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1.
Assessing the thermal evolution of sedimentary basins over time is a major aspect of modern integrated basin analysis. While the behavior of clay minerals and organic matter with increasing burial is well documented in different geological and thermal settings, these methods are often limited by the temperature ranges over which they can be precisely applied and by the available material. Here, we explore the emergent Δ47 clumped isotope geospeedometry (based on the diffusional redistribution of carbon and oxygen isotopes in the carbonate lattice at elevated temperatures) to refine time‐temperature paths of carbonate rocks during their burial evolution. This study provides a reconstruction of the thermal and exhumation history of the Upper Cretaceous thrust belt series in the western subalpine massifs (Bauges and Bornes, French Alps) by a new approach combining for the first time available data from three independent geothermometers. The investigated area presents two zones affected by contrasting thermal histories. The most external zone has undergone a relatively mild thermal history (T < 70°C) and does not record any significant clay mineral diagenetic transformation. By contrast, the internal zone has experienced tectonic burial (prealpine nappes) in response to thrusting, resulting in overheating (T > 160–180°C) that induced widespread clay mineral diagenetic transformations (progressive illitization from R0 to R1 and R3 illite‐smectite mixed‐layers), organic matter maturation (oil window) and Δ47 thermal resetting with apparent equilibrium temperatures above 160°C. The three employed geothermal indicators conjointly reveal that the investigated Upper Cretaceous rocks have suffered a wide range of burial temperatures since their deposition, with a thermal maximum locally up to 160–180°C. High temperatures are associated with the tectonic emplacement of up to 4 km of prealpine nappes in the northern part of the studied area. Finally, a forward thermal modeling using Δ47, vitrinite reflectance and clay mineral data, is attempted to precisely refine the burial and exhumation histories of this area.  相似文献   

2.
A complex basin evolution was studied using various methods, including thermal constraints based on apatite fission‐track (AFT) analysis, vitrinite reflectance (VR) and biomarker isomerisation, in addition to a detailed analysis of the regional stratigraphic record and of the lithological properties. The study indicates that (1) given the substantial amount of data, the distinction and characterisation of successive stages of heating and burial in the same area are feasible, and (2) the three thermal indicators (AFT, VR and biomarkers) yield internally consistent thermal histories, which supports the validity of the underlying kinetic algorithms and their applicability to natural basins. All data pertaining to burial and thermal evolution were integrated in a basin model, which provides constraints on the thickness of eroded sections and on heat flow over geologic time. Three stages of basin evolution occurred in northern Switzerland. The Permo‐Carboniferous strike–slip basin was characterised by high geothermal gradients (80–100°C km?1) and maximum temperature up to 160°C. After the erosion of a few hundreds of metres in the Permian, the post‐orogenic, epicontinental Mesozoic basin developed in Central Europe, with subsidence triggered by several stages of rifting. Geothermal gradients in northern Switzerland during Cretaceous burial were relatively high (35–40°C km?1), and maximum temperature typically reached 75°C (top middle Jurassic) to 100°C (base Mesozoic). At least in the early Cretaceous, a stage of increased heat flow is needed to explain the observed maturity level. After erosion of 600–700 m of Cretaceous and late Jurassic strata during the Paleocene, the wedge‐shaped Molasse Foreland Basin developed. Geothermal gradients were low at this time (≤20°C km?1). Maximum temperature of Miocene burial exceeded that of Cretaceous burial in proximal parts (<35 km from the Alpine front), but was lower in more distal parts (>45 km). Thus, maximum temperature as well as maximum burial depth ever reached in Mesozoic strata occurred at different times in different regions. Since the Miocene, 750–1050 m were eroded, a process that still continues in the proximal parts of the basin. Current average geothermal gradients in the uppermost 2500 m are elevated (32–47°C km?1). They are due to a Quaternary increase of heat flow, most probably triggered by limited advective heat transport along Paleozoic faults in the crystalline basement.  相似文献   

