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1.
碎屑岩的地球化学特征对应于特定的源区和构造环境,本文利用主微量元素对昌都盆地的早白垩纪景星组地层进行了地球化学分析,并与兰坪思茅盆地的早白垩纪地层进行了物源对比研究。岩相学研究显示景星组沉积岩的成分成熟度较低,其物源以火山岩为主。昌都地区景星组的主量元素地球化学分析显示其源区为石英质沉积岩源区和长英质火成岩源区。相比兰坪思茅地区早白垩纪地层,景星组地层物源的输入比较单一。景星组地层的CIA在59～78之间,平均为67,明显低于扒沙河组地层,表明兰坪思茅盆地的早白垩纪地层的风化强度明显高于昌都盆地。主微量构造环境判别图解显示昌都—兰坪思茅盆地早白垩纪地层的物源构造环境主要为被动大陆边缘与活动大陆边缘,同时具有大陆岛弧的特征。  相似文献   

2.
选取云南石林红土剖面作为研究对象,探讨在岩溶盆地这一独特地貌单元中主量、稀土元素的地球化学特征。研究表明：① 云南石林土壤中主量和稀土元素的组成具有较好的一致性;② 通过对化学蚀变指数（CIA）与Na/K比值关系图以及A-CN-K（Al2O3-CaO*+Na2O-K2O）三角图分析发现：石林地区2个剖面均经历了温暖湿润环境下的强烈化学风化作用;石林地区土壤中稀土元素含量较高,其稀土元素球粒陨石标准化分布模式表现出高度相似性,且继承了基岩的特征,两者均表现为Eu处负异常,但剖面CK在Ce处表现为负异常,而剖面KP在Ce处无明显变化;③ 2个剖面元素组成及含量变化基本保持一致,表明此地土壤受外来物质影响程度较小,2个剖面的元素地球化学特征与基岩存在一定相似性。  相似文献   

3.
思茅盆地晚白垩世勐野井组地层是我国唯一的古代固体钾盐发育地层,由于盆地内部断层纵横,地层横向对比困难,急需有效的标志性地层以完善区域对比及后续研究的深入。在确认早白垩世扒沙河组地层良好的区域可对比性基础上,通过对比思茅盆地江城地区两个典型地质露头剖面及勐野井钾盐矿床钻孔岩芯的元素地球化学特征,探讨了江城地区含盐系地层及其下伏扒沙河组地层的化学风化、构造背景及物源属性特征。结果表明,1)思茅盆地江城地区勐野井组与扒沙河组地层在形成过程中,其物源区均经历了中至强的化学风化作用过程;2)尽管这两套地层间呈不整合接触关系,但在物源属性上二者却均具有混和物源的特性(活动大陆边缘或大陆岛弧背景的长英质物源与被动大陆边缘背景的古老沉积物物源的混合),扒沙河组地层在沉积过程中可能还受到了少量基性岩物源的影响;3)云南江城勐野井组及其下伏扒沙河组地层的主要物源区可能为哀牢山隆起带和扬子古陆块。  相似文献   

4.
思茅盆地晚白垩世勐野井组地层是我国唯一的古代固体钾盐发育地层,由于盆地内部断层纵横,地层横向对比困难,急需有效的标志性地层以完善区域对比及后续研究的深入。本次在确认早白垩世扒沙河组地层良好的区域可对比性基础上,通过对比思茅盆地江城地区两个典型地质露头剖面及勐野井钾盐矿床钻孔岩心的元素地球化学特征探讨了江城地区含盐系地层及其下伏扒沙河组地层的化学风化、构造背景及物源属性特征。结果表明,1）思茅盆地江城地区勐野井组与扒沙河组地层在形成过程中,其物源区均经历了中至强的化学风化作用过程;2）尽管这两套地层间呈不整合接触关系,但在物源属性上二者却均具有混和物源的特性（活动大陆边缘或大陆岛弧背景的长英质物源与被动大陆边缘背景的古老沉积物物源的混合）,而扒沙河组地层在沉积过程中可能还受到了少量基性岩物源的影响;3）云南江城勐野井组及其下伏扒沙河组地层的主要物源区可能为哀牢山隆起带和扬子古陆块。  相似文献   

