U–Pb perovskite ages for brazilian kamafugitic rocks: further support for a temporal link to a mantle plume hotspot track     

Patrícia B. A. Sgarbi  Larry M. Heaman  Jos Carlos Gaspar 《Journal of South American Earth Sciences》2004,16(8):95

We present the results of a U–Pb perovskite age study of kamafugites from Mata da Corda (MC) and Santo Antônio da Barra (SAB), Minas-Goiás alkaline province, Brazil. Perovskite crystals were separated from MC mafurites, ugandites, and cognate pyroxenites, as well as from SAB melilite mafurite. The range of ages of Brazilian kamafugitic samples is 15 Ma. The ²⁰⁶Pb/²³⁸U perovskite ages generally cluster into three age groupings: 88–90, 80–81, and 75–76 Ma. The two younger periods of kamafugitic magmatism occur in the MC area, whereas the older samples are from the SAB area. These new age results provide the first robust evidence of a progressive eastward younging of mafic alkaline magmatism, most likely related to a mantle plume hotspot track.  相似文献   

Emplacement of kamafugite lavas from the Goiás alkaline province,Brazil: constraints from whole-rock simulations     

《Journal of South American Earth Sciences》2005,18(3-4):323-335

The Late Cretaceous Goiás alkaline province (GAP) is composed of alkaline plutonic bodies (north), diatremes with subordinate flows, dykes, and plugs (central), and dominant lava flows and pyroclastics (south). In this work, we describe field and petrographic aspects of coherent kamafugites from Santo Antônio da Barra in the southern GAP and Águas Emendadas in the central GAP. Intensive variables inferred from simulations using whole-rock chemical data constrain the behavior of these kamafugitic magmas from their origin in the mantle to their final emplacement as upper-crust magma chambers, diatreme structures, and lava flows. In most cases, the evidence indicates that differentiation in both deep- and shallow-seated magma chambers intervened in their evolution. The discordance between the Precambrian basement and the Phanerozoic sedimentary rocks is the most likely site where the shallow chambers were established, whereas the deeper chambers were probably located in the upper crust. CO₂ seems to be the most important volatile phase. An interplay of various possible evolution paths involving crystal fractionation, magma mixing, and liquid immiscibility may explain the range of observed features in GAP kamafugites.  相似文献   

我国东北小古里河-科洛-五大连池-二克山火山带钾质矿物成因及地质意义   总被引：3，自引：2，他引：1  

李霓  张柳毅  赵勇伟  曹园园  盘晓东 《岩石学报》2012,28(4):1173-1180

东北黑龙江小古里河-科洛-五大连池-二克山火山岩带是我国近代保存最好的火山群之一,此带火山岩的岩石化学特点全都强碱富钾,K₂O/Na₂O>1.2,属于一套高钾过碱性火山岩。通过对东北钾质火山岩及金云母橄榄岩地幔捕虏体中钾质矿物金云母、白榴石的成分、结晶环境与岩浆成分及来源关系的研究,认为在岩石圈伸展构造背景下,地幔金云母橄榄岩的低度部分熔融形成钾质岩浆,钾质岩浆上升到地壳浅部经历了白榴石的结晶作用。岩浆演化晚期,因钾质矿物大量晶出导致岩浆相对富钠而出现他形霞石和方钠石等填隙矿物。火山岩及地幔捕虏体中富挥发分矿物金云母、白榴石、磷灰石、霞石和方钠石还提供了钾质岩浆富含H₂O、F、Cl、P等挥发分的证据。  相似文献   

Geochemical exploration of a Precambrian Batholith, source of a Cu-W mineralization of the tourmaline breccia in Southern Finland     

Gabor Gal  Kai Front  Kristiina Aro 《Journal of Geochemical Exploration》1981,15(1-3)

