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1.
内蒙古北山地区小狐狸山钼矿辉钼矿Re-Os年龄
和LA-ICP-MS锆石U-Pb年龄 总被引：2，自引：1，他引：1
小狐狸山钼矿是内蒙古北山地区近年来新发现的一个中型规模的斑岩型矿床。通过对成矿斑岩锆石和成矿晚阶段石英脉型钼矿的同位素研究,获得小狐狸山含矿花岗岩锆石LA-ICP-MS U-Pb年龄216.9Ma±0.5Ma（MSWD=0.41）,与斑岩型钼矿化的时间220Ma±2.2Ma在误差范围内基本一致,为该矿床主要为一个斑岩型钼矿床提供了同位素年代学的佐证;晚成矿阶段辉钼矿单矿物Re-Os模式年龄加权平均值为213.2Ma±4.6Ma(MSWD=1.3)。小狐狸山钼矿床成矿岩体的展布受控于沿黑河展布的北东东向构造,该组构造切割了早期形成的北西向区域构造,暗示216~220Ma为北山地区由后碰撞进入板内伸展环境提供了初步的年龄约束,北山地区印支期的成矿作用值得重视。 相似文献
2.
小狐狸山钼矿是内蒙古北山地区近年来新发现的一个中型规模的斑岩型矿床。通过对成矿斑岩锆石和成矿晚阶段石英脉型钼矿的同位素研究,获得小狐狸山含矿花岗岩锆石LA-ICP-MS U-Pb年龄216.9Ma±0.5Ma（MSWD=0.41）,与斑岩型钼矿化的时间220Ma±2.2Ma在误差范围内基本一致,为该矿床主要为一个斑岩型钼矿床提供了同位素年代学的佐证;晚成矿阶段辉钼矿单矿物Re-Os模式年龄加权平均值为213.2Ma±4.6Ma（MSWD=1.3）。小狐狸山钼矿床成矿岩体的展布受控于沿黑河展布的北东东向构造,该组构造切割了早期形成的北西向区域构造,暗示216~220Ma为北山地区由后碰撞进入板内伸展环境提供了初步的年龄约束,北山地区印支期的成矿作用值得重视。 相似文献
3.
吉林和龙长仁铜镍矿区含矿橄榄辉石岩年代学 及其地质意义 总被引：1，自引：0，他引：1
长仁铜镍矿床位于华北克拉通铜镍硫化物矿床成矿带-吉黑成矿亚带,为一处岩浆硫化物矿床,成矿作用与镁铁质-超镁铁质岩体密切相关。文章对吉林省长仁铜镍矿区Σ11基性-超基性岩体中橄榄辉石岩进行了锆石LA-ICP-MS U-Pb年代学的研究,获得谐和年龄为(226±1)Ma,为印支晚期,限定长仁铜镍矿成岩成矿时代为晚三叠世,与红旗岭、漂河川、茶尖岭等矿床为同期岩浆活动的产物。结合区域内前人研究成果,认为古亚洲洋最终闭合时间为晚二叠世到早三叠世,晚三叠世已进入古亚洲洋闭合后伸展环境,长仁矿区成岩成矿大地构造背景为古亚洲洋闭合后的造山后伸展环境。 相似文献
4.
辽东青城子矿集区姚家沟钼矿床成矿物质来源、成矿年代及成矿动力学背景 总被引：1，自引：0，他引：1
本文对辽东青城子矿集区姚家沟钼矿床与成矿密切的姚家沟花岗岩进行了元素地球化学、锆石LA-ICP-MS U-Pb定年和矿床金属硫化物硫同位素系统分析。结果表明:姚家沟花岗岩侵入时代为(167.47±0.87)Ma,具有富硅、富铝、全碱含量中等、过铝质-强过铝质的特征;稀土配分模式呈现轻稀土富集、重稀土亏损的右倾型,Eu弱正异常;富集K、Rb、U、Sr、Pb等大离子亲石元素,亏损Nb、Ti、P等高场强元素,δ34S值为2.0‰~3.9‰,平均值为2.7‰。结合姚家沟矿床辉钼矿Re-Os同位素研究成果进一步得出,姚家沟岩体至少为两期岩浆活动的产物,辉钼矿成矿与本次获得的(167.47±0.87)Ma岩浆活动有关,二者成岩、成矿时代一致。硫同位素指示成矿物质来源于岩浆。姚家沟钼矿成岩、成矿构造背景为受古亚洲洋闭合影响,华北板块与西伯利亚板块后碰撞造山阶段构造-岩浆-流体活动的环境。 相似文献
5.