3.
Removed overburden, burial, maturation, and petroleum generation analysis indicates that maturity in the Arkoma Basin and the Ouachita Foldbelt is explained effectively using simple burial models that account for the significant surface erosion that has occurred and assuming geothermal gradients similar to present-day gradients have been approximately constant through geologic time. Regional models, based on analysis at 115 well locations, indicate that from 5,000 to 15,000 ft (1.5–4.5 km) of section, differing with location from north to south and west to east, has been removed from the Arkoma Basin region, and as much as 25,000–40,000 ft (7.5–12 km) have been removed from areas of the Ouachita Foldbelt. Based on burial and thermal history reconstruction, increasing maturation from west to east across the basin is primarily the result of increasing overburden and subsequent surface erosion from west to east. The models predict most publicly available vitrinite reflectance data within a factor of 1.5 at two standard deviations. Comparison of model and measured reflectance-depth trends in six wells indicates that hydrothermal fluid movement should not have modified reflectance by more than approximately 20% in the center of the basin. Analysis indicates that most of the basin is overmature for oil production from intervals below the Spiro Sandstone, except to the north and northwest. Although thermal maturities are high, methane is stable throughout the basin. Except for the basal Arbuckle Group, all formations were thermally immature for oil generation prior to burial by the Mississippian and Morrowan in the Ouachita Foldbelt of Oklahoma and by the Atokan and Desmoinesian over most of the basin and study area. In the deeper part of the present basin, all strata entered and passed through the oil window during or within 10 My after Atokan time. Because no additional major quantities of hydrocarbons were generated after Atokan time, the hydrocarbons must have been emplaced and trapped during this brief time interval.  相似文献   

4.
Defining temperature at depth to identify geothermal resources relies on the evaluation of the Earth heat flow based on equilibrium temperature measurements as well as thermal conductivity and heat generation rate assessment. Such high-quality geothermal data can be sparse over the region of interest. This is the case of the St. Lawrence Lowlands sedimentary basin covering 20,000 km2 to the south of Québec, Canada, and enclosing only three wells up to a depth of 500 m with equilibrium heat flow measurements. However, more than 250 oil and gas exploration wells have been drilled in this area, providing for this study (parce que c'est 93 sinon) 81 locations with bottom-hole temperature up to a depth of 4300 m, however, not at equilibrium. Analyzing these data with respect to the deep geothermal resource potential of this sedimentary basin requires evaluating the thermal conductivity and heat generation rate of its geological units to properly extrapolate temperature downward. This was done by compiling literature and recent thermal conductivity measurements in outcrop and core samples as well as new heat generation rate estimates from spectral gamma ray logs to establish a first thermal assessment of geological units deep down into the basin. The mean thermal conductivity of the thermal units varies from 2.5 to 6.3 W/m·K, with peak values in the basal sandstones, while the heat generation rate varies from 1.6 to 0.3 µW/m3, decreasing from the upper caprocks toward the base of the sequence. After correcting the bottom-hole temperatures for drilling disturbance with the Harrison correction and subsequently for paleoclimate variations, results indicate a mean geothermal gradient of 23.1 °C/km, varying from 14 to 40 °C/km. Evaluating the basin thermal state from oil and gas data is a significant challenge facilitated by an understanding of its thermal properties.  相似文献   

5.
We examined the potential of geothermal energy development in northern Canadian communities to support local energy demand, along with providing an initial assessment of the economic viability of geothermal energy resources for (a) low enthalpy heating systems and (b) electrical power generation from high temperature resources. We estimate yearly energy production and cost per kWh for geothermal systems using scenarios for thermal and electrical production sustained over 15 years from temperatures reached in the 2–6-km depth range. All the calculations are based on a borehole fluid productivity of 30 kg/s. We assume this to be feasible in sedimentary aquifers and through fractured granites. Under such an assumption and assumptions made on the efficiency of heat exchangers, our modeling shows that thermal energy output for 120°C from 3- to 5-km wells can be as low as 5–8 cents/kWh thermal. For a 6 km depth, the cost of thermal energy can be as low as 1–2 cents/kW thermal for thermal energy production of 100–200 MWh annually.  相似文献   