The Hämeenkyrö batholith is a round-shaped plutonic body of an areal size of 147 km². It is composed of calc-alkaline to alkaline rocks that intruded previously metamorphosed Svecofennian volcanogenic and sedimentary schists 1860 Ma ago. The Cu-W bearing tourmaline breccia of the Ylörvi deposit occurs in metavolcanic rocks close to the eastern contact of the batholith.The average sampling density in the batholith was 1 sample per km², and 175 samples were analyzed for Cu, Au, Ag, Ni, Pb, Co, Zn, S by AAS for SiO₂, TiO₂, Al₂O₃, FeO, MnO, MgO, CaO, Na₂O, K₂O, As, Sn and P by X-ray fluorescence. Mo and W were determined colorimetrically. Barth mesonorms were calculated for each sample and the rock type was determined according to Streckeisen's classification. Element distributions are displayed on contour maps.The rock types of the batholith exhibit an asymmetric concentric arrangement, the order from the center towards the margin being alkali-feldspar granite, syenogranite, monzogranite, quartz monzonite, quartz syenite, alkali-feldspar, quartz syenite, syenite and alkali-feldspar syenite. Anomalously high Cu, As, Sn, S, K₂O and Na₂O contents have been found at the eastern margin of the batholith in a N—S-trending zone, which is characterized by hydrothermal alteration phenomena, propylitization, tourmalinization and scapolitization. Three anomalous areas have been defined within this zone, one of them is associated with the Ylöjärvi deposit and the other two are regarded as exploration targets.  相似文献   

Intergrowths of nepheline-potassium feldspar and kalsilite-potassium feldspar: A re-examination of the ‘pseudo-leucite problem’     

J. Gittins  J. J. Fawcett  C. K. Brooks  J. C. Rucklidge 《Contributions to Mineralogy and Petrology》1980,73(2):119-126

The alkalic ultramafic Batbjerg intrusion of East Greenland contains rocks in which nepheline and leucite are important constituents. In addition, there are vermicular, finger print intergrowths of nepheline with potassium feldspar, and patchy to micrographic intergrowths of kalsilite with potassium feldspar. The history of the pseudoleucite problem is reviewed, and it is suggested that the term pseudoleucite be restricted to intergrowths of nepheline with alkali feldspar that appear to be pseudomorphs with the crystal morphology of leucite. It is further suggested that flame-like or feather-like finger print intergrowths of nepheline with alkali feldspar, that are either interstitial to the other minerals of the rock or have grown perpendicularly on relative large and often euhedral nepheline grains are an entirely different problem and are best explained by late-stage magmatic crystallization within the system NaAlSiO₄-KAlSiO₄-SiO₂-H₂O.In the Batbjerg intrusion the early crystallization of nepheline was followed by the co-crystallization of nepheline with leucite, or in some cases by nepheline and a silica-rich leucite. Although the magma was essentially dry, as indicated by the dominantly pyroxenitic character of the rocks, water pressure rose toward the late stages of crystallization as indicated by the presence of phlogopite and occasionally both amphibole and zeolite. Shrinkage of the leucite stability field attendant upon this rise in left the liquid that was crystallizing nepheline and leucite stranded on the nepheline-alkali feldspar cotectic. Shrinkage occurred too rapidly for the liquid to remain at the reaction point of the system, and leucite, therefore, was not resorbed. The remaining liquid crystallized rapidly as flames of vermicular intergrowth of nepheline with potassium feldspar (composition Ne 24.0, Ks 45.9, Qz 30.1), a texture that might be attributable to supercooling. Silica-rich leucite compositions (Ks 68.8, Qz 31.2) decomposed to intergrowths of kalsilite with potassium feldspar but reaction kinetics, or possibly variations in throughout the intrusion, prevented the breakdown of leucite.  相似文献   

A basalt-trachyte-phonolite series from Ua Pu,Marquesas Islands,Pacific Ocean     

Arthur Clive Bishop  Alan Robert Woolley 《Contributions to Mineralogy and Petrology》1973,39(4):309-326

The paper describes a suite of volcanic and intrusive rocks from Ua Pu, one of the Marquesas Islands, situated in the central Pacific Ocean. The rocks comprise alkali olivine basalts, hawaiites, mugearites, trachytes, and phonolites. Their petrographic characters are briefly described and 24 new chemical analyses presented. The rocks fall into a sodic and a potassic series, since some rocks are richer in K₂O than Na₂O, whilst the phonolites have exceptionally high total alkali contents.The differentiation of the series is discussed and special attention is paid to the phonolites in which icositetrahedral pseudomorphs occur. It is concluded that these pseudomorphs are probably after analcime rather than leucite.  相似文献   

