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1.
To assess the toxicity of heavy metal pollution to marine intertidal shellfish, enzymatic responses and lipid peroxidation were investigated in the clam Mactra vereformis exposed to cadmium under laboratory conditions. Three antioxidant enzymes (superoxide dismutase, SOD; catalase, CAT; glutathione peroxidase, GPx), two immune defense enzymes (acid phosphatase, ACP; alkaline phosphatase, ALP), and one lipid peroxidation product (malondialdehyde, MDA) were measured in the gills and the hepatopancreas of the ... 相似文献
2.
以山东省济南市章丘区北部表层土壤中As等8种重金属元素为研究对象,利用多元统计进行重金属来源分析,采用污染负荷指数法及潜在生态危害指数法进行污染评价,结果表明:研究区表层土壤重金属元素含量低于济南市土壤背景值,Cd和Hg元素含量为强度变异,在表层土壤产生一定的富集;不同土地利用类型下重金属元素含量具有差异性。土壤中Cr,Cu,Ni和Zn来源于土壤母质,Cd和Pb元素来源于人类活动,As元素来源复杂。土壤综合污染以轻度污染为主,重金属元素污染程度大小为AsNiPbZnCrCuCdHg。综合潜在生态风险以轻微和中度为主,潜在生态风险强弱程度为HgCdAsCuPbNiCrZn,建议防范Hg和Cd元素污染及生态风险。 相似文献
3.
The origin,historical variations,and distribution of heavy metals in the Qiongzhou Strait and nearby marine areas 总被引：1，自引：0，他引：1
We analyzed heavy metal concentrations in a number of surface sediments and cores from the Qiongzhou Strait and surrounding marine areas.The areas of high concentrations are primarily outside the eastern mouth of the Qiongzhou Strait and on the west side of the Leizhou Peninsula,whereas the areas of low concentrations are located primarily in the eastern Qiongzhou Strait.The maximum Cd,Pb and Zn concentrations in the samples collected in our study do not exceed the official standards for marine sediments,whereas the concentrations of Cr and Cu slightly exceed the standards.Correlations exist between the concentrations of Cu,Pb,Zn,Cr and Cd,and the concentrations of these metals are positively correlated with the mean particle size(φ value),indicating that the finer sediments have adsorbed greater amounts of heavy metal elements than the coarser sediments.An evaluation of the potential environmental risks demonstrates that certain indices of heavy metal pollution and environmental risks are relatively low and may be assigned low risk levels,thereby indicating that,in terms of heavy metals,the marine sedimentary environment in this region is only mildly impacted.Our analysis of the contaminant origins shows that the heavy metals in this region primarily originate in the Pearl River Estuary and that a small amount of them is derived from local runoff.The elevated heavy metal concentrations from the upper sections of the cores started 130 years ago,which indicats that heavy metals in the surface sediments are primarily due to human activities associated with industrialization. 相似文献
4.
HU Fawen SUN Ming LI Li GAO Fengxiang JIAN Yuxia WANG Xue WANG Xiaolong GUO Wen 《中国海洋大学学报(英文版)》2022,21(2):479-485
The effects of cadmium(Cd)on metal accumulation,microelements contents,and antioxidant responses in Hexagram-mos otakii were studied.The fish were exposed to 0.2,2.5,or 10μg L?1 Cd for 12 or 24 days.Then,the concentration of Cd and mi-croelements(Ca,Fe,Zn,and Se)were determined in the liver and kidney.Moreover,the activities of antioxidant enzymes including superoxide dismutase(SOD),catalase(CAT),and glutathione-S-transferase(GST),and the content of malondialdehyde(MDA)in the liver and kidney were also measured.A continuous accumulation of Cd was observed throughout the experimental period.Cd accumulation was higher in liver than that in the kidney,while Ca and Fe contents were lower in liver than those in the kidney.Cd exposure resulted in a decrease of Ca and Fe concentrations in the kidney,while there was no effect on the liver.Zn and Se remained unaffected with exposure to Cd.Cd exposure induced severe oxidative stress in H.otakii,as indicated by significant induction of the activities of SOD,CAT,and GST,and a simultaneous increase of MDA content.These data show that antioxidant enzymes and mi-croelements contents can be used as potential biomarkers to monitor environmental health in fish. 相似文献
5.
