,而珠长洞单元的源区物质具有早古元古代平均地壳存留年龄。富城杂岩体的各单元之间没有显示一致的变化规律,表明它们不是单一岩浆演化的结果,它们成分的差异主要受源区成分影响。LA-ICPMS 的锆石 U-Pb 定年显示富城黑云母花岗岩形成较早(239±17Ma),而粗石坝和珠长洞花岗岩形成稍晚(231±16 Ma 和229±6.8 Ma)。它们的形成时代与华南印支期早期构造-岩浆活动的峰期一致。结合地球化学和岩石组合特征,可以认为富城-红山杂岩形成于同构造背景。  相似文献   

8.
腾冲地块梁河早始新世花岗岩成因机制及其地质意义   总被引：1，自引：0，他引：1  
腾冲地块梁河地区芒东和青木寨花岗岩是新特提斯洋演化过程中重要的壳源岩浆活动产物。岩石形成年龄为48~51Ma,属于早始新世,与腾冲地块西缘盈江地区大量的酸性和基性侵入岩的形成年龄相近。梁河地区的早始新世花岗岩具有高硅、钾的特征,属于准铝质-强过铝质高钾钙碱性S型花岗岩。这些花岗岩具有高的初始~(87)Sr/~(86)Sr比值和富集的Nd同位素组成,Nd模式年龄显示源岩应为中元古代的地壳岩石。同时,芒东花岗岩具有高的CaO/Na_2O和相对低的Al_2O_3/TiO_2、Rb/Sr和Rb/Ba比值,说明源区为变质杂砂岩。而青木寨花岗岩具有低的CaO/Na_2O和Al_2O_3/TiO_2、相对高的Rb/Sr和Rb/Ba比值,指示其源岩以变泥质岩为主。结合区域内中-新生代岩浆活动特征,我们认为芒东和青木寨花岗岩是印度-亚洲大陆东向初始碰撞或同碰撞时期挤压背景下,腾冲地块中下地壳成熟度较低的杂砂岩以及成熟度较高的泥岩在高温条件下部分熔融的产物。  相似文献   

9.
谢克家  曾令森  刘静  高利娥 《岩石学报》2010,26(4):1016-1026
打拉二云母花岗岩岩体位于雅拉香波穹隆的东南,侵入到中生代以前的变质岩系(眼球状花岗质片麻岩和石榴黑云母片麻岩)和特提斯沉积岩(页岩和砂岩)中,主要由石英、斜长石、钾长石、黑云母和白云母组成,形成于～44.3Ma。打拉二云母花岗岩地球化学特征表明:打拉花岗岩具有高Al_2O_3(16.0%～17.0%)、Na_2O/K_2O(1.2)以及A/CNK比值(1.05),表明打拉花岗岩为富钠过铝质花岗岩;轻稀土(LREE)富集,重稀土(HREE)相对亏损,HREE中的Ho到Lu元素有变平的特征((Ho/Lu)_N=1.11～1.46);具有微弱或无Eu异常,Eu/Eu~*=0.87～0.95;较高的初始Sr同位素比值(~(87)Sr/~(86)Sr(i)=0.71754～0.71785)和较低的初始Nd比值(ε_(Nd)(i)=-9.15～-12.4)。打拉花岗岩具有高Sr含量(为355×10~(-6)～416×10~(-6))和Sr/Y的比值(59.1～71.5)、高La/Yb比值、低Y及HREE亏损的特征,与埃达克质花岗岩类似。上述特征表明打拉花岗岩是在较高压力条件下,以角闪岩为主的深部岩石部分熔融的结果。  相似文献   