青海南部沱沱河冻土水合物潜在区火山岩地球化学特征及地质意义          下载免费PDF全文

谭盼盼  卢振权  蔡俊军  王婷  唐世琪 《沉积与特提斯地质》2016,36(2):87-96

沱沱河盆地是冻土天然气水合物潜在分布区之一,其内发育下—中二叠统开心岭群九十道班组、上二叠统乌丽群那益雄组、上三叠统结扎群巴贡组、中—渐新统雅西措组4套烃源岩以及不同类型的火山岩。研究表明,火山岩岩石类型主要为玄武岩、玄武安山岩、安山岩、玄武质粗面安山岩和粗面安山岩。火山岩主量元素低TiO_2,Al_2O_3含量较高,K_2O含量较低,K_2ONa_2O;火山岩的稀土元素配分模式为轻稀土富集型;微量元素配分模式呈锯齿状,Ta、Nb、P_2O_5、TiO_2、Y、Yb以及铁族元素Sc、Cr、Ni亏损,综合判断青海南部沱沱河地区火山岩形成于岛弧环境。结合火山岩的地球化学特征,推断火山活动可以加快烃源岩的热成熟,进而促使有机质裂解,产生热解气,为水合物的生成提供气源条件。同时,火山岩的气孔构造发育,连通性较好,有可能成为水合物的储层。火山热液具有的高压使周围的烃源岩产生裂隙,这些裂隙不仅是水合物气源的运移通道,还可以为水合物提供形成场所和储存空间。  相似文献   

Geochemistry constraints of Mesozoic–Cenozoic calc-alkaline magmatism in the South Shetland arc, Antarctica   总被引：1，自引：0，他引：1  

A. Machado  E.F. Lima  F. Chemale  Jr.  D. Morata  O. Oteiza  D.P.M. Almeida  A.M.G. Figueiredo  F.M. Alexandre  J.L. Urrutia 《Journal of South American Earth Sciences》2005,18(3-4):407-425

Geochemical data from basalts, basaltic andesites, and andesites of the Mesozoic–Cenozoic (143–44 Ma) from Livingston, Greenwich, Robert, King George, and Ardley Islands of the South Shetland archipelago, Antarctica, are presented. The rocks have variable SiO₂ of approximately 46–61 wt%, Al₂O₃ of 15–26 wt%, and total alkali (K₂O+Na₂O) of 2–6 wt%. Most samples have low Mg#, Cr, and Ni, which indicates that they have undergone significant fractional crystallization from mantle-derived melts. The presence of olivine cumulatic in the samples from Livingston and Robert Islands explains some high MgO, Ni, and Cr values, whereas low Rb, Zr, and Nb values could be related to undifferentiated magmas. N-MORB-normalized trace element patterns show that South Shetland Islands volcanic rocks have a geochemical pattern similar to that found for other island arcs, with enrichment in LILE relative to HFSE and in LREE relative to HREE. The geochemistry pattern and presence of calcic plagioclase, orthopyroxene, Mg-olivine, and titanomagnetite phenocrysts suggest a source related to the subduction process. The geochemical data also suggest magma evolution from the tholeiitic to the calc-alkaline series; some samples show a transitional pattern. Samples from the South Shetland archipelago show moderate LREE/HREE ratios relative to N-MORB and OIB, depletion in Nb relative to Yb, and high Th/Yb ratios. These patterns probably reflect magma derived from a lithospheric mantle source previously modified by fluids and sediments from a subduction zone.

Resumo

Dados geoquímicos de basaltos, andesitos basálticos e andesitos mesozóicos–cenozóicos (143–44 Ma) das ilhas Livingston, Greenwich, Robert, King George e Ardley do Arquipélago Shetland do Sul, Antártica são discutidas neste artigo. As rochas tem conteúdos de SiO₂ variando de 46 a 61%, Al₂O₃ de 15 a 26% e álcalis (K₂O+Na₂O) de 2 a 6%. A maior parte das amostras tem conteúdos baixos de Mg#, Cr e Ni, indicando que sofreram significante cristalização fracionada de fusões derivadas do manto. A presença de fases cumuláticas nas amostras das ilhas Livingston e Robert explicaria os elevados valores de MgO, Ni, Cr, enquanto que baixos valores de Rb, Zr e Nb observados nas amostras destas ilhas poderiam estar relacionados a magmas não diferenciados. Os padrões de elementos-traço normalizados pelo N-MORB mostram que as rochas vulcânicas das Ilhas Shetland do Sul têm padrão geoquímico similar àqueles encontrados em outros arcos de ilhas com enriquecimento em LILE em relação aos HFSE e em ETRL em relação aos ETRP. O padrão geoquímico e a ocorrência de fenocristais de plagioclásio cálcico, ortopiroxênio, olivina magnesiana e titanomagnetita sugerem origem relacionada a processos de subducção. Dados geoquímicos obtidos para as amostras do arquipélago Shetland do Sul sugerem um magma evoluindo de toleítico para cálcico-alcalino, observando-se em algumas amostras um padrão transicional. As amostras do arquipélago Shetland do Sul mostram em relação ao N-MORB e OIB, moderadas razões ETRL/ETRP, empobrecimento em Nb relativo a Yb e elevada razão Th/Yb Estes padrões refletem, provavelmente, magma derivado de uma fonte mantélica litosférica, que foi modificada por fluídos e sedimentos da zona de subducção.  相似文献   