5.
哈尔滨沙尘沉降物的化学风化特征及物源区意义   总被引：1，自引：0，他引：1  
对哈尔滨2006年3月10日沙尘沉降物的化学组成及化学风化特征进行研究,结果表明:SiO2、Al2O3和TFe2O3含量分别为54.87%、13.27%和5.63%,三者之和达73.77%;CaO、MgO、K20、Na2O、TiO2、P2O5和MnO含量分别为3.78%、2.57%、2.63%、1.76%、O.77%、0.24%和O.11%.沉降物中的常量元素多表现为迁移淋失,Mn和Ti明显富集而Mg和Fe轻微富集,元素的迁移淋失率依次为:Na>P>K>Si>Al>Ca>Fe>Mg>Ti>Mn;微量元素除Nb、Sr迁移淋失外,其余元素表现出富集特征.与哈尔滨2002年沙尘沉降物、黄土高原第四纪黄土与古土壤、晚第三纪红粘土、镇江下蜀土及宣城风成红土等典型风成堆积物进行对比分析,(A1+Fe+Ti+Mn)/(Mg+Ca+K+Na)比值、成分变异指数ICV、CIA等化学风化参数及A-CN-K化学风化趋势图均显示,哈尔滨沙尘沉降物经历了低等化学风化程度,明显强于兰州黄土和古土壤,弱于洛川黄土,显著弱于洛川古土壤、西峰红粘土、镇江下蜀土和宣城风成红土.哈尔滨沙尘源区处于大陆化学风化的早期,气候生物状况好于西北地区,包括沙漠和黄土高原在内的西北地区不会是哈尔滨沙尘沉降物的物源区,或者至少不是主要物源区.  相似文献   

6.
地球化学元素不仅反映地球表层沉积物的组成特征,并在分析物源、沉积过程及重建古环境等方面有积极意义。通过野外采样、室内实验,对巴丹吉林沙漠伊和吉格德湖、巴丹湖高大沙山区沉积物地球化学特征进行了分析。结果表明：沙山沉积物元素组成特征和含量略有区域差异;与上部陆壳平均化学组成（UCC）相比,常量元素中仅Si富集,其余均亏损;趋向迎风坡上部剖面,Si、K富集程度相对增加,其他常量元素（除Na）亏损程度增加。常量元素间的关系表明SiO2影响沙山沉积物的地球化学组成及性质;迎风坡底部剖面沉积物呈现出多源性特征,可能是不同外力作用的结果。两湖区沙山的沙源属局部范围混合的结果,就近供应;干旱气候下沙山沉积物缺少较高等化学风化产生的条件,基本处在大陆风化早期阶段的初期。  相似文献   

7.
雅丹沉积物蕴含丰富的区域环境变化和物源演变信息。以柴达木盆地西北部的长垄状雅丹为研究对象,通过对地球化学元素的研究,探讨沉积物的化学风化特征及其对物质输移的指示意义。结果表明：（1）雅丹沉积物的常量元素以SiO2、CaO、Al2O3、MgO和Na2O为主,微量元素Cl、Sr、Ba和Zr含量较高。相较于上陆壳平均化学元素组成,雅丹沉积物常量元素CaO和MgO富集程度较高,微量元素中Cl和As富集程度较高。（2）雅丹沉积物的CIA值平均为39.03,且在A-CN-K三角图上准平行于A-CN连线,主体在斜长石与钾长石连线的下方,因此雅丹沉积物的化学风化程度较低,处于初期的脱Na、Ca阶段。（3）特征元素比值表明雅丹体内赋存的大量细颗粒物质为廊道流沙的源区。细颗粒物质经过外营力的风化、剥蚀等过程而出露,在雅丹廊道内堆积并向下风向输移,遇阻堆积而形成沙丘。雅丹是否为下风向黄土的物源区,尚需进一步验证。  相似文献   