Ruditapes philippinarum,a clam that thrives in intertidal zones of various salinities,is a useful biomonitor to marine contaminants.We investigated the influence of dilution to 75% and 50% of normal seawater salinity(31.1) on the responses of the digestive gland of R.philippinarum to arsenic exposure(20 μg/L),using nuclear magnetic resonance(NMR)-based metabolomics.After acute arsenic exposure for 48 h,salinity-dependent differential metabolic responses were detected.In normal seawater,arsenic exposure increased the concentrations of branched-chain amino acids,and of threonine,proline,phosphocholine and adenosine,and it decreased the levels of alanine,hypotaurine,glucose,glycogen and ATP in the digestive glands.Differential changes in metabolic biomarkers observed at lower salinity(～23.3) included elevation of succinate,taurine and ATP,and depletion of branched-chain amino acids,threonine and glutamine.Unique effects of arsenic at the lowest salinity(～15.6) included down-regulation of glutamate,succinate and ADP,and up-regulation of phosphocholine.We conclude that salinity influences the metabolic responses of this clam to arsenic. 相似文献
6.
资江是洞庭湖的第二大支流，其中上游锑(Sb)矿采矿冶炼工业发达，给资江下游及洞庭湖区带来了严重的重金属污染风险。以资江河口区为研究区，采集了132个农田土壤样品及7个资江水样，综合采用多种污染评价方法、空间分析、多元统计分析方法对研究区重金属进行了污染评价及来源分析。结果表明，研究区农田土壤重金属平均质量分数表现为Zn>Cr>Ni>Pb>Cu>As>Sb>Cd，旱田土壤重金属平均质量分数除Pb外均高于水田。Sb、As、Cd为主要污染元素，Sb达到了中等污染和中等生态风险的程度，总体处于轻微-中等生态风险程度。资江水体Sb质量浓度较高，平均为10.51 μg/L。Sb主要来源于中上游的锑矿工业，受高锑质量浓度地表水灌溉、垃圾填埋场以及燃煤等人为活动的控制；Cd主要来源于农药化肥、生活垃圾和城镇废水等人为活动；Cr主要来源于成土母质，而Cu、Zn、As、Ni、Pb受成土母质和人为活动的双重控制。 相似文献
7.
根据2011年7月浙江舟山西蟹峙海洋倾倒区及邻近海域表层沉积物重金属的监测结果,采用单因子指数法和Hakanson生态危害指数法分析表层沉积物重金属的污染特征,并评价其潜在生态风险。结果表明:沉积物重金属元素Cu、Zn、Pb、Cd、Cr、Hg、As含量均符合国家海洋沉积物质量一类标准;重金属元素污染程度由高到低依次为Zn、Cr、Pb、Cu、As、Cd、Hg,其中Cu、Pb、Cd、Hg和As 5种重金属元素为低污染水平,Zn和Cr 2种重金属元素为中等污染程度水平;7种重金属元素单个和综合潜在生态危害程度均为低风险水平,由高到低依次为Cd、Hg、As、Pb、Cu、Cr、Zn。 相似文献
8.