安徽庐枞盆地酸性蚀变岩帽地质地球化学特征研究   总被引：5，自引：4，他引：1  

李旋旋  张乐骏  高昌生  谢杰  Noel C WHITE 《岩石学报》2017,33(11):3545-3558

酸性蚀变岩帽是浅成低温热液系统演化的产物,形成于酸性高氧化性流体的化学条件下;在高硫化型浅成低温热液金矿床中广泛发育,是该类矿床的显著识别特征。通过对酸性蚀变岩帽的野外地质特征、矿物共生组合和地球化学特征研究,能较好阐明浅成低温成矿热液系统的特征、性质、发生和发展演化及成矿作用过程。庐枞矿集区是长江中下游成矿带重要的矿集区之一,盆地内广泛发育以明矾石为特征蚀变矿物的酸性蚀变岩帽,面积超过30km~2,指示盆地内高硫化浅成低温热液系统的存在。目前为止,前期工作主要针对明矾石矿床地质特征和明矾石资源储量进行,该酸性蚀变岩帽的地质地球化学特征研究尚未开展。本次工作通过对酸性蚀变岩帽系统的野外采样、全岩地球化学分析和短波红外光谱测试分析技术(PNIRS测试)分析,确定其主要赋存在砖桥组火山岩中,组成矿物为石英、明矾石、高岭石、地开石,此外有少量绢云母、伊利石、珍珠陶土、叶蜡石、褐铁矿,极少数的叶腊石和黄钾铁矾等,在钻孔深部存在浸染状和半自形粒状黄铁矿。由于受到地表风化剥蚀和不同热热中心的影响,水平方向从矾山明矾石矿床向外围发育石英+明矾石带、石英+高岭石/地开石+明矾石带、石英+高岭石/地开石带、硅化带以及最外围的泥质带即高岭石±绢云母±伊利石带。根据酸性蚀变岩帽的矿物组合和主量元素特征,可将其分为三类:硅质蚀变岩、明矾石蚀变岩和粘土蚀变岩。硅质蚀变岩中SiO_2含量发生明显的富集作用,其余主量元素(K_2O、Na_2O、Al_2O_3、Fe_2O_3、P_2O5)含量显著降低;明矾石蚀变岩和粘土蚀变岩具有相似的地球化学特征,SiO_2、Al_2O_3、Fe_2O_3、P_2O_5元素含量范围变大,K_2O和Na_2O含量降低,且Na_2O降低更加明显;而钛为不活泼元素,在岩石发生蚀变过程中TiO_2含量变化很小。矾山地区的酸性蚀变岩帽的产状、蚀变类型、地球化学特征受构造和地层的双重控制。  相似文献   

Petrography and mineral chemistry of Alkaline-Carbonatite Complex in Singhbhum Crustal Province,Purulia region,Eastern India     