10.
闽西南古田-小陶花岗质杂岩体的形成时代和成因   总被引：8，自引：4，他引：8  
古田-小陶花岗质杂岩体是由小陶、古田、华家、蛟洋和姑田等单元组成。小陶、古田和华家单元为含黑云母二长花岗岩,蛟洋和姑田单元是含角闪石黑云母石英二长岩。小陶和古田花岗岩以高 SiO_2(>71.77%)、K_2O(>4.67%)和低 CaO(<1.71%)为特征,属于弱过铝-强过铝花岗岩;它们含高的 Rb、Nh、Ta、Th、U 和低的 Sr、Ba 含量;稀土(REE)含量和轻重稀土分异((La/Yb)_N)变化大,分别变化于143×10~(-6)～548×10~(-6),和3.3～26.5,Eu 亏损中等到强。姑田和蛟洋单元都以低SiO_2(62.88%～66.38%)和高 Al_2O_3(15.44%～16.51%)为特征。姑田单元的 REE 总量低而蛟洋单元的 REE 总量高,但两者的 Eu 负异常都不明显。华家单元花岗岩的地球化学特征介于上述两组花岗岩之间。LA-ICPMS 锆石 U-Pb 定年显示小陶花岗岩形成于222±3Ma,而古田花岗岩形成于161±1Ma。小陶、古田和姑田花岗岩具有相似的~(87)Sr/~(86)Sr 初始比值(0.7089～0.7099)和ε_(Nd)(t)值(-11.1～-11.5),而且古田和小陶花岗岩的锆石 Hf 同位素组成也相似,表明它们起源于相同的源区。地球化学和 Sr-Nd-Hf 同位素指示它们的源区物质是具有1.73～1.5Ga 平均地壳存留年龄的变质沉积岩。而位于杂岩体南部的华家花岗岩显示明显高的~(87)Sr/~(86)Sr 初始比值(0.7310)和更低的ε_(Nd)(t)值(-16.4),指示它的母岩浆起源于古元古代壳源物质,暗示杂岩体南北基底组成可能不同。古田花岗岩形成于燕山早期的板内伸展构造背景,而小陶花岗岩形成于印支晚期,地球化学特征以及同时代岩石组合以及构造应力场分析表明其最可能形成于后造山构造背景。  相似文献   

11.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations.  相似文献   

12.
Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km2 and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.  相似文献   

13.
This article advances critical geographies of youth through examining the spatiality implicit in the imagined futures of young women in rural India. Geographers and other scholars of youth have begun to pay more attention to the interplay between young people’s past, present, and imagined futures. Within this emerging body of scholarship the role of the family and peer group in influencing young people’s orientations toward the future remain underexamined. Drawing on eleven months of ethnographic fieldwork, my research focuses on a first generation of college-going young women from socioeconomically marginalized backgrounds in India’s westernmost state of Gujarat. I draw on the “possible selves” theoretical construct in order to deploy a flexible conceptual framework that links imagined post-educational trajectories with motivation to act in the present. In tracing the physical movement of these young women as they navigate and complete college, my analysis highlights the ways in which particular kinds of spaces and spatial arrangements facilitate and limit intra- and inter-generational contact, and the extent to which this affects young women’s conceptions of the future. I conclude by considering the wider implications of my research for ongoing debates surrounding youth transitions, relational geographies of age, and education in the Global South.  相似文献   

14.
The contents of As, Cd, Cu, Cr, Mg, Mn, Ni, Pb and Zn have been determined in sediment and water samples from Valle de las Garzas estuary and Port Manzanillo (Colima, Mexico) using ICP-AES. The concentrations of these elements were used for a comparative study to determine the distribution of heavy metals and to evaluate which elements reflect natural or anthropogenic backgrounds. For this purpose, seven sampling points were selected: Four of them correspond to the lagoon, and three were situated in the port. Statistical analysis of the mineral content was assessed. Initially, data comparison was assessed by statistical tests for each variable. Principal component analysis was then applied considering the influence of all variables at the same time by obtaining the distribution of samples according to their scores in the principal component space. In this way, four studies were carried out: (1) study of sediments collected during the dry season; (2) study of sediments collected during the rainy season; (3) comparative study between sediments from rainy and dry season; and (4) study of water composition collected during rainy season. From the results of the performed analyses, it can be concluded that metals distribution pattern reflected natural and anthropogenic backgrounds (e.g., sediments from the lagoon, situated at the beginning of the rain channel, presented high contents of Zn and Cu, perhaps related to anthropogenic activities or the influence of igneous sediments).  相似文献   

15.
Partition coefficients of Hf,Zr, and REE between zircon,apatite, and liquid   总被引：25，自引：2，他引：25  
Concentration ratios of Hf, Zr, and REE between zircon, apatite, and liquid were determined for three igneous compositions: two andesites and a diorite. The concentration ratios of these elements between zircon and corresponding liquid can approximate the partition coefficient. Although the concentration ratios between apatite and andesite groundmass can be considered as partition coefficients, those for the apatite in the diorite may deviate from the partition coefficients. The HREE partition coefficients between zircon and liquid are very large (100 for Er to 500 for Lu), and the Hf partition coefficient is even larger. The REE partition coefficients between apatite and liquid are convex upward, and large (D=10–100), whereas the Hf and Zr partition coefficients are less than 1. The large differences between partition coefficients of Lu and Hf for zircon-liquid and for apatite-liquid are confirmed. These partition coefficients are useful for petrogenetic models involving zircon and apatite.  相似文献   

16.
Emilio Biagini 《GeoJournal》1998,44(2):163-165
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17.
《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2.  相似文献   