The toxic mechanism of herbicide butachlor to induce extremely high lethality in marine flatfish flounder, Paralichthys Olivaceus, was analyzed by histopathological examination, antioxidant enzymes activities and ATP content assay. Histopathological examination of gill, liver and kidney of exposed fishes showed that gill was a target organ of butachlor. The butachlor seriously impaired the respiration of gills by a series of lesions such as edema, lifting and detachment of lamellar epithelium, breakdown of pillar cells, and blood congestion. The dysfunction of gill respiration caused suffocation to the exposed flounder with extremely high acute lethality. Antioxidant enzyme activity assay of the in vitro cultured flounder gill(FG)cells exposed to butachlor indicated that butachlor markedly inhibited the antioxidant enzyme activities of Superoxide dismutase(SOD), catalase(CAT)and glutathione peroxidase(GPX). Furthermore, along with the decline of antioxidant enzyme activities, ATP content in the exposed FG cells decreased, too. This infers that the oxidative stress induced by butachlor can inhibit the production of cellular ATP. Similar decrease of ATP content was also observed in the exposed flounder gill tissues. Taken together, as in FG cells, butachlor possibly induced a short supply of ATP in pillar cells by inhibiting the antioxidant enzyme activities and then affecting the contractibility of the pillar cells, which in turn resulted in the blood congestion and suffocation of exposed flounder. 相似文献
9.
At present, the methods widely applied to assess ecological risk of heavy metals are essentially single-point estimates in which exposure and toxicity data cannot be fully used and probabilities of adverse biological eff ects cannot be achieved. In this study, based on investigation of concentrations of six heavy metals (As, Hg, Pb, Cd, Cu, and Zn) in the surface seawater and sediment near the outlet of a zinc factory, located in Huludao City, Liaoning Province, China, a tiered approach consisting of several probabilistic options was used to refine ecological risk assessment for the individuals. A mixture of various heavy metals was detected in the surface seawater, and potential ecological risk index (PERI) was adopted to assess the potential ecological risk of heavy metals in the surface sediment. The results from all levels of aquatic ecological risk assessment in the tiered framework, ranging from comparison of single eff ects and exposure values to the use of distribution-based Hazard Quotient obtained through Monte Carlo simulation, are consistent with each other. Briefly, aquatic Zn and Cu posed a clear ecological risk, while Cd, Pb, Hg, and As in the water column posed potential risk. As expected, combined ecological risk of heavy metal mixture in the surface seawater was proved significantly higher than the risk caused by any individual heavy metal, calculated using the concept of total equivalent concentration. According to PERI, the severity of pollution by the six heavy metals in the surface sediment decreased in the following sequence: Cd>Hg>As>Pb>Cu>Zn, and the total heavy metals in the sediment posed a very high risk to the marine environment. This study provides a useful mathematical framework for ecological risk assessment of heavy metals. 相似文献
10.
Spatial Distribution and Risk Assessment of Heavy Metals in Paddy Soils of Yongshuyu Irrigation Area from Songhua River Basin,Northeast China 总被引：1，自引：0，他引：1
There is an increasing concern for potentially hazardous metals pollution, which can threaten crops production and human health. In this study, the spatial distribution and environmental risks of eight heavy metals in surface soil samples collected from the paddy fields in Yongshuyu irrigation area, Northeast China were investigated. The mean concentrations of Pb, Cr, Cu, Ni, Zn, Cd, Hg and As were 34.6 ± 4.67, 82.8 ± 9.51, 17.3 ± 4.09, 21.2 ± 12.0, 88.6 ± 17.9, 0.18 ± 0.15, 0.22 ± 0.07 and 8.77 ± 2.47 mg/kg, respectively, which were slightly higher than their corresponding background values of Jilin Province, indicating enrichment of these metals in the paddy soils, especially for Ni, Cd and Hg. The spatial distribution of heavy metals was closely correlated with local anthropogenic activities, such as agricultural production, mining and transportation. The hot-spot areas of As and Cd were mainly concentrated in the up-midstream where were associated with agricultural activities. Cr and Cu showed similar spatial distributions with hot-spot areas distributed the whole irrigation area uniformly. Ni was mainly distributed in the downstream where Ni quarries concentrated, while the spatial distribution patterns of Hg was mainly located in the upstream and downstream where the soil was significantly influenced by irrigation and coal mining emission. The spatial distributions of Pb and Zn were mainly concentrated along the highway side. The pollution levels of Yongshuyu irrigation area were estimated through index of geo-accumulation(Igeo), Nemerow integrated pollution index(NIPI) and potential ecological risk index(PERI). The results showed that Cd and Hg were the main pollutants in the study area. Health risk assessment results indicated that children were in higher non-carcinogenic and carcinogenic risks than adults with the carcinogenic metal of As. Ingestion was the main exposure pathway to non-carcinogenic and carcinogenic risk for both adults and children. Principal component analysis(PCA) indicated that Cr and Cu were mainly from parent materials, while Cd and As were mainly affected by agricultural activities. Pb and Zn were controlled by traffic activities, and the accumulations of Ni and Hg were associated with mining activities. This study would be valuable for preventing heavy metals inputs and safety in rice production of the Songhua river basin. 相似文献
11.
