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1.
中国东部新生代玄武岩中巨晶矿物的地球化学   总被引:14,自引:0,他引:14  
本文对安徽女山、河北汉诺坝和广东普宁碱性玄武岩中的单斜辉石和角闪石巨晶进行了主要元素、稀土元素、微量元天和Sr_Nd同位素的综合分析。数据显示产出于3个研究区的单斜辉石巨晶有3类:Al普通辉石、透辉石和Fe_Na透辉石。普宁地区的角闪石巨晶乃世界上罕见的绿钙闪石巨晶。女山和普宁的单斜辉石和角闪石巨晶是碱性玄武岩浆在幔源高压下的结晶产物;汉诺坝的单斜辉石巨晶既可以是碱性玄武岩浆又可以是拉斑玄武岩浆的高压结晶体。所有巨晶相对于寄主岩者属于偶然捕掳晶。巨晶的形成符合“流动结晶模式”。它们与共存的橄榄岩色体无成因  相似文献   

2.
陕西岚皋境内赋存于早古生代碱质潜火山煌斑杂岩中的“金云角闪辉石岩”捕虏体是交代地幔捕虏体。主要组成矿物为单斜辉石、角闪石、金云母、磷灰石、钙钛矿、钛铁矿及榍石,发育“三联晶”、“碎裂边”等固相线下的变质变形结构;矿物学研究表明单斜辉石富SiO_2、MgO,贫Al_2O_3、TiO_2,与寄主岩中深源单斜辉石巨晶及单斜辉石斑晶成分差别明显,形成于地幔压力范畴。角闪石和金云母具地幔交代成因的成分待点。Sm-Nd同位素的研究表明,本区交代地幔是原始地幔受来源于地幔柱  相似文献   

3.
山东昌乐新生代碱性玄武岩中的巨晶单斜辉石成因研究   总被引:2,自引:0,他引:2  
陈小明  陈立辉  徐夕生 《岩石学报》2009,25(5):1105-1116
山东昌乐新生代碱性玄武岩中除斑晶单斜辉石和基质单斜辉石外,还发育大量巨晶单斜辉石和同源斜方辉石捕掳晶。巨晶单斜辉石与玄武岩间发育复杂和简单两种类型的反应边。复杂反应边往往发育在颗粒较大的巨晶单斜辉石外围。复杂反应边可分为4个带:内部带、过渡带、外部带和边缘带,其中,内部带、过渡带和外部带均由具不同结构特征的单斜辉石+熔体+金属氧化物构成,边缘带为不含熔体和金属氧化物的干净的单斜辉石;内部带的单斜辉石具梳状构造,过渡带的单斜辉石具细密筛孔构造,外部带为具似砂钟构造的筛孔状单斜辉石。反应边中单斜辉石、熔体及金属氧化物的成分显示,只有内部带受到单斜辉石巨晶的影响,其余带均受玄武岩浆的制约。简单反应边往往发育在颗粒较小的巨晶单斜辉石外围。简单反应边仅发育不含熔体和金属氧化物的干净的单斜辉石。巨晶单斜辉石的反应边是巨晶与玄武岩浆间温度差造成的。在与玄武岩浆反应的过程中,大颗粒的单斜辉石巨晶需要较长的时间与玄武岩浆达到温度平衡,从而有足够的时间发育包含4个带的复杂反应边;反之,由于缺乏足够的反应时间,小颗粒单斜辉石巨晶的外围只发育不含熔体和金属氧化物的简单反应边。同源斜方辉石捕掳晶的成分与地幔二辉橄榄岩包体中的斜方辉石类似,其边部发育类似于Bowen反应(1956)形成的单斜辉石环边。在单斜辉石AlIV-AlVI图解上,巨晶单斜辉石、二辉橄榄岩包体中的单斜辉石以及部分单斜辉石斑晶的核部,均位于较高压力的“麻粒岩和玄武岩中包体”区域,反应边中单斜辉石、基质单斜辉石以及绝大部分斑晶单斜辉石位于“火成岩”区域,说明部分斑晶单斜辉石核部来源于地幔二辉橄榄岩,属于捕掳晶。结合单斜辉石结晶压力的估算,笔者认为巨晶单斜辉石的成因模式为:来自软流圈的碱质基性熔体上侵到地幔岩石圈下部,结晶形成单斜辉石巨晶,后来该熔体携带巨晶单斜辉石与来自上地幔岩石圈、夹带大量二辉橄榄岩包体以及斜方辉石(和单斜辉石)捕掳晶的玄武岩浆混合,巨晶单斜辉石随混合后的碱性玄武岩浆上升、喷出地表。  相似文献   