S. K. Basu  T. Bhattacharyya 《Journal of the Geological Society of India》2014,83(1):54-70

The variant rock types of an Alkaline-Carbonatite Complex (ACC) comprising alkali pyroxenite, nepheline syenite, phoscorite, carbonatite, syenitic fenite and glimmerite along with REE and Nb-mineralization are found at different centres along WNW-ESE trending South Purulia Shear Zone (SPSZ) in parts of Singhbhum Crustal Province. The ACC occurs as intrusions within the Mesoproterozoic Singhbhum Group of rocks. Alkali pyroxenite comprises of aegirine augite, magnesiotaramite, magnesiokatophorite as major constituents. Pyrochlore and eucolite are ubiquitous in nepheline syenite. Phoscorite contains fluorapatite, dahllite, collophane, magnetite, hematite, goethite, phlogopite, calcite, sphene, monazite, pyrochlore, chlorite and quartz. Coarse fluorapatite shows overgrowth of secondary apatite (dahllite). Secondary apatite is derived from primary fluorapatite by solution and reprecipitation. The primary fluorapatite released REE to crystallize monazite grains girdling around primary apatite. Carbonatite is composed dominantly of Srcalcite along with dolomite, tetraferriphlogopite, phlogopitic biotite, aegirine augite, richterite, fluorapatite, altered magnetite, sphene and monazite. The minerals comprising of the carbonatite indicate middle stage of carbonatite development. Fenite is mineralogically syenite. Glimmerite contains 50–60% tetraferriphlogopite. An alkali trend in the evolution of amphiboles (magnesiotaramite-magnesiokatophorite-richterite) and chinopyroxenes (aegirine augite, aegirine) during the crystallization of the suite of rocks is noted. Monazite is the source of REE in phoscorite and carbonatite. Fluorapatite has low contents of REE, PbO, ThO₂ and UO₂. Pyrochlore reflects Nb-mineralization in nepheline syenite and it is enriched in Na₂O, CaO, TiO₂, PbO and UO₂. Pyrochlore containing UO₂ (6.605%) and PbO (0.914%) in nepheline syenite has been chemically dated at 948 ± 24 Ma by EPMA.  相似文献   

The geochemistry and origin of quaternary volcanism in the New Hebrides     

M.P. Gorton 《Geochimica et cosmochimica acta》1977,41(9):1257-1270

Analyses of young volcanic rocks from the New Hebrides reveal the existence of two geochemical groups which may be identified on the basis of their contents of K₂O and related trace elements. Low K₂O rocks are believed to be comparable with conventional island arc volcanism, whereas the high K₂O rocks are believed to be related to volcanism associated with tensional rifting. By comparison with high pressure experimental data it is concluded that these rocks can be derived by partial melting of hydrous mantle above the Benioff zone. However this mantle must have different concentrations of incompatible elements from the source of ocean ridge tholeiites, and residual minerals must have RE partition coefficients which differ from those of phenocrysts in volcanic rocks.  相似文献   

Late Devonian and Triassic basalts from the southern continental margin of the East European Platform,tracers of a single heterogeneous lithospheric mantle source     

Françoise Chalot-Prat  Petr Tikhomirov  Aline Saintot 《Journal of Earth System Science》2007,116(6):469-495

In Late Devonian and Early-to-Late Triassic times, the southern continental margin of the Eastern European Platform was the site of a basaltic volcanism in the Donbas and Fore-Caucasus areas respectively. Both volcanic piles rest unconformably upon Paleoproterozoic and Late Paleozoic units respectively, and emplaced during continental rifting periods some 600 km away from expected locations of active oceanic subduction zones. This paper reports a comparative geochemical study of the basaltic rocks, and views them as the best tracers of the involved mantle below the Eastern European Platform. The Late Devonian alkaline basic rocks differ from the calc-alkaline Triassic basic rocks by their higher alkali-silica ratio, their higher TiO₂, K₂O, P₂O₅ and FeO contents, their higher trace element contents, a higher degree of fractionation between the most and the least incompatible elements and the absence of Ta-Nb negative anomalies. These general features, clearly distinct from those of partial melting and fractional crystallization, are due to mantle source effects. With similar Nd and Sr isotopic signatures indicating mantle-crust mixing, both suites would originate from the melting of a same but heterogeneous continental mantle lithosphere (refertilized depleted mantle). Accordingly the Nd model ages, the youngest major event associated with mantle metasomatism occurred during Early Neoproterozoic times (∼650Ma).  相似文献   

Chemical composition,volatile components,and trace elements in the melts of the Gorely volcanic center,southern Kamchatka: Evidence from inclusions in minerals   总被引：1，自引：0，他引：1  

M. L. Tolstykh  V. B. Naumov  M. G. Gavrilenko  A. Yu. Ozerov  N. N. Kononkova 《Geochemistry International》2012,50(6):522-550