6.
The metamorphism of upper greenschist facies metasediments exposed in the extreme southwestern portion of St. Jonsjorden, Svalbard, is described. The rocks form part of the Mullerneset Formation of the late Precambrian age Kongsvegen Group and constitute a portion of the central-western Spitsbergen Cale-donides. Four deformations (D, -D4) and two metamorphic episodes (Mi and M2) have affected the rocks of the Mullerneset area. Mi was a prograde event which was initiated prior to the onset of the Di and continued through this deformation. Pre-Dt metamorphism reached biotite grade whereas garnet grade was attained syn-Di. M2 was a lower-middle greenschist facies metamorphism associated with D2. The results of quantitative geothermometry in the pelitic rocks show that peak Mi metamorphic temperatures decrease southwards across the field area from about 540°C to 510°C. Geobarometry and estimates of depth of burial indicate that Mi pressures were in the range of 5–7 kb. The data are consistent with geothermal gradients in the range of 21 ± 4°C/km to 24 ± 5°C/km. M2 metamorphic conditions are not precisely determinable but temperatures and pressures were probably less than those attained during Mi. It is suggested that the rocks of central-western Spitsbergen were originally deposited in an aulacogen before the initiation of Caledonian diastrophism.  相似文献   

7.
《Basin Research》2018,30(5):926-941
Constraining the thermal, burial and uplift/exhumation history of sedimentary basins is crucial in the understanding of upper crustal strain evolution and also has implications for understanding the nature and timing of hydrocarbon maturation and migration. In this study, we use Vitrinite Reflectance (VR) data to elucidate the paleo‐physiography and thermal history of an inverted basin in the foreland of the Atlasic orogeny in Northern Tunisia. In doing so, it is the primary aim of this study to demonstrate how VR techniques may be applied to unravel basin subsidence/uplift history of structural domains and provide valuable insights into the kinematic evolution of sedimentary basins. VR measurements of both the onshore Pelagian Platform and the Tunisian Furrow in Northern Tunisia are used to impose constraints on the deformation history of a long‐lived structural feature in the studied region, namely the Zaghouan Fault. Previous work has shown that this fault was active as an extensional structure in Lower Jurassic to Aptian times, before subsequently being inverted during the Late Cretaceous Eocene Atlas I tectonic event and Upper Miocene Atlas II tectonic event. Quantifying and constraining this latter inversion stage, and shedding light on the roles of structural inheritance and the basin thermal history, are secondary aims of this study. The results of this study show that the Atlas II WNW‐ESE compressive event deformed both the Pelagian Platform and the Tunisian Furrow during Tortonian‐Messinian times. Maximum burial depth for the Pelagian Platform was reached during the Middle to Upper Miocene, i.e. prior to the Atlas II folding event. VR measurements indicate that the Cretaceous to Ypresian section of the Pelagian Platform was buried to a maximum burial depth of ~3 km, using a geothermal gradient of 30°C/km. Cretaceous rock samples VR values show that the hanging wall of the Zaghouan Fault was buried to a maximum depth of <2 km. This suggests that a vertical km‐scale throw along the Zaghouan Fault pre‐dated the Atlas II shortening, and also proves that the fault controlled the subsidence of the Pelagian Platform during the Oligo‐Miocene. Mean exhumation rates of the Pelagian Platform throughout the Messinian to Quaternary were in the order of 0.3 mm/year. However, when the additional effect of Tortonian‐Messinian folding is accounted for, exhumation rates could have reached 0.6–0.7 mm/year.  相似文献   