4.
本文对华北克拉通晚中生代和新生代碱性玄武质岩石中的单斜辉石巨晶进行了主、微量元素和Sr-Nd同位素的综合研究,发现晚中生代和新生代单斜辉石巨晶存在明显的主、微量元素和同位素组成上的差异。新生代单斜辉石巨晶有Al-普通辉石和次透辉石两类;而中生代单斜辉石巨晶只有Al-普通辉石。新生代单斜辉石SiO_2含量高、REE配分型式为上凸型、LILE和放射性元素含量高,并具有比寄主碱性玄武岩更亏损的Sr和Nd同位素组成;而中生代单斜辉石SiO_2含量低、REE配分型式为LREE富集型、LILE和部分HFSE以及放射性元素含量低,并具有比寄主碱性玄武岩稍富集的Sr和Nd同位素组成;巨晶的结构、矿物成分和地球化学特征,以及Mg-Fe在熔体与单斜辉石间的分配状况皆说明,新生代碱性玄武岩中单斜辉石巨晶是碱性玄武岩浆在高压下结晶的,因此二者是同源的;而中生代单斜辉石巨晶是被寄主岩浆偶然捕获的捕虏晶,是不同源的。华北新生代单斜辉石巨晶存在于碱性玄武岩和拉斑玄武岩中,它们具有比寄主碱性玄武岩更亏损的Sr和Nd同位素组成,说明即使是碱性玄武岩也不能完全代表软流圈来源的原始岩浆,其在上升过程中或多或少存在同位素组成富集的物质的混入。同时,拉斑玄武岩不是碱性玄武质岩浆直接结晶分异的产物,亦不是完全由部分熔融程度的不同造成的。拉斑玄武岩中存在岩石圈地幔物质的贡献或是岩浆房内碱性玄武质岩浆受地壳混染作用的结果。  相似文献   

5.
南海新生代玄武岩中发育有大量的单斜辉石斑晶,与橄榄石、角闪石等斑晶共存,多数被熔蚀,呈浑圆状,部分发育有很窄的反应边。研究表明单斜辉石具有巨晶的特征,是在高压下在与寄主岩同源的岩浆中形成,没有经历长时间的沉淀生长而直接向上运移被带到地表,因而具有巨晶的主量及微量元素的特征却不具有巨晶的形态。单斜辉石稀土元素含量不高,HREE及LREE亏损,而MREE富集;大离子亲石元素Rb、Ba、Sr均出现明显的亏损,高场强元素Nb、Zr出现亏损而Hf略富集。Nb、Ta与Zr、Hf分馏明显。Th较为富集,而Pb强烈亏损,U的变化范围较大。研究发现南海新生代玄武岩中的单斜辉石的来源较为简单,为地幔柱的直接产物,并没有受到洋中脊—地幔柱相互作用的影响,由于岩浆上升速度较快压力迅速下降,橄榄石大量晶出,引起了岩浆成分的变化,致使单斜辉石与寄主岩成分和结构上没有达到平衡。  相似文献   

6.
安徽女山橄榄岩包体中辉石的氢同位素组成   总被引:2,自引:0,他引:2  
本文运用离子探针技术分析了来自安徽女山橄榄岩包体中辉石的氢同位素组成。无论是颗粒内部还是同一样品不同颗粒之间,氢同位素比值都是均一的。氢同位素比值和氢含量之间没有相关性,说明氢同位素组成反映的是地幔源区的特征。结合共存的角闪石的氢同位素数据来看,女山上地幔至少经历过两期交代作用:一期交代形成了角闪石中不均一的氢同位素组成;另一期交代形成了包体中单斜辉石、单斜辉石巨晶和云母巨晶中的高δD值(高至-20‰)。高δS值说明女山上地幔曾经经历过俯冲流体的交代作用。  相似文献   