8.
青海湖区是研究亚洲季风和西风环流强度变化和相互作用的良好区域。与青海湖湖泊钻孔沉积物一样,青海湖岸边广泛堆积的陆相风成沉积独立地记录了青海湖区晚第四纪以来的环境演变。过去对青海湖风成沉积的元素地球化学特征虽有过一些研究,但对于这套风成沉积的化学风化研究相当薄弱。通过对青海湖东岸种羊场剖面晚第四纪风成沉积的常量元素组成及主要的化学风化指标进行研究,结果表明:1)化学风化指标CIA(化学蚀变指数)、CIW(化学风化指数)、K2O/Na2O和Fe2O3/Mg O比值均反映了种羊场风成沉积经历了早期化学风化强度弱、中期强和晚期再度变弱的变化特征;2)在距今~5 ka时,风化指标显示化学风化作用最强,可能记录了青海湖区暖湿的气候特征;3)种羊场风成沉积的Fe2O3/Mg O比值与!fd%(频率磁化率的百分比)呈显著线性正相关(相关系数R2为0.939),指示在化学风化过程中Fe元素的富集对于磁化率增强具有重要贡献。  相似文献   

9.
雅丹沉积物蕴含丰富的区域环境变化和物源演变信息。以柴达木盆地西北部的长垄状雅丹为研究对象,通过对地球化学元素的研究,探讨沉积物的化学风化特征及其对物质输移的指示意义。结果表明：（1）雅丹沉积物的常量元素以SiO_2、CaO、Al_2O_3、MgO和Na_2O为主,微量元素Cl、Sr、Ba和Zr含量较高。相较于上陆壳平均化学元素组成,雅丹沉积物常量元素CaO和MgO富集程度较高,微量元素中Cl和As富集程度较高。（2）雅丹沉积物的CIA值平均为39.03,且在A-CN-K三角图上准平行于A-CN连线,主体在斜长石与钾长石连线的下方,因此雅丹沉积物的化学风化程度较低,处于初期的脱Na、Ca阶段。（3）特征元素比值表明雅丹体内赋存的大量细颗粒物质为廊道流沙的源区。细颗粒物质经过外营力的风化、剥蚀等过程而出露,在雅丹廊道内堆积并向下风向输移,遇阻堆积而形成沙丘。雅丹是否为下风向黄土的物源区,尚需进一步验证。  相似文献   

10.
大青山发育的石英闪长岩在地球化学上具有埃达克质花岗岩的特点。它们以较高的硅(Si O2一般大于56%,较高的铝(Al2O3一般大于14%),富钠(Na2O通常大于4%),低K2O/Na2O比(分子数)(通常小于0.4)。它们还富大离子亲石元素(如Rb、Sr)、过渡元素(如Cr、Ni)亏损高场强元素(如Nb、Ti)为特征。球粒陨石标准化稀土图谱显示轻稀土富集型,并具有明显的正Eu异常。锆石U-Pb SHRIMP的测年,结合野外地质和前寒武纪消减带花岗岩演化特征,推断埃达克质花岗岩形成于2435±12Ma。表明该区古元古代存在真正意义的板块构造,俯冲作用已经发生。  相似文献   