18.
Materials and energy are the interdependent feedstocks of economic systems, and thermodynamics is their moderator. It costs energy to transform the dispersed minerals of Earth's crust into ordered materials and structures. And it costs materials to collect and focus the energy to perform work — be it from solar, fossil fuel, nuclear, or other sources. The greater the dispersal of minerals sought, the more energy is required to collect them into ordered states.But available energy can be used once only. And the ordered materials of industrial economies become disordered with time. They may be partially reordered and recycled, but only at further costs in energy. Available energy everywhere degrades to bound states and order to disorder — for though entropy may be juggled it always increases. Yet industry is utterly dependent on low entropy states of matter and energy, while decreasing grades of ore require ever higher inputs of energy to convert them to metals, with ever increasing growth both of entropy and environmental hazard.Except as we may prize a thing for its intrinsic qualities — beauty, leisure, love, or gold — low-entropy is the only thing of real value. It is worth whatever the market will bear, and it becomes more valuable as entropy increases. It would be foolish of suppliers to sell it more cheaply or in larger amounts than their own enjoyment of life requires, whatever form it may take. For this reason, and because of physical constraints on the availability of all low-entropy states, the recent energy crises is only the first of a sequence of crises to be expected in energy and materials as long as current trends continue.The apportioning of low-entropy states in a modern industrial society is achieved more or less according to the theory of competitive markets. But the rational powers of this theory suffer as the world grows increasingly polarized into rich, over-industrialized nations with diminishing resource bases and poor, supplier nations with little industry. The theory also discounts posterity, the more so as population density and percapita rates of consumption continue to grow. A new social, economic, and ecologic norm that leads to population control, conservation, and an apportionment of low-entropy states across the generations is needed to assure to posterity the options that properly belong to it as an important but voiceless constituency of the collectivity we call mankind.
Zusammenfassung Rohstoffe und Energie sind die Grundlagen unseres ökonomischen Systems, das von den Gesetzen der Thermodynamik bestimmt wird. Es kostet Energie, um die auf der Erde verteilten Rohstoffe diesem System zuzuführen. Andererseits braucht man Rohstoffe, um die Energie nutzbar zu machen.Die verfügbare Energie kann nur einmal genutzt werden und das Material verbraucht sich. Verbrauchtes Material kann teilweise zur weiteren Nutzung zurückgeführt werden, das kostet wiederum Energie. Die verfügbare Energie nimmt überall ab, und einmal geschaffene Ordnung gerät wieder in Unordnung — das heißt, die Entropie des Systems nimmt ständig zu. Die Industrie ist jedoch abhängig von einem niedrigen Entropiezustand sowohl der Materie als auch der Energie.Je ärmer die Erze sind, um so höher wird die Energie sein, um sie in Metalle umzuwandeln, wobei die Entropie und die Belastung der Umwelt ständig zunimmt.Außer den Dingen, die wir wegen höherer ideeller Werte schätzen, ist eine niedrige Entropie der einzige realistische Wertmaßstab, und der wirkliche Wertzuwachs ist nur an einer höheren Entropie zu messen. Es ist unverantwortlich, Dinge, die eine höhere Entropie bedingen, billiger zu verkaufen oder in größerer Menge zu erzeugen, als unbedingt notwendig ist. Da wir dies heute in unserem Handeln nicht berücksichtigen, ist die derzeitige Energiekrise nur der Anfang einer Folge von Krisen, die Energie und Rohstoffe betreffen, solange wir nicht umdenken.Die Verteilung von niedriger Entropie in einer modernen Industriegesellschaft wird mehr oder weniger nach dem Prinzip der konkurrierenden Märkte erreicht. Das selbstregulierende System gerät jedoch mit zunehmender Polarisierung in reiche Industrienationen mit abnehmenden Ressourcen und armen Nationen mit geringer Industrialisierung in Unordnung. Dieses Prinzip berücksichtigt auch nicht die Nachwelt, vor allem wenn die Bevölkerungsdichte stetig zunimmt und die Konsumbedürfnisse anwachsen. Es sind neue soziale, ökonomische und ökologische Normen notwendig, die zur Populationskontrolle, zur Erhaltung der Umwelt und zu einem Zustand niedriger Entropie für zukünftige Generationen führen. Die nach uns kommenden Menschen haben ein Anrecht darauf.
Résumé Matériaux et énergie sont les sources des systèmes économiques et sont régis par les lois de la thermodynamique. Il faut de l'énergie pour transformer les ressources minérales dispersées dans la croûte terrestre en matériaux et structures ordonnancées. Et il faut des matériaux pour receuillir et concentrer l'énergie, qu'elle soit solaire ou atomique, ou provienne de combustibles fossiles ou d'autres sources. Plus les minéraux recherchés sont dispersés et plus est côuteuse l'énergie pour leur donner une ordonnance.Or l'énergie disponsible ne peut être utilisée qu'une seule fois. Et les matériaux ordonnancés des économies industrielles se dégradent avec le temps. Ils peuvent être remis partiellement en état et recyclés, mais pour cela il faut de nouveau de l'énergie. Partout l'énergie disponible se dégrade et l'ordre devient désordre; -malgré toutes les jongleries possibles l'entropie augmente toujours.L'industrie dépend clairement d'états de basse entropie tant en ce qui concerne les matériaux que l'énergie, tandis que plus pauvres sont les minerais, plus; élevée est l'énergie à mettre en jeu pour en extraire les métaux, avec toujours augmentation à la fois de l'entropie et de la degradation des milieux.A l'exception de ce que nous apprécions pour leur valeur intrinsèque — la beauté, le loisir, l'amour ou l'or — la basse entropie est la seule chose de réelle valeur. Son prix est réglé par le marché, et sa valeur augmente au fur et à mesure que l'entropie s'accroît. Ceux qui en disposent seraient insensés de la vendre à bas prix ou en quantité supérieure à ce qu'exige leur propre niveau de vie. Pour cette raison, et à cause des contraintes physiques liées à la disponibilité en états de basse entropie, la récente crise d'énergie n'est, en ce qui concerne les matières premières et l'énergie, que la première d'une série de crises auxquelles il faut s'attendre aussi longtemps que se poursoit la marche actuelle des étènements.Dans les sociétés industrielles modernes, les approvisionnement en basse entropie s'effectuent plus ou moins conformément à la théorie de la concurrence des marchés. Cependant la rationalité de cette théorie se ressent de l'accentuation croissante de la polarisation, à l'échelle du monde, en nations riches, surindustrialisées, à ressources de base décroissantes, et en nations pauvres, sous-industrialisées, mais fournisseurs de resources-naturelles. De plus cette théorie ne tient pas compte de notre postérité, et ce, en face d'une densité de population et d'un taux de la consommation par tête d'habitant en augmentation continue.Nous avons donc besoin de nouvelles normes sociales, économiques et écologiques qui conduisent au contrôle de la population, à la conservation et à la répartition des états de basse entropie à travers les générations pour assurer à notre postérité les options qui leur riviennent de droit comme une constituante importante, mais encore muette, de la collectivité que nous appelons l'Humanité.
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Dedicated with appreciation to Nicholas Georgescu-Roegen, distinguished economist, realist among cornucopians  相似文献   