7.
叶松  张保民等 《地质学报》2002,76(3):431-431
江西安远县路迳产出的超基性岩筒,是幔源岩浆岩的一个特殊类型,命名为金伯利质煌斑岩。岩筒的Rb- Sr等时线年龄37Ma。该岩筒中含有幔源单斜辉石巨晶和辉石岩、尖晶石橄榄岩、石榴石辉石岩包体,这些巨晶和包体来自上地幔不同深度。本文应用傅立叶变换红外光谱研究了该岩筒中巨晶单斜辉石和3种包体中辉石的含水性,探讨辉石含水量与其成分及来源深度的关系。单斜辉石以3607~3630cm_(-1)和3522~3542cm_(-1)两组吸收谱带为主,斜方辉石存在3410  相似文献   

8.
延边地区中侏罗世和早白垩世火山岩中包含有较多的辉石岩捕虏体和角闪石捕虏晶,前者为普通辉石变种,其化学成分类似于中国东部新生代玄武岩中单斜辉石巨晶的成分,具有岩浆堆积成因特征;后者为韭闪石和镁质绿钠闪石变种,其成分类似于中生代晚期玄武岩中角闪二辉石岩包体里的角闪石和新生代玄武岩中的角闪石巨晶.矿物温压计算结果显示,它们形成深度介于25~37km.延边地区中生代火山岩的(87Sr/86Sr)i值介于0.704 3~0.705 0,εNd(t)值介于2.33~4.71,表明岩浆源区应是一套具有亏损性质的新增生的地幔物质.综合上述结果,可以判定延边地区中生代火山岩的原始岩浆应来源于新增生的壳幔过渡带物质的部分熔融,地壳增生事件的时间为新元古代.  相似文献   

9.
雷州半岛英峰岭火山岩中单斜辉石巨晶以低Mg^#值(0.62—0.47)、贫重稀土(HREE)和富Al2O3、TiO2、Na2O和中稀土(MREE)为特征,并具有明显的成分变化。随着Mg^#降低,单斜辉石的Al:O,(11.58~6.97%,)、TiO,(2.28~1.06%)和HREE逐渐降低。这种变化特征不同于世界上大多数辉石巨晶的变化规律。随着演化辉石巨晶的大多数不相容元素,如Nb、Sr、Zr、Hf和LREE—MREE逐渐增加。低的Mg^#值和Ni、Co、Cr含量指示巨晶母岩浆是一种强烈演化的残余岩浆(Mg^#=0.27~0.35)。分离结晶模拟表明本研究最富镁的巨晶(Lz-54)的母岩浆很可能是由拉斑玄武质岩浆经70~80%,以单斜辉石为主的结晶分异后形成。而本研究的其它辉石巨晶是该母岩浆在不同演化阶段(25~80%)分离结晶的产物。分离矿物中除了单斜辉石还包含了大量的石榴子石、斜长石和钛铁矿。温压计算表明英峰岭巨晶是高温岩浆在56~60km深的上地幔的结晶产物(r=1290℃~1130℃,P=1.73~1.83GPa),这一深度有利于石榴子石结晶。对比不同地区辉石巨晶的成分特征和形成条件,作者指出不同地区单斜辉石巨晶各种元素的不同变化规律主要受母岩浆成分和结晶条件控制。巨晶母岩浆在地幔结晶时对围岩橄榄岩进行了不同程度的交代作用。早期贫流体的岩浆对橄榄岩的交代作用较弱,只有Sr,La等强活动性元素被明显改变;晚期富流体(F,P,H2O)岩浆对橄榄岩的交代作用强烈,大多数元素被明显改变。因此,可以推断交代熔体中流体的含量是影响地幔橄榄岩交代作用的关键。  相似文献   