11.
Frequent and serious aeolian disasters occur in the upper and middle reaches of the Yarlung Zangbo River, which runs through the high-elevation Tibet Plateau. Sediment geochemical characteristics can be used as a proxy to identify the sediment's provenance. To determine the provenance of aeolian sediments in the river's basin, we analysed major and trace element contents from surface samples and local clastic rocks throughout the basin. We found that the major and trace elements differed between the middle reaches, upper reaches and regions south of the river. Major element contents were similar in the upper and middle reaches, but trace elements differed. Al2O3, MgO and Na2O concentrations increased from the upper reaches to the lower reaches, and in the lower reaches, MgO and Na2O were enriched compared with the crustal average. The similarities between samples in the lower part of the upper reaches and those in the middle reaches indicated that sediment transported by fluvial systems from the upper reaches were first deposited in the wide valleys near Xigaze, where they formed a large area of shifting sand. These deposits were then transported by the wind to the river's middle reaches, where they formed a large area of shifting sand. When we compared aeolian sediment in the middle reaches with the local clastic rocks, they appeared to be unrelated. The difference between sediments south of the river and those in the middle reaches means that the southern sediments were not transported to the middle reaches. Therefore, the aeolian sediment in the middle reaches of the Yarlung Zangbo River mainly came from the lower part of the upper reaches, not from the local clastic rocks.  相似文献   

12.
The varicolored hills in the northern foothills of the Qilian Mountains of northern China, in the Hexi Corridor of Gansu Province's Sunan Yugur Autonomous County, have given this region a unique geomor...  相似文献   

13.
通过对江西沟风成沉积剖面的地球化学分析,并结合OSL年代、粒度和磁化率数据,探讨了末次冰消期以来青海湖南岸气候的演变。剖面常量元素氧化物含量呈SiO_2Al_2O_3CaOFe_2O_3MgOK_2ONa_2O变化特征,常量元素氧化物及化学元素综合参数与地层有较好的对应性。不同的环境指标对气候变化的敏感性不同,总体上看,地球化学元素的敏感性高,全新世以来粒度和磁化率的变幅较小,即使在全新世大暖期,其值变化都很小。地球化学元素记录所反映的气候变化过程如下。Ⅰ.末次冰消期~12 ka BP,13.2 ka BP前总体上呈相对温暖状态,可能受B/A暖期的影响,13.2~12 ka BP气候不断向干冷方向发展,寒冷程度不断加剧并在12 ka BP达到最强,可能反映出12 ka BP左右的新仙女木事件;Ⅱ.12~9 ka BP,气候呈波动回升状态,暖湿程度呈增加趋势,表现出温凉的气候变化特征;Ⅲ.9~4.5 ka BP,气候温暖湿润,与全新世大暖期相对应,该阶段水热组合达到最佳,但存在阶段性的变化;Ⅳ.4.5~2 ka BP,气候总体向冷干方向转变,3 ka BP前变化幅度较小,气候较温暖湿润,3~2 ka BP气候凉偏干。  相似文献   

14.
通过对晋南地区中梁铁厂全新世黄土剖面常量元素含量分析和粒度、磁化率及光释光年代测定,探讨全新世以来该剖面的化学风化特征及其古环境意义。剖面沉积物的Al2O3、TFe2O3、K2O含量变化趋势基本一致,三者含量在古土壤层中较高,代表气候暖湿;剖面常量元素含量与UCC对比具有富Ca而贫Na、K的特征;剖面总体处于低等化学风化强度,介于陕西扶风和宁夏彭阳的剖面之间,其中古土壤层处于中等风化强度,Ca、Na大量淋失。常量元素地球化学特征指示该区全新世以来气候经历了"气候回暖→温暖湿润→气候转凉→持续干凉"的转化过程。1.2-2.5 ka BP期间区域地表流水作用较强,导致了Ca的相对淋失。  相似文献   