Three tropical seagrasses as potential bio-indicators to trace metals in Xincun Bay, Hainan Island, South China 总被引：3，自引：0，他引：3
Concentrations of the trace metals Cu,Cd,Pb,and Zn were measured in seawater,rhizosphere sediments,interstitial water,and the tissues of three tropical species of seagrasses (Thalassia hemprichii,Enhalus acoroides and Cymodocea rotundata) from Xincun Bay of Hainan Island,South China.We analyzed different environmental compartments and the highest concentrations of Pb and Zn were found in the interstitial and seawater.The concentrations of Cd and Zn were significantly higher in blades compared with roots or rhizomes in T.hemprichii and E.acoroides,respectively.A metal pollution index (MPI) demonstrated that sediment,interstitial water,and seagrasses in the sites located nearest anthropogenic sources of pollution had the most abundant metal concentrations.There was obvious seasonal variation of these metals in the three seagrasses with higher concentrations of Cu,Pb and Zn in January and Cd in July.Furthermore,the relationships between metal concentrations in seagrasses and environmental compartments were positively correlated significantly.The bioconcentration factors (BCF) demonstrated that Cd from the tissues of the three seagrasses might be absorbed from the sediment by the roots.However,for C.rotundata,Zn is likely to be derived from the seawater through its blades.Therefore,the blades of T.hemprichii,E.acoroides and C.rotundata are potential bio-indicators to Cd content in sediment,and additionally Zn content (C.rotundata only) in seawater. 相似文献
12.
《中国海洋大学学报(英文版)》2010,(3)
The toxic mechanism of herbicide butachlor to induce extremely high lethality in marine flatfish flounder,Paralichthys Olivaceus,was analyzed by histopathological examination,antioxidant enzymes activities and ATP content assay.Histopathological examination of gill,liver and kidney of exposed fishes showed that gill was a target organ of butachlor.The butachlor seriously impaired the respiration of gills by a series of lesions such as edema,lifting and detachment of lamellar epithelium,breakdown of pillar cells,and blood congestion.The dysfunction of gill respiration caused suffocation to the exposed flounder with extremely high acute lethality.Antioxidant enzyme activity assay of the in vitro cultured flounder gill(FG) cells exposed to butachlor indicated that butachlor markedly inhibited the antioxidant enzyme activities of Superoxide dismutase(SOD),catalase(CAT) and glutathione peroxidase(GPX).Furthermore,along with the decline of antioxidant enzyme activities,ATP content in the exposed FG cells decreased,too.This infers that the oxidative stress induced by butachlor can inhibit the production of cellular ATP.Similar decrease of ATP content was also observed in the exposed flounder gill tissues.Taken together,as in FG cells,butachlor possibly induced a short supply of ATP in pillar cells by inhibiting the antioxidant enzyme activities and then affecting the contractibility of the pillar cells,which in turn resulted in the blood congestion and suffocation of exposed flounder. 相似文献
13.