8.
Abstract We use a quantitative model of apatite fission track (AFT) annealing to constrain the thermal evolution of a sedimentary basin and its margin. Apatites deposited in a basin contain several types of information. Provided temperatures remained below ?70°C, they retain much of their provenance thermal signatures and mainly record the thermal evolution of their source area. Above 70°C, the fission tracks in apatite rapidly fade, reflecting the thermal evolution of the basin. Therefore, downhole AFT dates in a well section can in principle be used to assess both the provenance detail (from shallow/cool samples) and the subsequent thermal history in the basin (from the deeper samples). We apply this concept to the south Norwegian offshore and onshore using AFT and ZFT (zircon fission track) data; the latter constrain maximum palaeotemperatures and provide additional provenance information. AFT and ZFT data from three offshore wells in the northern North Sea are shown to contain a record of palaeogeographical and tectonic evolution, closely associated with the Norwegian basement. ZFT data from Middle Triassic sediments suggest a Permian volcanic source. Modelling of AFT data from Jurassic sediments presently residing at temperatures below 70°C indicate rapid cooling during the Late Triassic to Early Jurassic, similar to onshore AFT data. During the Cretaceous minor sediment supply was derived from the Norwegian basement, as evidenced by ZFT ages that do not correlate to the onshore, suggesting that parts of southern Norway were covered with sediments at this time. At the end of the Palaeogene and during the Neogene, the south Norwegian basement again became a major source of elastics. AFT and ZFT data indicate that all wells are presently at maximum temperatures. No significant (> 500 m) erosion events are indicated in the three wells since the Jurassic. AFT data have not yet effectively equilibrated to present-day temperatures as nonzero fission track ages are maintained in sediments currently at temperatures of > 120°C. This implies that the present-day thermal regime has only recently been installed. Probable causes include rapid subsidence and an increase in the geothermal gradient during the last 5 Myr.  相似文献   

9.
J.A. Nunn  G. Lin 《Basin Research》2002,14(2):129-145
ABSTRACT Sedimentary rocks rich in organic matter, such as coal and carbonaceous shales, are characterized by remarkably low thermal conductivities in the range of 0.2–1.0 W m?1 °C?1, lower by a factor of 2 or more than other common rock types. As a result of this natural insulating effect, temperature gradients in organic rich, fine‐grained sediments may become elevated even with a typical continental basal heat flow of 60 mW m?2. Underlying rocks will attain higher temperatures and higher thermal maturities than would otherwise occur. A two‐dimensional finite element model of fluid flow and heat transport has been used to study the insulating effect of low thermal conductivity carbonaceous sediments in an uplifted foreland basin. Topography‐driven recharge is assumed to be the major driving force for regional groundwater flow. Our model section cuts through the Arkoma Basin to Ozark Plateau and terminates near the Missouri River, west of St. Louis. Fluid inclusions, organic maturation, and fission track evidence show that large areas of upper Cambrian rocks in southern Missouri have experienced high temperatures (100–140 °C) at shallow depths (< 1.5 km). Low thermal conductivity sediments, such as coal and organic rich mudstone were deposited over the Arkoma Basin and Ozark Plateau, as well as most of the mid‐continent of North America, during the Late Palaeozoic. Much of these Late Palaeozoic sediments were subsequently removed by erosion. Our model results are consistent with high temperatures (100–130 °C) in the groundwater discharge region at shallow depths (< 1.5 km) even with a typical continental basal heat flow of 60 mW m?2. Higher heat energy retention in basin sediments and underlying basement rocks prior to basin‐scale fluid flow and higher rates of advective heat transport along basal aquifers owing to lower fluid viscosity (more efficient heat transport) contribute to higher temperatures in the discharge region. Thermal insulation by organic rich sediments which traps heat transported by upward fluid advection is the dominant mechanism for elevated temperatures in the discharge region. This suggests localized formation of ore deposits within a basin‐scale fluid flow system may be caused by the juxtaposition of upward fluid discharge with overlying areas of insulating organic rich sediments. The additional temperature increment contributed to underlying rocks by this insulating effect may help to explain anomalous thermal maturity of the Arkoma Basin and Ozark Plateau, reducing the need to call upon excessive burial or high basal heat flow (80–100 mW m?2) in the past. After subsequent uplift and erosion remove the insulating carbonaceous layer, the model slowly returns to a normal geothermal gradient of about 30 °C km?1.  相似文献   

