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1.
拉萨地块松多榴辉岩主要矿物组合为石榴子石、绿辉石、角闪石、多硅白云母、绿帘石、金红石。石榴子石环带不明显,核部成分均一,从核部到边部,镁铝榴石和钙铝榴石含量降低,可能分别记录了榴辉岩峰期及退变质过程信息。绿辉石显示微弱的成分环带,硬玉含量从核部到边部略有升高,部分绿辉石边部发育韭闪石退变质边,反映了在减压过程中外来流体进入体系的过程。多硅白云母具有高的Si含量(3.5~3.6),其中石榴石包体中的多硅白云母相对基质中的白云母有更高的Si值。本文利用Thermocalc变质相平衡模拟软件,结合详细岩相学观察,在NCKMn FMASHTO体系下,模拟松多含多硅白云母榴辉岩的变质演化过程。其中,榴辉岩峰期矿物组合为g+o+law+phn+ru,石榴石核部最大镁铝榴石值和石榴子石包体中多硅白云母最大Si值确定的榴辉岩峰期温压条件约为620℃,32×105Pa,榴辉岩经历了近等温降压的退变质过程。相平衡模拟结果表明拉萨地块松多榴辉岩经历了超高压变质作用过程,并经历了相对快速的折返过程到中部地壳层次。 相似文献
2.
柴达木盆地北缘大柴旦和锡铁山榴辉岩中石榴子石环带对比及地质意义 总被引：14，自引：4，他引：14
大柴旦榴辉岩和锡铁山榴辉岩同为柴达木盆地北缘高压—超高压变质带的组成部分,但它们的岩相学特征、形成的PT条件及榴辉岩中石榴子石中保存的成分环带均具有明显的差异。大柴旦榴辉岩峰期变质的PT条件为T=620～730℃,P=2.3～2.8GPa,岩相学研究表明其经历了近等温降压或降温降压的后榴辉岩相历史,保存有进变质的矿物组合和石榴子石的生长环带及增生结构。相反,锡铁山榴辉岩的榴辉岩相的温度较高,岩相学研究显示其具有明显的后榴辉岩相的高温麻粒岩相的叠加,PT轨迹显示压力峰期早于温度峰期,具有略升温降压的后榴辉岩相变质历史,榴辉岩中石榴子石的成分环带表现为扩散环带,没有生长环带保留。大柴旦榴辉岩和锡铁山榴辉岩的不同的石榴子石环带特征反映了两者在形成过程中,特别是折返过程中不同的构造热历史。 相似文献
3.
造山带中的高级变质岩是研究造山带形成和演化历史的重要窗口.西秦岭北缘秦岭杂岩主要由正片麻岩、副片麻岩、少量变基性岩（基性麻粒岩）和大理岩组成.岩相学、矿物化学和相平衡模拟结果表明副片麻岩经历了3个变质演化阶段:（1）进变质阶段,以石榴子石核部包裹细粒片状黑云母和大小不等的石英为代表;（2）峰期变质阶段,矿物组合为石榴子石+斜长石+钾长石+夕线石+黑云母+金红石+石英.石榴子石变斑晶幔部成分在视剖面图上确定出峰期温压条件为T=793~803 ℃,P=8.8~9.5 kbar;（3）降温降压的退变质阶段,主要由石榴子石的最边部及后期斜长石记录.结合已有研究资料,表明西秦岭北缘秦岭杂岩可能经历了早古生代晚期与碰撞造山作用有关的变质作用与深熔作用. 相似文献
4.
北苏鲁荣成地区超高压变质带大理岩中的退变质石榴辉石岩包裹体具有“核-幔-边”结构,核部主要由石榴子石与单斜辉石组成,幔部含有由细小角闪石与绿帘石组成的后成合晶以及颗粒较大的角闪石与单斜辉石,通过详细的岩相学分析以及矿物成分分析,认为这些后成合晶是由石榴子石、单斜辉石以及来自围岩的流体共同反应而产生,大颗粒的角闪石主要是由辉石转变而来的,在幔部这个转变并不彻底,仍有一些残余辉石颗粒。边部主要由角闪石和绿帘石组成。该石榴辉石岩曾经历榴辉岩相超高压变质阶段。没有柯石英超高压代表性矿物（采样处的其他类型岩石都含有柯石英）的原因是石榴辉石岩的原岩为超基性岩。 相似文献
5.