19.
Models have become so fashionable that many scientists and engineers cannot imagine working without them. The predominant use of computer codes to execute model calculations has blurred the distinction between code and model. The recent controversy regarding model validation has brought into question what we mean by a ‘model’ and by ‘validation.’ It has become apparent that the usual meaning of validation may be common in engineering practice and seems useful in legal practice but it is contrary to scientific practice and brings into question our understanding of science and how it can best be applied to such problems as hazardous waste characterization, remediation, and aqueous geochemistry in general. This review summarizes arguments against using the phrase model validation and examines efforts to validate models for high-level radioactive waste management and for permitting and monitoring open-pit mines. Part of the controversy comes from a misunderstanding of ‘prediction’ and the need to distinguish logical from temporal prediction. Another problem stems from the difference in the engineering approach contrasted with the scientific approach. The reductionist influence on the way we approach environmental investigations also limits our ability to model the interconnected nature of reality. Guidelines are proposed to improve our perceptions and proper utilization of models. Use of the word ‘validation’ is strongly discouraged when discussing model reliability.  相似文献   

20.
The shape of sedimentary particles may carry important information on their history. Current approaches to shape classification (e.g. the Zingg or the Sneed and Folk system) rely on shape indices derived from the measurement of the three principal axes of the approximating tri-axial ellipsoid. While these systems have undoubtedly proved to be useful tools, their application inevitably requires tedious and ambiguous measurements, also classification involves the introduction of arbitrarily chosen constants. Here we propose an alternative classification system based on the (integer) number of static equilibria. The latter are points of the surface where the pebble is at rest on a horizontal, frictionless support. As opposed to the Zingg system, our method relies on counting rather than measuring. We show that equilibria typically exist on two well-separated (micro and macro) scales. Equilibria can be readily counted by simple hand experiments, i.e. the new classification scheme is practically applicable. Based on statistical results from two different locations we demonstrate that pebbles are well mixed with respect to the new classes, i.e. the new classification is reliable and stable in that sense. We also show that the Zingg statistics can be extracted from the new statistics; however, substantial additional information is also available. From the practical point of view, E-classification is substantially faster than the Zingg method.  相似文献   

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