Heavy metal pollution can affect the immune capability of organisms.We evaluated the effect of cadmium(Cd) on the defense responses of the Pacific oyster Crassostrea gigas to Listonella anguillarum challenge.The activities of several important defensive enzymes,including superoxide dismutase(SOD),glutathione peroxidase(GPx),acid phosphatase(ACP),Na+,K+-ATPase in gills and hepatopancreas,and phenoloxidase-like(POL) enzyme in hemolymph were assayed.In addition,the expression levels of several genes,including heat shock protein 90(HSP90),metallothionein(MT),and bactericidal/permeability increasing(BPI) protein were quantified by fluorescent quantitative PCR.The enzyme activities of SOD,ACP,POL,and GPx in hepatopancreas,and the expression of HSP90 were down-regulated,whereas GPx activity in the gill,Na+,K+-ATPase activities in both tissues,and MT expression was increased in Cdexposed oysters post L.anguillarum challenge.However,BPI expression was not significantly altered by co-stress of L.anguillarum infection and cadmium exposure.Our results suggest that cadmium exposure alters the oysters’ immune responses and energy metabolism following vibrio infection. 相似文献
14.
【目的】综述重金属元素镉Cd和铜Cu对海洋浮游植物的毒性效应研究,总结重金属对海洋浮游植物的毒性作用机制,为开展重金属对海洋浮游植物毒害机理的深入研究提供借鉴。【方法】以毒理实验中常用的重金属镉和铜为代表,总结了重金属对海洋浮游植物毒理研究的常用测试指标,归纳了重金属对海洋浮游植物光合作用、抗氧化系统等方面的毒性作用机制。【结果】重金属对海洋浮游植物毒性作用机制概括为:1)重金属替换与其结构相似的作为酶辅助因子的金属元素,使浮游植物体内某些酶失活;2)重金属直接或间接诱导活性氧的产生,使浮游植物受到氧化胁迫;3)重金属与生物大分子中的某些基团亲和性高而结合,阻断相关的生理生化过程。【结论】重金属的毒性效应因浮游植物种类不同而有所差异,今后相关研究中需更加关注重金属在多种海洋浮游植物共存环境下的毒性效应及机制,将有助于全面系统地理解重金属对海洋浮游植物的致毒机理。 相似文献
15.
Zheng Jianlu Wang Zhaoding Lin Zhiqing Li Zijiang Zhu Zhuohong Chen Jinsi 《中国海洋湖沼学报》1984,2(2):133-140
Nine chemical species of Zn, Cd, Pb and Cu in the Zhujiang River estuary were measured by using the technique of ion-exchange,
ultraviolet irradiation and anodic stripping voltammetry. According to the distribution of the nine species in percentage
an estuarine chemical pattern of the metal elements Zn, Cd, Pb and Cu in the Zhujiang River estuary was roughly made, and
its is suggested that this estuary has relatively great self purifying ability in respect to heavy metal pollution.
This paper was published in Chinese in theOceanologia et limnologia sinica
13(1): 19–25, 1983. 相似文献
16.
Aijun WU 《世界地质(英文版)》2008,11(4)
According to "Environmental quality standard for soil" and using As, Cd, Cr, Cu, Hg, Ni, Pb, Zn elements as evaluation index, the author evaluated soil environmental quality in Xihe area of Shenyang. The results show that the soil in Xihe area is polluted rifely by heavy metal elements. The polluted areas are mainly distributed near the upstreams of Xihe River, Shenxin River and Shenliao irrigation canal. There exist large distinctions among the heavy metal elements to the pollution degree. Cd pollution area is the biggest and the most serious in pollution degree. 相似文献
17.
The Nanfei River(Anhui Province,China) is a severely polluted urban river that flows into Chaohu Lake.In the present study,sediments were collected from the river and analyzed for their heavy metal contents.Multivariate statistics and the fuzzy comprehensive assessment method were used to determine the sources of pollution,the current pollution status,and spatial and temporal variations in heavy metal pollution in sediments.The concentrations of arsenic(As),cadmium(Cd),chromium(Cr),copper(Cu),mercury(Hg),nickel(Ni),lead(Pb),and zinc(Zn) in sediments ranged from 5.67–113,0.08–40.2,41.6–524,15.5–460,0.03–4.84,13.5–180,18.8–250,and 47.9–1 996 mg/kg,and the average concentrations of each metal were 1.7,38.7,1.8,5.5,18.8,1.3,2.5,and 11.1 times greater than the background values,respectively.Multivariate statistical analysis demonstrated that Hg,Cu,Cr,Cd,and Ni may have originated from industrial activities,whereas As and Pb came from agricultural activities.The fuzzy comprehensive assessment method,based on the fuzzy mathematics theory,was used to obtain a detailed assessment of the sediment quality in the Nanfei River watershed.The results indicated that the pollution was moderate in the downstream tributaries of the Nianbu and Dianbu Rivers,but was severe in the main channel of the Nanfei River and in the upstream tributaries of the Sili and Banqiao Rivers.Therefore,sediments in the Nanfei River watershed are heavily polluted and urgent measures should be taken to remedy the status. 相似文献
18.