新疆西南天山哈布腾苏河高压-超高压变质带中榴辉岩和蓝片岩的岩石学及变质演化 总被引：1，自引：0，他引：1
对西南天山哈布腾苏河一带出露的典型榴辉岩和蓝片岩进行了详细的岩相学、矿物化学和温压条件综合研究。榴辉岩可分为蓝闪石榴辉岩、钠云母榴辉岩、绿帘石榴辉岩和蓝闪石榴角闪岩(退变榴辉岩)4类,蓝片岩可分为含蓝闪石石榴白云母钠长片岩、石榴白云母蓝闪片岩和石榴白云母蓝闪石英片岩3类。新鲜榴辉岩主要矿物组合为石榴石+绿辉石+钠云母+绿帘石,退变榴辉岩则为石榴石+蓝闪石+角闪石;蓝片岩主要矿物组合为石榴石+蓝闪石+多硅白云母+钠云母+钠长石+石英。榴辉岩和蓝片岩中石榴石变斑晶均保存进变质生长环带,从核部到边部XMn和XFe降低,XMg和XCa升高,指示了升温进变质的演化过程。根据榴辉岩矿物共生组合、石榴石内部包体组合分布特征及传统地质温压计估算结果,确定榴辉岩经历了4阶段的变质演化:早期硬柱石蓝片岩相进变质阶段、峰期榴辉岩相变质阶段(t=543～579℃,p=1.5～1.6 GPa)、峰后绿帘蓝片岩相退变质阶段(t=～450℃,p1.0GPa)和晚期蓝闪绿片岩相退变质阶段(t400℃,p0.5 GPa)。利用p-T视剖面图计算的榴辉岩、蓝片岩峰期变质温压条件与传统地质温压计估算结果十分相近,其中榴辉岩的峰期变质条件t=520～550℃,p=1.7～1.9 GPa;蓝片岩峰期变质条件t=520～620℃,p=1.7～2.3 GPa。本文估算的榴辉岩峰期变质压力条件与前人根据柯石英的发现而认为研究区部分榴辉岩及其围岩曾经历超高压变质作用的认识明显相悖,原因可能如下:①后期退变质作用引起研究区榴辉岩全岩成分、矿物化学成分的调整,在采用Grt-Cpx-Phe温压计和以全岩成分为基础的相平衡模拟方法估算峰期温压条件时受到影响,从而使估算峰期压力条件普遍偏低;②西南天山的榴辉岩可能并非全都经历了超高压变质作用,高压、超高压榴辉岩可能分别代表了不同变基性岩块在不同俯冲深度变质的产物。 相似文献
6.
鱼卡榴辉岩型金红石矿床位于柴北缘超高压变质带西侧,是青藏高原发现的第一个超大型金红石矿床。为研究该矿床的控矿因素和成矿机制,在详细的野外地质调查和岩相学研究的基础上,利用电子探针对该矿床榴辉岩中的各特征矿物进行分析。研究表明,粗粒块状高钛榴辉岩的石榴子石保存了较完整的成分环带,从核部到边部,石榴子石的化学成分、矿物包裹体的种类和粒度都具有明显的分带性;细粒片麻状低钛榴辉岩的矿物颗粒较小,石榴子石的成分环带较差。鱼卡榴辉岩的p-T演化特征反映,它们经历了深俯冲阶段的升温升压到早期折返阶段的升温降压,再到之后的降温降压的顺时针演化轨迹。榴辉岩中进变质矿物组合和生长环带的保存说明,榴辉岩的形成经历了相对快速俯冲和折返的动力学过程,钛成矿作用时金红石很少发生转变。超高压变质前后为金红石最主要的成矿期。 相似文献
7.
扬子板块西缘的康定杂岩为一套由侵入岩和变质岩共同组成的岩浆—变质混合杂岩,是研究罗迪尼亚超大陆裂解的重要窗口。长期以来对康定杂岩中的岩浆杂岩研究较多,但对变质杂岩研究较为薄弱。为全面了解康定杂岩形成的构造背景及成因机制,笔者等对扬子板块西缘的攀枝花大田地区康定群咱里组石榴夕线黑云斜长片麻岩进行了详细的岩相学、矿物地球化学、变质P—T条件估算研究,同时对同一层位的石榴二云片岩进行了锆石LA-ICP-MS U-Pb年代学分析。结果表明：石榴夕线黑云斜长片麻岩可识别出三期变质矿物组合：进变质阶段矿物组合(M1)为石榴子石变斑晶核部及其核部包裹体(石榴子石核部+第一期黑云母+第一期夕线石+钛铁矿+石英),P—T条件为609～690℃—0.2～0.3 GPa;峰期变质阶段矿物组合(M2)为石榴子石变斑晶幔部及变基质矿物(石榴子石幔部+第二期黑云母+第二期夕线石+斜长石+石英),P—T条件为643～732℃—0.20～0.51 GPa;退变质阶段矿物组合(M3)为石榴子石变斑晶边部及变基质矿物(石榴子石边部+第二期黑云母+第二期夕线石+斜长石+石英),P—T条件为602～687℃—0.27～0.3... 相似文献
8.