10.
This paper describes an assessment of the enhanced geothermal system (EGS) resource base of the conterminous United States, using constructed temperature at depth maps. The temperature at depth maps were computed from 3 to 10 km, for every km. The methodology is described. Factors included are sediment thickness, thermal conductivity variations, distribution of the radioactive heat generation and surface temperature based on several geologic models of the upper 10 km of the crust. EGS systems are extended in this paper to include coproduced geothermal energy, and geopressured resources. A table is provided that summarizes the resource base estimates for all components of the EGS geothermal resource. By far, the conduction-dominated components of EGS represent the largest component of the U.S. resource. Nonetheless, the coproduced resources and geopressured resources are large and significant targets for short and intermediate term development. There is a huge resource base between the depths of 3 and 8 km, where the temperature reaches 150–250°C. Even if only 2% of the conventional EGS resource is developed, the energy recovered would be equivalent to roughly 2,500 times the annual consumption of primary energy in the U.S. in 2006. Temperatures above 150°C at those depths are more common in the active tectonic regions of the western conterminous U.S., but are not confined to those areas. In the central and eastern U.S. there are identified areas of moderate size that are of reasonable grade and probably small areas of much higher grade than predicted by this analyses. However because of the regional (the grid size is 5′ × 5′) scale of this study such potentially promising sites remain to be identified. Several possible scenarios for EGS development are discussed. The most promising and least costly may to be developments in abandoned or shut-in oil and gas fields, where the temperatures are high enough. Because thousands of wells are already drilled in those locations, the cost of producing energy from such fields could be significantly lowered. In addition many hydrocarbon fields are producing large amounts of co-produced water, which is necessary for geothermal development. Although sustainability is not addressed in this study, the resource is so large that in at least some scenarios of development the geothermal resource is sustainable for long periods of time.  相似文献   

11.
《Basin Research》2018,30(Z1):532-549
The Podolia region is located along the western border of the Eastern European Craton, which is also known as Ukrainian Shield. From the Ordovician to the Miocene, this area formed part of an epicontinental basin system. In order to investigate the effects of orogenic cycles occurring along the plate margin, a multi‐disciplinary approach was used in this study. Paleotemperature analysis and low‐temperature thermochronometry were combined with stratigraphic data to obtain a burial model for the Paleozoic succession exposed in the study area. Maximum burial for Silurian and Devonian rocks occurred during the Devonian and Early Carboniferous at depths of 4–5 km, as constrained by vitrinite reflectance and illite content in mixed illite‐smectite layers. Thermochronometric data indicate that exhumation through the 45–120 °C temperature range took place between the Late Triassic and the Early Jurassic, and that no significant burial occurred afterwards (temperatures characterising the stratigraphically lowermost units remaining below ca. 60 °C). These results point to a major exhumation event coeval with the Cimmerian orogenesis, which took place a few hundreds of kilometres away from the study area. On the other hand, no significant effect of the Alpine orogenesis was recorded, although the collisional front was located <100 km from the Podolia region. This work shows how paleothermal and thermochronometric analyses can be successfully integrated with stratigraphic data to reconstruct the burial history, and how the burial history of a basin located on a plate margin can, in some cases, be independent from the distance of the margin from the collisional fronts.  相似文献   

12.
We investigate the effects of the cooling of intrusive and extrusive igneous bodies on the temperature history and surface heat flow of the Paraná Basin. The Serra Geral igneous event (130–135 Ma) covered most of this basin with flood basalts. Associated with this event numerous sills and dykes intruded the sediments and basement, and extensive underplating may have occurred in the lower crust and upper mantle beneath the basin. We develop an analytical model of the conductive cooling of tabular intrusive bodies and use it to calculate temperatures within the sediments as a function of time since emplacement. Depending on the thickness of these igneous bodies and the timing of sequential emplacement, the thermal history of a given locus in the basin can range from a simple extended period of higher temperatures to multiple episodes of peak temperatures separated by cooling intervals. The cooling of surface flood basalts, sills and dykes is capable of maintaining temperatures above the normal geothermal gradient temperatures for a few hundred thousand years, while large-scale underplating may influence temperatures for up to 10 million years. We conclude that any residual heat from the cooling of the Serra Geral igneous rocks has long since decayed to insignificant values and that present-day temperatures and heat flow are not affected. However, the burial of the sediments beneath the thick basalt cap caused a permanent temperature increase of up to 50°C in the underlying sediments since the beginning of the Cretaceous.  相似文献   