小狐狸山钼多金属矿床是近年来在北山地区发现的一个具中—大型规模的隐伏钼矿床. 该矿床成矿特征典型,赋矿岩体可以明显的划分为三个相带,即边缘相、过渡相和中心相。岩体中心相具强硅化、钾长石化现象,过渡相和边缘相具有明显的钠长石化蚀变特征,并叠加有岩浆期后云英岩化蚀变现象。钼矿体主要产于岩体过渡相和边缘相的钠长石化带和云英岩化带中。小狐狸山钼多金属矿床成矿时代为三叠纪, 属印支期构造-岩浆活动的产物。通过对Mo→Pb-Zn→稀有金属的复合矿化特征分析,推测该矿床可能是不同期次岩浆热液活动形成的热液叠加矿床。结合岩石地球化学、构造环境及其矿化、蚀变特征分析,该矿床应为板内伸展构造环境下形成的高-中温岩浆热液叠加型矿床。 相似文献
6.
新疆东天山地区白山钼矿床的成因分析 总被引：6，自引：1，他引：5
白山钼矿床位于东天山觉罗塔格构造带的东部,赋矿围岩为下石炭统干墩组的黑云母长英质角岩,矿化石英网脉发育.文章测得含矿石英脉中的石英流体包裹体δ18OSMOW值为9.1%O～10.0‰,平均9.425‰,与石英相平衡的水δ18OH2O值为3.357‰～4.257‰,平均为3.682‰;δDSMOW值为-105‰～- 69%,平均-89.25‰.氢氧同位素组成显示白山钼矿床的成矿流体是岩浆水与发生了水-岩作用的大气降水的混合热液,含矿流体以岩浆水为主,演化大气降水的加入是成矿物质沉淀的重要因素.测得辉钼矿的Re-Os等时线年龄为(227.7±4.3)Ma(MSWD=0.32),指示白山钼矿床形成于中三叠世.矿床地质特征和地球化学特征指示白山钼矿床是斑岩型矿床,推测成矿物质主要来自于矿体下部的矿化花岗(斑)岩体.此外,作者还探讨了白山钼矿床的成矿背景,认为矿床形成于挤压的构造环境,是受到同时代古特提斯洋闭合的陆内远程效应影响而产生的成岩成矿作用. 相似文献
7.
辽宁姚家沟钼矿床辉钼矿Re-Os同位素年龄测定及其地质意义 总被引：5，自引：1，他引：4
本文对青城子矿田姚家沟钼矿床中的8件辉钼矿样品进行Re-Os同位素分析,所获辉钼矿的模式年龄值为166.1±2.3Ma~169.1±2.5Ma,等时线年龄为168.8±3.9Ma(MSWD=1.12),代表流体成矿年龄,结合姚家沟花岗岩体已有的年代学数据,我们推测姚家沟地区可能存在多期次岩浆侵入,姚家沟钼矿床与168.8±3.9Ma 的岩浆侵入活动有关。结合区域成矿地质背景,我们推断早中侏罗纪时期,姚家沟钼矿床可能受古亚洲洋闭合的影响,是华北板块与西伯利亚板块后碰撞造山阶段构造-岩浆作用及相关流体活动的产物。 相似文献
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稻城贡巴纳岩体位于义敦岛弧碰撞造山带的南东侧。采用LA-ICP-MS的方法研究了贡巴纳岩体,结果表明岩体锆石LA-ICP-MS U-Pb表面年龄为(226.7±2.8)Ma,是印支期岩浆活动的产物。岩性组合复杂,在岩相学特征上,呈浅灰-灰白色,暗色矿物含量低,并出现褐帘石等富铝矿物。岩石地球化学特征显示:高w(SiO2)=71.24%～73.86%,低MgO、FeOT、CaO,ALK=6.47%～6.86%,A/CNK=1.04～1.07,δ=1.36～1.57,AR=4.43～4.90,属于高钾钙碱性系列过铝质花岗岩。相对富集大离子亲石元素,贫化高场强元素;Rb/Sr=0.71～0.88,w(∑REE)=159.3×10-6～190×10-6,轻稀土元素相对富集,轻重稀土元素的分馏比值较高La/Yb=12.87～16.54,δEu=0.16～0.18,总体表现为右倾型,显示与Ⅰ型花岗岩的特征相似。根据花岗岩的R1-R2,Nb-Y构造环境判别图解及区域构造演化史研究,认为该岩体形成于同碰撞构造环境,其形成与义敦岛弧带俯冲碰撞造山活动有关,即三江古特提斯洋闭合事件对接时间为三叠纪。 相似文献
9.
