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1.
Oil refinery wastewater was treated using a coupled treatment process including electrocoagulation (EC) and a fixed film aerobic bioreactor. Different variables were tested to identify the best conditions using this procedure. After EC, the effluent was treated in an aerobic biofilter. EC was capable to remove over 88% of the overall chemical oxygen demand (COD) in the wastewater under the best working conditions (6.5 V, 0.1 M NaCl, 4 electrodes without initial pH adjustment) with total petroleum hydrocarbon (TPH) removal slightly higher than 80%. Aluminum release from the electrodes to the wastewater was found an important factor for the EC efficiency and closely related with several operational factors. Application of EC allowed to increase the biodegradability of the sample from 0.015, rated as non-biodegradable, up to 0.5 widely considered as biodegradable. The effluent was further treated using an aerobic biofilter inoculated with a bacterial consortium including gram positive and gram negative strains and tested for COD and TPH removal from the EC treated effluent during 30 days. Cell count showed the typical bacteria growth starting at day three and increasing up to a maximum after eight days. After day eight, cell growth showed a plateau which agreed with the highest decrease on contaminant concentration. Final TPHs concentration was found about 600 mgL−1 after 30 days whereas COD concentration after biological treatment was as low as 933 mgL−1. The coupled EC-aerobic biofilter was capable to remove up to 98% of the total TPH amount and over 95% of the COD load in the oil refinery wastewater. 相似文献
2.
Gellrt Gligor Tams Szolnoky Milana Dra&#x;kovi&#x; Nenad &#x;uri&#x; Zdravko Hojka Jelena Bo&#x;kovi&#x; Milena
ua 《洁净——土壤、空气、水》2019,47(10)
Anaerobically stabilized sludge from wastewater treatment is always a challenge from the environmental aspect of management. The agrarian environmental surroundings present a possibility for swift and efficient utilization of compost from anaerobically stabilized sludge in order to increase the quality of the biological product. With intensification of the composting procedure by means of the microbiological consortium Geocell‐1 (Cellvibrio sp., Pseudomonas fluorescens with the addition of micro‐ and macro‐elements), the results show that the compost obtained from stabilized sludge after inoculation is significantly improved in terms of moisture reduction (39–43%), while in the control compost, this value is significantly higher with 61%. The results of the pathogenic effect show a significant reduction in the number of fecal coliform (<1 × 103) and Enterococcus bacteria (<1 × 104) in the inoculated (treated) compost. With a slight decrease in the concentration of limiting factors such as As, Cd, Cu, a quality biological product can be achieved, which can be safely deposited on soil. The phytotoxicological germination test with white mustard (Sinapis alba) shows a higher number of sprouting plants with a mixture of treated compost and standard soil for flowers 1:1 and 1:4 compared to the control group. 相似文献
3.
水丰水库亚洲公鱼和大银鱼种群生态的比较研究 总被引：4，自引：0，他引：4
1998年 10月至 2 0 0 0年 11月对水丰水库亚洲公鱼和大银鱼的食性、生长、繁殖、群体结构进行了比较研究 .亚洲公鱼为杂食性鱼类但主要以浮游动物为食 ,繁殖时还摄食同类卵 ,出现频率达 4 2 .9% ,在冬季也摄食大银鱼卵 (2 .8% ) ;体长 (L)、体重 (W)呈异速生长 (W =1.176×10 - 6 L3.5555) ;群体繁殖速度比 1984年以前提高了 4 9.2 % ;群体结构中体长、体重的离散度很小 .大银鱼前期主要以浮游动物为食 ,后期以小鱼小虾为主要食物 ,也捕食公鱼 ,出现频率 6 .9% -9 6 % ;体长、体重呈等速生长 ,W =4 .4 82× 10 - 6 L3.0 0 0 9;群体繁殖速度高出公鱼 1.18倍 ;群体结构中体长、体重的离散度较大 ,表现出了个体间的差异性 相似文献
4.
Recycling domestic wastewaters is one way to maximize the utilization of freshwater. Although sewage treatment plants help to remove particulate wastes, organic matter still remains, which can be used to harvest sizeable populations of zooplankton. In an effort to identify cladocerans which could grow on this organic matter, we tested the life table demography of the commonly found cladocerans (Alona rectangula, Ceriodaphnia dubia, Moina macrocopa, and Daphnia pulex) feeding on wastewater at three different stages of purification (tank that receives crude wastes (A), the biological reactor (B), and the penultimate stage of the treatment process (C)) from the Iztacalco water treatment plant in Mexico City. Experiments were conducted using the medium from each of the 3 tanks previously mentioned and a control of Chlorella vulgaris at 1.0 × 106 cells mL?1. We found that the average lifespan ranged from 5…30 days with D. pulex living the longest. The growth rate, which ranged from ?0.57 to +1.5 was highest for M. macrocopa. Our data indicate that Moina macrocopa, which had higher reproductive rates on wastewater than the controls, was most suited for growing in wastewaters. 相似文献
5.