15.
The chemical composition of fine‐grained siliciclastic sediments is a powerful tool in provenance studies, either as a complement to other whole rock/single grain methods, or as a stand‐alone method when other techniques are not applicable, and particularly in those cases where the coarser sediment fractions are not available or the regional‐scale geologic framework is lost due major successive tectonic events. A comprehensive geochemical investigation of pelites from the post‐rift deposits of the Ligurian‐Piedmont ocean (sampled in tectonic units of the Alpine‐Apennine orogen: Balagne Nappe, Corsica; Tuscan Nappe and Internal Ligurian units, Northern Apennines; Err‐Platta units, Central Alps) has identified for the first time a major mafic‐ultramafic input immediately following rifting. Key trace element ratios (e.g. LaN/YbN < 10; avg. Eu/Eu* = 0.73 ± 0.06, 1SD; Th/(Cr + Ni + V) < 0.03) show that the pelitic siliciclastic layers intercalated in the Radiolarite Formation (the first post‐rift deposits) are systematically enriched in a mafic‐ultramafic source component compared with the younger post rift sediments (Calpionella Limestone and Palombini Shale). Such a peculiar chemical fingerprint is interpreted as the result of erosion and distribution across the whole basin (even to continental domains) of intraoceanic ophiolitic debris by turbidity and bottom currents sweeping the sea floor at the time of deposition of the Radiolarite Formation. Exhumed mantle and gabbroic‐basaltic rocks exposed at the morphologically articulated seafloor of the slow‐spreading Ligurian‐Piedmont ocean were available to erosion during the whole time‐span of the deposition of the Radiolarite Formation, whilst they became progressivey subordinate as a source as the basin floor was progressively covered by the siliciclastic input from the developing passive continental margins.  相似文献   

16.

Oil from the Oligocene oil sands of the Lower Ganchaigou Formation in the Northern Qaidam Basin and the related asphaltenes was analyzed using bulk and organic geochemical methods to assess the organic matter source input, thermal maturity, paleo-environmental conditions, kerogen type, hydrocarbon quality, and the correlation between this oil and its potential source rock in the basin. The extracted oil samples are characterized by very high contents of saturated hydrocarbons (average 62.76%), low contents of aromatic hydrocarbons (average 16.11%), and moderate amounts of nitrogen–sulfur–oxygen or resin compounds (average 21.57%), suggesting that the fluid petroleum extracted from the Oligocene oil sands is of high quality. However, a variety of biomarker parameters obtained from the hydrocarbon fractions (saturated and aromatic) indicate that the extracted oil was generated from source rocks with a wide range of thermal maturity conditions, ranging from the early to peak oil window stages, which are generally consistent with the biomarker maturity parameters, vitrinite reflectance (approximately 0.6%), and Tmax values of the Middle Jurassic carbonaceous mudstones and organic-rich mudstone source rocks of the Dameigou Formation, as reported in the literature. These findings suggest that the studied oil is derived from Dameigou Formation source rocks. Furthermore, the source- and environment-related biomarker parameters of the studied oil are characterized by relatively high pristane/phytane ratios, the presence of tricyclic terpanes, low abundances of C27 regular steranes, low C27/C29 regular sterane ratios, and very low sterane/hopane ratios. These data suggest that the oil was generated from source rocks containing plankton/land plant matter that was mainly deposited in a lacustrine environment and preserved under sub-oxic to oxic conditions, and the data also indicate a potential relationship between the studied oil and the associated potential source rocks. The distribution of pristane, phytane, tricyclic terpanes, regular steranes and hopane shows an affinity with the studied Oligocene Lower Ganchaigou Formation oil to previously published Dameigou Formation source rocks. In support of this finding, the pyrolysis–gas chromatography results of the analyzed oil asphaltene indicate that the oil was primarily derived from type II organic matter, which is also consistent with the organic matter of the Middle Jurassic source rocks. Thus, the Middle Jurassic carbonaceous mudstones and organic rock mudstones of the Dameigou Formation could be significantly contributing source rocks to the Oligocene Lower Ganchaigou Formation oil sand and other oil reservoirs in the Northern Qaidam Basin.