Melt inclusions in olivine and plagioclase phenocrysts from rocks (magnesian basalt, basaltic andesite, andesite, ignimbrite, and dacite) of various age from the Gorely volcanic center, southern Kamchatka, were studying by means of their homogenization and by analyzing the glasses in 100 melt inclusions on an electron microprobe and 24 inclusions on an ion probe. The SiO₂ concentrations of the melts vary within a broad range of 45–74 wt %, as also are the concentrations of other major components. According to their SiO₂, Na₂O, K₂O, TiO₂, and P₂O₅ concentrations, the melts are classified into seven groups. The mafic melts (45–53 wt % SiO₂) comprise the following varieties: potassic (on average 4.2 wt % K₂O, 1.7 wt % Na₂O, 1.0 wt % TiO₂, and 0.20 wt % P₂O₅), sodic (3.2% Na₂O, 1.1% K₂O, 1.1% TiO₂, and 0.40% P₂O₅), and titaniferous with high P₂O₅ concentrations (2.2% TiO₂, 1.1% P₂O₅, 3.8% Na₂O, and 3.0% K₂O). The melts of intermediate composition (53–64% SiO₂) also include potassic (5.6% K₂O, 3.4% Na₂O, 1.0% TiO₂, and 0.4% P₂O₅) and sodic (4.3% Na₂O, 2.8% K₂O, 1.3% TiO₂, and 0.4% P₂O₅) varieties. The acid melts (64–74% SiO₂) are either potassic (4.5% K₂O, 3.6% Na₂O, 0.7% TiO₂, and 0.15% P₂O₅) or sodic (4.5% Na₂O, 3.1% K₂O, 0.7% TiO₂, and 0.13% P₂O₅). A distinctive feature of the Gorely volcanic center is the pervasive occurrence of K-rich compositions throughout the whole compositional range (silicity) of the melts. Melt inclusions of various types were sometimes found not only in a single sample but also in the same phenocrysts. The sodic and potassic types of the melts contain different Cl and F concentrations: the sodic melts are richer in Cl, whereas the potassic melts are enriched in F. We are the first to discover potassic melts with very high F concentrations (up to 2.7 wt %, 1.19 wt % on average, 17 analyses) in the Kuriles and Kamchatka. The average F concentration in the sodic melts is 0.16 wt % (37 analyses). The melts are distinguished for their richness in various groups of trace elements: LILE, REE (particularly HREE), and HFSE (except Nb). All of the melts share certain geochemical features. The concentrations of elements systematically increase from the mafic to acid melts (except only for the Sr and Eu concentrations, because of active plagioclase fractionation, and Ti, an element contained in ore minerals). The paper presents a review of literature data on volcanic rocks in the Kurile-Kamchatka area in which melt inclusions with high K₂O concentrations (K₂O/Na₂O > 1) were found. K-rich melts are proved to be extremely widespread in the area and were found on such volcanoes as Avachinskii, Bezymyannyi, Bol’shoi Semyachek, Dikii Greben’, Karymskii, Kekuknaiskii, Kudryavyi, and Shiveluch and in the Valaginskii and Tumrok Ranges.  相似文献   

First data on composition of the volcanic rocks of the IVS 50th anniversary Fissure Tolbachik eruption (Kamchatka)     

A. O. Volynets  D. V. Melnikov  A. I. Yakushev 《Doklady Earth Sciences》2013,452(1):953-957

First data on major, minor and trace element (XRF. 1CP-MS) concentrations in the volcanic rocks of the IVS 50th anniversary Fissure Tolbachik eruption are reported for the period from 27.11.2012 to 25.01.2013; scheme of lava flows distribution by March 2013 is made. The volcanic rocks of the new eruption are substantially different from the other studied volcanic rocks of Tolbachinsky Dol by their higher alkalis and incompatible elements content. The rocks of the first three days of eruption (Menyailov Vent) have higher silica and alkalis content than all previously reported volcanic rocks of Tolbachinsky Dol. Volcanic rocks of the Naboko Vent, at silica content similar to high-Al basalts of Tolbachinsky Dol, have different concentrations of trace elements and some major elements (K₂O, CaO, TiO₂, P₂O₅). REE and other incompatible element concentrations in the rocks of the Menyailov Vent are higher than in the rocks of the Naboko Vent at the same element ratios. The differences of the volcanic rocks of the two vents of the new eruption may be caused by the fact that the erupted lavas came from the different levels of the same magma chamber.  相似文献   

Liquidas phase relationships in the system CaAl2Si2O8-NaAlSi3O8-KAlSi3O8-NaAlSiO4-KAlSiO4 atP(H2O)=5 kb     

Rhian H. Jones  W. S. MacKenzie 《Contributions to Mineralogy and Petrology》1989,102(1):78-92