10.
本文对辽宁宽甸碱性玄武岩中巨晶单斜辉石进行穆斯堡尔谱研究。应用晶体结构研究结果较合理地解释了单斜辉石的异常穆斯堡尔谱。结合XRD讨论了单斜辉石中Fe结构态的测定以及穆斯堡尔谱的可应用性。巨晶应结晶于相当氧化的环境。  相似文献   

11.
A deep-level crustal section of the Cretaceous Kohistan arc is exposed in the northern part of the Jijal complex. The occurrence of mafic to ultramafic granulite-facies rocks exhibits the nature and metamorphic evolution of the lower crust. Mafic granulites are divided into two rock types: two-pyroxene granulite (orthopyroxene+clinopyroxene+plagioclase±quartz [1]); and garnet–clinopyroxene granulite (garnet+clinopyroxene+plagioclase+quartz [2]). Two-pyroxene granulite occurs in the northeastern part of the Jijal complex as a relict host rock of garnet–clinopyroxene granulite, where the orthopyroxene-rich host is transected by elongated patches and bands of garnet–clinopyroxene granulite. Garnet–clinopyroxene granulite, together with two-pyroxene granulite, has been partly replaced by amphibolite (hornblende±garnet+plagioclase+quartz [3]). The garnet-bearing assemblage [2] is expressed by a compression–dehydration reaction: hornblende+orthopyroxene+plagioclase=garnet+clinopyroxene+quartz+H2O↑. Subsequent amphibolitization to form the assemblage [3] is expressed by two hydration reactions: garnet+clinopyroxene+plagioclase+H2O=hornblende+quartz and plagioclase+hornblende+H2O=zoisite+chlorite+quartz. The mafic granulites include pod- and lens-shaped bodies of ultramafic granulites which consist of garnet hornblendite (garnet+hornblende+clinopyroxene [4]) associated with garnet clinopyroxenite, garnetite, and hornblendite. Field relation and comparisons in modal–chemical compositions between the mafic and ultramafic granulites indicate that the ultramafic granulites were originally intrusive rocks which dissected the protoliths of the mafic granulites and then have been metamorphosed simultaneously with the formation of garnet–clinopyroxene granulite. The results combined with isotopic ages reported elsewhere give the following tectonic constraints: (1) crustal thickening through the development of the Kohistan arc and the subsequent Kohistan–Asia collision caused the high-pressure granulite-facies metamorphism in the Jijal complex; (2) local amphibolitization of the mafic granulites occurred after the collision.  相似文献   

12.
Three texturally distinct symplectites occur in mafic granofels of the Arthur River Complex at MtDaniel, Fiordland, New Zealand. These include symplectic intergrowths of clinopyroxene and kyanite, described here for the first time. Pods of mafic granofels occur within the contact aureole of the Early Cretaceous Western Fiordland Orthogneiss batholith. The pods have cores formed entirely of garnet and clinopyroxene, and rims of pseudomorphous coarse‐grained symplectic intergrowths of hornblende and clinozoisite that reflect hydration at moderate to high‐P. These hornfelsic rocks are enveloped by a hornblende–clinozoisite gneissic foliation (S1). Narrow garnet reaction zones, in which hornblende and clinozoisite are replaced by garnet–clinopyroxene assemblages, developed adjacent to fractures and veins that cut S1. Fine‐grained symplectic intergrowths of (1) clinopyroxene and kyanite and (2) clinozoisite, quartz, kyanite and plagioclase form part of the garnet reaction zones and partially replace coarse‐grained S1 hornblende and clinozoisite. The development of the garnet reaction zones and symplectites was promoted by dehydration most probably following cooling of the contact aureole. Maps of oxide weight percent and cation proportions, calculated by performing matrix corrections on maps of X‐ray intensities, are used to study the microstructure of the symplectites.  相似文献   