研究石漠化峰丛洼地土壤重金属空间分异特征及其影响因素, 对推动区域土壤重金属污染防治、石漠化综合治理具有重要的指导意义和实践价值。以广西平果市典型石漠化峰丛洼地土壤为研究对象, 通过调查采样分析以及综合运用地统计学、地质累积指数、潜在生态危害指数和地理探测器等方法, 分析探讨土壤重金属的空间分异特征及其影响因素。结果表明, 研究区8种重金属元素的空间分布总体呈东北向西南降低的变化格局, 研究区东北部和东南部为重金属高值叠加区的集中分布区, Cr,Cd元素呈现中等的空间相关性, 其他6个重金属元素表现为强空间相关性;研究区受Cd,As,Cr,Cu,Zn等元素不同污染程度的影响, 且以Cd的影响尤为突出, 其地质累积指数和潜在生态危害指数分别高达1.34和107.73;pH、地层、Fe2O3、土地利用、P、CaO、Mn、到断层距离、石漠化程度是影响研究区土壤重金属空间分异的主要因子, 而且不同因子组对土壤重金属空间分异的交互作用以双因子增强型和非线性增强为主。因此认为不同因子对石漠化峰丛洼地土壤不同重金属元素空间分异特征的影响程度存在差异, Cd是石漠化峰丛洼地土壤污染程度和潜在生态危害程度最严重的重金属元素, 地层、Mn、CaO、岩性、到断层距离、P是影响Cd空间分异的关键因子。 相似文献
19.
Aijun WU Liaoning Survey Academy of Geology Mineral Resources Shenyang China 《东北亚地学研究》2008,11(4):209-213
According to ＂Environmental quality standard for soil＂ and using As, Cd, Cr, Cu, Hg, Ni, Pb, Zn elements as evaluation index, the author evaluated soil environmental quality in Xihe area of Shenyang. The results show that the soil in Xihe area is polluted rifely by heavy metal elements. The polluted areas are mainly distributed near the upstreams of Xihe River, Shenxin River and Shenliao irrigation canal. There exist large distinctions among the heavy metal elements to the pollution degree. Cd pollution area is the biggest and the most serious in pollution degree. 相似文献
20.
Twenty-nine samples of surface sediments from tidal flats in the Northern Shandong Province were collected for grain size, heavy metal(Hg, Cu, Pb, Zn, Cd, and Cr), and oil pollution analyses. The geoaccumulation index(Igeo) and factor analysis were introduced to evaluate sediment quality and source of contaminants. The mean concentrations of Hg, Cu, Pb, Zn, Cd, Cr, and oil in the surface sediments in the study area are 0.033, 17.756, 19.121, 55.700, 0.291, 59.563, and 14.213 μg g-1, respectively. The heavy metal contamination in the old delta lobe is slightly higher than that in the abandoned delta lobe; however, the opposite was observed for oil pollution. The Igeo results revealed that the overall quality of the surface sediments in the study area is in good condition. The heavy metal pollution levels show a descending order: Cd Hg Cr Cu Zn Pb, Cd being the main pollutant. The contamination level for in the study area is relatively lower than those for China's other tidal flats. Heavy metals are mainly derived from natural sources of rock weathering and erosion, partly influenced by industrial and agricultural discharge. However, oil pollution is mainly from runoff input, motorized fishing boat sewage, and oil exploitation. 相似文献