Liquidus phase equilibria have been determined in the system CaAl₂Si₂O₈-NaAlSi₃O₈-KAlSi₃O₈-NaAlSiO₄-KAlSiO₄ (An-Ab-Or-Ne-Ks) at a pressure of water of 5 kb, for low anorthite contents. The main effects of increasing anorthite content on phase relationships in the system Ab-Or-Ne-Ks include the expansion of the plagioclase stability field towards the potassium-rich part of the system, and an accompanying contraction of the alkali feldspar, leucite, nepheline and kalsilite stability fields; and an increase in liquidus temperatures throughout most of the compositional range. Two quaternary invariant points have been identified in the system, one a reaction point between the fields of alkali feldspar, plagioclase, nepheline and kalsilite at approximately An₄, and the other probably a quaternary eutectic between the fields of alkali feldspar, plagioclase, leucite and kalsilite at approximately An₆. A shallow minimum trough in liquidus temperatures occurs on the two-feldspar surface, and this would be expected to control the paths of liquids cooling under equilibrium conditions. Phase relationships in this quaternary system have been applied to the interpretation of the histories of the potassium-rich rocks of the Roman Volcanic Region, Italy. Differentiation of the phonolitic series in this region may have occurred by two-feldspar fractionation.  相似文献   

Geochemistry of the Ilesha granite gneiss in the basement complex of southwestern Nigeria     

Anthony Azubuike Elueze 《Precambrian Research》1982,19(2):167-177

The Ilesha granite gneiss comprises a varied series ranging from porphyroblastic alkali gneiss and granitic gneiss to banded and strongly foliated melanocratic rocks. Deformation is intense and the dominant structural trend is approximately N-S.Chemical data show essentially a systematic variation reflecting the differences in the petrographic character of the outcrops. SiO₂, Na₂O, K₂O and related trace elements, particularly Rb, are higher in the alkali and granitic varieties, whereas the melanocratic types have lower contents of these elements. The basic rocks are likewise significantly enhanced in TiO₂, Fe, MgO, CaO, Cr and Ni concentrations, with some values being comparable to those of basaltic rocks.  相似文献   

Age and origin of a Palaeozoic nepheline syenite from northern Shanxi Province,China: U–Pb zircon age and whole-rock geochemical and Sr–Nd isotopic constraints     

《International Geology Review》2012,54(11):1296-1308

Geochronological, geochemical, and whole-rock Sr–Nd isotopic analyses were performed on a suite of Palaeozoic nepheline syenites from Zijinshan to characterize their ages and petrogenesis. Laser ablation inductively coupled plasma-mass spectrometry U–Pb zircon analyses yield consistent ages of 525.7 ± 2.8 million years for a sample (HYK01). These intrusive rocks belong to the foid syenite magma series in terms of K₂O?+?Na₂O contents (14.3–15.2 wt.%) and to the shoshonitic series based on their high K₂O contents (5.42–5.61 wt.%). The nepheline syenites are further characterized by high light rare earth element contents [(La/Yb) _N ?=?29.1–36.1]; show modest negative Eu anomalies (δEu?=?0.5–0.6) and positive anomalies in Rb, Th, U, Pb, Zr, and Hf; are depleted in Ba and high field strength elements (P and Ti). In addition, all the nepheline syenites in this study display relatively low radiogenic Sr (⁸⁷Sr/⁸⁶Sr) _i (0.7042–0.7043) and positive ?_Nd (t) (0.7–0.8). These results suggest that the nepheline syenites were derived from depleted continental crust. The parent magmas likely experienced fractional crystallization of plagioclase, Ti-bearing oxides (e.g. rutile, ilmenite, and titanite), apatite, and zircon during ascent, with negligible crustal contamination before final emplacement at a high crustal level.  相似文献   

Geochemistry of sediments from Lake Grand,Northeast Russia     

P. S. Minyuk  V. Ya. Borkhodoev 《Geochemistry International》2016,54(9):807-816

Major and trace element distribution in the bottom sediments from Hole 13 drilled in Lake Grand, Magadan district, was studied using the method of principal components. It was established that geochemical characteristics are correlated with environmental changes. The sediments of cold MIS2 and MIS4 are characterized by the enriched TiO₂, MgO, Al₂O₃, Fe₂O₃, and Cr and low Na₂O, K₂O contents, which is related to the grain-size composition of sediments. Sediments of warm stages show an opposite tendency. High concentration peaks of iron, phosphorus, and manganese correspond to the accumulation levels of vivianite and ferromanganese rocks. Silica is represented by biogenic and abiogenic varieties. Maximum SiO₂ contents were found in the Late Holocene sediments and mark the high biological productivity of the basin. Revealed variations of some elements are correlated with the Heinrich events.  相似文献   