13.
郭璇  朱永峰 《地学前缘》2011,18(2):180-190
出露于西南天山特克斯县东南的小哈拉军山辉长岩体主要由角闪辉长岩和含磁铁矿辉长岩组成。角闪辉长岩主要由单斜辉石、角闪石和斜长石组成;含磁铁矿辉长岩主要由斜长石和磁铁矿组成。这两类岩石都含少量方解石。这些方解石均呈独立矿物出现,且与长石、单斜辉石或黑云母平衡共生。这些方解石是原生碳酸盐矿物(不是后期热液蚀变的产物)。两类岩石属于钙碱性系列,富集轻稀土元素,亏损重稀土元素,轻重稀土之间的分异比较明显,但不显示Eu异常。辉长岩相对富集大离子亲石元素而亏损高场强元素。岩石学和地球化学研究表明,小哈拉军山辉长岩是碳酸盐化地幔极低程度部分熔融的产物,斜长石堆晶过程对岩浆演化起重要作用。  相似文献   

14.
Feldspathic hornblende granulites from Doubtful Sound, New Zealand with the assemblage plagioclase+hornblende+clinopyroxene+orthopy-roxene +oxide+apatite are criss-crossed by a network of garnetiferous anorthosite veins and pegmatites. The feldspathic gneiss in contact with anorthosite has a reaction zone containing the assemblage plagioclase +garnet+clinopyroxene+quartz+rutile+apatite. The garnet forms distinctive coronas around clinopyroxene. The origin of these rocks is discussed in the light of mineral and whole rock chemical analyses and published experimental work.It is thought that under conditions leading up to 750 °C, 8 kb load pressure and 5 kb H2O pressure, partial melting occured in feldspathic hornblende granulites. The melt migrated into extensional fractures and eventually crystallised as anorthosite pegmatites and veins. The gneisses adjacent to the pegmatites from which the melt was extracted changed composition slightly, by the loss of H2O and Na2O, so that plagioclase reacted simultaneously with hornblende, orthopyroxene, and oxide to form garnet, clinopyroxene, quartz and rutile.  相似文献   

15.
Abstract A garnet–hornblende Fe–Mg exchange geothermometer has been calibrated against the garnet–clinopyroxene geothermometer of Ellis & Green (1979) using data on coexisting garnet + hornblende + clinopyroxene in amphibolite and granulite facies metamorphic assemblages. Data for the Fe–Mg exchange reaction between garnet and hornblende have been fitted to the equation. In KD=Δ (XCa,g) where KD is the Fe–Mg distribution coefficient, using a robust regression approach, giving a thermometer of the form: with very satisfactory agreement between garnet–hornblende and garnet–clinopyroxene temperatures. The thermometer is applicable below about 850°C to rocks with Mn-poor garnet and common hornblende of widely varying chemistry metamorphosed at low aO2. Application of the garnet–hornblende geothermometer to Dalradian garnet amphibolites gives temperatures in good agreement with those predicted by pelite petrogenetic grids, ranging from 520°C for the lower garnet zone to 565–610°C for the staurolite to kyanite zones. These results suggest that systematic errors introduced by closure temperature problems in the application of the garnet–clinopyroxene geothermometer to the ‘calibration’data set are not serious. Application to ‘eclogitic’garnet amphibolites suggests that garnet and hornblende seldom attain Fe–Mg exchange equilibrium in these rocks. Quartzo-feldspathic and mafic schists of the Pelona Schist on Sierra Pelona, Southern California, were metamorphosed under high pressure greenschist, epidote–amphibolite and (oligoclase) amphibolite facies beneath the Vincent Thrust at pressures deduced to be 10±1 kbar using the phengite geobarometer, and 8–9kbar using the jadeite content of clinopyroxene in equilibrium with oligoclase and quartz. Application of the garnet–hornblende thermometer gives temperatures ranging from about 480°C at the garnet isograd through 570°C at the oligoclase isograd to a maximum of 620–650°C near the thrust. Inverted thermal gradients beneath the Vincent Thrust were in the range 170 to 250°C per km close to the thrust.  相似文献   