The population growth of the freshwater chlorophyte, Scenedesmus acutus and the cladoceran Moina macrocopa cultured in the laboratory and in microcosms of a wastewater treatment plant was studied. S. acutus was cultured in a defined algal medium and mixed with wastewater. On diets of S. acutus cultured using Bold medium or a mixture with wastewater, the peak densities of M. macrocopa were 6–7 ind. mL?1, while on a diet of algae cultured on wastewater alone the cladoceran density fluctuated around 2 ind. mL?1. Population growth rates of M. macrocopa, which ranged from 0.3 to 0.4 d?1, were significantly lower on alga cultured in wastewater alone. The body size structure of M. macrocopa was larger on algae cultured in Bold medium than in wastewater. Peak densities of M. macrocopa were around 700 ind. L?1 when the organic matter in the containers was supplemented with algae but it reached lower densities (400 ind. L?1) when cultured on the organic matter in wastewater alone. Our study indicates that the nutrients in the final stages of wastewater treatment can support the growth of both phytoplankton and zooplankton. 相似文献
6.
Ze‐Hua Liu Takeshi Hashimoto Yoichi Okumura Yoshinori Kanjo Satoshi Mizutani 《洁净——土壤、空气、水》2010,38(2):181-188
A solid‐phase extraction (SPE)‐gas chromatography (GC)‐mass spectrometry (MS) analytical method was developed for the simultaneous analysis of natural free estrogens and their conjugates in wastewater samples. Natural free estrogens and their conjugates in wastewater were successfully separated by the oasis hydrophilic‐lipophilic balance solid phase extraction (Oasis HLB SPE) method, and the conjugates were initially enzyme hydrolyzed by β‐glucuronidase or arylsulfatase from Helix pomatia prior to derivatization. N‐methyl‐N‐(tert‐butyldimethylsilyl)trifluoroacetamide (MTBSTFA) plus 1% tert‐butyldimetheylchlorosilane (TBDMCS) was chosen as the derivatization reagent, and the most appropriate conditions of derivatization were determined to be at 95°C for 90 min. The recovery ratios of nine target chemicals were determined by spiking them in 1 L of ultra‐purified water or the influent of a wastewater treatment plant (WWTP). The recovery ratios of six out of nine for the analytes ranged from 73.3–114.9% with relative standard deviations (RSD) from 1.6–19.9%. The established method was successfully applied to environmental wastewater samples which were collected from one municipal wastewater treatment plant (WWTP) in Osaka, Japan, for the determination of natural free estrogens and their conjugates. In the influent sample, E1, E2, E1‐3S, E3‐3S, and E1‐3G were detected at concentrations of 16.6, 9.6, 8.2, 21.9, and 3.2 ng L–1, respectively. However, only E1 was detected at a high concentration of 44 ng L–1 in the effluent sample, suggesting that it is the dominant natural free estrogen in the effluent. 相似文献
7.
Growing Spirodela polyrrhiza in Swine Wastewater for the Production of Animal Feed and Fuel Ethanol: A Pilot Study 总被引：1，自引：0，他引：1
To evaluate the performance of Spirodela polyrrhiza grown in swine wastewater for protein and starch production under field conditions, a pilot‐scale duckweed culture pond was installed at Barham Farm, Zebulon, North Carolina and operated from May to November 2010. The anaerobically treated swine wastewater was fed to the duckweed pond intermittently to provide nutrients for the growth of duckweed, and the duckweed biomass was harvested regularly from the pond and prepared as a protein‐ or starch‐rich feedstock for the production of animal feed or fuel ethanol. Over the experimental period, the duckweed pond produced protein and starch at rates of 2.68 and 1.88 g m?2 day?1, respectively. During the same time, NH4–N and o‐PO4–P in the wastewater were, respectively, removed at rates of 92.9 and 2.90 mmol m?2 day?1. 相似文献
8.