《现代地质》2020,(5)
大洋山斑岩型钼矿位于大兴安岭东北部呼中区,钼矿体主要产于石英二长斑岩体和上盘围岩中,产状受石英二长斑岩体控制。通过锆石LA-ICP-MS U-Pb定年,获得石英二长斑岩年龄为(119.83±0.87) Ma,可代表成矿年龄。岩石地球化学数据显示岩体偏铝、贫钛、富钾,具钾玄岩特征,为造山带岩石,岩浆熔体未与地幔相互作用;相对富集大离子亲石元素Rb和K,相对亏损高场强元素Nb、Ta、P、Ti和HREE,亲地幔元素亏损、轻稀土富集以及Eu中等亏损等特征显示岩浆源自陆壳。结合区域地质资料认为大洋山斑岩型钼矿形成于早白垩世晚期,成矿物质来源为地壳的重熔,与蒙古—鄂霍茨克洋的俯冲闭合相关,成矿环境为伸展构造背景。 相似文献
10.
吉林汪清夹皮沟斑岩型钼矿床的形成时代与成矿构造背景 总被引：2，自引：0，他引：2
夹皮沟钼矿床是吉林省汪清县近年来发现的一个中型斑岩型钼矿床.矿体赋存在受北东向断裂控制的似斑状黑云母二长花岗岩内.含矿岩体中锆石LA-ICP-MS U-Pb加权平均年龄为(193.1±1.0) Ma(MSWD=1.02),矿石中辉钼矿Re-Os等时线年龄为(188.6±4.7) Ma(MSWD=0.41),表明夹皮沟钼矿床形成于早侏罗世,与区域内其他斑岩型钼矿床(成岩成矿时代介于190～160Ma)同属于燕山早期大规模构造-岩浆-成矿事件的产物.似斑状黑云母二长花岗岩具有高硅[w(SiO2)=72.29％ ～72.81％]、富碱[w(Na2O+K2O)=7.62％ ～7.71％]的特点,属于弱过铝质的高钾钙碱性岩石系列;稀土元素分布型式呈明显的右倾型,轻、重稀土元素分馏明显(LREE/HREE为6.41～7.34),Eu异常中等(δEu=0.33 ～ 0.40);微量元素组成上表现为富集大离子亲石元素(LILE),亏损高场强元素(HFSE).似斑状黑云母二长花岗岩属于Ⅰ型花岗岩,矿床成岩成矿物质可能源于俯冲背景下增厚的下地壳.结合区域地质构造演化,认为夹皮沟钼矿形成于古亚洲洋构造体制与环太平洋构造体制叠加与转换的构造背景下,成岩成矿作用与燕山早期古太平洋板块的俯冲作用关系密切. 相似文献
11.
S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
15.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
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岩石密度和超高压岩石折返速率 总被引：1，自引：3，他引：1
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。 相似文献
18.
Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献
19.
Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA 总被引：1，自引：0，他引：1
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources. 相似文献
20.
滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床. 相似文献