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17.
A broad array of new provenance and stable isotope data are presented from two magnetostratigraphically dated sections in the south‐eastern Issyk Kul basin of the Central Kyrgyz Tien Shan. The results presented here are discussed and interpreted for two plausible magnetostratigraphic age models. A combination of zircon U‐Pb provenance, paleocurrent and conglomerate clast count analyses is used to determine sediment provenance. This analysis reveals that the first coarse‐grained, syn‐tectonic sediments (Dzhety Oguz formation) were sourced from the nearby Terskey Range, supporting previous thermochronology‐based estimates of a ca. 25–20 Ma onset of deformation in the range. Climate variations are inferred using carbonate stable isotope (δ18O and δ13C) data from 53 samples collected in the two sections and are compared with the oxygen isotope compositions of modern water from 128 samples. Two key features are identified in the stable isotope data set derived from the sediments: (1) isotope values, in particular δ13C, decrease between ca. 26.0 and 23.6 or 25.6 and 21.0 Ma, and (2) the scatter of δ18O values increased significantly after ca. 22.6 or 16.9 Ma. The first feature is interpreted to reflect progressively wetter conditions. Because this feature slightly post‐dates the onset of deformation in the Terskey Range, we suggest that it has been caused by orographically enhanced precipitation, implying that surface uplift accompanied late Cenozoic deformation and rock uplift in the Terskey Range. The increased scatter could reflect variable moisture source or availability caused by global climate change following the onset of Miocene glaciations at ca. 22.6 Ma, or enhanced evaporation during the Mid‐Miocene climatic optimum at ca. 17–15 Ma.  相似文献   

18.
采用等温溶解平衡法测定了含锂、硼硼酸盐水溶液体系在35℃时的溶解度、密度和折光率，根据实验数据，绘制了相应的溶解度图、密度图、折光率图和pH值图。该体系溶解度相图包含一个共饱点，两个单盐结晶区，分别为结晶相区较大的（L+ Mg2B6O11·15H2O）和结晶相区较小的（L + K2B4O7·4H2O），溶液体系中没有固溶体和复盐产生。溶液的密度、折光率和pH值随着硼酸钾溶液的浓度增大而呈现与规律的变化，并采用半经验公式对溶液的密度和折光率进行计算，计算值和实验值吻合较好。  相似文献   

19.
为了获取锂钠钾共存硫酸盐体系298.2 K下各盐结晶形式,采用等温溶解平衡法研究了298.2 K下四元体系Li2SO4+Na2SO4+K2SO4+H2O的相平衡关系,测定了该体系的溶解度和密度,采用X-ray粉晶衍射法测定了平衡固相组成,并绘制了相应的稳定相图和多温对比图。研究表明,298.2 K下该四元体系为复杂四元体系,有复盐2Li2SO4·Na2SO4·K2SO4、Li2SO4·3Na2SO4·12H2O、LiKSO4、Na2SO4·3K2SO4生成。其稳定相图由6个四元共饱点、12条单变量曲线以及7个结晶区组成。其中,复盐Na2SO4·3K2SO4结晶区最大,表明其在该体系中最易结晶析出;Li2SO4·H2O结晶区最小。对比273.2 K、288.2 K、298.2 K、323.2 K、373.2 K四元体系多温相图可知,273.2 K时未发现复盐Na2SO4·3K2SO4和2Li2SO4·Na2SO4·K2SO4结晶形式;Na2SO4·10H2O和Li2SO4·3Na2SO4·12H2O结晶形式在323.2 K和373.2 K时转变为Na2SO4和Li2SO4·Na2SO4。288.2~373.2 K时随温度升高,K2SO4和Na2SO4·10H2O结晶相区减小,Li2SO4·H2O、Na2SO4、LiKSO4和Li2SO4·Na2SO4结晶相区增大;Na2SO4·3K2SO4结晶相区先增大后减小,在298.2 K时结晶相区最大;2Li2SO4·Na2SO4·K2SO4结晶相区先减小后增大,298.2 K时结晶相区最小。  相似文献   

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