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1.
本文从矿物岩石学、地球化学和沉积盆地分析角度,研究贵州天柱大河边-湖南贡溪两个超大型重晶石矿床中重晶石(矿)岩及其共生岩石的地球化学特征及构造地质背景。天柱-新晃-玉屏寒武纪热水沉积成矿盆地是发育在大陆斜坡上的断陷型热水沉积成矿盆地,由于同生断层作用将盆地切割成一系列次级盆地,大河边-碧林及龙背-铜盆盖三级热水沉积成矿盆地是大型重晶石矿床的构造定位空间。重晶石矿层主要赋存于下寒武统牛蹄塘组第一岩性段的黑色岩系中。 重晶石矿层是由海底低温热水同生沉积作用形成(105-192℃),古热水场的地球化学类型为硫酸盐型热水。硫酸盐型热水发生大规模同生沉积成岩成矿作用形成超大型重晶石矿床,重晶石矿层之上的黑色碳质粘土岩可能形成于封闭、还原、滞流的深水沉积环境,黑色碳质粘土岩构成矿层的封闭保存条件。  相似文献   

2.
贵州镇宁乐纪泥盆系重晶石矿热水沉积特征   总被引:6,自引:0,他引:6  
贵州镇宁乐纪泥盆系重晶石矿床地质储量3 302万t,属大型矿床类型。通过对矿床沉积结构、构造特征研究发现,矿床(体)中分布:纹层状构造、条带状构造、角砾状构造、碎屑状构造、块状构造等,它们与天柱-大河边重晶石矿、广西古潭热水沉积重晶石岩及北秦岭二郎坪群热水沉积重晶石岩类似,海底热水喷流形成的热水喷流通道相、单一热水沉积岩相及热水混合同生沉积相在镇宁重晶石矿层中广泛分布,共同构成了热水浊流沉积相,这与秦岭泥盆系热水沉积岩(矿)类似,矿层沉积结构、构造及岩相特征很好的记录了海底热水喷流、演化的信息,沉积韵律特征说明了热水喷流由弱-强-弱的变化过程。海底热水喷流沉积形成的镇宁重晶石矿中热水沉积结构、构造及热水沉积岩相发育,是研究古热水喷流沉积成岩、成矿、划分热水沉积岩相的理想场所。  相似文献   

3.
重晶石沉积类型丰富,具有多种成因过程。通常,沉积型重晶石可分为生物、热液、成岩和冷泉重晶石四种类型。富钡与富硫酸盐的流体(海水、早成岩孔隙水或热液流体)及其相互作用过程(水柱、热液系统、沉积柱、沉积物-水界面附近)决定了重晶石的沉积环境、宏微观产出方式、同位素组成及相应的地质意义。另外,根据扬子地区下寒武统富重晶石沉积的地质特征,简述了其各种富集机制的适用性及争论。据此建议,结合埃迪卡拉纪-寒武纪转折时期的古海洋背景,对其进行详细的沉积学及地球化学分析,有助于深化成因认识,弥合分歧。  相似文献   

4.
提出秦岭泥盆纪热水沉积岩相,划分了热水沉积岩相的亚相,微相,并总结其特征,按成岩成矿作用方式可划分为热水同生沉积亚相,热水同生交代亚相,热水浊流沉积亚相,热水液压致裂一隐爆亚相,热卤水渗滤交代亚相,热水(岩浆)流体隐爆-液压致裂亚相等6个亚相,沉积盆地分析中,它们是建立热水沉积盆地中地层格架的构造岩石地层单位组成单元,按地球化学动力学-岩石组合可划分为硅质岩亚相,重晶石岩亚相,钠长石岩亚相,铁镁碳酸盐岩亚相,方柱石-黑云母岩亚相,硫化物岩亚相等6个亚相,在热水沉积成矿盆地的地球化学分析与模拟中,它们是建立热水沉积体系及古热水成矿流体场地球化学类型的岩石地球化学地层层序单元及古热水成矿流体场地球化学类型单元。  相似文献   