《Marine pollution bulletin》2014,78(1-2):235-245
The major aim of this study was to investigate heavy metal content of edible fish in the PRD. Eleven species of fish (consisting of 711 individuals) [catfish (Clarias fuscus), tilapia (Oreochromis mossambicus), grass carp (Ctenopharyngodon idellus), bighead carp (Aristichthys nobilis), mandarin fish (Siniperca kneri), snakehead (Channa asiatiea), black bass (Micropterus salmoides), mangrove snapper (Lutjanus griseus), star snapper (Lutjanu stellatus), snubnose pompano (Trachinotus blochii) and orange-spotted grouper (Epinephelus coioides)] were collected for the analyses of heavy metals. Overall concentrations (mg/kg, ww) in the fish muscles were: As (0.03–1.53), Pb (0.03–8.62), Cd (0.02–0.06), Ni (0.44–9.75), Zn (15.7–29.5), Cr (0.22–0.65), Cu (0.79–2.26), Mn (0.82–6.91). Significant level of Pb were found in tilapia at all locations. It is recommended that heavy metal concentrations in different fish species must be determined on a regular basis in the future so as to reduce human health risks from acute and chronic food intoxication. 相似文献
9.
白龟山水库银鱼移植试验 总被引：5，自引：3，他引：2
1987年一次性向白龟山水库投放太湖新银鱼有效受精卵21×10~4粒,后形成强大种群生产力,1991～1993年累计生产银鱼190t,创经济效益500余万人民币。太湖新银鱼具有生命周期不长、食物链较短、适应环境能力较强、容易捕捞等优点,是“填补”移植驯化的理想对象。白龟山水库生态系中鱼类区系组成不够饱和,存有空闲小生境,饵料竞争比较缓和,敌害压力较小,是移植驯化银鱼的适宜水体。白龟山水库银鱼食性组成中以桡足类和枝角类为主;分布遍及全库,尤以上、中游水草区为最多。1991年全库银鱼相对资源蕴藏量为108920kg,即1.56×10~(?)尾。1991年约有29.5％的浮游动物被银鱼利用转化成为银鱼产品,生物学效益较高。综合考虑银鱼的繁殖和生长,在现有捕捞强度下,捕捞生产宜安排在11月～翌年2月为宜。 相似文献
10.
11.
S. Gupta 《洁净——土壤、空气、水》1988,16(2):189-195
Fish, Cyprinus carpio and Channa punctatus in four sizes (6.0 ± 1.2; 12.5 ± 1.6; 20.6 ± 1.5 and 28.0 ± 1.8 cm in total length) were exposed to industrial effluents from the Sangam Dyeing Factory (Ludhiana), the Sterling Steel and ABC Paper Mills (Hoshiarpur) to evaluate the acute toxicity of these effluents at different fish sizes. Results reveal that the toxicity of industrial effluents decreased with the increased fish size from 6.0 ± 1.2 to 20.6 ± 1.5 cm in length. However, for specimens of the size of 28.0 ± 1.6 cm and more, the toxicity of the effluents increased with an increase in fish size. On the basis of the relative toxicity to fish, effluent from the Sterling Steel Mill was found to be highly toxic to fish and effluent from the Dyeing Factory least toxic except for the fish of 6.0 ± 1.2 cm at which dyeing factory effluent was most toxic and ABC paper mill effluent the least toxic. 相似文献
12.
三峡水库调度运行改变了库区江段的水文情势,影响漂流性卵苗在库区江段内的时空分布特征。在水库低水位运行时,具有流水生境特征的库中和库尾江段是产漂流性卵鱼类在整个三峡库区内重要的产卵江段。了解三峡库中和库尾江段产漂流性卵鱼类的早期资源状况及其对水文和水温特征的响应关系,对于采取适宜的保护措施促进鱼类早期资源的恢复具有重要的意义。本文通过2017—2020年5—7月在库中涪陵断面进行的逐日早期资源监测,了解三峡库中和库尾江段产漂流性卵鱼类早期资源的种类组成、产卵规模、产卵场分布及其年际变动特征,并采用随机森林(RF)模型,分析鱼类逐日产卵规模变动与水文、水温格局及其过程的关系,辨识影响不同种类产卵规模变动的关键水文及水温要素。结果表明:2017—2020年共采集到漂流性鱼卵21种,包括长江上游特有鱼类鱼卵3种;以圆筒吻鮈Rhinagobio cylindricus、蒙古鲌Chanodichthys mongolicus、贝氏(?)Hemiculter bleekeri等6种鱼类的鱼卵为主,占总采集鱼卵数的88.76%;各年的鱼卵规模分别为83.04×108、14.29×... 相似文献
13.