16.
全吉地块中段古元古代早期的德令哈二长花岗片麻岩中发育一个来自围岩的变质镁铁质岩包体。该包体的岩性从核部到边缘依次为角闪斜长辉石岩、斜长角闪岩和石榴石角闪片岩。角闪斜长辉石岩的显微结构指示三个世代的矿物演化,世代Ⅰ为单斜辉石+棕绿色普通角闪石+斜长石+石英+钛铁矿,世代Ⅱ为蓝绿色普通角闪石+斜长石+石榴子石,世代Ⅲ为阳起石+钠长石+黝帘石。世代Ⅰ指示其峰期变质达高角闪岩相条件。角闪斜长辉石岩的锆石全部为浑圆状多晶面晶体,其CL图像具高温变质结晶特征。LA ICPMS技术测定获得上交点U Pb年龄为(1 913±38) Ma(MSWD=015),指示峰期变质发生在古元古代末。研究表明,全吉地块中区域性分布的古元古代早期的二长花岗片麻岩与达肯大坂岩群在响应全球Columbia超大陆汇聚事件中一起发生了区域变质作用。  相似文献   

17.
Abstract The prograde metamorphism of eclogites is typically obscured by chemical equilibration at peak conditions and by partial requilibration during retrograde metamorphism. Eclogites from the Eastern Blue Ridge of North Carolina retain evidence of their prograde path in the form of inclusions preserved in garnet. These eclogites, from the vicinity of Bakersville, North Carolina, USA are primarily comprised of garnet–clinopyroxene–rutile–hornblende–plagioclase–quartz. Quartz, clinopyroxene, hornblende, rutile, epidote, titanite and biotite are found as inclusions in garnet cores. Included hornblende and clinopyroxene are chemically distinct from their matrix counterparts. Thermobarometry of inclusion sets from different garnets record different conditions. Inclusions of clinozoisite, titanite, rutile and quartz (clinozoisite + titanite = grossular + rutile + quartz + H2O) yield pressures (6–10 kbar, 400–600 °C and 8–12 kbar 450–680 °C) at or below the minimum peak conditions from matrix phases (10–13 kbar at 600–800 °C). Inclusions of hornblende, biotite and quartz give higher pressures (13–16 kbar and 630–660 °C). Early matrix pyroxene is partially or fully broken down to a diopside–plagioclase symplectite, and both garnet and pyroxene are rimmed with plagioclase and hornblende. Hypersthene is found as a minor phase in some diopside + plagioclase symplectites, which suggests retrogression through the granulite facies. Two‐pyroxene thermometry of this assemblage gives a temperature of c. 750 °C. Pairing the most Mg‐rich garnet composition with the assemblage plagioclase–diopside–hypersthene–quartz gives pressures of 14–16 kbar at this temperature. The hornblende–plagioclase–garnet rim–quartz assemblage yields 9–12 kbar and 500–550 °C. The combined P–T data show a clockwise loop from the amphibolite to eclogite to granulite facies, all of which are overprinted by a texturally late amphibolite facies assemblage. This loop provides an unusually complete P–T history of an eclogite, recording events during and following subduction and continental collision in the early Palaeozoic.  相似文献   

18.
Retrograde coronas of Caledonian age, between clinopyroxene and plagioclase in the Jotun Nappe Complex, Norway, illustrate the effects of diffusion kinetics on mineral distributions among layers and on the compositions of hornblende-actinolite. One corona type comprises a symplectite of epidote + quartz adjacent to plagioclase, and a less well-organized intergrowth of amphibole + quartz replacing clinopyroxene. The observed mineral proportions imply an open-system reaction, but the similarity of Al/Si ratios in reactant plagioclase and product symplectite indicates approximate conservation of Al2O3 and SiO2. The largest inferred open-system flux is a loss of CaO, mostly derived from consumption of clinopyroxene. The approximate layer structure, Pl|Ep + Qtz|Hbl + Qtz|Act±Hbl + Qtz|Cpx, is modelled using the theory of steady-state diffusion-controlled growth with local equilibrium. To obtain a solution, it is necessary to use a reactant plagioclase composition which takes into account aluminous (epidote) inclusions. The results indicate that, in terms of Onsager diffusion coefficients L ii , Ca is more mobile than AL (L CaCa/L AlAl3.) (where means greater than or approximately equal to). This behaviour of Ca is comparable with that of Mg in previously studied coronas around olivine. Si is non-diffusing in the present modelling, because of silica saturation. Oxidation of some Fe2+ to Fe3+ occurs within the corona. Mg diffuses towards its source (clinopyroxene) to maintain local equilibrium. Other coronas consist of two layers, hornblende adjacent to plagioclase and zoned amphibole + quartz adjacent to clinopyroxene. In the zoned layer, actinolitic hornblende forms relict patches, separated from quartz blebs by more aluminous hornblende. A preliminary steady-state, local-equilibrium model of grain-boundary diffusion explains the formation of low-Al and high-Al layers as due to Al immobility. Zoning and replacement are qualitatively explained in terms of evolution of actinolite to more stable aluminous compositions. This is modelled by a non-steady-state modification of the theory, retaining local equilibrium in grain boundaries while relatively steep zoning profiles develop in grain interiors through slow intracrystalline diffusion. Replacement of actinolite by hornblende does not require a change in PT conditions if actinolite is a kinetically determined, non-equilibrium product. The common preservation of a sharp contact between hornblende and actionolite layers may be explained by ineffectiveness of intracrystalline diffusion: according to the theory, given sufficient grain-boundary Al flux, a metastable actinolite + quartz layer in contact with hornblende may be diffusionally stable and may continue to grow in a steady state.  相似文献   