Aspects of the geology, petrology and chemistry of some Angolan carbonatites   总被引：1，自引：0，他引：1  

A. Issa Filho  A.B.R.M.D. Dos Santos  B.F. Riffel  F.E.V. Lapido-Loureiro  I. McReath   《Journal of Geochemical Exploration》1991,40(1-3)

Using published data and the results of a new study, the main characteristics of seven Angolan carbonatite complexes are here presented. With the exception of the Lupongola complex which intrudes anorthosites, the remaining complexes are hosted by Precambrian silicic rocks. The complexes are of central or dike type and are well exposed. They represent some of the seven morpholithological types present in the province and have some intermediate lithochemical features between those of Brazilian and East African examples.Sovites at Lupongola are the richest in Sr and F, and also have the highest CaO/MgO and La/Y ratios of all sovites studied. Carbonatites from Bonga and Bailundo are the richest in P₂O₅, while those from Coola and Longonjo are the richest in BaO. Ferrocarbonatites from Bailundo and Virulundo have the highest REE contents. TiO₂ contents are usually low. Only Bonga carbonatites show well-defined variation between Ba and Mn contents and the index CaO/(CaO+Fe₂O₃+FeO+MnO+MgO).The CO₂-SiO₂-(Al₂O₃+Na₂O+K₂O) diagram distinguishes silicified carbonatites, feldspar-bearing carbonatites in which the main silicate mineral is K-feldspar, carbonatites and fenites. Potassic fenitization of country rocks is well developed at Bailundo, Bonga and Virulundo, and probably it also affected cogenetic nepheline syenites at Tchivira and Monte Verde.Fluorcarbonates of Ca and REE are encountered in all chemical varieties of carbonatites, and crystallized during late stages of rock formation. They have a strong influence both on total REE contents and on the slopes of chondrite-normalized patterns. Fluorapatite and pyrochlore are other important potential REE host minerals in the rocks studied. The REE patterns usually have discrete negative Ce anomalies, and sometimes show very discrete negative Eu anomalies. Apart from these anomalies, some rocks have very near-linear patterns, but most show inflections, which may occur between light and middle, and between middle and heavy REE. The origins of these variations are still uncertain.Other aspects of rock geochemistry show that, while some features could be explained by crystal fractionation differentiation processes, late-stage or secondary chemical modifications were widespread.  相似文献   

青藏米巴勒地区中新世钠质方沸石(霞石)响岩中单斜辉石环带研究:对岩浆-构造演化的启示   总被引：5，自引：3，他引：2  

赵文霞  于丽芳  陈建林  郭倩  王保弟 《岩石学报》2011,27(7):2073-2082

在拉萨地块中部米巴勒地区产出的中新世钠质方沸石(霞石)响岩中的单斜辉石发育大量环带结构,环带结构包括正环带、反环带和韵律环带。其中正环带结构从核部到边部Mg^#、MgO、Cr₂O₃呈逐渐降低趋势,而FeO、Na₂O、Al₂O₃、TiO₂呈逐渐升高的趋势,它反映了岩浆正常结晶的历史。反环带结构中Mg^#、MgO、Cr₂O₃从核部到边部呈升高的趋势,FeO、Na₂O、Al₂O₃的含量总体上呈降低趋势,本文认为响岩中单斜辉石的这种环带结构是受到了和它共存的钾质-超钾质火山岩岩浆混合或混染所致,两种岩石应是各自独立的母岩浆的结晶产物。具韵律环带结构的单斜辉石从核部到边部出现成分规律性波动,Na₂O、Al₂O₃、TiO₂、Cr₂O₃含量的变化在正反环带的范围内,Mg^#值的变化范围较小,在正环带斑晶和基质的范围内,它是岩浆多次混合作用的结果。该地区钠质过碱性岩的出现可能指示青藏高原在这套火山岩喷发时(13~12Ma),构造体制发生了显著的改变,进入到一个典型的陆内伸展阶段。  相似文献