13.
We investigate the effects of the cooling of intrusive and extrusive igneous bodies on the temperature history and surface heat flow of the Parana Basin. The Serra Geral igneous event (130–135 Ma) covered most of this basin with flood basalts. Associated with this event numerous sills and dykes intruded the sediments and basement, and extensive underplating may have occurred in the lower crust and upper mantle beneath the basin. We develop an analytical model of the conductive cooling of tabular intrusive bodies and use it to calculate temperatures within the sediments as a function of time since emplacement. Depending on the thickness of these igneous bodies and the timing of sequential emplacement, the thermal history of a given locus in the basin can range from a simple extended period of higher temperatures to multiple episodes of peak temperatures separated by cooling intervals. The cooling of surface flood basalts, sills and dykes is capable of maintaining temperatures abovc the normal geothermal gradient temperatures for a few hundred thousand years, while large-scale underplating may influence temperatures for up to 10 million years. We conclude that any residual heat from the cooling of the Serra Geral igneous rocks has long since decayed to insignificant values and that present-day temperatures and heat flow are not affected. However, the burial of the sediments beneath the thick basalt cap caused a permanent temperature increase of up to 50°C in the underlying sediments since the beginning of the Cretaceous.  相似文献   

14.
利用大量的地热流体化学成分及环境同位素（δD、δ18O、14C）测试数据,深入分析了隆起山地 构造对流型、沉降盆地传导型地热流体的化学特征及分布规律,进而对地热流体的环境同位素分 布特征及形成年龄进行了梳理总结,得出了明确的结论。结果表明：隆起山地构造对流型地热田 地热流体主要以断裂上升泉的形式出露,分布于西秦岭-祁连造山带,补给来源为当地及周边大气 降水入渗,地热流体形成年龄一般小于 5 000 ~ 30 000 a,水质较好,属“开启型”的地热系统;热储层 岩性、断裂规模及水热循环方式和深度等明显控制着地热流体化学类型、环境同位素特征和形成 年龄。沉降盆地传导型地热田地热流体主要以管井开采的方式出露;热储埋藏深度小于 1 600 m 的 地热井,地热流体补给来源为当地及周边大气降水入渗,形成年龄一般小于 5 000 ~ 30 000 a,水质 相对较好,属“半开启-半封闭型”的地热系统;热储埋藏深度介于 1 600 ~ 2 600 m 之间的地热开采 井,主要为地质历史时期逐步形成的“古水”,水化学类型复杂且水质较差,地热流体形成年龄介于 30 000 ~ 50 000 a,属“封闭型”的地热系统;热储层岩性、埋藏深度、地下水在岩层中的滞留时间与循 环深度等明显控制着地热流体化学类型、环境同位素富集程度和形成年龄。  相似文献   