19.
《Precambrian Research》2001,105(2-4):183-203
Previous studies have shown that the 2.04 Ga Kangâmiut dyke swarm of SW Greenland was injected into an active tectonic environment associated with the formation of the Nagssugtoqidian orogenic belt. Major and trace element modelling of the swarm shows that its chemical evolution was controlled by simple clinopyroxene–plagioclase fractionation. However, such trends — although typical of continental flood basalts and mafic dyke swarms — are at variance with their mineralogy and petrography, which show that locally hornblende is the dominant primary ferromagnesian mineral. Modelling of intradyke fractionation alone shows that hornblende could locally have been an important crystallising phase within several dykes. Normal basaltic fractionation must have occurred before dyke injection at the exposed crustal levels, where the influx of water into the dykes is believed to be responsible for the transition from clinopyroxene–plagioclase (tholeiitic) to hornblende–plagioclase±oxides (calc–alkaline) crystallisation. Overall geochemical trends are dominated by tholeiitic fractionation because (1) hornblende fractionation tended to buffer chemical composition; (2) the presence of water in the surrounding country rocks may have resulted in the advection of heat away from the dyke and consequently resulted in rapid crystallisation, particularly in thin dykes. There is no evidence from trace element data, and particularly Pb isotopic ratios, of any significant assimilation of country rocks occurring during clinopyroxene–plagioclase fractionation, although this does not preclude contamination of the mantle source prior to magma generation. It is likely that the incompatible element enrichment within the dykes resulted from subduction-related mantle metasomatism. The Kangâmiut dyke swarm was both a syn-tectonic and thermal event, which triggered it may be linked to passage of a slab window underneath the metasomatised region, or a mantle plume ascending under a subduction zone.  相似文献   

20.
Calcic amphiboles are ubiquitous in the East Bull Lake anorthosite-gabbro complex, northeastern Ontario. The mode of occurrence suggests the amphiboles replaced clinopyroxene throughout the stratigraphic levels of the pluton, but they are also prolific in the top younger units. Three types of amphiboles, namely (1) tremolite-actinolite, (2) actinolitic hornblende and (3) hornblende, were identified. The composition of the amphiboles shows that they define a continuous series without any obvious compositional-miscibility gap. The analyses further indicated that the amphiboles evolved from actinolite to hornblende through coupled substitution involving edenite and tschermakite end members. Among the three coexisting amphiboles, chlorine is concentrated in hornblende. This is due to preferential location of hornblende along grain boundaries and/or its favourable structure.The compositional variability of amphiboles is controlled by (1) bulk rock composition and (2) faulting and fracturing. The most Fe- and Al-rich hornblendes are confined generally to top units in the gabbro. These units are rich in Si and Fe, but relatively poor in Mg. The Mg-rich tremolite is restricted to a Si-poor, Mg-rich troctolite unit. Amphiboles in gabbro samples from fault zones also contain relatively Mg-rich calcic amphibole. The fault gabbro is highly oxidized.  相似文献   

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