拉萨地块东部松多(超)高压榴辉岩记录了古特提斯洋俯冲及折返过程。松多榴辉岩带已发现松多、新达多、白朗和吉朗4个榴辉岩出露区,它们的峰期温压条件及变质p-T轨迹的研究对揭示拉萨地块古特提斯时期的俯冲及折返过程有重要意义。松多榴辉岩带东段吉朗榴辉岩的主要矿物为石榴子石、绿辉石、多硅白云母、角闪石、金红石、绿帘石、石英以及退变形成的后成合晶结构(透辉石+角闪石+斜长石)和少量的黑云母。石榴子石具有含丰富矿物包裹体的"脏"核和极少包裹体的"净"边,具有典型的进变质成分环带特征,从核部到边部镁铝榴石组分升高,锰铝榴石和钙铝榴石组分降低。石榴子石边部发育窄的角闪石+斜长石(An=28)组成的冠状体,表明石榴子石边部发生了后期角闪岩相退变质作用。通过变质相平衡模拟计算得到石榴子石以及多硅白云母记录的峰期温压条件为563℃、2. 4 GPa。结合岩相学特征,确定吉朗榴辉岩经历了4期变质演化阶段:(1)进变质阶段以石榴子石核部及其包裹体为代表性矿物组合;(2)峰期变质阶段矿物组合为石榴子石边部、绿辉石、多硅白云母、蓝闪石、硬柱石、金红石和石英;(3)早期退变质阶段以硬柱石分解产生绿帘石为特征;(4)晚期退变质阶段以绿辉石发育后成合晶和石榴子石生长冠状体为特征。认为吉朗榴辉岩为典型的低温高压榴辉岩,经历了顺时针p-T演化轨迹,折返过程为近等温降压过程。与松多带内其他(超)高压岩石相比,吉朗榴辉岩峰期温压条件较低,其围岩为变石英岩,区别于区内其他(超)高压榴辉岩的石榴子石白云母片岩及蛇纹岩围岩。推测吉朗榴辉岩来自于俯冲带浅部,由俯冲隧道中低密度沉积物裹挟折返。 相似文献
9.
对钦杭结合带首次发现的加里东期榴闪岩进行了详细的年代学、矿物学和变质作用研究。结果表明,榴闪岩的变质时代为454±4Ma,经历了早期角闪岩相进变质、中期榴辉岩相峰期变质和晚期角闪岩相退变质三个阶段,具顺时针P-T-t轨迹。早期角闪岩相进变质作用阶段的矿物共生组合为角闪石+斜长石+石英,温压条件分别为719℃~795℃和7.56Kpa~8.30Kpa;中期榴辉岩相峰期变质作用阶段的矿物共生组合为石榴子石+绿辉石(后期退变为透辉石+钠长石)±石英,温压条件分别为668℃~821℃和26.42Kpa~33.46Kpa;晚期角闪岩相退变质作用阶段的矿物共生组合为石榴子石+角闪岩+斜长石±石英(即榴闪岩),相应的温压条件分别为611℃~854℃和4.76Kpa~9.30Kpa。结合前人资料推断,区域内加里东期可能经历了榴辉岩相超高压变质→高温麻粒岩相退变质→角闪岩相退变质的演化过程。钦杭结合带首次厘定出加里东期超高压变质作用,表明华夏和扬子两大陆块碰撞拼合发生在加里东期。 相似文献
10.
《矿物岩石地球化学通报》2017,(6)
为查明柴北缘超高压变质带铁石观地区榴辉岩变质时间及流体活动,利用LA-ICP-MS对该区榴辉岩进行了锆石U-Pb定年分析,同时对锆石中包裹体进行了研究。结果表明,榴辉岩中变质锆石~(206)Pb/~(238)U加权平均年龄为426.1±4.9 Ma(MSWD=1.18),与区域上鱼卡、锡铁山、都兰等地榴辉岩变质峰期年龄一致。激光拉曼分析结果显示,包裹体核部矿物为金红石、绿辉石,边部为磷灰石、斜长石,可能为榴辉岩变质峰期捕获的产物。锆石~(176)Hf/~(177)Hf=0.282691~0.282795,~(176)Lu/~(177)Hf=0.000002~0.000228,Hf同位素两阶段亏损地幔模式年龄为769.7~1002.8 Ma,与区域上测得榴辉岩原岩年龄一致。通过搜集区域变质岩年龄数据分析,柴北缘地区超高压变质带年龄可分3期:第1期(470~440 Ma)与洋壳俯冲事件相关,第2期(440~420 Ma)与陆陆俯冲碰撞事件相关,第3期(420~400 Ma)为岩石退变化时期。 相似文献
11.
E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
12.
奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
13.
S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
14.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations. 相似文献
15.
Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA 总被引：1，自引：0，他引：1
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources. 相似文献
16.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
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18.
S. M. Moosavirad J. Rasouli M. R. Janardhana M. R. Moghadam M. Shankara 《Arabian Journal of Geosciences》2013,6(10):3623-3634
This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds. 相似文献
19.