5.
新晃贡溪超大型重晶石矿床的岩石学特征与沉积成岩作用   总被引:9,自引:0,他引:9  
胡清洁 《湖南地质》1997,16(2):106-111
本文阐述了新晃贡溪矿床沉积型重晶石岩的组构特征和5类重晶石岩,进而讨论了重晶石岩的组构特征与沉积成岩作用的成生联系。  相似文献   

6.
广西热水沉积矿床中重晶石岩地质地球化学特征   总被引:4,自引:0,他引:4  
文章从岩石学和地球化学角度,研究广西热水沉积矿床中重晶石岩的地质地球化学特征。重结晶岩在Al/(Al+Fe+Mn)和Al-Fe-Mn图解上的坐标落在热水沉积区内,为热水沉积形成。区内As、Sb的含量与热水沉积物中As、Sb的含量接近,表现出热水沉积作用的特征。重晶石岩的稀土分配模式具有轻稀土富集,弱的负Ce异常和强正Eu异常特征,为典型的热水沉积物的分布模式。  相似文献   

7.
北秦岭二郎坪群中存在与地层整合产出的层状重晶石岩和铜多金属矿床。重晶石岩贫Al2O3、TiO2组分含量;富集热液组分As、Sb、Ba、Ag和Hg;微量元素U/Th>1;低ΣREE(平均值27.78×10-6)、富集轻稀土(LREE)、亏损重稀土(HREE)、具明显Eu正异常、Ce负异常及与大西洋TAG热液区热液沉积物相似的球粒陨石标准化的稀土元素配分模式特征。这些特征揭示研究区重晶石岩是热水沉积成因型。热水沉积重晶石岩与铜多金属矿床的紧密联系说明,研究区铜金属矿床是海底热液喷流沉积成岩成矿作用的产物。  相似文献   

8.
四川冕宁前寒武纪重晶石岩的地球化学特征   总被引:2,自引:0,他引:2  
倪志耀  莫怀毅 《地球化学》1996,25(5):512-519
四川冕宁前寒武幻尤黑木群含矿重量晶石岩是一种重要的热不沉积岩,稀土总量较低,分配模式为轻稀土富集型,具明显的铕负异常和弱的铈负异常。微量元素比较贫乏,重晶石0636^34S值与海水硫酸盐相似,是在中-低温,弱碱性,具较高氧逸度及较低硫逸度的弱氧化环境下,收快速的热水沉积作用形成。  相似文献   

9.
冕宁前寒武纪沉积岩的铕、铈异常特征及成因解释   总被引:5,自引:0,他引:5  
冕宁尤黑木地区的前寒武纪沉积岩可分为碎屑沉积岩和化学沉积岩两类。前者具明显的负铕异常和不太明显的负铈异常;后者包括重晶石岩和碳酸盐岩,重晶石岩有较明显的负铕异常和负铈异常,碳酸盐岩具明显的负铈异常和不太明显的负铕异常。自碎屑沉积岩经重晶石岩至碳酸盐岩,稀土总量及负铕异常依次降低,负铈异常则明显增大,反映出铕、铈异常的负相关关系。  相似文献   

10.
甘肃成县庙沟—大沙湾铅锌矿区位于西秦岭多金属成矿带西段的西成铅锌矿田内,矿区的铅锌矿化受安家岔组条带状大理岩化灰岩和条带状大理岩的控制,喷流沉积(成岩)作用是成矿的主要因素,为喷流沉积的SEDEX型矿床,同生沉积特征明显,具热水沉积特征,发育有硫化物岩、重晶石岩、硅质岩等。预测靶区为马蹄沟一带近EW向岩相突变带。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

13.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

14.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

15.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

16.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

17.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

18.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

19.
滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.  相似文献   

20.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

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