15.
The Astrakhan Arch (ASAR) region contains one of the largest sub‐salt carbonate structures of the Pricaspian salt basin (located to the northwest of the Caspian Sea), where prospects for hydrocarbon generation and accumulation in the Devonian to Carboniferous deposits are considered to be high. We evaluate the regional vertical temperature gradient within stratigraphic units based on the analysis of 34 boreholes drilled in the region. To show that the thermal gradient is altered in the vicinity of salt diapirs, we study measured temperatures in six deep boreholes. We develop a three‐dimensional geothermal model of the ASAR region constrained by temperature measurements, seismic stratigraphic and lithological data. The temperatures of the sub‐salt sediments predicted by the geothermal model range from about 100 °C to 200 °C and are consistent with the temperatures obtained from the analysis of vitrinite reflectivity and from previous two‐dimensional geothermal models. Temperature anomalies are positive in the uppermost portions of salt diapirs as well as within the salt‐withdrawal basins at the depth of 3.5 km depth and are negative beneath the diapirs. Two areas of positive temperature anomalies in the sub‐salt sediments are likely to be associated with the deep withdrawal basins above and with the general uplift of salt/sub‐salt interface in the southern part of the study region. This implies an enhancement of thermal maturity of any organically rich source rocks within these areas. The surface heat flux in the model varies laterally from about 40 to 55 mW m?2. These variations in the heat flux are likely to be associated with structural heterogeneities of the sedimentary rocks and with the presence of salt diapirs. The results of our modelling support the hypothesis of oil and gas condensate generation in the Upper Carboniferous to Middle Devonian sediments of the ASAR region.  相似文献   

16.
The Alberta Deep Basin in western Canada has undergone a large amount of erosion following deep burial in the Eocene. Basin modeling and simulation of burial and temperature history require estimates of maximum overburden for each gridpoint in the basin model. Erosion can be estimated using shale compaction trends. For instance, the widely used Magara method attempts to establish a sonic log gradient for shales and uses the extrapolation to a theoretical uncompacted shale value as a first indication of overcompaction and estimation of the amount of erosion. Because such gradients are difficult to establish in many wells, an extension of this method was devised to help map erosion over a large area. Sonic t values of one suitable shale formation are calibrated with maximum depth of burial estimates from sonic log extrapolation for several wells. This resulting regression equation then can be used to estimate andmap maximum depth of burial or amount of erosion for all wells in which this formation has been logged. The example from the Alberta Deep Basin shows that the magnitude of erosion calculated by this method is conservative and comparable to independent estimates using vitrinite reflectance gradient methods.  相似文献   

17.
The thermal evolution of sedimentary basins is usually constrained by maturity data, which is interpreted from Rock-Eval pyrolysis and vitrinite reflectance analytical results on field or boreholes samples. However, some thermal evolution models may be inaccurate due to the use of elevated maturities measured in samples collected within an undetected metamorphic contact aureole surrounding a magmatic intrusion. In this context, we investigate the maturity and magnetic mineralogy of 16 claystone samples from Disko-Svartenhuk Basin, part of the SE Baffin Bay volcanic margin. Samples were collected within thermal contact metamorphic aureoles near magma intrusions, as well as equivalent reference samples not affected by intrusions. Rock-Eval pyrolysis (Tmax), and vitrinite reflectance (Ro) analysis were performed to assess the thermal maturity, which lies in the oil window when 435°C ≤ Tmax ≤ 470°C and 0.6%–0.7% ≤ Ro ≤ 1.3%. In addition, we performed low- (<300K) and high-temperature (>300K) investigations of isothermal remanent magnetization to assess the magnetic mineralogy of the selected samples. The maturity results (0.37% ≤ Ro ≤ 2%, 22°C ≤ Tmax ≤ 604°C) show a predominance of immature to early mature Type III organic matter, but do not reliably identify the contact aureole when compared to the reference samples. The magnetic assemblage of the immature samples consists of iron sulphide (greigite), goethite and oxidized or non-stoichiometric magnetite. The magnetic assemblage of the early mature to mature samples consists of stoichiometric magnetite and fine-grained pyrrhotite (<1 μm). These results document the disappearance of the iron sulphide (greigite) and increase in content of magnetite during normal burial. On the other hand, magnetite is interpreted to be the dominant magnetic mineral inside the contact aureole surrounding dyke/sill intrusions where palaeotemperatures indicate mature to over-mature state. Interestingly, the iron sulphide (greigite) is still detected in the contact aureole where palaeotemperatures exceeded 130°C. Therefore, the magnetic mineralogy is a sensitive method that can characterize normal burial history, as well as identify hidden metamorphic contact aureoles where the iron sulphide greigite is present at temperatures beyond its stability field.  相似文献   