One of the critical technological parameter in operation of aerated submerged fixed‐bed biofilm reactor (ASFBBR) is the control over process of biofilm detachment. Both, an excessive growth of biomass with its accumulation in the bioreactor and an exceeded biofilm detachment rate, cause serious operational and technological problems. The studies presented in this paper demonstrate that in an ASFBBR reactor with a PVC bed carrier media, an effective way to maintain a proper shear stress acting on the biofilm and causing its detachment could be an internal recirculation of wastewater instead of backwashing with wastewater or air flushing. In case of polishing of oil‐refinery wastewater with average COD loading rate equal to 9 g COD/(m2 day), the minimum value of the hydraulic loading rate in such reactor is 1.9 m3/(m2 h), at which there was no excessive growth of biofilms. Despite a significant decrease of the biofilms thickness and amount of biomass in the reactor, there was no significant decline in the efficiency of pollutant removal from oil‐refinery wastewater, which made it possible to obtain the quality of effluent at the outlet of the bioreactor significantly below the water permits and standards. 相似文献
14.
Natural estrogens from humans increasingly attract attention because of their strong endocrine disrupting potency. The discharge of sewage water is considered as the most important source of these endocrine disrupting chemicals (EDCs) in the environment. Therefore, a GC‐MS method was developed for the simultaneous analysis of six natural free estrogens and their sulfate conjugates in municipal wastewater, in which natural free estrogens and sulfate conjugates were successfully separated from an Oasis HLB solid phase extraction (SPE) cartridge with two different eluents, and the sulfate conjugates were then transformed to their corresponding free estrogens by acid solvolysis. Before the analysis with GC‐MS, samples were derivatized by N,O‐bis (trimethylsilyl) trifluoroacetamide (BSTFA) plus 1% trimethylchlorosilane (TMCS) at 80°C for 40 min. Satisfactory recoveries ranging from 64 to 112.3% were obtained by spiking ultra‐purified water, raw, and treated municipal wastewater with the six estrogens at 50, 100, and 50 ng/L, respectively. The method was successfully applied to wastewater samples from one WWTP, which suggested that E1 was the dominant natural estrogens in effluent and E3‐3S was one of the conjugates possibly occurring in the effluent. 相似文献
15.
Luciane Minetto Francieli M. Mayer Carlos A. Mallmann Ayrton F. Martins 《洁净——土壤、空气、水》2012,40(9):950-957
In this study the occurrence of diclofenac and sub‐products in effluent emerging from the University Hospital at the Federal University of Santa Maria was investigated. One metabolite was identified and, in aqueous solution, three degradation products. The quantification was conducted by means of HPLC‐DAD, and the determination of metabolite and degradation products by LC–ESI–MS/MS–QTrap. For the HPLC‐DAD method, a 70:30 mixture of methanol/sodium phosphate was used in isocratic mode. For the LC–ESI–MS/MS–QTrap determinations, a mobile phase, where phase A was an ammonium acetate solution 5 × 10?3 mol L?1, and phase B was methanol (5 × 10?3 mol L?1)/ammonium acetate (9:1, v/v), on gradient mode. The LDs for the HPLC and LC–MS/MS methods, respectively, were 2.5 and 0.02 µg L?1, the LQs, 8.3 and 0.05 µg L?1, and the linear range from 10 up to 2000 µg L?1 and 0.05 up to 10 µg L?1. As expected, the LC–ESI–MS/MS–QTrap method was more sensitive and less laborious. The metabolite 4′‐hydroxy‐diclofenac was identified. Photolysis was used for the degradation studies and three products of diclofenac were identified (m/z of 214, 286 and 303) in aqueous solution. These results notwithstanding, no degradation products of diclofenac were found in the hospital effluent. 相似文献
16.
&#x;pek elen‐Erdem 《洁净——土壤、空气、水》2020,48(3)
The aim of this study is to evaluate the feasibility of sludge digester effluent as feeding solution to enrich anaerobic ammonium oxidation (anammox) bacteria. The performance of the two parallel pilot scale‐upflow packed bed anammox reactors (UPBAn1 and UPBAn2) are examined in terms of the enrichment of anammox bacteria. The control experiment is set up conducting synthetic wastewater as feeding solution in the UPBAn1 reactor whereas, the sludge digester effluent is fed to the nitritation reactor and then the partially nitrated digester effluent to the UPBAn2 reactor. Anammox activities are evaluated by mass balances based on ammonium (NH4+), nitrite (NO2?), and nitrate (NO3?) analysis and NRR. Microbial community of anammox bacteria is analyzed using real‐time polymerase chain reaction (PCR). The results demonstrate that UPBAn 1 and UPBAn2 reactors are successfully enriched on days 64 and 40 with NRRs of 19.54 and 19.43 g N m?3 per day, respectively. This study reveals that both synthetic wastewater and digester effluent are suitable for the enrichment of anammox bacteria; however, digester effluent as feeding solution for enrichment of anammox bacteria based on the ease of process control and process stability is more advisable. 相似文献
17.
We investigated trophic transfer efficiency in the pelagic food chain of deep, oligotrophic Lake Stechlin (Germany) by analyses of the primary, secondary, and fish production. Primary production between April and November 2000 was estimated at 78 g C m−2, pelagic secondary production at 14 g C m−2, and production of the main planktivorous fish species [European cisco, Coregonus albula (L.)] at 0.77 g C m−2. Thus, trophic transfer efficiency between primary and pelagic secondary production was around 18%, whereas between pelagic and fish production around 6%. The high efficiency at the first step of the chain is discussed to be due to the high food quality in oligotrophic lakes due to the dominance of Bacillariophyceae and Chlorophyceae rich in essential fatty acids. In turn, the relatively low trophic transfer efficiency between the secondary and the fish production is mainly explained by the avoidance of calanoid copepods as food source by the ciscoes. Concerning the trophic transfer efficiency, results from this study support the general assumption of a 10% transfer between neighbouring trophic levels within ecosystems. 相似文献
18.
对湖北省阳新县网湖所采得的862尾似刺鳊鮈的年龄与生长的研究表明,其年轮特征主要为切割型和碎裂型。其体长与鳞径呈直线相关:L=5.6784+4.3056R;体长与体重呈幂函数的增长关系:W=2.8026×10~(-2)L~(2.8754)。应用Van Bertalanffy生长方程拟合该鱼的一般生长规律,其生长参数为:L_∞=25.0143cm,W_∞=277.8876g,K=0.4668,t_0=-1.3886,拐点年龄t_i=1龄,拐点体长L_i=16.42cm,拐点体重W_i=82.82g。 相似文献
19.
20.
To remove chromate from a wastewater, a porous permeable reactive barrier system (PRBS), using pyrite and biotite, was adapted. This study included bench‐scale column experiments to evaluate the efficiency of the PRBS and investigate the reaction process. The total chromium concentration of the effluent from the biotite and pyrite columns reached the influent concentration of 0·10 mM after passing through more than 150 pore volumes (PVs) and 27 PVs respectively, and remained constant thereafter. The CrVI concentration in the effluent from the biotite column became constant at about 0·08 mM , accounting for approximately 80% of the influent concentration, after passing through 200 PVs. Moreover, in the pyrite column, the CrVI concentration remained at about 0·01 mM , 10% of the input level, after passing through 116 PVs. This shows that both columns maintained their levels of chromate reduction once the CrVI breakthrough curves (BTCs) had reached the steady state, though the steady‐state output concentration of total chromium had reached the influent level. The variances of the iron concentration closely followed those of the chromium. The observed data for both columns were fitted to the predicted BTCs calculated by CXTFIT, a program for estimating the solute transport parameters from experimental data. The degradation coefficient µ of the total chromium BTCs for both columns was zero, suggesting the mechanisms for the removal of chromate limit the µ of the CrVI BTCs. The CrVI degradation of the pyrite column (6·60) was much greater than that of the biotite column (0·27). In addition, the CrVI retardation coefficient R of the pyrite column (253) was also larger than that of the biotite column (125). The R values for the total chromium BTCs from both columns were smaller than those of the CrVI BTC. Whereas the total chromium BTC for the pyrite column showed little retardation (1·5), the biotite column showed considerable retardation (80). The results for the 900 °C heat‐treated biotite column were analogous to those of the control column (quartz sand). This suggests that the heat‐treated biotite played no role in the retardation and removal of hexavalent chromium. The parameters of the heat‐treated biotite were calculated to an R of 1·2 and µ of 0·01, and these values confirmed quantitatively that the heated biotite had little effect on the transport of CrVI. These solute transport parameters, calculated by CXTFIT from the data obtained from the column tests, can provide quantitative information for the evaluation of bench‐ or field‐scale columns as a removal technology for CrVI in wastewater or contaminated groundwater. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献