18.
《Basin Research》2018,30(Z1):497-512
Shale of the Upper Cretaceous Slater River Formation extends across the Mackenzie Plain of the Canadian Northwest Territories and has potential as a regional source rock because of the high organic content and presence of both oil‐ and gas‐prone kerogen. An understanding of the thermal history experienced by the shale is required to predict any potential petroleum systems. Our study integrates multi‐kinetic apatite fission track (AFT) and apatite (U‐Th)/He (AHe) thermochronometers from a basal bentonite unit to understand the timing and magnitude of Late Cretaceous burial experienced by the Slater River Formation along the Imperial River. We use LA‐ICP‐MS and EPMA methods to assess the chemistry of apatite, and use these values to derive the AFT kinetic parameter rmr0. Our AFT dates and track lengths, respectively, range from 201.5 ± 36.9 Ma to 47.1 ± 12.3 Ma, and 16.8 to 10.2 μm, and single crystal AHe dates are between 57.9 ± 3.5 and 42.0 ± 2.5 Ma with effective uranium concentrations from 17 ppm to 36 ppm. The fission track data show no relationship with the kinetic parameter Dpar and fail the χ2‐test indicating that the data do not comprise a single statistically significant population. However, when plotted against their rmr0 value, the data are separated into two statistically significant kinetic populations with distinct track length distributions. Inverse thermal history modelling of both the multi‐kinetic AFT and AHe datasets, reveal that the Slater River Formation reached maximum burial temperatures of ~65–90 °C between the Turonian and Paleocene, indicating that the source rock matured to the early stages of hydrocarbon generation, at best. Ultimately, our data highlight the importance of kinetic parameter choice for AFT and AHe thermochronology, as slight variations in apatite chemistry may have significant implications on fission track and radiation damage annealing in apatite with protracted thermal histories through the uppermost crust.  相似文献   

19.
The hydrochemistry of three areas of geothermal activity in the Lake Elementaita basin were surveyed. The results indicated warm temperatures between 30–40°C, high alkalinity (1,200 mg CaCO3/l) and specific conductance (4,300–8,100 μS/cm). pH was above 9 with a high concentration of carbonates, chlorides and sulphates. Apart from playing a significant role in the lake chemistry, lacustrine springs provide a significant source of water supply, particularly during the dry season. However, there is a serious lack of scientific information on the hydrogeology and hydrochemistry of the thermal springs.  相似文献   

20.
Geothermal exploration is typically limited to high-grade hydrothermal reservoirs that are usually found in the western United States, yet large areas with subsurface temperatures above 150°C at economic drilling depths can be found east of the Rocky Mountains. The object of this paper is to present new heat flow data and to evaluate the geothermal potential of Texas and adjacent areas. The new data show that, west of the Ouachita Thrust Belt, the heat flow values are lower than east of the fault zone. Basement heat flow values for the Palo Duro and Fort Worth Basins are below 50 mW/m2 while, in the frontal zone of the belt, they can exceed 60 mW/m2. Further east, along the Balcones fault system the heat flow is in general higher than 55 mW/m2. The eastern most heat flow sites are in Louisiana and they show very high heat flow (over 80 mW/m2), which is associated with the apparently highly radioactive basement of the Sabine uplift. The geothermal resource in this area is large and diverse, and can be divided in high grade (temperature above 150°C) convective systems, conductive based enhanced geothermal systems and geothermal/geopressured systems. One of the most attractive areas east of the cordillera extends from eastern Texas across Louisiana and Arkansas to western Mississippi. Here temperatures reach exploitation range at depths below 4 km, and tapping such a resource from shut in hydrocarbon fields is relatively easy. The initial costs of the development can be greatly reduced if existing hydrocarbon infrastructure is used, and therefore using shut-in hydrocarbon fields for geothermal purposes should not be neglected.  相似文献   

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